ASTM D2007M/ASTM D2549M In-house method/astm D6560/D3279

Transcription

1 ID Test Standard Amount Required Price for Cost Recovery Projects (Can $) Sulfur compounds distribution by boiling point (GC-SCD) Sulfur compound speciation by GC-SCD Nitrogen compounds distribution by boiling point (GC-NCD) Nitrogen compounds speciation by GC-NCD SARA (Asphaltene+ Saturates+Aromatics+Polars) 6 Asphaltenes (C5 or C7) 7 SOAP (Sat, Olefins, Arom, Polars) by SPE (Solid Phase Extraction) In-house method 2 g 396 In-house method 2 g by quotation In-house method 2 g 396 In-house method 2 g by quotation ASTM D2007M/ASTM D2549M In-house method/astm D6560/D g g 152 In-house method 1 ml SAP (Sat, Arom, Polars) by SPE In-house method 1 ml Total Olefins by SPE In-house method 1 ml Olefins distributed by boiling point (Separation by SPE +Sim Dist) 11 Hydrocarbon Types by SFC In-house method 1 ml 726 ASTM D5186/CGSB ml Hydrocarbon Types by FIA ASTM D ml Saturates/Mono/Di/Poly Aromatics by RI-HPLC (BP: C) Hydrocarbon Types ( C) by GC-MS (Olefins not included) Hydrocarbon Types ( C) by GC-MS (Olefins included) ASTM D6591Mod/IP-391 Modified ASTM D2007M or SAP/ASTM D2786/ASTM D3239 SOAP by SPE/ASTM D2786/ASTM D ml g g Hydrocarbon Types by GC-FIMS In-house method 1 ml by quotation 17 Naphthalenes by UV ASTM D Total Naphthenic Acids 19 Hydrocarbon Types Distribution by Boiling Point (by GC-SIMDIS- MS) (Olefins not included) In-house method by SPE- IR ASTM D2007M or SAP/ASTM D2786/D3239/D2887(X2)/ Calc 1 g + incl. Density info g g 1723

2 Hydrocarbon Types Distribution by Boiling Point (by GC-SIMDIS- MS) (Olefins included) Hydrocarbon Types by GC-MS Robinson Method Detailed Hydrocarbon Analysis (DHA) by High Resolution GC (RT-204 C) Hydrocarbon Types (RT-204 C) by PIONA (Without prefractionator) Hydrocarbon Types (RT-525 C) by PIONA (With prefractionator) SOAP by SPE/ASTM D2786/D3239/D2887(X3)/ Calc In-house method adapted from the Robinson Method CAN/CGSB-3.0 No M94 10 g ml ml 560 ASTM D ml 508 In-house method based on ASTM D6839/ASTM D ml H/C Ratio by GC-AED In-house method 2 ml Qualitative GC-MS (Capillary GC+MS identify major components) Quantitative GC-MS (SCAN or SIM with ISTD quantification of n compounds) In-house method 1 ml 304 In-house method 5 ml Distillation (atmospheric pressure) ASTM D ml ml charge) 500 g charge) 1000 g charge) 3000 g charge) Small Spinning Band Distillation (up to 3 liters, up to 5 cuts, up to 350 C) Large Spinning Band Distillation (up to 12 liters, up to 5 cuts, up to 350 C) 35 Distact (Short Path Distillation) ASTM D ml 714 ASTM D ml 873 ASTM D ml 1109 ASTM D ml 1443 In-house method up to 3.2 liters 1440 In-house method up to 13 liters 3485 KDT-6 from Chemtech Services Inc up to 10 liters 1440 (one cut) 36 TBP 15/5 Distillation (3 liters) ASTM D2892/D liters Dewatering for ASTM D2892/5236 High Volume (up to 3.2 liters, High Speed Sorvall Evol. RC Centr. 700 ml 792

3 CHN (Carbon, Hydrogen, Nitrogen) Total Sulfur (by XRF or Combustion/IR) Trace Sulfur (by GC-SCD or GC- AED, ppm) ASTM D5291 /(ASTM D5373) ASTM D4294/D1552/D g ml 107 ASTM D ml Elemental Sulphur GC-AED or SCD 1 ml Trace Nitrogen (by Chemiluminescence Detection) ASTM D ml Loss on ignition 2 g Metals by ICP-MS In-house method 100 g Chlorine in Crude Oil and Petroleum fractions (ASTM D86 Distillation, Potentiometric Titration of Chloride) Oxygen (by direct determination by Elementar Oxygen Analyzer) 47 Simulated Distillation by GC 48 Refinery Gas Analysis (gas bag) Refinery Gas Analysis-on line (24 hours monitoring) Photoacoustic FTIR Spectra (Far IR) Photoacoustic FTIR Spectra (Mid IR) Photoacoustic FTIR Spectra (Near IR) Dispersive Photoacoustic Spectra (UV/Vis) ASTM D4929 or in-house instrumental method In-house instrumental method ASTM D2887/D2887 Ext/D6352/D7169 Agilent 3000 Fast Micro GC Online Agilent 3000 Fast Micro GC 200 ml for D4929 or 2 ml for inhouse Instrum. method g ml ml IFS66v/s 10 mg 360 IFS88 10 mg 360 IFS88 10 mg 360 In-house 200 mg Dispersive Raman Spectra Renishaw 200 mg Fourier Transform Raman Spectra Bruker FRA mg Absorption Spectra (UV/Vis/NIR) Cary 5E 200 mg Transmission FTIR (Far IR) Transmission FTIR (Mid IR) IFS66v/s 1 g 360 IFS88 1 g 360

