Petroleum CRMs and reference standards 2015/2016

Transcription

1 Petroleum CRMs and reference standards 2015/2016 Wear metal standards Used oil analysis Prof icien cy tes tin g B io di es el P hys ical tes t standard s S ulf u r, ni tr o ge n, ch lor ine Ma trix oils & solvents Metallo-organic standards LGC Quality - ISO Guide 34 GMP/GLP ISO 9001 ISO/IEC ISO/IEC Petroleum-Cover-d5.indd 1 11/9/ :50:04 AM

2 Welcome to the LGC catalogue of petroleum Certifed Reference Materials (CRMs) The frst section of the catalogue details the extensive VHG Labs line of analytical reference standards for both new and used oil applications. Our petroleum standards may be used for analysis by ICP, ICP-MS, AA, XRF, RDE, UVF, physical testing instruments and other used oil analysis instruments. We have been manufacturing single and multi-element standards (both sulfonate-based and sulfur-free versions) for more than 30 years. We manufacture an equally extensive line of single and multi-element inorganic aqueous standards. The second section of this catalogue gives an overview of other CRMs which LGC offers. Most norms expect to complete development of an application (calibration) by analyzing a CRM as an unknown sample to validate or verify the analytical procedure. We can offer some standards with full analysis, including C, H and N, especially for XRF and its fundamental parameter mathematics. Our commitment to quality VHG brand petroleum standards are subjected to rigorous Quality Assurance checks prior to shipment. Raw materials are assayed and analyzed for trace impurities. Major constituents are generally verifed both instrumentally, against the appropriate NIST SRM (when available), and through classical wet chemical methods (titrimetry or gravimetry). Our standards are blended in pre-cleaned HDPE or glass reactors. Balances and volumetric flasks are calibrated according to NIST procedures. All VHG standards are accompanied by a comprehensive Certifcate of Analysis (COA). Each COA is supported by an unbroken chain of comparisons with traceability to national or international standards of measurement. Our manufacturing facility is registered to ISO 9001 and accredited to ISO Guide 34. Each product must pass rigorous Quality Control in our ISO/IEC laboratory and is shipped with a comprehensive Certifcate of Analysis (COA) with actual (not nominal) concentrations. Our profciency testing program for oil analysis is ISO/IEC accredited. Thank you to all of our customers. We look forward to supporting your continued success. The LGC team

3 About LGC LGC is a leading global producer and distributor of reference materials and profciency testing schemes. Headquartered in Teddington, Middlesex, UK, LGC has a network of dedicated sales offces extending across 20 countries in 5 continents. We have an unparalleled breadth of ISO Guide 34 accredited reference material production in facilities at 4 sites across the UK, US and Germany. In addition to our petroleum product line, we manufacture CRMs and reference materials for the following sectors: pharmaceutical, forensic, clinical, food, beverage, environmental, pesticides and contaminants sectors. We provide profciency testing schemes in support of these sectors, as well as others, to more than 10,000 laboratories worldwide. About our Webshop An up-to-date listing of all products is available on the LGC website:. Once registered, you can use the website to order products, check delivery times and access a range of resources for a wide variety of sectors. LGC technical staff are available to advise on the use and suitability of a particular product. Customers requiring assistance with the use or application of a particular reference material should contact their local offce. Contact details for your local sales offce are available at the back of this catalogue and on our website. About LGC LGC is an international life sciences measurement and testing company, building leading positions in sustainably growing markets. We provide reference materials, genomics solutions and analytical testing products and services, based on our innovations and own intellectual property. We work with customers in the pharmaceuticals, agricultural, biotechnology, food, environment, security and sports sectors, as well as, with governments and academia to achieve excellence in investigative, diagnostic and measurement science. For more information, please visit our website: Prices for the products listed, as well as detailed procedures and transport charges are available from your local sales offce, where applicable. For products requiring special delivery procedures (dangerous goods, etc.), additional charges may be applied.

4 OIL PT Oils and fuels proficiency scheme #2 Diesel fuel Crude oil Engine oil lubricants Simulated in service engine oil LGC is an accredited international provider of proficiency testing (PT) schemes. With more than 30 years of experience, we run more than 1600 PT exercises each year for more than 10,000 laboratories worldwide. Available online Science for a safer world LGC Quality - ISO 9001 LGC Limited, All rights reserved. LGC is part of the LGC Group. 4436/CB/0815

5 Table of contents Petroleum for ICP, RDE and XRF... 2 Wear Metal... 2 Internal... 2 Metal Additives... 3 Matrix Oils and Solvents... 3 V-Solv TM... 4 Stabilizer for Wear Metal... 4 Single-Element Metallo-Organic... 5 D-Series Multi-Element Wear Metal... 6 for Used Oil Analysis... 7 Acid Number and Base Number... 7 Soot Content... 7 Fuel Dilution... 8 Glycol in Oil... 8 Multi-Element Coolant... 8 Crackle Test Reference... 9 Karl Fischer Titration Certified Reference... 9 Reference Gas Oil... 9 Distillation... 9 Proficiency Testing Program for S, N, Cl, and Metals Single-Element, Sulfur-Free Metallo-Organic Metallo-Organic Concentrates Wear Metal for XRF for Sulfur & Metals in Crude and Residual Oils Lube Oil for Sulfur in Diesel Fuel Analysis Sulfur in Kerosene Sulfur in Isooctane Sulfur in Crude and Residual Oil Matrix Oils and Solvents Polysulfide Oil Sulfur in Petroleum Products (Ampoules) Sulfur & Nitrogen Products (Ampoules) Chlorine in Oil for Lead in Gasoline Internal for XRF Analysis Petroleum Physical Test Flash Point Reference Materials Viscosity Reference Pour Point, Cloud Point, and Freezing Point Reference Materials Cold Filter Plug Point Reference Materials Biodiesel Metals in Biodiesel Sulfur in Biodiesel Biodiesel/Diesel Fuel Blends... 23

6 CRMs to Verify Analytical Procedures Diesel CRMs CRMs for Bio-Diesel CRMs for Gasoline / Gasoil / Kerosene Lube Oil CRMs / Lubricants CRMs for Residual Oil / Bunker Crude Oil CRMs Waste Oil CRMs with given C-H-N-composition Other petrochemical CRMs Reference documents Conversion Tables for Reference Wear Metal Set (VHG-WRMTLSET-17X50G) Addendum... 37

7 VHG Petroleum products LGC Quality - ISO Guide 34 GMP/GLP ISO 9001 ISO/IEC ISO/IEC Petroleum-Cover-d5.indd 4 11/9/ :50:09 AM

8 VHG Tips Section 1 Petroleum Metallo-organic standards should be kept away from moisture. Preferably store in a cool, dry location. We welcome inquiries into custom metallo-organic standards. Contact your local sales office for assistance. See back cover for list of locations. Wear metal standards For ICP, RDE, XRF and other techniques u We manufacture the highest quality metallo-organic mixes in the industry in our ISO 9001 and ISO Guide 34 facility. Customers are assured of getting the best value and consistency available. u Each product must pass rigorous Quality Control in our ISO/IEC laboratory. u Each product is accompanied by a comprehensive Certificate of Analysis with actual (not nominal) concentrations. V21 Wear Metal V21+K Wear Meta l V23 Wear Metal Ag, Al, B, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, All of the elements included All of the elements included Mo, Na, Ni, P, Pb, Si, Sn, Ti, V, Zn in V21 plus K in V21 plus K and Sb combined in hydrocarbon oil Conc.* Size Product No. Product No. Product No. (µg/g) (grams) VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G VHG-V G VHG-V21+K G VHG-V G 200 VHG-V G VHG-V21+K G VHG-V G * For catalogue purposes, nominal concentrations (µg/g) are provided. Internal For Wear Metal Analysis by ICP The use of an internal standard, such as Ce, Co or Y, can significantly improve the accuracy of your results by correcting for wide variations in the viscosity or oil composition of your samples. Internal standards are easy to use when added to the diluent prior to sample preparation. Element Matrix Concentration Size Product No. (grams) Cerium (Ce) Hydrocarbon Oil 5000µg/g 200 VHG-OCE G Cobalt (Co) Mineral Spirits 6 wt. % 100 VHG-OCO-6PIS-100G Cobalt (Co) Mineral Spirits 6 wt. % 200 VHG-OCO-6PIS-200G Cobalt (Co) Mineral Spirits 6 wt. % 400 VHG-OCO-6PIS-400G Cobalt (Co) Hydrocarbon Oil 5000µg/g 200 VHG-OCODN G Cobalt (Co) Hydrocarbon Oil 5000µg/g 800 VHG-OCODN G Lanthanum (La) Hydrocarbon Oil 5000µg/g 200 VHG-OLA G Yttrium (Y) Hydrocarbon Oil 5000µg/g 400 VHG-OY-5000-A-400G Yttrium (Y) Hydrocarbon Oil 2 wt. % 100 VHG-OYDN-2P-100G Yttrium (Y) Hydrocarbon Oil 2 wt. % 200 VHG-OYDN-2P-200G 2

