Polyamide 6 & 66 for Injection Moulding

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1 Polyamide 6 & 66 for Injection Moulding Promyde is a trademark of NUREL 1

Your Polyamide Service and Design Partner becoming part of your business With sophisticated laboratories for analysing both chemical and mechanical properties, along with parallel synergies

2 NUREL Engineering Polymers Polymerization Integrated into In-House Compounding 50 years experience in polymerization processes and brand new investments in state-of-the-art compound extrusion enables us to improve and widen our polyamide offer with increased capacity of PA6 & PA66 compounds for all polyamide markets involving new and exciting products and partnerships. Your Polyamide Service and Design Partner becoming part of your business With sophisticated laboratories for analysing both chemical and mechanical properties, along with parallel synergies with other polymerization companies within The SAMCA Group, NUREL can take customer requests for new developments from laboratory stages to full scale industrial production in months. Why not ask us? Promyde Polyamide 6 & 66 Promyde is processed by injection moulding and extrusion to produce parts and components for electrical and electronics, automotive and general industry combining cost effectiveness with performance. Your local supply of Promyde NUREL has a PAN European distribution network giving a broad offer of polyamide, technical advice and a quick delivery service. 2

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4 Promyde Product Overview Unreinforced PA 6 Unreinforced Promyde is produced in NUREL s polymerization process in which unique additivation packages and polymer chain modifications are made combining cost effectiveness and differential properties. Customers receive Promyde unreinforced polyamide 6 in its purest state. Promyde unreinforced products are melted for the first time in our customer s injection moulding machines. Hence, optimizing processing and performance. Promyde Unreinforced Polyamide 6 Overview Multi Purpose Fast Injection B300 P Extremely High Flowing for design innovation, for very small pieces. Also to aid production of large parts in smaller machines. UL Certified. B15 P For very fast multi cavity moulding of small parts. UL Certified. B20 P For precise technical moulding of both large or small parts. UL Certified. B30 P Wide processing window for general purpose unreinforced applications. B30 P is UL Certified with a Glow Wire Flamability Index 850ºC applicable for electrical parts. UL Certified. B30 PN Non nucleated with slightly improved impact resistance over B30 P. Excellent colourability. UL Certified. B35 P For Injection of thick wall parts, for example, thick chains or wheels. UL Certified. B930 P For transparent applications requiring chemical resistance and mechanical strength. High Viscosity Polyamide B33 BR1 For strong wheels and castors required to lift heavy loads. B36 BR1 High viscosity injection moulding grade. B38 BR1 For wheels and other thick walled parts. B40 BR1 High viscosity injection moulding grade suitable for both small and large heavy duty wheels. Impact Modified B30 P MID Injection of wall plugs, fixing systems and other applications. A combination of flexibility and resistance to breakage by impact. Also useful in over moulding. B30 P2 HI B30 P2 HI C B30 P2 HI 60 For applications requiring extra resistance to breakage by impact. For extra high impact resistance is in freezing cold temperatures over -30ºC. For example ski wear and auto shock absorbers. For impact resistance for Charpy 60 and below. Flame Retardant B15 U For small electrical parts. Glow Wire Flammability Index 960ºC. UL Certified. B30 U For natural and coloured electrical parts requiring a Glow Wire Flammability Index of 960ºC. UL certified. B30 P2 U0 For standard unfilled V0 requests. UL certified. 4

Promyde Product Overview: Reinforced PA 6 & 66 NUREL s offer for PA 6 & PA 66

processing & smooth surface appearance High Flow All our reinforced grades

and high impact resistant products Flame Retardant and Self Extinguishing For

5 Promyde Product Overview: Reinforced PA 6 & 66 NUREL s offer for PA 6 & PA 66 compounds guarantees that our customers receive consistency in processing and product behaviour. Promyde reinforced products include: 10-60% Glass Filled Excellent flow processing & smooth surface appearance High Flow All our reinforced grades are also available with a high flow polymer base Impact Modified Both medium and high impact resistant products Flame Retardant and Self Extinguishing For electrical and electronics 30% & 40% Mineral Filled For extra flatness Colouring In RAL colour cards and customized colour matching under demand 5

NUREL High Flow Polyamides High Flowing PA 6 - B300 Types Promyde High Flow B300 product

PAs, to achieve an easier and smoother injection process.

earlier Remarkable Cycle Time improvement Cooler more fluid processing improves output.

temperatures permits the use of smaller machines Make smoother parts.

