MUTINEER EXETER CRUDE OIL. Santos Limited

Transcription

1 Crude Assay Job Number 08-January API 0.10 mgkoh/g TAN %m Sulphur 11.8 K Factor on behalf of Santos Limited :Report By Approved By: Joshua Camens Lab. Supervisor Jhonas Fernandez Lab. Manager Intertek - Commodities Port Adelaide Laboratory Australia NATA accredited lab for ASTM D2892 Full accreditation details available at Accreditation No

2 Crude Assay Job Number Date: January 8, 2015 Santos Limited 60 Flinders Street Adelaide SA 5001 Australia For the Attention of : Cathy Frost Sample(s) received from : Santos Limited Sample(s) submitted as : Mutineer Exeter Crude Oil 2 x 20 L epoxy lined cans 5 x 20 ml VOA vials 2 x 1 L glass bottle Sample description : Mutineer Exeter Crude oil dated ex FPSO Modec, Venture 11 Seals on Sample(s) : Sealed: , , ,

3 TABLE OF CONTENTS Report ID: Description Page No. Sample Details Assay Slate Summary 1 Properties of Whole Crude Oil 2 Distillation Overview 3 Front End Overview 4 Graph of True Boiling Point (Cumulative % mass and % volume) 5 Graph of Cumulative % Middle Volume vs API Gravity 6 Graph of True Boiling Point vs Simulated Distillation 7 Properties of Naphtha 8 Properties of Kerosene 9 Properties of Gas Oil 10 Properties of Residue Detailed Hydrocarbon Analysis, Full report (C5-70 C) Component List. Total by group type & Carbon number. Detailed Hydrocarbon Analysis, Full Report ( C) Component List. Total by group type & Carbon number. 11 appendix i appendix ii

4 Whole Crude LPG Naptha C5-70C Naptha C Kerosene C Gas Oil C Residue 360C+ ASSAY SLATE SUMMARY Report ID Crude ID Client ID Date Santos Limited 08-January-2015 Cut Range Test Fractional Distillation Method ASTM D2892 Unit mass% vol% (note 1) C kg/l (note 6) ASTM D5002/ASTM Specific F D4052/ IP 365 API Gravity API Rapid Yield SIMDIS ASTM D7169+LE C See page 3 Aromatics - FIA ASTM D1319 %volume 7.5 Aniline Point ASTM D611 C Aniline Gravity Product ASTM D611, Calc (note 2) Arsenic (Note 3) ICP-MS wt ppb <10 Lead (Note 3) ICP-MS wt ppb <10 Ash Content ASTM D482 %mass Asphaltenes IP143 %mass 1.3 Carbon Residue - Micro ASTM D4530 %mass 5.9 Characterisation Factor UOP Colour Saybolt ASTM D Copper Strip Corrosion ASTM D130-1A 1A 1A Cetane Index ASTM D4737(proc. A) Cloud Point ASTM D2500 C -13 Colour - ASTM ASTM D <0.5 DHA ASTM D6730 %volume/%mass See appendix i See appendix ii Distillation ASTM D86 C See page 10 Freeze Point ASTM D2386 C Kinematic -20 C Kinematic 20 C ASTM D445 cst Kinematic 40 C Kinematic 50 C Metal - Nickel <1 1 Metal - Copper <1 <1 Metal - Iron ICPES wt ppm <1 1 Metal - Sodium <1 3 Metal - Vanadium <1 <1 Metal - Mercury (Note 3) UOP938 wt ppb <1 Naphthalenes ASTM D1840 %volume 0.14 Nitrogen - Basic UOP269 wt ppm 355 Nitrogen - Total ASTM D4629 wt ppm RON (Note 4) DHA Calc Pour Point - Upper ASTM D5853 C <-36 Pour Point ASTM D97 C Reid Vapour Pressure (Note 5) ASTM D323 psi 2.61 Salt Content ASTM D3230 PTB <1 Sediment by Extraction ASTM D473 %mass 0.04 Smoke Point ASTM D1322 mm 29.5 Sulphur - Mercaptan UOP163 wt ppm 2 1 <1 1 Sulphur - Total ASTM D5453 wt ppm 6.8 < Sulphur - Total IP 336 %mass Total Acid Number ASTM D664 mg KOH/g 0.10 < Water by Distillation ASTM D4006 %volume 0.00 Wax Content UOP46 %mass < NOTES: (1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150 C in proportion to their yields. (2) Aniline point not possible on the residue as sample matrix outside of instrument's scope. (3) Arsenic, Lead and Mercury values were determined on separate acid washed VOA vial samples supplied by the client. (4) Calculated DHA properties are indicative only and are not meant to replace values derived by relevant physical testing methods. (5) RVP was tested on a separate 1L bottle sample supplied by client. (6) LPG density is estimated and for indicative purpose only. Unable to perform actual analysis due to insuficient amount of fraction. Santos Mutineer Exeter Crude oil - Final Report.xls Page 1 of 11