9 Metal additives standards For ICP, RDE, XRF and other techniques Metal Additives Standard MA3 5000µg/g; P, 1600µg/g combined in hydrocarbon oil* Size (grams) Product No. 100 VHG-MA3-100G 200 VHG-MA3-200G Metal Additives Standard MA4 5000µg/g; Mg, P, 1600µg/g combined in hydrocarbon oil* Size (grams) Product No. 100 VHG-MA4-100G 200 VHG-MA4-200G Metal Additives Standard MA5 Ba, Ca, Mg, P, Zn combined in hydrocarbon oil Conc.* Size Product No. (µg/g) (grams) VHG-MA G 200 VHG-MA G VHG-MA G 200 VHG-MA G VHG-MA G 200 VHG-MA G VHG-MA G 200 VHG-MA G * For catalogue purposes, nominal concentrations (µg/g) are provided Section 1 Petroleum ICP, RDE, and XRF Wear Metals Metal Additives V-Solv Single Elements D Series for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Petroleum Physical Test Biodiesel Metal Additives Standard MA6 B, Ba, Ca, Mg, P, Zn combined in hydrocarbon oil Conc.* Size Product No. (µg/g) (grams) VHG-MA G 200 VHG-MA G * For catalogue purposes, nominal concentrations (µg/g) are provided Matrix Oils and Solvents Solvents for the Preparation of Working for Hydrocarbon/Petrochemical Analysis High-purity solvents supplied with a Certificate of Analysis that includes trace metal concentrations. Item Volume Product No. 75 cst Hydrocarbon Oil 500mL VHG-OIL Gal. VHG-OIL-75-1GAL 20 cst Hydrocarbon Oil 500mL VHG-OIL Gal. VHG-OIL-20-1GAL V-SOLV ICP Solvent 1 Gal. VHG-V-SOLV-1GAL 5 Gal. VHG-V-SOLV-5GAL Kerosene, low odor 500mL VHG-KERO Gal. VHG-KERO-1GAL 3

10 VHG Tips Section 1 Petroleum The use of stabilizer is particularly important for long-term stability when diluting these standards in solvents. V-Solv ICP Solvent V-Solv ICP Solvent is a proprietary solvent that is used for diluting oil and other organic liquids for analysis by ICP and ICP-MS. Use V-Solv as a matrix blank and as a diluent for your calibration standards and samples for outstanding nebulization characteristics. V-Solv ICP Solvent offers the following advantages over conventional low odor/odorless kerosene, xylene and other commercial solvents: u Very high purity (essentially no trace metals or sulfur) - each bottle is accompanied by a COA that states the trace impurity levels of 36 metals and sulfur. u Makes very stable dilutions of metallo-organic standards and oil samples. u Extremely low odor (no kerosene or aromatic smell), which results in a comfortable work environment and is also VOC-exempt for consumer products applications (EPA Title 40, Volume 5, Parts 53-59). u Extremely low toxicity compared with kerosene or xylene. u Very competitively priced and non-hazardous to ship (flashpoint of 260 F). u One gallon bottle size for ease of use and for shipment via common carrier. ICP Solvent for the Preparation of Working for Hydrocarbon/Petrochemical Analysis High-purity solvents supplied with a Certificate of Analysis that includes trace metal concentrations. Item Volume Product No. V-SOLV ICP Solvent 1 Gal. VHG-V-SOLV-1GAL V-SOLV ICP Solvent 5 Gal. VHG-V-SOLV-5GAL Stabilizer for Wear Metal Stabilizer to Improve Stability of Mixes or Dilutions Solvent stabilizer can improve stability of mixes or dilutions of VHG s 1000µg/g and 5000µg/g stock metallo-organic standards, as well as multi-element mixes after dilution in solvent. Product Product Use Product No. Size (grams) MO Stabilizer VHG s wear metal VHG-STAB-50G 50 standards. Add to solutions at 0.6wt% 4

11 Single-Element Metallo-Organic For ICP, RDE and Other Techniques u Metallo-organic compounds* in hydrocarbon oil u Accuracy ensured by Quality Testing with NIST Standard Reference Materials when available u Certificate of Analysis supplied with each standard u Certificate of Analysis includes trace metal concentrations confirmed with ICP-AES scans u Stocked for prompt shipment Single-Element in Concentration Concentration Concentration Hydrocarbon oil (1000µg/g) (2000µg/g) (5000µg/g) Element Product No Product No. Aluminum AI VHG-OAL G VHG-OAL G Antimony Sb VHG-OSB G VHG-OSB G Arsenic As VHG-OAS G N/A Barium Ba VHG-OBA G VHG-OBA G Beryllium Be VHG-OBE G Inquire Bismuth Bi VHG-OBI G Inquire Boron B VHG-OB G VHG-OB G Cadmium Cd VHG-OCD G VHG-OCD G Calcium Ca VHG-OCA G VHG-OCA G Cerium Ce VHG-OCE G VHG-OCE G Chromium Cr VHG-OCR-1000-A-50G VHG-OCR-5000-A-50G Cobalt Co VHG-OCO-1000-A-50G VHG-OCODN G Copper Cu VHG-OCU-1000-A-50G VHG-OCU-5000-A-50G Indium In Inquire Inquire Iron Fe VHG-OFE G VHG-OFE G Lanthanum La VHG-OLA G VHG-OLA G Lead Pb VHG-OPB G VHG-OPB G Lithium Li VHG-OLI G VHG-OLI G Magnesium Mg VHG-OMG G VHG-OMG G Manganese Mn VHG-OMN G VHG-OMN G Mercury Hg VHG-OHG G N/A Molybdenum Mo VHG-OMO G VHG-OMO G Nickel Ni VHG-ONI G VHG-ONI G Phosphorus P VHG-OP G VHG-OP G Potassium K VHG-OK G VHG-OK G Scandium Sc VHG-OSC G VHG-OSC G N/A Selenium Se VHG-OSE G VHG-OSE G Silicon Si VHG-OSI G VHG-OSI G Silver Ag VHG-OAG G VHG-OAG G Sodium Na VHG-ONA G VHG-ONA G Strontium Sr VHG-OSR G Inquire Sulfur S VHG-OS G VHG-OS G Thallium Tl VHG-OTL G N/A Tin Sn VHG-OSN G VHG-OSN G Titanium Ti VHG-OTI G VHG-OTI G Tungsten W VHG-OW G VHG-OW G Vanadium V VHG-OV G VHG-OV G Yttrium Y VHG-OY-1000-A-50G VHG-OY-5000-A-50G Zinc Zn VHG-OZN G VHG-OZN G Zirconium Zr VHG-OZR G VHG-OZR G Section 1 Petroleum ICP, RDE, and XRF Wear Metals Metal Additives V-Solv Single Elements D Series for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Petroleum Physical Test Biodiesel * Many of these compounds are sulfonate-based, and thus, contain high levels of sulfur. If absence of sulfur is important for your application, please use VHG s line of sulfur-free standards on Page 11. 5

12 Section 1 Petroleum D-Series Multi-Element Wear Metal For Military Applications Using RDE u We have supplied single-element concentrated standards to the Joint Oil Analysis Program - Technical Support Center (JOAP-TSC) for making D-Series standards (D3, D12, D19) for almost a decade. Now D-Series standards are available directly from VHG. u Our D-Series standards are made in our ISO 9001 and ISO Guide 34 facility. u Each product must pass rigorous quality control in our ISO/IEC laboratory. u Each standard is accompanied by a comprehensive Certificate of Analysis. u Each D-Series standard standard is supplied with a convenient squirt cap. D3 B, Mo, Zn in Aviation Reference Oil Conc. Size Product (µg/g) (ml) No VHG VHG D12 Ag, Al, Cr, Cu, Fe, Mg, Na, Ni, Pb, Si, Sn, Ti in Aviation Reference Oil Conc. Size Product (µg/g) (ml) No VHG VHG VHG VHG VHG VHG VHG D19 Ag, Al, B, Ba, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Na, Ni, Pb, Si, Sn, Ti, V, Zn in Aviation Reference Oil Conc. Size Product (µg/g) No mL VHG g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G g VHG-D G KIT* Various VHG * includes 2x , 1xD G, 1xD G, 1xD G, 1xD G, 1xD G, 2xD G, 1xD G, 1xD G, 1xD G, 1xD G, and 1xD G. Special sizes, concentrations, and blends available upon request. 6

13 Acid Number and Base Number Acid Number (AN) Reference Materials VHG Labs AN Reference materials are intended for use in the determination of Acid Number (AN) in petroleum products in accordance with ASTM D664/IP 177 (by potentiometric titration) or ASTM D974 (by color-indicator titration). Each standard is supplied with a full Certificate of Analysis (COA) which states the certified values and uncertainty by both ASTM D664 and D974. Matrix Nominal Value Size Product No. (mg KOH/g)* (grams) Hydrocarbon Oil VHG-AN G Hydrocarbon Oil VHG-AN G Hydrocarbon Oil VHG-AN-1-100G Hydrocarbon Oil VHG-AN G Hydrocarbon Oil VHG-AN-2-50G Hydrocarbon Oil VHG-AN-3-50G *Acid number is defined as the quantity of base, expressed as milligrams (mg) of potassium hydroxide (KOH) per gram of sample, required to titrate a sample in a specific solvent to a specified end point. Base Number (BN) Reference Materials VHG Labs BN Reference Materials are intended for use in the determination of Base Number (BN) in petroleum products in accordance with ASTM D2896/IP 276 (by potentiometric perchloric acid titration) or ASTM D4739 (by potentiometric titration). Each standard is supplied with a full Certificate of Analysis (COA) which states the certified values and uncertainty by both ASTM D2896 and D4739. Matrix Nominal Value Size Product No. (mg KOH/g)* (grams) Hydrocarbon Oil 6 50 VHG-BN-6-50G Hydrocarbon Oil VHG-BN-10-50G Hydrocarbon Oil VHG-BN-15-50G Hydrocarbon Oil VHG-BN-30-50G Hydrocarbon Oil VHG-BN-40-50G Hydrocarbon Oil VHG-BN-70-50G *Base number is defined as the quantity of acid, expressed as milligrams (mg) of potassium hydroxide (KOH) per gram of sample, required to titrate a sample in a specified solvent to a specified end point. Section 1 Petroleum ICP, RDE, and XRF Wear Metals Metal Additives V-Solv Single Elements D Series for Used Oils AN & BN Fuel Dilution Coolant in Oil Soot Crackle Karl Fischer Distillation Performance Testing Program for S, N, Cl and Metals Petroleum Physical Test Biodiesel Soot Content Reference standards for use in the determination of soot content in 15W40 diesel motor oil by infrared spectroscopy or other techniques. All values certified by thermogravimetric analysis (TGA). Nominal Soot Content Range (%) Volume (ml) Product No. Blank 50 VHG-SOOT-BLK VHG-SOOT-A VHG-SOOT-B VHG-SOOT-C VHG-SOOT-D VHG-SOOT-E-50 Set of all 6 6 x 50 VHG-SOOT-SET 7