6 NUREL High Flow Polyamides High Flowing PA 6 - B300 Types Promyde High Flow B300 product range, includes unreinforced and 15-60% Glass filled references along with other reinforced PAs, to achieve an easier and smoother injection process. Processing at 30ºC to 45ºC lower temperature Polymer enters mould cooler and is released earlier Remarkable Cycle Time improvement Cooler more fluid processing improves output. Reduces cycle time by 30% Reduce Clamp Force significantly Process at your regular temperatures permits the use of smaller machines Make smoother parts. Improve surface finish Outstanding surface finish up to 60% glass content Innovative design is permitted Extremely small and intricate parts can be designed with Promyde B300 6

Comparative Moldflow Study A simulation of a technical part benefitting from injection with Promyde B300 P2 G30 is compared to a conventional PA6 + 30% glass fiber from a market leader.

812 Process at 250ºC, improve cycle time by 30% Setting the temperature 45ºC lower with Promyde B300 P2 G30 than the competitor s result in: The same clamp force for both materials Promyde cools 30%

7 Comparative Moldflow Study A simulation of a technical part benefitting from injection with Promyde B300 P2 G30 is compared to a conventional PA6 + 30% glass fiber from a market leader. Simulation of Automobile Front Bumper with two injection inlets Filling time programmed: 3.65s (s) Process at 250ºC, improve cycle time by 30% Setting the temperature 45ºC lower with Promyde B300 P2 G30 than the competitor s result in: The same clamp force for both materials Promyde cools 30% faster Not only saving energy, but also increasing productivity. Filling Temperature: 250ºC Promyde B300 P2 G30 / 295ºC Competitor PA6 G Clamp force is reduced by 30% with Promyde Both materials are programmed with the same temperature, time and holding pressure. The clamp force is reduced by 30% with Promyde. Thus smaller injection machine can be used, enhancing cost effectiveness. Reduction in Clamping Force Tones Promyde B300 P2 G Competitors PA6 G30 Melt Temperature 270ºC Holding press 80MPa (15s) (C) (C) Promyde B300 P2 G30 20s* * Time to reach ejection temperature Competitor s PA6 G30 29s* * Time to reach ejection temperature 7

8 Polyamide Weight Reduction Solutions Lightweight materials have always been an important topic in product design across several industries. The concept has been most important in aviation and automotive as a strategy to significantly reduce fuel consumption and CO 2 emissions. NUREL offers different solutions on its weight reduction portfolio. Nano Clay Fortifed Polyamide 6 We take special clay and exfoliate it in nano size particles which are then chemically bonded to the polymer matrix. Nano Clay benefits B30 NC 100 is 17% lighter than 30% mineral filled and glass bead filled PA Mechanical performance is maintained against PA6 & PA66 compounds 1,4 1,35 1,3 1,25 1,2 1,15 1,1 Besides these benefits Nanoclay has light 1,05 blocking properties 1 Density (g/ml) B30 NC100 PA6 30 GB PA6 30 M PA66 30 GB PA66 30 M Stress at Break Promyde B30 NC100 vs Mineral filled and Glass beads reinforced PA 6 Stress at Break Promyde B30 NC100 vs Mineral filled and Glass beads reinforced PA Stress at Break (MPa) Stress at Break (MPa) B30 NC100 PA6 30 GB PA6 30 M PA6 40 M PA6 10 GF+ 20 GB PA6 30 (GF+M) 0 B30 NC100 PA66 40 M PA66 30 M PA66 GB 30 PA66 GB 40 8

Promyde reinforced solutions Glass fibers & Glass beads 10% Reduced Density in Glass Filled PA6 B30 P2 G25 WR is our new proposal for weight reduction where conventional PA with 25-30%GF can be

reduction is a need. Flexural Modulus (MPa) Flexural Strenght (MPa) Charpy Impact CE 23ºC Density g/cm 3 Weight Reduction % ISO 178 ISO 178 ISO 179/1eU ISO 1183 - B300 P2 G20 M15 8,437 181.5 4.