5 Whole Properties of Crude Oil Report ID Crude ID Client ID Date Santos Limited 08-January-2015 Test Method Unit Simulated Distillation ASTM D LE - See page 3 C kg/l Specific F ASTM D API Gravity API 43.1 Arsenic (Note 3) ICP-MS wt ppb <10 Lead (Note 3) ICP-MS wt ppb <10 Characterisation Factor UOP Kinematic C Kinematic C ASTM D445 cst Kinematic C Metal - Nickel <1 Metal - Copper <1 Metal - Iron ICPES wt ppm <1 Metal - Sodium <1 Metal - Vanadium <1 Metal - Mercury (Note 3) UOP938 wt ppb <1 Nitrogen - Total ASTM D4629 wt ppm 107 Pour Point - Upper ASTM D5853 C <-36 Reid Vapour Presure (Note 5) ASTM D323 psi 2.61 Salt Content ASTM D3230 PTB <1 Sediment by Extraction ASTM D473 %mass 0.04 Sulphur - Mercaptan UOP163 wt ppm 2 Sulphur - Total IP336 %mass Total Acid Number ASTM D664 mg KOH/g 0.10 Water by Distillation ASTM D4006 %volume 0.00 Wax Content UOP46 %mass <5.0 NOTES: (3) Arsenic, Lead and Mercury values were determined on separate acid washed VOA vial samples supplied by the client. (5) RVP was tested on a separate 1L bottle sample supplied by client. Santos Mutineer Exeter Crude oil - Final Report.xls Page 2 of 11

6 Crude Name: Report ID: Sample Number: DISTILLATION OVERVIEW Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150 C in proportion to their yields Cumulative % Density API mass (kg/l) SG 60/60F Gravity %volume ASTM D2892 TBP DATA Cum. % volume Cum. Mid. %vol Temp C % mass Mid %vol (6) LPG density is estimated and for indicative purpose only. Unable to perform actual analysis due to insuficient amount of fraction. SIMDIS DATA temp C mass% temp C mass% temp C mass% Santos Mutineer Exeter Crude oil - Final Report.xls Page 3 of 11

7 Front End Overview REPORT ID: ASSET ID: Boiling Range Yield C mass% vol % LPG (C1-C5) C (Note 6) kg/l Specific F ISO API Gravity API Boiling Range C Yield mass% vol % C5-70C C kg/l Specific F D API Gravity API 84.3 Summary mass% vol% n-paraffins Iso-Paraffins Naphthenes Aromatics <0.010 <0.010 Olefins <0.010 <0.010 Unidentified <0.010 <0.010 DHA CALCULATED PROPERTIES** Average Molecular Weight : Relative Density: Octane Number: Boiling Range C C Yield mass% 22.9 vol % 25.2 C kg/l Specific F D API Gravity API 61.5 Summary mass% vol% n-paraffins Iso-Paraffins Naphthenes Aromatics Olefins <0.010 <0.010 Unidentified <0.010 <0.010 DHA CALCULATED PROPERTIES** Average Molecular Weight : Relative Density: Octane Number: **Calculated DHA properties are indicative only and are not meant to replace values derived by relevant physical testing methods (6) LPG density is estimated and for indicative purpose only. Unable to perform actual analysis due to insuficient amount of fraction. Santos Mutineer Exeter Crude oil - Final Report.xls Page 4 of 11

8 Temperature, o C TRUE BOILING POINT CURVE NOVEMBER Vol%-TBP Mass%-TBP Cumulative % Recovered Santos Mutineer Exeter Crude oil - Final Report.xls Page 5 of 11

9 API Gravity Graph of API vs Mid Volume NOVEMBER Cumulative Middle % Volume Santos Mutineer Exeter Crude oil - Final Report.xls Page 6 of 11

10 Temperature, o C Graph of True Boiling Point vs Simdis NOVEMBER mass%-tbp mass%-ht Simdis Cumulative % Recovered Santos Mutineer Exeter Crude oil - Final Report.xls Page 7 of 11

11 C5-70C C Properties of Naphtha Report ID Crude ID Client ID Date Santos Limited 08-January-2015 NAPHTHA Test Method Unit Fractional Distillation ASTM D2892 mass% vol% (Note 1) C kg/l Specific F ASTM D API Gravity API Copper Strip Corrosion, 50 C ASTM D130-1A RON (Note 4) Calc Sulphur - Mercaptan UOP 163 wt ppm 1 <1 Sulphur - Total ASTM D5453 wt ppm 6.8 <1.0 NOTES: (1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150 C in proportion to their yields. (4) Calculated DHA properties are indicative only and are not meant to replace values derived by relevant physical testing methods. Santos Mutineer Exeter Crude oil - Final Report.xls Page 8 of 11