14 VHG Tips Section 1 Petroleum Fuels for the fuel dilution standards are devolatilized by removing 10% of the lights using a rotovap. Fuel Dilution Fuel Dilution These standards are intended for use in the determination of fuel (diesel fuel or gasoline) in used engine oils by GC, IR, fuel dilution meter (fuel sniffer), or flash point analyzer. They are prepared gravimetrically from well-characterized fuels and hydrocarbon oils, and are verified by GC-FID in accordance with ASTM Method D3524 or D3525. Volume: 100mL Description Product No. Blank for Diesel Fuel Dilution VHG-DSLFD-BLK-100 2% (v/v) Devolatilized Diesel Fuel in hydrocarbon oil VHG-DSLFD-2P-100 5% (v/v) Devolatilized Diesel Fuel in hydrocarbon oil VHG-DSLFD-5P % (v/v) Devolatilized Diesel Fuel in hydrocarbon oil VHG-DSLFD-10P-100 Blank for Gas Fuel Dilution VHG-GASFD-BLK-100 2% (v/v) Devolatilized Gasoline in hydrocarbon oil VHG-GASFD-2P-100 5% (v/v) Devolatilized Gasoline in hydrocarbon oil VHG-GASFD-5P % (v/v) Devolatilized Gasoline in hydrocarbon oil VHG-GASFD-10P-100 Glycol in Oil for ASTM D7922 Ethylene Glycol in Engine Oil These standards are intended for use in the determination of ethylene glycol in engine oil by gas chromatography (GC). They are intended for use with ASTM D7922. Matrix: Multi-grade Diesel Engine Oil Description Volume Product No. Ethylene Glycol Blank Standard 80mL VHG-EGOIL-BLK µg/g Ethylene Glycol Standard 80mL VHG-EGOIL µg/g Ethylene Glycol Standard 80mL VHG-EGOIL µg/g Ethylene Glycol Standard 80mL VHG-EGOIL µg/g Ethylene Glycol Standard 80mL VHG-EGOIL µg/g Ethylene Glycol QC Check Standard 80mL VHG-EGOILCS Set of all 6 6 x 80mL VHG-EGOIL-SET-6X80 Multi-Element Coolant Standard Our Multi-Element Coolant Standard is intended for use in the analysis of metals in ethylene glycol or other coolants. It can be diluted 1:1 with ethylene glycol (for matrix matching) or in dilute nitric acid. Matrix: 1% HNO3, tr. HF. Volume (ml) Product No. 500 VHG-GLYCOLSTD-500 Element Conc. (µg/g) Element Conc. (µg/g) Al 50 Mo 500 B 1000 Na 1000 Ca 50 P 2500 Cu 50 Pb 50 Fe 50 Si 500 K 1000 Zn 50 Mg 50 8

15 Crackle Test Reference Crackle Test reference standards for determining water in oil (all values nominal). The crackle test is a visual test performed by placing a small drop of oil onto a hot plate (usually around 300º F). The amount of water present in oil samples is estimated by comparison to these standards. All values certified by gravimetric preparation. Nominal Water Concentration (%) Volume (ml) Product No. Blank 100 VHG-CT-BLK VHG-CT-0.1P VHG-CT-0.5P VHG-CT-1.0P-100 Karl Fischer Titration Certified Reference Karl Fischer Titration certified reference standards for determining water in motor oil (all values certified by Karl Fischer Titration). This test determines the amount of water present in the oil and is the most commonly-used test for this type of determination, with a high degree of accuracy. For use with ASTM D6304. Nominal Water Concentration (%) Volume (ml) Product No. Blank 100 VHG-KF-BLK VHG-KF-0.05P VHG-KF-0.1P VHG-KF-0.5P VHG-KF-1.0P-100 Section 1 Petroleum ICP, RDE, and XRF for Used Oils AN & BN Fuel Dilution Coolant in Oil Soot Crackle Karl Fischer Distillation Performance Testing Program for S, N, Cl and Metals Petroleum Physical Test Biodiesel Reference Gas Oil No. 2 for ASTM D2887 This reference standard is intended for use in the determination of boiling range distribution of petroleum fractions by gas chromatography (GC), in accordance with ASTM Method D2887 Simulated Distilation. Description Volume Product No. Reference Gas Oil No x 1 ml ampoules VHG-RGO-10X1 Reference Gas Oil No. 2 2 oz. VHG-RGO-2OZ Distillation ASTM D86 Group 1 & 2 Synthetic Distillation Standard VHG Labs Group 1 & 2 Distillation Standard is intended for use in accordance with ASTM Method D86 Distillation Groups 1 & 2 and ASTM D850, for distillation of petroleum products at atmospheric pressure. This standard is a synthetic blend of hydrocarbons that boil in the temperature range specified in ASTM D86 Distillation Groups 1 & 2. It covers the boiling range 129 F to 368 F (54 C to 187 C), and was verified by consensus analysis. Volume: 500mL Description Product No. Synthetic Distillation Standard VHG-D ASTM D86 Group 4 Distillation Standard VHG Labs Group 4 Distillation Standard is intended for use in accordance with ASTM Method D86 Distillation Group 4 for distillation of petroleum products at atmospheric pressure. This standard is a diesel oil whose distillation range is specified in ASTM D86 Distillation Group 4. It covers the boiling range 379º F to 700º F (193º to 371º C) and was verified by consensus analysis. Volume: 500mL Description Product No. Distillation Standard VHG-D

16 Section 1 Petroleum Proficiency Testing Program ISO/IEC Accredited Provides an instant response to submitted values VHG Labs Proficiency Testing Program (PTP) was specially designed to give analytical laboratories instant validation while measuring metals, sulfur, viscosity, and particle count in new or used oils. The PTP provides participating labs with a superior method of monitoring their analytical performance as measured against Certified Reference Materials (CRMs) in three quick and easy steps. Web-based, Accurate, Immediate Results: 1) Analyze the PTP Sample 2) Enter results online 3) Check your accuracy 4) Receive immediate results VHG Proficiency Testing Program Each sample includes a single use log-in code with a 90-day expiration. Name Description Size Product No. Sample for Elemental Analysis of Elements: Ag, Al, B, Ba, Ca, Cd, 25g VHG-VPTPMO-25G Oils by ICP, RDE or other Cr, Cu, Fe, K, Mg, Mn, Mo, Na, techniques Ni, P, Pb, Sb, Si, Sn, Ti, V, Zn Sample for Viscosity Analysis Viscosity Test Standard: 40 C 50mL VHG-VPTPVISC-50 and 100 C Sample for Particle Count Analysis Particle Count Standard: 4µm, 125mL VHG-VPTPPC-125 (For ISO only) 6µm, 8µm, 14µm, 21µm, 38µm, 50µm and 70µm ranges Set: VPTPMO-25G, Elemental Analysis Test 1 each VHG-VPTPSET1 VPTPVISC-50, and Standard, Viscosity Test VPTPPC-125 Standard and Particle Count Standard Sample for Elemental Analysis Elements: Ba, Ca, Cl, Mg, 25mL VHG-PTPLUBEMO-25 of Lube Oil by XRF or other Mo, P, S, Si, Zn techniques Sample for Lead in Isooctane Element: Pb 25g VHG-PTPPBISO-25G Analysis Sample for Sulfur in #2 Diesel Element: S 25mL VHG-PTPSDSL-25 Fuel Analysis Sample for Sulfur in 20 cst Element: S 25mL VHG-PTPS20M-25 Mineral Oil Analysis Sample for Sulfur in Isooctane Element: S 25mL VHG-VHG-PTPSISO-25 Analysis Sample for Sulfur in B100 Element: S 25mL VHG-PTPSB Biodiesel Analysis 10

17 Single-Element, Sulfur-Free Metallo-Organic For XRF and Other Techniques Section 1 Petroleum u Sulfur-free metallo-organic compounds in hydrocarbon oil u Certificate of Analysis supplied with each standard u Accuracy ensured by Quality Testing with NIST Standard Reference Materials when available u Certificate of Analysis includes trace metal concentrations Sulfur-Free Single Concentration Concentration Element in Oil (1000µg/g) (5000µg/g) Element Product No. Product No. Aluminum AI VHG-OSF-AL G VHG-OSF-AL G Antimony Sb VHG-OSF-SB G VHG-OSF-SB G Arsenic As VHG-OSF-AS G N/A Barium Ba VHG-OSF-BA G VHG-OSF-BA G Beryllium Be VHG-OSF-BE G VHG-OSF-BE G Bismuth Bi VHG-OSF-BI G VHG-OSF-BI G Boron B VHG-OSF-B G VHG-OSF-B G Cadmium Cd VHG-OSF-CD-1000-A-50G VHG-OSF-CD-5000-A-50G Calcium Ca VHG-OSF-CA G VHG-OSF-CA G Cerium Ce VHG-OSF-CE-1000-A-50G VHG-OSF-CE-5000-A-50G Chromium Cr VHG-OSF-CR G VHG-OSF-CR G Cobalt Co VHG-OSF-CO G VHG-OSF-CO G Copper Cu VHG-OSF-CU G VHG-OSF-CU G Gallium Ga VHG-OSF-GA G VHG-OSF-GA G Gold Au VHG-OSF-AU G N/A Iron Fe VHG-OSF-FE G VHG-OSF-FE G Lead Pb VHG-OSF-PB G VHG-OSF-PB G Lithium Li VHG-OSF-LI G VHG-OSF-LI G Magnesium Mg VHG-OSF-MG G VHG-OSF-MG G Manganese Mn VHG-OSF-MN G VHG-OSF-MN G Mercury Hg VHG-OSF-HG G N/A Molybdenum Mo VHG-OSF-MO G VHG-OSF-MO G Nickel Ni VHG-OSF-NI G VHG-OSF-NI G Phosphorus P VHG-OSF-P G VHG-OSF-P G Potassium K VHG-OSF-K G VHG-OSF-K G Selenium Se VHG-OSF-SE G N/A Silicon Si VHG-OSF-SI G VHG-OSF-SI G Silver Ag VHG-OSF-AG G VHG-OSF-AG G Sodium Na VHG-OSF-NA G VHG-OSF-NA G Strontium Sr VHG-OSF-SR G VHG-OSF-SR G Thallium Tl VHG-OSF-TL G N/A Tin Sn VHG-OSF-SN G VHG-OSF-SN G Titanium Ti VHG-OSF-TI G VHG-OSF-TI G Vanadium V VHG-OSF-V G VHG-OSF-V G Yttrium Y VHG-OSF-Y-1000-A-50G VHG-OSF-Y-5000-A-50G Zinc Zn VHG-OSF-ZN G VHG-OSF-ZN G Zirconium Zr VHG-OSF-ZR G VHG-OSF-ZR G ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Sulfur-Free Metallo- Organics Metallo-Organic Concentrates Sulfur & Metals for XRF Sulfur Nitrogen Chlorine Lead in Gas Petroleum Physical Test Biodiesel 11