9 Promyde reinforced solutions Glass fibers & Glass beads 10% Reduced Density in Glass Filled PA6 B30 P2 G25 WR is our new proposal for weight reduction where conventional PA with 25-30%GF can be substituted for a lighter weight alternative. Tensile Modulus MPa HDT ºC Density g/cm 3 ISO 527-1/-2 ISO 75-1/-2 ISO 1183 B30 P2 G30 9, B30 P2 G25 8, B30 P2 G25 WR 7, % Weight reduction in Glass & Mineral Filled compounds A combination of both above technologies can provide further weight reduction up to 20% for applications where mechanical and weight reduction is a need. Flexural Modulus (MPa) Flexural Strenght (MPa) Charpy Impact CE 23ºC Density g/cm 3 Weight Reduction % ISO 178 ISO 178 ISO 179/1eU ISO B300 P2 G20 M15 8, B300 P2 G16 HB M15 8, New developments with natural fibers The NEW natural fiber-reinforced Promyde range offers PA compounds with a considerable weight reduction, superior thermal resistance and a renewable content from 15 to 30%. Tensile Modulus MPa HDT ºC Density g/cm 3 ISO 527-1/-2 ISO 75-1/-2 ISO 1183 B300 P2 NF 5, B30 P2 M30 5,

Made to Measure Developments Responding to modern consumer tendencies In touch with current market trends via other activities within the SAMCA Group, such as ceramic

Improved transparency with Promyde Recent market requests, asking for transparent polyamides, have coincided with NUREL s continued development program.

B930 P is a semi-crystalline polymer. It is only recommended for applications under 60ºC and up to 2 mm thick.

10 Made to Measure Developments Responding to modern consumer tendencies In touch with current market trends via other activities within the SAMCA Group, such as ceramic sciences, and conductive technologies, we can modify polymer crystalation capabilities and also conductive properties to respond to specific modern requirements. Improved transparency with Promyde Recent market requests, asking for transparent polyamides, have coincided with NUREL s continued development program. Promyde B930 P is available upon request for applications where extra transparency is desired over conventional Polyamide 6 applications. B930 P is a semi-crystalline polymer. It is only recommended for applications under 60ºC and up to 2 mm thick. Main applications include: Automotive applications can be used for decorative surfaces and liquid level indicators Window and inspection glasses, flow meters Ink cartridges for printers % Haze ASTMD1003 (1,5mm; Mould Temperature: 30 ºC) Transparent PA Promyde B930 P 10

Conductive compounds adjustable to your needs In response to a growing demand in the electrical, electronic and automotive sectors, where weight limitation and design requirements are becoming

Thanks to our extensive knowledge in polymerization as well as in nanotechnology, we have been able to increase the electrical and thermal conductivity of PA6.

11 Conductive compounds adjustable to your needs In response to a growing demand in the electrical, electronic and automotive sectors, where weight limitation and design requirements are becoming stronger, NUREL works in the development of new materials with controlled thermal and electrical properties. Thanks to our extensive knowledge in polymerization as well as in nanotechnology, we have been able to increase the electrical and thermal conductivity of PA6. Electrical conductivity Currently we can offer PA6 polymers with wide range of electrical conductivity, from antistatic grades to highly conductive grades (from 10 to 10 ^ 12 Ohm), with the possibility of being coloured. Electrical conductive compounds are used for applications such as electrostatic painting parts, very fine electronic parts or electrostatic surfaces for medical applications. Thermal conductivity NUREL offers the possibility of adding heat-conducting properties to our polymers to help dissipate the heat caused by electrical and electronic circuits. Our new range of Promyde PA6 compounds can reach values of thermal conductivity of between 2 to 10 W / mk, offering a wide range of products for black or also for coloured parts. The thermo-conductive plastics can obtain a considerable reduction of weight thanks to the substitution of metallic pieces. Thermoconductive materials are mainly used for heat sinks in electric motors, circuits or lamps. 11

