Crude Assay Report. Crude Oil sample marked. Barrow Crude Oil. On Behalf Of. Chevron Australia Pty Ltd. Laboratory Supervisor. Crude Assay Chemist

Transcription

1 Crude Assay Report on Crude Oil sample marked Barrow Crude Oil On Behalf Of Chevron Australia Pty Ltd. Reported by: Approved by: Michelle Fernandez Laboratory Supervisor Jhonas Fernandez Crude Assay Chemist 2 Elder Road Largs North, South Australia, 5016 Australia Tel.: Fax.: adelaidelab@intertek.com

2 Barrow Crude Oil ex-eagle Tacoma INDEX Sl. No. Description Page No. 1 Description of sample 1 2 Detailed Assay All Cuts Overview 2 3 Summary of Whole Crude Oil Characteristics 3 4 True Boiling Point Distillation Data 4 5 Rapid Yield Simdis - Whole Crude Oil 5 6 True Boiling Point Distillation - Curve 6 7 Rapid Yield Simdis / True Boiling Point Curve 7 8 Summary of Product / Residue Cut Points & Yield 8 9 Fraction Analysis Residue Analysis ASTM D 86 - Distillation data Detailed Hydrocarbon Analysis 15-16

3 Date: July 14, 2017 Chevron Australia Pty Ltd. 250 St Georges Tce Perth WA 6831 Australia For the Attention of : Jody Rogers Sample(s) received from : Chevron Australia via Intertek-Perth Purchase Order No. (RFQ) : Not Supplied Sample(s) submitted as : Barrow Crude Oil Description(s) on Label(s) : Barrow Crude Oil ex-eagle Tacoma sampled on 29-May-2017 Seals on Sample(s) : None Sample(s) received on : June 8, 2017 The above sample(s) was/were examined as detailed below and the following results obtained: Please refer attached sheet for analytical results. Page 1

4 DETAILED ASSAY ALL CUTS OVERVIEW Barrow Crude Oil ex-eagle Tacoma TEST METHOD UNIT Whole Crude LPG Cut Range Initial BP C Final BP C Distillation of Crude Oil Yield % Wt ASTM D 2892 Yield % Vol C ASTM D 5002 / IP 365 / ASTM D4052 / ISO 8973 kg/l Specific 60/60 F Conversion API 60 F Calculated API Rapid Yield Simdis ASTM D7900/D7169 C Page 5 Aniline Point ASTM D611, Proc E C Aniline Gravity Product Calculated Aromatics - FIA ASTM D 1319 % Vol Arsenic Content (Note 1) ICP MS wt ppb 7 Ash Content ASTM D482 %mass Asphaltenes IP 143 %mass <0.50 <0.50 Carbon Content 87.9 ASTM D5291 %mass Hydrogen Content 11.5 Carbon Residue - Micro ASTM D4530 %mass Cetane Index ASTM D4737 A 38.0 UOP Characterization Factor UOP Chloride, Organic UOP 588 wt ppm <1 Cloud Point ASTM D2500 C -38 Color, ASTM ASTM D6045 Color, Saybolt Copper Corrosion ASTM D130-1a 1a 1a 1a Detailed Hydrocarbon Analysis (DHA) ASTM D6730 Page 15 Page 16 Distillation ASTM D86 Page 14 Freeze Point ASTM D2386 C <-60.0 Gross Heat of Combustion ASTM D 240 MJ/kg Kinematic -20 C Kinematic 20 C ASTM D 445 mm 2 /s Kinematic 40 C Kinematic 50 C Metals Lead <1 <1 Nickel <1 <1 Copper <1 <1 ASTM D5185 Mod mg/kg Iron <1 2.7 Sodium <1 1.3 Vanadium <1 7.9 Mercury (Note 1) UOP 938 ppb Wt <1 Naphthalene Content ASTM D 1840 Nitrogen - Basic UOP 269 Nitrogen - Total Octane Number- Research (RON) ASTM D5762 Calculated % Vol. mg/kg mg/kg Pour Point - Upper ASTM D5853 C < Pour Point ASTM D97 C <-36 9 Reid Vapour Pressure (Note 2) ASTM D323 kpa Salt Content ASTM D3230 PTB 0.5 Sediment By Extraction ASTM D473 %mass 0.03 Smoke Point ASTM D1322 mm 23.5 Sulphur - Mercaptan UOP 163 wt ppm Sulphur - Total ASTM D5453 mg/kg Sulphur - Total IP 336 %mass Total Acid Number ASTM D 664 mg KOH/g 0.10 < Water by Distillation ASTM D4006 % Vol. 0 Wax Content UOP 46 %mass <5.0 <5.0 Notes: 1) Arsenic and Mercury were tested on a sample contained in a VOA vial. 2) RVP was tested on a sample from a separate 1L bottle. Page 2