18 VHG Tips Section 1 Petroleum Many commercial metallo-organic standards have matrices of sulfur-containing compounds. Use VHG s unique sulfur-free standards if the absence of S is important for your application. Alternatively, known amounts of S can be blended intentionally. For multi-element XRF analysis, the element concentrations should be spread randomly across the suite of standards in order to best correct for inter-element effects. Metallo-Organic Concentrates Sulfur-Free Matrix: Excellent for XRF Metallo-Organic Concentrates - Single Element These sulfur-free, metallo-organic concentrates are ideal for X-ray fluorescence (XRF). They can be used to prepare single or multi-element standards, individually or as a set. Sulfur can be added for the simultaneous analysis of sulfur and metals. Each product is accompanied by a Certificate of Analysis that documents the assayed concentration and any trace impurities. Element Nominal Conc. Product No. Product No. Aluminum Al 3% VHG-ROSFAL3-25G VHG-ROSFAL3-100G Antimony Sb 2% VHG-ROSFSB2-25G VHG-ROSFSB2-100G Barium Ba 7% VHG-ROSFBA7-25G VHG-ROSFBA7-100G Bismuth Bi 28% VHG-ROSFBI28-25G VHG-ROSFBI28-100G Boron B 3% VHG-ROSFB3-25G VHG-ROSFB3-100G Cadmium Cd 7% VHG-ROSFCD7-25G VHG-ROSFCD7-100G Calcium Ca 2% VHG-ROSFCA2-25G VHG-ROSFCA2-100G Cerium Ce 12% VHG-ROSFCE12-25G VHG-ROSFCE12-100G Chromium Cr 9% VHG-ROSFCR9-25G VHG-ROSFCR9-100G Cobalt Co 8% VHG-ROSFCO3-25G VHG-ROSFCO3-100G Copper Cu 3% VHG-ROSFCU3-25G VHG-ROSFCU3-100G Iron Fe 6% VHG-ROSFFE6-25G VHG-ROSFFE6-100G Lead Pb 10% VHG-ROSFPB10-25G VHG-ROSFPB10-100G Lithium Li 2% VHG-ROSFLI2-25G VHG-ROSFLI2-100G Magnesium Mg 2% VHG-ROSFMG2-25G VHG-ROSFMG2-100G Manganese Mn 6% VHG-ROSFMN6-25G VHG-ROSFMN6-100G Molybdenum Mo 15% VHG-ROSFMO15-25G VHG-ROSFMO15-100G Nickel Ni 8% VHG-ROSFNI8-25G VHG-ROSFNI8-100G Phosphorus P 11% VHG-ROSFP11-25G VHG-ROSFP11-100G Potassium K 4% VHG-ROSFK4-25G VHG-ROSFK4-100G Praseodymium Pr 3% VHG-ROSFPR3-25G VHG-ROSFPR3-100G Silicon Si 18% VHG-ROSFSI18-25G VHG-ROSFSI18-100G Silver Ag 1% VHG-ROSFAG1-25G VHG-ROSFAG1-100G Sodium Na 3% VHG-ROSFNA3-25G VHG-ROSFNA3-100G Strontium Sr 9% VHG-ROSFSR9-25G VHG-ROSFSR9-100G Thallium Tl 3% VHG-ROSFTL3-25G VHG-ROSFTL3-100G Tin Sn 18% VHG-ROSFSN18-25G VHG-ROSFSN18-100G Titanium Ti 7% VHG-ROSFTI7-25G VHG-ROSFTI7-100G Vanadium V 4% VHG-ROSFV4-25G VHG-ROSFV4-100G Yttrium Y 2% VHG-ROSFY2-25G VHG-ROSFY2-100G Zinc Zn 18% VHG-ROSFZN18-25G VHG-ROSFZN18-100G Zirconium Zr 24% VHG-ROSFZR24-25G VHG-ROSFZR24-100G Stabilizer for Sulfur-Free Standard Preparation Solvent stabilizer can improve stability of mixes or dilutions of VHG s 1000µg/g and 5000µg/g stock metallo-organic standards or concentrates, as well as multi-element mixes. Product Product Use Product No. Size (grams) MOSF Stabilizer VHG s sulfur-free VHG-SF-STAB-100G 100 metallo-organics. Add to solutions at 15-30% v/v 12

19 Wear Metal For XRF Wear Metal Calibration Set Set of 17 standards with concentrations randomly arranged across the set to correct for interelement effects. See appendix on Page 37 for exact concentrations. Suitable for ASTM D4927. Matrix: Hydrocarbon Oil Size: 50g each Element Concentration Range (µg/g) Ag Al Ba Ca Cd Cr Cu Fe K Mg Mn Mo Na Ni P Pb Sb Si Sn Ti V Zn Product No. VHG-WRMTLSET-17X50G Section 1 Petroleum ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Sulfur-Free Metallo- Organics Metallo-Organic Concentrates Sulfur & Metals for XRF Sulfur Nitrogen Chlorine Lead in Gas Petroleum Physical Test Biodiesel Elemental concentrations are randomly arranged across the set to correct for interelement effects. in the set are not available for individual sale. See appendix on Page 37 for exact concentrations. for Sulfur & Metals in Crude and Residual Oils For XRF Sulfur and Metals in Oil Suitable for ASTM D5708 For S and metals in crude and residual oils Matrix: 20 cst Mineral Oil Volume: 100mL Elemental Concentrations Sulfur (wt%) Iron (µg/g) Nickel (µg/g) Vanadium (µg/g) Product No VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL VHG-SMOIL Product No. VHG-SMOILSET-12X100 13

20 Section 1 Petroleum Lube Oil For XRF Lubricating Oil Suitable for ASTM D4927, D6481, D6443 Matrix: Lubricating Oil Volume: 100mL Elemental Concentrations Sulfur (wt%) Calcium (wt%) Phosphorus (wt%) Zinc (wt%) Product No VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL VHG-LOIL Product No. VHG-LOILSET-16X100 Lube Oil Calibration Set Suitable for ASTM D4927 Matrix: Lubricating Oil Volume: 50mL Elemental Concentrations (µg/g) Ba Ca Cl Mg Mo P S Si Zn Product No. VHG-LUBESET-23X50 Elemental concentrations are randomly arranged across the set to correct for interelement effects. 14

21 Sulfur in Petroleum Products u Wide range of products for ULSD analysis u are manufactured in accordance with applicable ASTM methods in VHG Labs ISO 9001 and ISO Guide 34 facility u Certificate of Analysis provided from our ISO/IEC laboratory showing NIST traceability of standard u Blank standards include ppb-level sulfur concentration on Certificate of Analysis for Sulfur in Diesel Fuel Analysis Full-range of Sulfur for XRF. ASTM Methods D2622, D4294, D5453, D7039, D7212, D7220 and others. Matrix: See Below Volume: 100mL Concentration Light Mineral Oil Heavy Mineral Oil #2 Diesel Fuel (µg/g) (wt%) Product No. Product No. Product No. Blank Blank VHG-S20MIN-BLK-100 VHG-SMIN-BLK-100 VHG-SDSL-BLK VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL VHG-S20MIN VHG-SMIN VHG-SDSL , VHG-S20MIN-1P-100 VHG-SMIN-1P-100 VHG-SDSL-1P , VHG-S20MIN-2P-100 VHG-SMIN-2P-100 VHG-SDSL-2P , VHG-S20MIN-3P-100 VHG-SMIN-3P-100 VHG-SDSL-3P , VHG-S20MIN-4P-100 VHG-SMIN-4P-100 VHG-SDSL-4P , VHG-S20MIN-5P-100 VHG-SMIN-5P-100 VHG-SDSL-5P-100 Section 1 Petroleum ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Sulfur-Free Metallo- Organics Metallo-Organic Concentrates Sulfur & Metals for XRF Sulfur Nitrogen Chlorine Lead in Gas Petroleum Physical Test Biodiesel Sulfur in Kerosene Sulfur in Kerosene suitable for use with ASTM D2622, D3120, D4045, D4294, D5453, and others. Volume: 100mL Concentration Product No. (µg/g) (wt%) Blank Blank VHG-SKERO-BLK VHG-SKERO VHG-SKERO VHG-SKERO VHG-SKERO VHG-SKERO VHG-SKERO VHG-SKERO