12 Promyde Polyamide 6 Unreinforced PHYSICAL PROPERTIES CONDITIONS TEST METHOD UNIT Density 23 ºC ISO 1183 g/cm 3 Viscosity Number 25 ºC ISO 307 cm 3 /g Moisture absorption 23 ºC/50% r.h. ISO 62 % Water absorption 23 ºC/saturation ISO 62 % Flammability 1.5 mm UL-94 Class Glow wire flammability index 1.5 mm IEC ,12 ºC Glow wire ignitability temperature 1.5 mm IEC ,12 ºC PROCESSING CONDITIONS Melt Volume rate 275 ºC / 5 kg ISO 1133 cm 3 /10min Melt temperature, injection moulding ºC Mould temperature ºC Mould Shrinkage longitudinal % transversal % MECHANICAL PROPERTIES (dry/cond.)* Tensile modulus 23 ºC, 1 mm/min ISO 527-1/-2 MPa Tensile strength 23 ºC, 50 mm/min ISO 527-1/-2 MPa Elongation at yield 23 ºC, 50 mm/min ISO 527-1/-2 % Elongation at break 23 ºC, 50 mm/min ISO 527-1/-2 % Flexural modulus 23 ºC, 2 mm/min ISO 178 MPa Flexural strength 23 ºC, 2 mm/min ISO 178 MPa Charpy unnotched impact strength 1) 23 ºC -30 ºC ISO 179/1eU kj/m 2 Charpy notched impact strength 23 ºC -30 ºC ISO 179/1eU kj/m 2 THERMAL PROPERTIES Melting temperature (DSC) 10 ºC/min ISO 3146 ºC Heat Deflection Temperature (HDT) 1,8 MPa 0,45 MPa ISO 75-1/-2 ºC Thermal coefficient of linear expasion ºC long ºC transv. ISO / /k ELECTRICAL PROPERTIES (dry/cond.)* Dielectric constant 1MHz ISO Dissipation factor 1MHz ISO Volume resistivity ISO Ω.m Surface resistivity ISO Ω Comparative tracking index ISO UNREINFORCED B15 P B20 P V-2 V ,300 / 1,100 3,300 / 1, / / / / / > / > 50 2,800 / 1,000 2,800 / 1, / / 30 NB / NB NB / NB / / / / / 3, / 3, / / / / ) NB: No break. * dry = dry as moulded / cond. = conditioned according to ISO

13 UNREINFORCED B30 P B30 PN B35 P B33 BR1 B36 BR1 B40 BR1 B930 P V-2 V-2 V-2 V-2 V-2 V-2 V ,300 / 1,100 3,200 / 1,100 3,300 / 1,100 3,400 / 1,100 3,400 / 1,100 3,400 / 1,100 2,600 / 1, / / / / / / / / / / / / / / / > / > / > / > / > / > / >50 2,800 / 1,000 2,700 / 1,000 2,800 / 1,000 2,900 / 1,000 2,800 / 1,000 2,900 / 1,000 2,500 / 1, / / / / / / / 30 NB / NB NB / NB NB / NB NB / NB NB / NB NB / NB 95 / NB / / / / / / / / / / / / / / / 3, / 3, / 3, / 3, / 3, / 3, / 3, / / / / / / / / / / / / / / DISCLAIMER: Values have been established by standard tests. The data should be considered as a guide and not as binding minimum values. Because may factors affect processing or applications, we recommend that individual tests are performed to determine the suitability of the product use. 13