5 WHOLE CRUDE OIL PROPERTIES Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma 15 C ASTM D 5002 kg/l Specific 60/60 F Conversion API 60 F Calculated API 35.9 Rapid Yield Simdis ASTM D7900/D7169 C Page 5 Arsenic Content (Note 1) ICP MS wt ppb 7 Asphaltenes IP 143 %mass <0.50 Carbon Residue - Micro ASTM D4530 %mass 0.28 UOP Characterization Factor UOP Chloride, Organic UOP 588 wt ppm <1 Gross Heat of Combustion ASTM D 240 MJ/kg Kinematic 20 C Kinematic 40 C ASTM D 445 mm2/s Kinematic 50 C Metals TEST METHOD UNIT RESULT Lead <1 Nickel <1 Copper ASTM D5185 Mod mg/kg <1 Iron <1 Sodium <1 Vanadium <1 Mercury (Note 1) UOP 938 ppb Wt <1 Nitrogen - Basic UOP 269 mg/kg 94.2 Nitrogen - Total ASTM D5762 mg/kg 229 Pour Point - Upper ASTM D5853 C <-36 Reid Vapour Pressure (Note 2) ASTM D323 kpa Salt Content ASTM D3230 PTB 0.5 Sediment By Extraction ASTM D473 %mass 0.03 Sulphur - Mercaptan UOP 163 wt ppm 2 Sulphur - Total IP 336 %mass Total Acid Number ASTM D 664 mg KOH/g 0.10 Water by Distillation ASTM D4006 % Vol. 0 Wax Content UOP 46 %mass <5.0 Notes: 1) Arsenic and Mercury were tested on a sample contained in a VOA vial. 2) RVP was tested on a sample from a separate 1L bottle. Page 3

6 TRUE BOILING POINT DISTILLATION DATA (ASTM D 2892) Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma Vapour Temperature Sl. No. % mass Cumulative % mass % Volume C Cumulative % Volume 1 LPG Residue Page 4

7 Sample Descriptions / Label Barrow Crude Oil ex-eagle Tacoma LABORATORY REPORT NO PTAD RAPID YIELD SIMDIS DATA (ASTM D7900 & ASTM D7169) Sl. No. Temperature ( C) % mass Sl. No. Temperature ( C) % mass Sl. No. Temperature ( C) % mass Page 5

8 400 TRUE BOILING POINT DISTILLATION CURVE "Barrow Crude Oil" Temperature C Recovery % % Mass % Volume Page 6

9 460 RAPID YIELD SIMDIS / TRUE BOILING POINT DISTILLATION CURVE "Barrow Crude Oil" Temperature C Recovery % % Mass RY SIMDIS Page 7

10 SUMMARY OF PRODUCT / RESIDUE CUT POINTS AND YIELDS Sample Descriptions / Label: Barrow Crude Oil ex-eagle Tacoma Yield % Cut Points Barrow Crude Oil ex-eagle Tacoma ( C) % mass Volume % LPG < NAPHTHA KEROSENE GAS OIL RESIDUE Page 8

11 Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma Test Method Unit LPG Fraction mass% 1.1 Fractional Distillation ASTM D2892 vol% 1.7 C kg/l Specific F ISO API Gravity API Composition mass% vol% Ethane Propane n-butane Isobutane Trans-2-Butene <0.01 <0.01 ISO 7941 Isobutene <0.01 <0.01 n-pentane Isopentane ,2 - dimethylpropane C Page 9

12 Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma TEST METHOD UNIT Naphtha Fractions Initial BP C Final BP C Distillation of Crude Oil Yield % Wt ASTM D 2892 Yield % Vol C ASTM D 4052 kg/l Specific 60/60 F Conversion API 60 F Calculated API Copper Corrosion ASTM D130-1a 1a Detailed Hydrocarbon Analysis (DHA) ASTM D6730 Page 15 Page 16 Octane Number- Research (RON) Calculated Sulphur - Mercaptan UOP 163 wt ppm Sulphur - Total ASTM D5453 mg/kg Page 10