22 VHG Tips Section 1 Petroleum Matrix oil blanks are necessary for most analytical techniques of petroleum products. VHG Labs provides a wide range of clean, pure blanks designed to get the most from your analysis. Sulfur in Isooctane Sulfur in Isooctane standards that are ideal for use with the following ASTM methods: D2622, D3120, D3246, D4045, D4294, D5453, D6334, D6445, D7039, D7212, D7220, and others. Volume: 100mL Concentration Product No. (µg/g) (wt%) Blank Blank VHG-SISO-BLK VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO VHG-SISO Sulfur in Crude and Residual Oil Sulfur in Crude Oil and Sulfur in Residual Oil that are suitable for use with ASTM D2622, D4294, and others. Matrix: See Below Volume: 100mL Concentration Crude Oil Residual Oil (µg/g) (wt%) Product No. Product No. Unspiked Matrix Blank VHG-CRUDE VHG-SCRD VHG-SCRD VHG-SRES VHG-SCRD VHG-SRES , VHG-SCRD-1P-100 VHG-SRES-1P , VHG-SCRD-2P-100 VHG-SRES-2P , VHG-SCRD-3P-100 VHG-SRES-3P , VHG-SCRD-4P-100 VHG-SRES-4P , VHG-SCRD-5P-100 VHG-SRES-5P Matrix Oils and Solvents High-purity Matrix Oils and Solvents (<1ppm Sulfur) for the preparation of working standards for petroleum analysis. Supplied with a Certificate of Analysis that includes trace sulfur and metal concentrations. Matrix Volume Product No. 20 cst Mineral Oil 500mL VHG-OIL-20MIN cst Mineral Oil 0.5 gal. VHG-OIL-20MIN-1/2GAL 75 cst Mineral Oil 500mL VHG-OIL-MIN cst Mineral Oil 0.5 gal. VHG-OIL-MIN-1/2GAL #2 Diesel Fuel 500mL VHG-ULSDSL-500 #2 Diesel Fuel 0.5 gal. VHG-ULSDSL-1/2GAL Isooctane 500mL VHG-ISO-500 Isooctane 0.5 gal. VHG-ISO-1/2GAL Kerosene, low odor 500mL VHG-KERO-500 Kerosene, low odor 0.5 gal. VHG-KERO-1/2GAL

23 Polysulfide Oil Sulfur QC Samples, Drift Monitors and Calibration Made from Polysulfide Oil Our polysulfide oils have been formulated for long shelf life and optimal stability even when exposed to x-rays from modern high wattage XRF spectrometers. In addition, our polysulfide oil products offer high purity, low volatility, and minimal diffusion through sample films. These standards are well suited to ultra low level sulfur analysis, quality control, drift correction, blank measurement and calibration standards for XRF and other sulfur analysis techniques. Our polysulfide oil standards are intended for use in accordance with ASTM D2622, D4294, D7039, D7212, D7220 and others. Description QC Samples 5µg/g, Polysulfide oil, 1L 10µg/g, Polysulfide oil, 1L 25µg/g, Polysulfide oil, 1L Drift Monitors 100µg/g, Polysulfide oil, 1L 500µg/g, Polysulfide oil, 1L 1000µg/g, Polysulfide oil, 1L Blank Polysulfide Oil Blank Calibration Sets Sulfur Standard Set (low concentrations). Set of 13 Calibration with 0, 1, 2.5, 5, 10, 25, 50, 75, 100, 250, 500, 750, 1000µg/g, made from high-purity polysulfide oil, 50mL each Sulfur Standard Set (high concentrations). Set of 12 Calibration with 0, 0.1, 0.5, 1, 1.5, 2,2.5, 3, 3.5, 4, 4.5 and 5wt%, made from high-purity polysulfide oil, 50mL each Sulfur Standard Set (low concentrations). Set of 6 Calibration with 0, 10, 25, 50, 100 and 250µg/g, made from high-purity polysulfide oil, 50mL each Ultra Low Sulfur EPA Qualification Set Set of 40 Calibration with 10 5 and 15µg/g each, and 10µg/g, made from high-purity polysulfide oil, 20mL each High Sulfur EPA Qualification Set Set of 40 Calibration with and 500µg/g each, and 300µg/g, made from high-purity polysulfide oil, 20mL each Product No. VHG-PS13M-5-1L VHG-PS13M-10-1L VHG-PS13M-25-1L VHG-PS13M-100-1L VHG-PS13M-500-1L VHG-PS13M L VHG-OIL-13-1L VHG-PS13M-SET1-13X50 VHG-PS13M-SET2-12X50 VHG-PS13M-SET3A-6X50 VHG-PS13M-SET4-40X20 VHG-PS13M-SET5-40X20 Section 1 Petroleum ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Sulfur-Free Metallo- Organics Metallo-Organic Concentrates Sulfur & Metals for XRF Sulfur Nitrogen Chlorine Lead in Gas Petroleum Physical Test Biodiesel 17

24 Section 1 Petroleum Sulfur in Petroleum Products (Ampoules) For Low-Level Sulfur Analytical Techniques Total Sulfur by UV Fluorescence Calibration Set for ASTM Method D Total Sulfur in Liquid Petroleum Hydrocarbons by Ultraviolet Fluorescence. Composition: Sulfur in Isooctane. Offered only as a single set of 6 x 2mL ampoules. Sets also available in toluene upon request. Concentration (ng/µl) Matrix Size Product No. 0, 1.0, 2.5, 5, 7.5, 10 Isooctane 6x2mL VHG-SUVF-SET1 0, 5, 25, 50, 100, 200 Isooctane 6x2mL VHG-SUVF-SET2 0, 100, 250, 500, 750, 1000 Isooctane 6x2mL VHG-SUVF-SET3 Sulfur by Hydrogenolysis and Rateometric Colorimetry Calibration Set for ASTM D Sulfur in Petroleum Products by Hydrogenolysis and Rateometric Colorimetry. Composition: Sulfur (from n-dibutyl sulfide) in isooctane. Offered only as a single set of 7 x 2mL ampoules. Concentration (µg/g) Matrix Size Product No. 0, 0.1, 0.5, 1.0, 2.5, 5.0, 10 Isooctane 7x2mL VHG-SRC-SET1A Determination of Mercaptan Sulfur Calibration for UOP 163 and ASTM D Mercaptan Sulfur in Hydrocarbon Liquids by Potentiometric Titration. Composition: Sulfur (from 1-octanethiol) in isooctane/toluene. Offered only as a single set of 6 x 20mL ampoules. Concentration (µg/g) Matrix Size Product No % Isooctane/ 6x20mL VHG-UOP X20 20% Toluene Sulfur Compounds by Selective Detection (100µg/g) Calibration Standard for ASTM D Sulfur compounds in Light Hydrocarbon Liquids by Selective Detection. Composition: Multi-component mixture that contains fourteen (14) sulfur species in base fuel (40% LV isooctane/40% LV hexane/20% LV toluene). Sulfur species include: methanethiol, ethanethiol, dimethylsulfide, 2-propanethiol, t-butanethiol, 1-propanethiol, thiophene, diethylsulfide, 1-butanethiol, diethyl disulfide, thiophenol, benzothiophene, bromothiophene (as internal standard), and phenyl sulfide. Offered as a single 2mL ampoule. Concentration of Species Matrix Size Product No. 100µg/g (as Sulfur) Base Fuel 2mL VHG-MSX14-2 Sulfur Compounds by Selective Detection (50µg/g) Calibration Standard for ASTM D Sulfur Compounds in Light Hydrocarbon Liquids by Selective Detection. Composition: Multi-component mixture containing twenty-two (22) sulfur species in base fuel (40% LV isooctane/40% LV hexane/20% LV toluene). Sulfur species include: 2-methyl-1-propanethiol, 2-methylthiophene, 3-methylthiophene, 1,2-ethane dithiol, 1-pentanethiol, 2-ethylthiophene, propylsulfide, t-butyldisulfide, 1,5-pentanedithiol, 1-nonanethiol, 1-decanethiol, propanethiol, t-butylsulfide, 1-heptanethiol, 1,4-butanedithiol, methyl ethylsulfide, propyl disulfide, 1-octanethiol, benzothiophene, 1-hexanethiol, carbon disulfide, and methyl sulfide. Offered as a single 2mL ampoule. Concentration of Species Matrix Size Product No. 50µg/g (as component) Base Fuel 2mL VHG-MSX

25 Sulfur and Nitrogen Products (Ampoules) For Low-Level Analytical Techniques Sulfur and Nitrogen Combined Calibration Set for instruments designed for simultaneous determination of sulfur and nitrogen. Composition: Sulfur and Nitrogen in isooctane. Offered only as a single set of 6 x 2mL ampoules. Also available in toluene upon request. Concentration (ng/µl) Matrix Size Product No. 0, 1, 5, 10, 15, 20; Isooctane 6x2mL VHG-SN-SET1 0, 1, 5, 20, 35, 50 Trace Nitrogen by Chemiluminescence Calibration Set for ASTM Method D Trace Nitrogen in Liquid Petroleum Hydrocarbons by Chemiluminescence Detection. Composition: N (from pyridine) in isooctane. Offered only as a single set of 9 x 2mL ampoules. Also available in toluene upon request. Concentration (ng/µl) Matrix Size Product No. 0, 1, 2, 10, 20, 50, 100, Isooctane 10x2mL VHG-NCH-SET1 200, 500, 1000 Trace Nitrogen by Oxidative Combustion and Electrochemical Detection Calibration Set for ASTM D Total Trace Nitrogen and its Derivatives in Liquid Aromatic Hydrocarbons by Oxidative Combustion and Electrochemical Detection. Composition: N (from pyridine) in p-xylene [Set 1] or isooctane [Set 2]. Offered only as single sets of 2mL ampoules. Set also available in toluene upon request (with N from carbazole). Concentration (ng/µl) Matrix Size Product No. 0.1, 0.5, 1.0, 2.5, 5.0, 10 p-xylene 6x2mL VHG-NCED-SET1B 10, 25, 50, 75, 100 Isooctane 5x2mL VHG-NCED-SET2 Section 1 Petroleum ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Sulfur-Free Metallo- Organics Metallo-Organic Concentrates Sulfur & Metals for XRF Sulfur Nitrogen Chlorine Lead in Gas Petroleum Physical Test Biodiesel Chlorine in Oil For XRF, ICP and Other Techniques Chlorine in Oil (ASTM D4929 or D5384) Matrix: Heavy Mineral Oil Volume: 100mL Concentration (µg/g) (wt%) Oil Product No Blank Blank VHG-CLOIL-BLK VHG-CLOIL VHG-CLOIL VHG-CLOIL VHG-CLOIL , VHG-CLOIL-1P , VHG-CLOIL-5P