14 Promyde Polyamide 6 Reinforced PHYSICAL PROPERTIES CONDITIONS TEST METHOD UNIT Density 23 ºC ISO 1183 g/cm 3 Viscosity Number 25 ºC ISO 307 cm 3 /g Moisture absorption 23 ºC/50% r.h. ISO 62 % Water absorption 23 ºC/saturation ISO 62 % Flammability 1.5 mm UL-94 Class Glow wire flammability index 1.5 mm IEC ,12 ºC Glow wire ignitability temperature 1.5 mm IEC ,12 ºC PROCESSING CONDITIONS Melt Volume rate 275 ºC / 5 kg ISO 1133 cm 3 /10min Melt temperature, injection moulding ºC Mould temperature ºC Mould Shrinkage longitudinal % transversal % MECHANICAL PROPERTIES (dry/cond.)* Tensile modulus 23 ºC, 1 mm/min ISO 527-1/-2 MPa Tensile strength 23 ºC, 50 mm/min ISO 527-1/-2 MPa Elongation at yield 23 ºC, 50 mm/min ISO 527-1/-2 % Elongation at break 23 ºC, 50 mm/min ISO 527-1/-2 % Flexural modulus 23 ºC, 2 mm/min ISO 178 MPa Flexural strength 23 ºC, 2 mm/min ISO 178 MPa Charpy unnotched impact strength 1) 23 ºC -30 ºC ISO 179/1eU kj/m 2 Charpy notched impact strength 23 ºC -30 ºC ISO 179/1eU kj/m 2 THERMAL PROPERTIES Melting temperature (DSC) 10 ºC/min ISO 3146 ºC Heat Deflection Temperature (HDT) 1,8 MPa 0,45 MPa ISO 75-1/-2 ºC Thermal coefficient of linear expasion ºC long ºC transv. ISO / /k ELECTRICAL PROPERTIES (dry/cond.)* Dielectric constant 1MHz ISO Dissipation factor 1MHz ISO Volume resistivity ISO Ω.m Surface resistivity ISO Ω Comparative tracking index ISO REINFORCED B30 P2 G10 B30 P2 G15 B30 P2 G HB HB HB ,500 / 2,700 6,000 / 3,400 6,500 / 4, / / / 85 - / - - / - - / / / / 6.5 4,300 / 2,400 5,000 / 2,400 5,500 / 3, / / / - 40 / / / / / / / / / / 2, / 2, / 2, / / / / / / ) NB: No break. * dry = dry as moulded / cond. = conditioned according to ISO

15 REINFORCED B30 P2 G30 B30 P2 G35 B30 P2 G40 B30 P2 G50 B30 P2 GFC15 B30 P2 GFC30 B30 P2 GB30 B30 P2 M30 B30 P2 M HB HB HB HB HB HB HB HB HB / - - / / - - / - 9,300 / 6,200 11,000 / 7,500 13,000 / 8,500 15,600 / 10,000 6,000 / 3,400 9,300 / 6,200 4,400 / 1,900 5,200 / 2,000 6,000 / 3, / / / / / / / / / 60 - / - - / - - / - - / - - / - - / - - / - - / - - / / / / / / / / / / 7.0 8,000 / 5,100 9,500 / 6,000 10,600 / 6,500 14,000 / 8,000 5,000 / 2,400 8,000 / 5,100 4,000 / 1,700 3,900 / 2,000 5,500 / 2, / / / / / / / / / / / / / / / / 75 - / - - / / / / / / / / / / / / / / / / / / / / 2, / 2, / 1, / 1, / 2, / 2, / 2, / 2, / 1, / / / / / / / / / / / / / / / / / / DISCLAIMER: Values have been established by standard tests. The data should be considered as a guide and not as binding minimum values. Because may factors affect processing or applications, we recommend that individual tests are performed to determine the suitability of the product use. 15

16 Promyde Polyamide 6 Impact Modified PHYSICAL PROPERTIES CONDITIONS TEST METHOD UNIT Density 23 ºC ISO 1183 g/cm 3 Viscosity Number 25 ºC ISO 307 cm 3 /g Moisture absorption 23 ºC/50% r.h. ISO 62 % Water absorption 23 ºC/saturation ISO 62 % Flammability 1.5 mm UL-94 Class Glow wire flammability index 1.5 mm IEC ,12 ºC Glow wire ignitability temperature 1.5 mm IEC ,12 ºC PROCESSING CONDITIONS Melt Volume rate 275 ºC / 5 kg ISO 1133 cm 3 /10min Melt temperature, injection moulding ºC Mould temperature ºC Mould Shrinkage longitudinal % transversal % MECHANICAL PROPERTIES (dry/cond.)* Tensile modulus 23 ºC, 1 mm/min ISO 527-1/-2 MPa Tensile strength 23 ºC, 50 mm/min ISO 527-1/-2 MPa Elongation at yield 23 ºC, 50 mm/min ISO 527-1/-2 % Elongation at break 23 ºC, 50 mm/min ISO 527-1/-2 % Flexural modulus 23 ºC, 2 mm/min ISO 178 MPa Flexural strength 23 ºC, 2 mm/min ISO 178 MPa Charpy unnotched impact strength 1) 23 ºC -30 ºC ISO 179/1eU kj/m 2 Charpy notched impact strength 23 ºC -30 ºC ISO 179/1eU kj/m 2 THERMAL PROPERTIES Melting temperature (DSC) 10 ºC/min ISO 3146 ºC Heat Deflection Temperature (HDT) 1,8 MPa 0,45 MPa ISO 75-1/-2 ºC Thermal coefficient of linear expasion ºC long ºC transv. ISO / /k ELECTRICAL PROPERTIES (dry/cond.)* Dielectric constant 1MHz ISO Dissipation factor 1MHz ISO Volume resistivity ISO Ω.m Surface resistivity ISO Ω Comparative tracking index ISO IMPACT MODIFIED B30 P MI D B30 P2 MI B30 P2 HI HB HB HB ,800 / 1,100 2,800 / 1,100 2,100/1, / / / / 25 5 / / / / / > 50 2,400 / 700 2,300 / 750 1,700 / / / / 35 NB / NB NB / NB NB / NB - NB NB 13 / NB 14 / NB** 65 / / / / / 2, / 3, / 1, / / / / / / ) NB: No break. * dry = dry as moulded / cond. = conditioned according to ISO ** measured with 2-Joule pendulum. 16