4 59 Transmission FTIR (Near IR) IFS88 1 g Quantum Cascade Laser PAS (Mid IR) Daylight Solutions (4.55um, 9.7um) 61 Fluorescence Spectrum In-house C Aromaticity 63 13C Spectrum 64 1H Spectrum 65 Olefin content by 1H NMR 66 Specialized NMR Services Inova 600 Mhz NMR Inova 600 Mhz NMR Inova 600 Mhz NMR Modified CAPP method with Inova 600 Mhz NMR 2-D experiments, carbon chemical functional group fingerprinting, etc g g g g by quotation 67 Aniline Point ASTM D ml Ash of coals/coke ASTM D g Ash of Petroleum Products ASTM D g Ash sulfated ASTM D g Bromine Number (BN) ASTM D g Catalyst Steaming ASTM D g Calorific Value ASTM D g Cetane number ASTM L Cloud Point ASTM D g Color ASTM D ml Copper Corrosion Test ASTM D ml Dean-Stark Soxholet extraction (large- 300 g) Dean-Stark Soxholet extraction (small-50 g) In-house method 300 g 290 In-house method 50 g Density of petroleum liquids ASTM D ml Density of Solids by He Pycnometer Density of viscous petroleum products ASTM D 2638 D g 144 ASTM D g Diene Value (MAV) UOP / UOP g Flash Point ASTM ml Freezing Point ASTM g 143

5 86 Insolubles, Pentane ASTM D g Insoluble, Hexane In-house method 5 g Insoluble, Heptane ASTM D g Insolubles, THF In-house method 5 g Insolubles, Toluene ASTM D g Mercaptan Sulfur in Distillates (up to 270 C) ASTM D g Micro Activity Test (MAT) ASTM D g Micro Carbon Residue (MCRT) ASTM D g Moisture of coals, coke, catalysts etc Moisture of crude oil by KF titration Molecular Weight of hydrocarbons by VPO Molecular Weight by Freezing Point Depression ASTM D g 46 ASTM D 4377/D g 121 ASTM D mg 218 In-house method 1 g Octane Number (Motor) ASTM D Liter Octane Number (Research) ASTM D Liter Penetration Point ASTM D 5 20 g Pour Point ASTM D g TGA: general In-house method 2 g TGA: FTIR In-house method 2 g Proximate Analysis of coals,coke, catalyst etc (moisture/ash/vol.matt.) ASTM D g Refractive Index ASTM D ml Reid Vapor Pressure ASTM D g Salt in Crude Oil ASTM D 6470M 40 g Shell Hot Filtration Test (SHFT) Shell SHFT 10 g Smoke Point ASTM D ml Softening Point ASTM D g Total Acid Number (TAN) ASTM D g Total Base Number (TBN) ASTM D g 137

6 Dynamic Viscosity (by Brookfield/Capillary/Stabinger viscometer) Water and Sediments in Fuel by Centrifuge ASTM D 5018/D544/D g 133 ASTM D ml Centrifugation (4X1 liter) Sorvall RC-3C Centrifuge up to 3 liter P-Value 20 g Wiehe Compatibility Test Wiehe method 20 g Fouling of Liquid Hydrocarbons Existent Gum in Fuel by Jet Evaporation Oxydation Stability of Gasoline (Induction Period Method) Oxydation Stability of Aviation Fuels (Potential Residue Method) Oxydation Stability of Distillate Fuel Oil (Accelerated Method) Thermal Oxyd. Stability of Aviat. Turbine Fuels (JFTOT) Distillate Fuel Storage Stability at 43 C Octel 180 or 90, 150 C Accelerated Fuel Oil Stability Test Density of Solids by He Pycnometer Particle Size Distribution by Laser Granulometry 128 BET Surface Area 129 BET Surface Area and Pore Size Distribution Alcor HLPS (Hot Liquid Process Simulator) 1 liter 1440 ASTM D g 172 ASTM D g 264 ASTM D g 330 ASTM D ml 482 ASTM D g 396 ASTM D g 508 ASTM D g 330 ASTM D2638 or D g 144 ASTM D4464/D197/C1070 In-house method by N2 adsorption with Micromeritics ASAP 2020 In-house method by N2 adsorption with Micromeritcs ASAP g mg mg 480