26 VHG Tips Section 1 Petroleum To convert lead in isooctane concentrations from g/gal to µg/g (ppm), multiply by 380 i.e., 0.1 g/gal=38µg/g. for Lead in Gasoline Lead In Isooctane for XRF (ASTM D5059) Matrix: Isooctane Volume: 100 Grams Method Conc. (g/gal)* Product No. ASTM D5059 Pt. A 0.0 VHG-PBISO-BLK-100G 0.1 VHG-PBISO G 1.0 VHG-PBISO-1-100G 2.0 VHG-PBISO-2-100G 3.0 VHG-PBISO-3-100G 4.0 VHG-PBISO-4-100G 5.0 VHG-PBISO-5-100G ASTM D5059 Pt. A Set VHG-PBISOSETA-7X100G ASTM D5059 Pt. C VHG-PBISO-BLK-100G VHG-PBISO G VHG-PBISO G VHG-PBISO G VHG-PBISO G VHG-PBISO G VHG-PBISO G ASTM D5059 Pt. C Set VHG-PBISOSETC-7X100G *Note: For approximate conversion from g/gal to µg/g (ppm), multiply by 380 i.e., 0.1 g/gal=38µg/g Bismuth Internal Standard for ASTM D5059 Matrix: Mineral Oil Method Conc. Bi Size (grams) Product No. ASTM D5059 Pt. A and C 0.793g/L 100 VHG-BIIS-100G 0.793g/L 400 VHG-BIIS-400G Internal for XRF Analysis Sulfur-Free Raw Material in Oil Internal for XRF Analysis Element Method Concentration Product No. Product No. Bismuth ASTM D g/L VHG-BIIS-100G VHG-BIIS-400G Pb Analysis Manganese ISO % VHG-MNIS-100G VHG-MNIS-400G Ni and V Analysis Zirconium ISO % VHG-ZRIS1P-100G VHG-ZRIS1P-400G Sulfur Analysis 20

27 Petroleum Physical Test Flash Point Reference Materials VHG Labs Flash Point Reference materials are intended for use with and certified by the appropriate ASTM Methods [ASTM D56, D92, D93]. Each standard is verified by consensus analysis, and is supplied with a full Certificate of Analysis (COA) that states the certified value. Volume: 250mL Specification Apparatus Typical Flash Product No. Point Range ( C) ASTM D93 (Flash Point) Pensky-Martens VHG-FP Closed-Cup Tester VHG-FPPM VHG-FP VHG-FP ASTM D92 Cleveland Open Cup VHG-FP (Flash and Fire Point) Tester VHG-FP ASTM D56 (Flash Point) Tag Closed Cup VHG-FP Tester VHG-FP VHG-FPTC Flash Point Certified Reference Materials VHG Labs Flash Point Certified Reference Materials are intended for use in accordance with the specified ASTM Methods [ASTM D56, D92, D93]. They consist of stable, pure hydrocarbons with a method-specific flash point determined by an inter-laboratory study. Each standard is supplied with a full Certificate of Analysis (COA) that states the certified value. Volume: 250mL ASTM Method Hydrocarbon Typical Flash Product No. Point Range ( C) D93 Flash Point n-decane VHG-FP Pensky-Martens n-undecane VHG-FP Closed Cup Tester n-tetradecane VHG-FP n-hexadecane VHG-FP D92 Flash & Fire Point n-tetradecane VHG-FP Cleveland Open Cup Tester n-hexadecane VHG-FP D56 Flash Point n-decane VHG-FP Tag Closed Cup Tester n-undecane VHG-FP Section 1 Petroleum ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Sulfur-Free Metallo- Organics Metallo-Organic Concentrates Sulfur & Metals for XRF Sulfur Nitrogen Chlorine Lead in Gas Petroleum Physical Test Flash Point Viscosity Pour Point Cloud Point Freezing Point Cold Filter Plug Point Biodiesel Viscosity Reference VHG Labs provides viscosity reference standards, intended for use in accordance with standard methods [e.g. ASTM D445]. Each standard is manufactured in our ISO 9001 and ISO Guide 34 facility and certified in our ISO/IEC laboratory. Volume: 500mL Nominal 40ºC (cst) Nominal 100ºC (cst) Product No VHG-VISC VHG-VISC VHG-VISC VHG-VISC VHG-VISC VHG-VISC60A VHG-VISC VHG-VISC100A VHG-VISC VHG-VISC VHG-VISC VHG-VISC VHG-VISC

28 Section 1 Petroleum Petroleum Physical Test u The following physical test standards are not intended for use with Phase Instruments. ASTM D97 Pour Point Reference Materials VHG Labs Pour Point Reference Materials are intended for use in accordance with ASTM D97 only, for determination of the pour point of petroleum products. Each standard is verified by consensus analysis, and is supplied with a full Certificate of Analysis (COA) that states the certified value. Volume: 250mL Typical Pour Point Range ( C) Product No. -7 to -3 VHG-P to -8 VHG-P to -13 VHG-P to -18 VHG-P to -36 VHG-P to -47 VHG-P ASTM D2500 Cloud Point Reference Materials VHG Labs Cloud Point Reference Materials are intended for use in accordance with ASTM D2500 for the determination of the cloud point of petroleum products. The cloud point of a petroleum product is an index of the lowest temperature of their utility for certain applications. Each standard is verified by consensus analysis, and is supplied with a full Certificate of Analysis (COA) that states the certified value. Volume: 250mL Typical Cloud Point Range ( C) Product No. +3 to +9 VHG-C to 0 VHG-C to -8 VHG-C to -13 VHG-C to -18 VHG-C ASTM D2386 Freezing Point Reference Materials VHG Labs Freezing Point Reference Materials are intended for use in accordance with ASTM Method D2386 for determination of the freezing point of aviation fuels. Each standard is verified by consensus ayalysis, and is supplied with a full Certificate of Analysis (COA) that states the certified value. Volume: 250mL Typical Freezing Point Range ( C): Product No. -47 to -42 VHG-F to -48 VHG-F ASTM D6371 Cold Filter Plug Point Reference Materials VHG Labs Cold Filter Plug Point are intended for use in accordance with ASTM Method D6371/IP309 for determination of the cold filter plug point of diesel and heating fuels. Each standard is verified by consensus analysis, and is supplied with a full Certificate of Analysis (COA) that states the certified value. Volume: 250mL Typical Plug Point Range ( C) Product No. -20 to -17 VHG-CFP

29 Biodiesel As the demand for biofuels continues to rise, the need to reliably analyze these products has become a necessity for the petroleum industry. Most biodiesel fuels are comprised of a blend of traditional refined diesel combined with biodiesel fuel. The percentage of biodiesel in the blend is generally 5%, 10% or 15%, and is labeled B5, B10, or B15 respectively. Pure biodiesel (100%) is labeled B100. All of our diesel standards have a matrix of 100% biodiesel. This is important in the analysis of materials by ICP and other methods because the analysis can often be encumbered by the variance of matrices from standards to samples. Our biodiesel standards have been formulated specifically for the analysis of metals and sulfur in biodiesel fuel. Our B100 is made from soybean oil and is an excellent matrix match for almost all biodiesel fuel analysis. Metals in Biodiesel These standards have been formulated specifically for the analysis of metals in biodiesel fuel in accordance with ASTM D6751, EN 14107, EN 14108, EN 14109, EN 14214, or EN Description Product No. Ca, K, Mg, Na, 5µg/g, B100 Biodiesel, 100g VHG-B100M G Ca, K, Mg, Na, B100 Biodiesel, 100g VHG-B100M G Ca, K, Mg, Na, B100 Biodiesel, 100g VHG-B100M G S Sulfur in Biodiesel These standards have been formulated specifically for the analysis of sulfur in biodiesel fuel in accordance with ASTM D2622, D4294, or D5453. Description Product No. 5µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB µg/g, B100 Biodiesel, 100mL VHG-SB Biodiesel Blanks These solutions are intended for use as calibration blanks for analysis of metals or sulfur in biodiesel. Each is supplied with a Certificate of Analysis (COA) that includes relevant trace metal and sulfur concentrations. Description Product No. B100 Biodiesel Blank, 100mL VHG-B100-BLK-100 B100 Biodiesel Blank, 500mL VHG-B100-BLK-500 Biodiesel/Diesel Fuel Blends These standards are intended for use as calibration or reference standards for the determination of fatty acid methyl esters (FAME) biodiesel content in diesel fuel by infrared (IR) spectroscopy. They are formulated specifically for use with ASTM Method D7371 or EN Description Product No. 100% High Cetane Diesel Fuel, 20mL VHG-BDBLEND-BLK-20 2% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-2P-20 5% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-5P-20 10% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-10P-20 15% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-15P-20 20% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-20P-20 25% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-25P-20 30% (v/v) Biodiesel in High Cetane Diesel Fuel, 20mL VHG-BDBLEND-30P % (v/v) Biodiesel, 20mL VHG-BDBLEND-100P-20 Section 1 Petroleum ICP, RDE, and XRF for Used Oils Distillation Performance Testing Program for S, N, Cl and Metals Petroleum Physical Test Flash Point Viscosity Pour Point Cloud Point Freezing Point Cold Filter Plug Point Biodiesel 23

30 Reference standards for residue and environmental testing Over 8000 pesticide and other organic reference materials The Dr. Ehrenstorfer range of neats, solutions and mixes includes: PAHs Dyes Phthalates Toxaphene single components Pharmaceutical and veterinary compounds PCBs Phenols Chlorinated paraffins Pesticides and pesticide metabolites And many more LGC Quality - ISO Guide 34 GMP/GLP ISO 9001 ISO/IEC ISO/IEC Science for a safer world LGC Limited, All rights reserved. 4436/CB/1115