17 IMPACT MODIFIED B30 P2 HI B30 P2 HIC B30 P2 G10 MI B30 P2 G15 MI B30 P2 G15 MIC B30 P2 G30 MI B30 P2 G40 MI B30 P2 G45 MI HB HB HB HB HB HB HB HB ,200 / 1,100 2,000 / 1,000 4,000 / 2,500 4,500 / 2,400 4,100 / 2,000 9,000 / 6,000 11,000 / 6,200 14,300 / 9, / / / / / / / / / / 35 - / - - / - - / - - / - - / - - / - 35 / > / > / / - 10 / / / / 8.0 1,700 / 400 1,700 / 400 4,100 / 2,300 3,900 / 2,000 3,600 / 1,900 7,500 / 4,000 9,500 / 6,000 11,900 / 7, / / / / / / / / 150 NB / NB NB / NB 60 / / / / / / 120 NB NB / / NB 10 / / / / / / / / / / / / / / / 2, / 2, / 2, / 2, / 2, / 2, / 2, / 1, / / / / / / / / / / / / / / / / DISCLAIMER: Values have been established by standard tests. The data should be considered as a guide and not as binding minimum values. Because may factors affect processing or applications, we recommend that individual tests are performed to determine the suitability of the product use. 17

18 Promyde Polyamide 6 High Flow PHYSICAL PROPERTIES CONDITIONS TEST METHOD UNIT Density 23 ºC ISO 1183 g/cm 3 Viscosity Number 25 ºC ISO 307 cm 3 /g Moisture absorption 23 ºC/50% r.h. ISO 62 % Water absorption 23 ºC/saturation ISO 62 % Flammability 1.5 mm UL-94 Class Glow wire flammability index 1.5 mm IEC ,12 ºC Glow wire ignitability temperature 1.5 mm IEC ,12 ºC PROCESSING CONDITIONS Melt Volume rate 275 ºC / 5 kg ISO 1133 cm 3 /10min Melt temperature, injection moulding ºC Mould temperature ºC Mould Shrinkage longitudinal % transversal % MECHANICAL PROPERTIES (dry/cond.)* Tensile modulus 23 ºC, 1 mm/min ISO 527-1/-2 MPa Tensile strength 23 ºC, 50 mm/min ISO 527-1/-2 MPa Elongation at yield 23 ºC, 50 mm/min ISO 527-1/-2 % Elongation at break 23 ºC, 50 mm/min ISO 527-1/-2 % Flexural modulus 23 ºC, 2 mm/min ISO 178 MPa Flexural strength 23 ºC, 2 mm/min ISO 178 MPa Charpy unnotched impact strength 1) 23 ºC -30 ºC ISO 179/1eU kj/m 2 Charpy notched impact strength 23 ºC -30 ºC ISO 179/1eU kj/m 2 THERMAL PROPERTIES Melting temperature (DSC) 10 ºC/min ISO 3146 ºC Heat Deflection Temperature (HDT) 1,8 MPa 0,45 MPa ISO 75-1/-2 ºC Thermal coefficient of linear ºC long. expasion ºC transv. ISO / /k ELECTRICAL PROPERTIES (dry/cond.)* Dielectric constant 1MHz ISO Dissipation factor 1MHz ISO Volume resistivity ISO Ω.m Surface resistivity ISO Ω Comparative tracking index ISO HIGH FLOW B300 P B300 P2 G20 M15 B300 P2 G30 B300 P2 G V-2 HB HB HB > ,200 / 1,100 9,500 / 5,500 9,900 / 6,700 14,500 / 8, / / / / / 25 - / - - / - - / - 10 / > / / / 3.5 2,800 / 1,000 8,400 / 4,500 8,400 / 5,200 12,000 / 3, / / / / 200 NB / NB 70 / / / / / / / / / / / / 3, / 2, / 2, / 1, / / / / / / / / ) NB: No break. * dry = dry as moulded / cond. = conditioned according to ISO