13 Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma TEST METHOD UNIT Kerosene Fractions Initial BP C 140 Final BP C 230 Distillation of Crude Oil Yield % Wt ASTM D 2892 Yield % Vol C ASTM D 4052 kg/l Specific 60/60 F Conversion API 60 F Calculated API 41.5 Aniline Point ASTM D611, Proc E C 51.1 Aniline Gravity Product Calculated Aromatics - FIA ASTM D 1319 % Vol Color, Saybolt Copper Corrosion ASTM D130-1a Freeze Point ASTM D2386 C <-60.0 Kinematic -20 C ASTM D 445 mm2/s Kinematic 20 C Naphthalene Content ASTM D 1840 % Vol Smoke Point ASTM D1322 mm 23.5 Sulphur - Mercaptan UOP 163 wt ppm 4.0 Sulphur - Total ASTM D5453 mg/kg 103 Total Acid Number ASTM D 664 mg KOH/g <0.10 Page 11

14 Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma TEST METHOD UNIT Gasoil Fraction Initial BP C 230 Final BP C 360 Distillation of Crude Oil Yield % Wt ASTM D 2892 Yield % Vol C ASTM D 4052 kg/l Specific 60/60 F Conversion API 60 F Calculated API 27.2 Cetane Index ASTM D4737 A 38.0 UOP Characterization Factor UOP Cloud Point ASTM D2500 C -38 Color, ASTM ASTM D Copper Corrosion ASTM D130-1a Distillation ASTM D86 C Page 14 Kinematic 40 C ASTM D 445 mm2/s Pour Point ASTM D97 C <-36 Sulphur - Total IP 336 %mass Total Acid Number ASTM D 664 mg KOH/g 0.10 Page 12

15 Sample Descriptions / Label: Barrow Crude Oil ex-eagle Tacoma TEST METHOD UNIT Residue Initial BP C 360+ Final BP C Distillation of Crude Oil Yield ASTM D 2892 % Wt Yield % Vol C IP 365 kg/l Specific 60/60 F Conversion API 60 F Calculated API 17.5 Aniline Point ASTM D611, Proc E C Aniline Gravity Product Calculated Ash Content ASTM D482 %mass Asphaltenes IP 143 %mass <0.50 Carbon Content ASTM D5291 %mass 87.9 Hydrogen Content %mass 11.5 Carbon Residue - Micro ASTM D4530 %mass 1.73 UOP Characterization Factor UOP Kinematic 50 C ASTM D 445 mm2/s Metals Lead <1 Nickel <1 Copper ASTM D5185 Mod mg/kg <1 Iron 2.7 Sodium 1.3 Vanadium 7.9 Nitrogen - Basic UOP 269 mg/kg 520 Nitrogen - Total ASTM D5762 mg/kg 1291 Pour Point ASTM D97 C 9 Sulphur - Total IP 336 %mass 0.16 Total Acid Number ASTM D 664 mg KOH/g 0.30 Wax Content UOP 46 %mass <5.0 Page 13

16 ASTM 86 - DISTILLATION DATA Sample Descriptions / Label : Barrow Crude Oil ex-eagle Tacoma Fractions Boiling range C Yield Wt. % 37.4 Vol.% 35.3 Initial boiling point C % recovered C % recovered C % recovered C % recovered C % recovered C % recovered C % recovered C % recovered C % recovered C % recovered C % recovered C Final Boiling Point C Volume recovered % Vol Residue % Vol. 1.2 Loss % Vol. 0.7 Page 14

17 DETAIL HYDROCARBON ANALYSIS Sample Descriptions / Label: Barrow Crude Oil ex-eagle Tacoma FRACTION C Totals by Group Type and Carbon Number (in Mass Percent) n-paraffins Iso-Paraffins Olefins Naphthenes Aromatics Total C3 C C C C7 C8 C9 C10 C11 Unknowns Total Totals by Group Type and Carbon Number (in Volume Percent) n-paraffins Iso-Paraffins Olefins Naphthenes Aromatics Total C3 C C C C7 C8 C9 C10 C11 Unknown Total Page 15

18 DETAIL HYDROCARBON ANALYSIS Sample Descriptions / Label: Barrow Crude Oil ex-eagle Tacoma FRACTION C Totals by Group Type and Carbon Number (in Mass Percent) n-paraffins Iso-Paraffins Olefins Naphthenes Aromatics Total C3 C C C C C8 C9 C10 C11 Unknown Total Totals by Group Type and Carbon Number (in Volume Percent) n-paraffins Iso-Paraffins Olefins Naphthenes Aromatics Total C3 C C C C C8 C9 C10 C11 Unknown Total Page 16