31 CRMs to verify analytical procedures LGC Quality - ISO Guide 34 GMP/GLP ISO 9001 ISO/IEC ISO/IEC 17043

32 Section 2 CRMs to verify Analytical Procedures CRMs to verify Analytical Procedures Diesel Code CRM BTU C % H % N % IARM-HP RE IARM-HP RD IARM-HP C IARM-HP C IARM-HP RC IARM-HP D S % S ppm Unit HP-14050RE (19500) (85) (13.1) each HP-14005RD each #2 Diesel % S each #2 Diesel % S oz bottle #2 Diesel % S RM oz bottle #2 Diesel % S CRM each IARM-HP- HP-14300RH each 14300RJ ERM-EF673 Diesel - Sulfur ml ERM-EF674 Diesel - Sulfur ml NIST-1624d Diesel fuel oil - Sulfur ml NIST-2723B Sulfur in Diesel Fuel Oil ml (Nominal Mass Fraction 10mg/kg) NIST-2770 Diesel fuel oil - Sulfur x 10 ml AR-2821 #2 Diesel Oil ml AR-2961 #2 Diesel Oil ml * For catalog purposes, nominal concentrations (µg/g) are provided. AR-2822 #2 Diesel Oil ml AR-2962 #2 Diesel Oil ml AR-2823 #2 Diesel Oil ml AR-2963 #2 Diesel Oil ml AR-2824 #2 Diesel Oil ml AR-2964 #2 Diesel Oil ml AR-2965 #2 Diesel Oil each AR-2825 #2 Diesel Oil ml AR-2826 #2 Diesel Oil ml AR-2827 #2 Diesel Oil ml AR-2828 #2 Diesel Oil ml AR-2829 #2 Diesel Oil ml AR-2868 Ultra Low #2 Diesel Oil < <1 118 ml AR-2882 Sulfur #2 Diesel Oil ml AR-2881 #2 Diesel Oil ml AR-2869 #2 Diesel each AR-2879 #2 Diesel Oil ml AR-2878 #2 Diesel Oil ml AR-2871 Ultra Low #2 Diesel Oil ml 26

33 Diesel Code CRM BTU C % H % N % S % S ppm Unit AR-2872 Ultra Low #2 Diesel Oil ml AR-2873 Ultra Low #2 Diesel Oil ml AR-2874 Ultra Low #2 Diesel Oil ml AR-2875 Ultra Low #2 Diesel Oil ml AR-2865 Ultra Low #2 Diesel Oil ml AR-2876 Ultra Low #2 Diesel Oil ml AR-2866 Ultra Low #2 Diesel Oil ml AR-2867 Ultra Low #2 Diesel Oil ml AR-2877 Ultra Low #2 Diesel Oil ml Section 2 CRMs to verify Analytical Procedures Bio-Diesel Code CRM FAME AR-2971 AR-2972 AR-2973 AR-2974 AR-2975 AR-2980 AR-2981 AR-2982 AR-2983 AR-2984 AR-2985 Biodiesel Contaminant in Synthetic Diesel Biodiesel Contaminant in Synthetic Diesel Biodiesel Contaminant in Synthetic Diesel Biodiesel Contaminant in Synthetic Diesel Biodiesel Contaminant in Synthetic Diesel Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel AR-2986 AR-2987 AR-2988 Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel Biodiesel Contaminant in #2 Diesel

34 Section 2 CRMs to verify Analytical Procedures VHG Tips We stock a variety of highquality sample cups and thin film for XRF instruments. Gasoline / Gasoil / Kerosene Code CRM BTU C % H % N % S % S ppm Unit ERM-EF104 Gas oil - Sulfur ml ERM-EF211 Petrol - Sulfur ml ERM-EF212 Petrol - Sulfur ml ERM-EF213 Petrol - Sulfur Amp. ERM-EF671 Gas oil - Sulfur ml ERM-EF672 Gas oil - Sulfur ml NIST-1616b Kerosene - Sulfur ml NIST-1617B Kerosene - Sulfur (86.30) (13.90) ml NIST-2294 Reformulated gasoline - Sulfur, benzene, MTBE and toluene NIST-2295 Reformulated gasoline - Sulfur, benzene, MTBE and toluene NIST-2296 Reformulated gasoline - Sulfur, benzene, MTBE and toluene x 20 ml x 20 ml x 20 ml NIST-2297 Reformulated gasoline x 20 Sulfur, benzene, MTBE ml * For catalog purposes, and nominal toluene concentrations (µg/g) are provided. NIST-2298 Gasoline (High-Octane) x 20 - Sulfur ml NIST-2299 Gasoline (Reformulated) x 20 - Sulfur ml BCR-105 Gas oil - Sulfur g BCR-106 Gas oil - Sulfur g BCR-107 Gas oil - Sulfur g AR-6201 Ultra Low Kerosene ml AR-6207 Ultra Low Kerosene ml AR-6208 Ultra Low Kerosene ml AR-6209 Ultra Low Kerosene ml AR-6202 Ultra Low Kerosene ml AR-6210 Ultra Low Kerosene ml AR-6211 Ultra Low Kerosene ml AR-6212 Ultra Low Kerosene ml AR-6213 Ultra Low Kerosene ml AR-6203 Ultra Low Kerosene ml AR-6204 Ultra Low Kerosene ml AR-6205 Ultra Low Kerosene ml AR-6206 Ultra Low Kerosene ml AR-2849 Kerosene < <1 118 ml AR-2841 Kerosene ml AR-2951 Kerosene, 0.02% S ml AR-2842 Kerosene ml 28

35 Gasoline / Gasoil / Kerosene Code CRM BTU C % H % Pb % N % S % S ppm Unit AR-2952 Kerosene, 0.04% S ml AR-2843 Kerosene ml AR-2953 Kerosene, 0.06% S ml AR-2954 Kerosene, 0.07% S ml AR-2955 Kerosene, 0.08% S ml AR-2956 Kerosene, 0.09% S ml AR-2844 Kerosene ml AR-2845 Kerosene ml AR-2846 Kerosene ml AR-2847 Kerosene ml AR-2848 Kerosene ml AR-2921 JP Fuel ml AR-2922 JP Fuel ml AR-2923 JP Fuel ml AR-2924 JP Fuel ml AR-2925 JP Fuel ml AR-2926 JP Fuel ml AR-2927 JP Fuel ml AR-2928 JP Fuel ml AR-3001 Sulfur in Gasoline ml AR-3002 Sulfur in Gasoline ml AR-3003 Sulfur in Gasoline ml AR-3004 Sulfur in Gasoline ml AR-3005 Sulfur in Gasoline ml AR-3006 Sulfur in Gasoline ml AR-3007 Sulfur in Gasoline ml AR-2067 Pb in Gasoline < ml AR-2066 Pb in Gasoline ml AR-2065 Pb in Gasoline ml AR-2064 Pb in Gasoline ml AR-2063 Pb in Gasoline ml AR-2062 Pb in Gasoline ml AR-2061 Pb in Gasoline ml AR-3111 Gasoline ml AR-3112 Gasoline ml AR-3113 Gasoline ml AR-3114 Gasoline ml AR-3115 Gasoline < < <1 118 ml Section 2 CRMs to verify Analytical Procedures 29

36 Section 2 CRMs to verify Analytical Procedures Lube Oil CRMs / Lubricants Code CRM S % S ppm Unit IARM-HP- White Mineral Oil % S each 13100C AR-2838 Lube Oil ml AR-2931 Lube Oil ml AR-2932 Lube Oil ml AR-2831 Lube Oil ml AR-2933 Lube Oil ml AR-2934 Lube Oil ml AR-2832 Lube Oil ml AR-2935 Lube Oil ml AR-2833 Lube Oil ml AR-2834 Lube Oil ml AR-2936 Lube Oil ml AR-2835 Lube Oil ml AR-2937 Lube Oil ml AR-2836 Lube Oil ml * AR-2938 For catalog purposes, Lube nominal Oil concentrations (µg/g) are provided ml AR-2839 Lube Oil ml AR-2939 Lube Oil ml AR-2837 Lube Oil ml AR-2857 Lube Oil ml AR-2858 High Sulfur Lube Oil ml Code CRM Cl % Cl ppm Unit AR-2004 Chlorine in Paraffin Oil ml AR-2005 Chlorine in Paraffin Oil ml AR-2006 Chlorine in Paraffin Oil ml AR-2007 Chlorine in Paraffin Oil ml AR-2008 Chlorine in Paraffin Oil ml AR-2009 Chlorine in Paraffin Oil ml AR-2010 Chlorine in Paraffin Oil ml AR-2011 Chlorine in Paraffin Oil ml AR-2012 Chlorine in Paraffin Oil ml AR-2015 Chlorine in Paraffin Oil ml 30

37 Lube Oil CRMs / Lubricants Code CRM Cl % S % Unit AR-3501 Sulfur/Chlorine in Lube Oil ml AR-3502 Sulfur/Chlorine in Lube Oil ml AR-3503 Sulfur/Chlorine in Lube Oil ml Section 2 CRMs to verify Analytical Procedures AR-3504 Sulfur/Chlorine in Lube Oil ml AR-3505 Sulfur/Chlorine in Lube Oil ml AR-3506 Sulfur/Chlorine in Lube Oil ml AR-3507 Sulfur/Chlorine in Lube Oil < < ml Code CRM Ash % Base No Ca % Mg % P % S % Zn % cst/100 cst/40 Unit AR-6301 Engine Oil <0.001 <0.001 < < ml AR-6302 Engine Oil ml AR-6303 Engine Oil ml AR-6304 Engine Oil ml AR-6305 Engine Oil ml Code CRM S % S ppm Unit AR-3521 Low Sulfur Lube Oil < <1 118 ml AR-3522 Low Sulfur Lube Oil ml AR-3523 Low Sulfur Lube Oil ml AR-3524 Low Sulfur Lube Oil ml AR-3525 Low Sulfur Lube Oil ml AR-3526 Low Sulfur Lube Oil ml AR-3527 Low Sulfur Lube Oil ml AR-3528 Low Sulfur Lube Oil ml Code CRM Ni ppm S % V ppm Unit AR-2901 Lube Oil ml AR-2902 Lube Oil ml AR-2903 Lube Oil ml AR-2904 Lube Oil ml AR-2905 Lube Oil ml 31