12 C Properties of Kerosene Report ID Crude ID Client ID Date Santos Limited 08-January-2015 Kerosene Test Method Unit Fractional Distillation ASTM D2892 mass% 26.2 vol% (Note 1) 27.0 C kg/l Specific F ASTM D API Gravity API 48.0 Aromatics - FIA ASTM D1319 %volume 7.5 Aniline Point ASTM D611 C Aniline Gravity Product ASTM D611, Calc Colour Saybolt ASTM D Copper Strip Corrosion, 100 C ASTM D130-1A Freeze Point ASTM D2386 C Kinematic -20 C Kinematic 20 C ASTM D445 cst Kinematic 40 C Naphthalenes ASTM D1840 %volume 0.14 Smoke Point ASTM D1322 mm 29.5 Sulphur - Mercaptan UOP 163 wt ppm 1 Sulphur - Total ASTM D5453 wt ppm 17 Total Acid Number ASTM D664 mg KOH/g <0.10 Notes: (1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150 C in proportion to their yields. Santos Mutineer Exeter Crude oil - Final Report.xls Page 9 of 11

13 C Properties of Gas Oil Report ID Crude ID Client ID Date Santos Limited 08-January-2015 Gas Oil Test Fractional Distillation Method ASTM D2892 Unit mass% 32.7 vol% (note 1) 30.6 C kg/l Specific F ASTM D API Gravity API 31.7 Copper Strip Corrosion, 50 C ASTM D130-1A Cetane Index ASTM D4737(proc. A) Cloud Point ASTM D2500 C -13 Colour - ASTM ASTM D <0.5 Kinematic 20 C Kinematic 40 C ASTM D445 cst Kinematic 50 C Pour Point ASTM D97 C -12 Sulphur - Total ASTM D5453 wt ppm 273 Notes: (1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150 C in proportion to their yields. Test - LV% Method Unit C Distillation - IBP Distillation - 5% Distillation - 10% Distillation - 20% Distillation - 30% Distillation - 40% Distillation - 50% C Distillation - 60% ASTM D86 Distillation - 70% Distillation - 80% Distillation - 90% Distillation - 95% Distillation - FBP Distillation - Recovery 98.2 Distillation - Residue %volume 1.4 Distillation - Loss 0.4 Santos Mutineer Exeter Crude oil - Final Report.xls Page 10 of 11

14 360C+ Properties of Residue Report ID Crude ID Client ID Date Santos Limited 08-January-2015 Residue Test Method Unit Fractional Distillation ASTM D2892 mass% 14.1 vol% (note 1) 12.3 C kg/l Specific F IP API Gravity API 20.6 Aniline Point ASTM D611 C Aniline Gravity Product ASTM D611, Calc - Note 2 Ash ASTM D482 %mass Asphaltenes IP143 %mass 1.3 Carbon Residue - Micro ASTM D4530 %mass 5.9 Kinematic 50 C ASTM D445 cst Metal - Nickel 1 Metal - Copper <1 Metal - Iron ICPES wt ppm 1 Metal - Sodium 3 Metal - Vanadium <1 Nitrogen - Basic UOP269 wt ppm 355 Nitrogen - Total ASTM D4629 wt ppm 787 Pour Point ASTM D97 C +33 Sulphur - Total IP336 %mass 0.17 Total Acid Number ASTM D664 mg KOH/g 0.46 Wax Content UOP46 %mass 18.2 NOTES: (1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150 C in proportion to their yields. (2) Aniline point not possible on residue as sample matrix outside of instrument's scope. Santos Mutineer Exeter Crude oil - Final Report.xls Page 11 of 11

15 Detailed Hydrocarbon Analysis CRUDE ID: REPORT ID: Boiling Range C Yield mass% vol % C5-70C Component mass% vol% ethane propane n-butane ,2-dimethylpropane i-pentane n-pentane ,2-dimethylbutane cyclopentane ,3-dimethylbutane methylpentane methylpentane n-hexane ,2-dimethylpentane methylcyclopentane ,4-dimethylpentane ,2,3-trimethylbutane ,3-dimethylpentane cyclohexane methylhexane ,3-dimethylpentane ,1-dimethylcyclopentane methylhexane c,3-dimethylcyclopentane t,3-dimethylcyclopentane t,2-dimethylcyclopentane n-heptane methylcyclohexane Santos Mutineer Exeter Crude oil - Final Report.xls appendix i

16 CRUDE ID: REPORT ID: Boiling Range C Yield mass% vol % Class Summary mass% vol% n-paraffins Iso-Paraffins Naphthenes Aromatics <0.010 <0.010 Olefins <0.010 <0.010 Unidentified <0.010 <0.010 DHA CALCULATED PROPERTIES** Average Molecular Weight : Relative Density: Octane Number: C5-70C **Calculated DHA properties are indicative only and are not meant to replace values derived by relevant physical testing methods Santos Mutineer Exeter Crude oil - Final Report.xls appendix i