38 Section 2 CRMs to verify Analytical Procedures Residual Oil / Bunker Code CRM BTU/Ib C % H % Joule/g N % S % Unit IARM- 3% S CHN & BTU in each HP21-10A Residual Fuel Oil Code CRM S % Unit IARM-HP-11050C Residual Fuel Oil CRM each 0.50% S IARM-HP-11200D Residual Fuel Oil % S 2.15 each IARM-HP-11300C Residual Fuel Oil 3.% PRELIM 3.2 each Code CRM As ppm Co ppm NIST- 1634C Fuel oil - Trace elements Ni ppm S ppm Se ppm V ppm Unit (2.0) ml Code CRM Hg ppm S % Unit NIST-1619B Residual fuel oil - Sulfur ml NIST-1620C Residual fuel oil - Sulfur ml NIST-1621E Residual fuel oil - Sulfur ml NIST-1622E Residual fuel oil - Sulfur ml NIST-2717A Residual fuel oil - Sulfur ml Code CRM S % Unit AR-2891 Residual Fuel Oil ml AR-2811 Residual Fuel Oil ml AR-2892 Residual Fuel Oil ml AR-2893 Residual Fuel Oil ml AR-2809 Residual Fuel Oil ml AR-2894 Residual Fuel Oil ml AR-2895 Residual Fuel Oil ml AR-2812 Residual Fuel Oil ml AR-2896 Residual Fuel Oil ml AR-2813 Residual Fuel Oil ml AR-2897 Residual Fuel Oil ml AR-2814 Residual Fuel Oil ml AR-2818 Residual Fuel Oil ml AR-2815 Residual Fuel Oil ml AR-2819 Residual Fuel Oil ml AR-2816 Residual Fuel Oil ml AR-2898 Residual Fuel Oil ml AR-2817 Residual Fuel Oil ml AR-2899 Residual Fuel Oil ml Code CRM S % Unit AR-3181 High Viscosity Residual Oil ml AR-3182 High Viscosity Residual Oil ml 32

39 Code CRM C % Cu ppm AR-1622 Ultimate Residual Oil Fe ppm H % N % Na ppm Ni ppm S % Si ppm gross- BTU < (5) (4) ml Unit Section 2 CRMs to verify Analytical Procedures Code CRM S % Unit AR-2859 High Sulfur Residual Oil ml AR-2861 High Sulfur Residual Oil ml AR-2862 High Sulfur Residual Oil ml AR-2863 High Sulfur Residual Oil ml AR-2864 High Sulfur Residual Oil ml Crude Oil Code CRM Hg ppm S % Unit NIST-2721 Crude oil (light-sour) - Sulfur x 10 and mercury ml NIST-2722 Crude oil (heavy-sweet) - Sulfur and mercury x 10 ml Code CRM S % S ppm Unit AR-2941 Stabilized Crude Oil ml AR-2942 Stabilized Crude Oil ml AR-2943 Stabilized Crude Oil ml AR-2944 Stabilized Crude Oil ml AR-2041 Stabilized Crude Oil ml AR-2945 Stabilized Crude Oil ml AR-2946 Stabilized Crude Oil ml AR-2947 Stabilized Crude Oil ml AR-2948 Stabilized Crude Oil ml AR-2042 Stabilized Crude Oil ml AR-2043 Stabilized Crude Oil ml AR-2044 Stabilized Crude Oil ml AR-2045 Stabilized Crude Oil ml AR-2046 Stabilized Crude Oil ml AR-2047 Stabilized Crude Oil ml AR-2048 Stabilized Crude Oil ml AR-2049 Stabilized Crude Oil ml AR-2050 Stabilized Crude Oil ml AR-2051 Stabilized Crude Oil ml Code CRM N ppm Unit AR-3032 Nitrogen in Crude Oil ml AR-3033 Nitrogen in Crude Oil ml AR-3034 Nitrogen in Crude Oil ml 33

40 Section 2 CRMs to verify Analytical Procedures Crude Oil Code CRM Cl ppm AR-2070 Wyoming Crude Oil AR-2071 North Sea Crude Oil AR-2072 Alaska Crude Oil AR-2078 Vacuum Gas Oil Cu ppm Fe ppm N ppm Na ppm Ni ppm S % Si ppm V ppm Unit ml ml ml ml Waste Oil Code CRM Cd ppm Cl ppm Cr ppm Pb ppm Unit AR-3161 Waste Oil ml AR-3162 Waste Oil ml AR-3163 Waste Oil ml Code CRM As ppm Unit AR-3171 Waste Oil ml AR-3172 Waste Oil ml AR-3173 Waste Oil ml CRMs with given C-H-N-composition Code CRM BTU BTU/ Ib IARM- HP14050RE IARM-HP21-10A AR-000 AR-100 AR % S in #2 Diesel Fuel CRM 3% S CHN & BTU in Residual Fuel Oil Paraffin Oil Residual Oil Residual Oil C % Cu ppm Fe ppm H % Joule/g N % Na ppm Ni ppm S % Si ppm gross- BTU (85) 13.1 (0.1) 0.5 each each ml ml ml AR-327 Kerosene ml AR-330 #2 Diesel ml Oil AR-1622 Ultimate < (5) (4) ml Residual Oil NIST-1617B Kerosene - Sulfur ml Unit 34

41 Other Petrochemical CRMs Code CRM S % Unit NIST-2720 Di-n-butyl sulfide - Sulfur (21.9) 5 x 4.5 ml Section 2 CRMs to verify Analytical Procedures Code CRM S % Unit AR-2851 Extreme Pressure Oil ml AR-2852 Extreme Pressure Oil ml AR-2853 Extreme Pressure Oil ml Code CRM N ppm S % Unit AR-2077 Vacuum Gas Oil ml AR-3151 Nitrogen in Vacuum Gas Oil ml AR-3152 Nitrogen in Vacuum Gas Oil ml AR-3153 Nitrogen in Vacuum Gas Oil ml AR-3154 Nitrogen in Vacuum Gas Oil ml AR-3155 Nitrogen in Vacuum Gas Oil ml AR-3156 Nitrogen in Vacuum Gas Oil ml AR-3157 Nitrogen in Vacuum Gas Oil ml Code CRM %C10-C40 Ratio Unit BAM-K009 Lubricating oil (type ml B) (ISO , ISO 16703, EN 14039) BAM-K010F Diesel Fuel (type A)/ ml Lubricating Oil (type B) (1:1) (ISO , ISO 16703, EN 14039) BAM-K011 Mineral oil calibration standard ml Code CRM SY124 Unit ERM-EF317 Gas oil - Solvent Yellow ml 124 (SY124) ERM-EF318 Gas oil - Solvent Yellow 124 (SY124) ml 35

42 Reference Information Conversion Tables For Reference Use these tables to find the information you need Tubing I.D. & Volumes I.D. I.D. Vol. Vol. (in.) (mm.) (µl/in) (µl/cm) Volume Conversion CC ml Liter Fl. Gallon (cm 3 ) Oz E Viscosity Conversion Centipoise Centistokes Examples (cp)* (cst) 1 1 water lotion veg. oil latex paint maple syrup SAE 30 oil *cp = cst x (density in g/ml) Weight Conversion Pound Ounce Gram Kilogram (lb) (oz) (g) (kg) Flow Rate Conversion L/min. L/sec. Gal./min. Gal./sec (gpm) (gps) ppm standard Desired Content: 100ppm 10ppm 1ppm 100ppb 10ppb 1ppb Dilution Table Volumetric Size (ml) mL 2.5mL 5.0mL 10.0mL 25.0mL 100µL 250µL 500µL 1mL 2.5mL (10µL) 25µL 50µL 100µL 250µL * (2.5µL) (5µL) (10µL) 25µL * * * * (2.5µL) * * * * * Those shown with * or ( ) not recommended due to overly ambitious dilution factor and small aliquot. Pressure Conversion psi bar Pa (N/m 2 ) Torr atm 1.45E E E E , , , , Aliquot Volume Dimension Conversion U.S.A. Metric U.S.A Fractional Decimal Inches Inches 1/ mm n/a 1.00mm / mm /8 3.18mm /4 6.35mm / mm /8 9.53mm n/a 10mm(1cm) / cm /2 1.27cm / cm /8 1.59cm / cm /4 1.91cm / cm /8 2.22cm / cm cm cm 2.00 n/a 10.0cm cm 5.00 n/a 50.0cm 19.7 n/a 100cm(1m)

43 Wear Metals Set for XRF (Part No: VHG-WRMTLSET-17X50G) Ag Al Ba Ca Cd Cr Cu Fe K Mg Mn Mo Na Ni P Pb Sb Si Sn Ti V Zn Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard not available for individual sale. See set information on Page 13. Reference Information Dilution Dimension Flow Rate Pressure Tubing I.D. & Volumes Viscosity Volume Weight Consumables 37

44 Notes

45 Notes

46 Notes

47 The ultimate online source for reference materials 100,000 reference materials + your search criteria = standard your petroleum Our website offers the most comprehensive source of reference materials now available for ONLINE ordering. To browse our products, visit: Check out our webinars and e-books at LGC Quality - ISO Guide 34 GMP/GLP ISO 9001 ISO/IEC ISO/IEC LGC Limited, All rights reserved. LGC is part of the LGC Group. 4239/LB/0315