17 Detailed Hydrocarbon Analysis (continued) Boiling Range C5-70C CRUDE ID: Yield, mass% 4.0 REPORT ID: Yield, vol % 4.9 Totals by Group Type & Carbon Number (in Mass Percent) C1: n-paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total: C2: C3: C4: C5: C6: C7: C8: C9: C10: C11: C12: Total : Oxygenates: Total Heavies: Total Unknowns: Grand Total: Totals by Group Type & Carbon Number (in Volume Percent) C1: n-paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total: C2: C3: C4: C5: C6: C7: C8: C9: C10: C11: C12: Total : Oxygenates: Total Heavies: Total Unknowns: Grand Total: Santos Mutineer Exeter Crude oil - Final Report.xls appendix i

18 Detailed Hydrocarbon Analysis CRUDE ID: REPORT ID: Boiling Range C Yield mass% vol % C Component mass% vol% i-pentane n-pentane ,2-dimethylbutane ,3-dimethylbutane methylpentane methylpentane n-hexane ,2-dimethylpentane methylcyclopentane ,4-dimethylpentane ,2,3-trimethylbutane ,3-dimethylpentane cyclohexane methylhexane ,3-dimethylpentane ,1-dimethylcyclopentane methylhexane c,3-dimethylcyclopentane t,3-dimethylcyclopentane ethylpentane t,2-dimethylcyclopentane n-heptane methylcyclohexane ,1,3-trimethylcyclopentane ethylcyclopentane ,5-dimethylhexane ,4-dimethylhexane c,2t,4-trimethylcyclopentane ,3-dimethylhexane t,2c,3-trimethylcyclopentane ,3,4-trimethylpentane ,3,3-trimethylpentane toluene ,3-dimethylhexane methyl-3-ethylpentane methylheptane Santos Mutineer Exeter Crude oil - Final Report.xls appendix ii

19 Detailed Hydrocarbon Analysis (continued) CRUDE ID: REPORT ID: Boiling Range C Yield mass% vol % C Component mass% vol% 4-methylheptane ,4-dimethylhexane c,2c,4-trimethylcyclopentane c,3-dimethylcyclohexane methylheptane c,2t,3-trimethylcyclopentane ethylhexane ,1-dimethylcyclohexane ,2,5-trimethylhexane c-ethylmethylcyclopentane t-ethylmethylcyclopentane t-ethylmethylcyclopentane ,1-methylethylcyclopentane ,2,4-trimethylhexane n-octane ,4,4-trimethylhexane N c,2-dimethylcyclohexane ,3,5-trimethylhexane ,1,4-trimethylcyclohexane ,4-dimethylheptane ethylcyclohexane *1c,3c,5-trimethylcyclohexane ,3-dimethylheptane ,5-dimethylheptane ,1,3-trimethylcyclohexane ethylbenzene Ethybenzene c,2t,4t-trimethylcyclohexane I ,3-dimethylbenzene ,4-dimethylheptane* N ethylheptane c,2t,3-trimethylcyclohexane ethylheptane Santos Mutineer Exeter Crude oil - Final Report.xls appendix ii

20 Detailed Hydrocarbon Analysis (continued) CRUDE ID: REPORT ID: C Boiling Range Yield C mass% 22.9 vol % 25.2 Component mass% vol% 1c,2t,4c-trimethylcyclohexane ,1,2-trimethylcyclohexane I I n-nonane ,6-dimethyloctane Boiling Range C Yield mass% vol % Class Summary mass% vol% n-paraffins Iso-Paraffins Naphthenes Aromatics Olefins <0.010 <0.010 Unidentified <0.010 <0.010 DHA CALCULATED PROPERTIES** Average Molecular Weight : Relative Density: Octane Number: C **Calculated DHA properties are indicative only and are not meant to replace values derived by relevant physical testing methods Santos Mutineer Exeter Crude oil - Final Report.xls appendix ii

21 Boiling Range C CRUDE ID: Yield, mass% 22.9 REPORT ID: Yield, vol % 25.2 Totals by Group Type & Carbon Number (in Mass Percent) C1: C2: C3: C4: n-paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total: C5: C6: C7: C8: C9: C10: C11: C12: Total : Oxygenates: Total Heavies: Total Unknowns: Grand Total: Totals by Group Type & Carbon Number (in Volume Percent) C1: C2: C3: C4: n-paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total: C5: C6: C7: C8: C9: C10: C11: C12: Total : Oxygenates: Total Heavies: Total Unknowns: Grand Total: Santos Mutineer Exeter Crude oil - Final Report.xls appendix ii