19 HIGH FLOW B300 P2 G50 B300 P2 G50 S B300 P2 G60 B300 P2 G60 S B300 P2 GFC15 B300 P2 GFC30 B300 P2 GFC50 B300 P2 M HB HB HB HB HB HB HB HB / / - 17,000 / 10,000 17,000 / 10,000 21,000 / 17,000 21,000 / 17,000 6,000 / 3,400 9,900 / 6,700 17,000 / 10,000 6,600 / 3, / / / / / / / / 60 - / - - / - - / - - / - - / - - / - - / - - / / / / / / / / / ,500 / 8,500 15,500 / 8,500 19,700 / 14,400 19,700 / 14,400 5,700 / 2,800 8,400 / 5,200 15,500 / 8,500 6,300 / 3, / / / / / / / / / / / / / / /130 - / /30 20/30 18 / / / / 25 20/ / / / / / / / / 1, / 1, / 2, / 2, / 1, / 1, / / / / / / / / / / / / / / / / DISCLAIMER: Values have been established by standard tests. The data should be considered as a guide and not as binding minimum values. Because may factors affect processing or applications, we recommend that individual tests are performed to determine the suitability of the product use. 19

20 Promyde Polyamide 6 Flame Retardant PHYSICAL PROPERTIES CONDITIONS TEST METHOD UNIT Density 23 ºC ISO 1183 g/cm 3 Viscosity Number 25 ºC ISO 307 cm 3 /g Moisture absorption 23 ºC/50% r.h. ISO 62 % Water absorption 23 ºC/saturation ISO 62 % Flammability 1.5 mm UL-94 Class Glow wire flammability index 1.5 mm IEC ,12 ºC Glow wire ignitability temperature 1.5 mm IEC ,12 ºC PROCESSING CONDITIONS Melt Volume rate 275 ºC / 5 kg ISO 1133 cm 3 /10min Melt temperature, injection moulding ºC Mould temperature ºC Mould Shrinkage longitudinal % transversal % MECHANICAL PROPERTIES (dry/cond.)* Tensile modulus 23 ºC, 1 mm/min ISO 527-1/-2 MPa Tensile strength 23 ºC, 50 mm/min ISO 527-1/-2 MPa Elongation at yield 23 ºC, 50 mm/min ISO 527-1/-2 % Elongation at break 23 ºC, 50 mm/min ISO 527-1/-2 % Flexural modulus 23 ºC, 2 mm/min ISO 178 MPa Flexural strength 23 ºC, 2 mm/min ISO 178 MPa Charpy unnotched impact strength 1) 23 ºC -30 ºC ISO 179/1eU kj/m 2 Charpy notched impact strength 23 ºC -30 ºC ISO 179/1eU kj/m 2 THERMAL PROPERTIES Melting temperature (DSC) 10 ºC/min ISO 3146 ºC Heat Deflection Temperature (HDT) 1,8 MPa 0,45 MPa ISO 75-1/-2 ºC Thermal coefficient of linear expasion ºC long ºC transv. ISO / /k ELECTRICAL PROPERTIES (dry/cond.)* Dielectric constant 1MHz ISO Dissipation factor 1MHz ISO Volume resistivity ISO Ω.m Surface resistivity ISO Ω Comparative tracking index ISO FLAME RETARDANT B15 U V ,300 / 1, / / / > 50 2,800 / 1, / 30 NB / NB / / / 3, / / ) NB: No break. * dry = dry as moulded / cond. = conditioned according to ISO

21 FLAME RETARDANT B30 U B30 P2 U0 B30 P2 G20 U0 B300 P2 G30 U V-2 V-0 V-0 V ,300 / 1,100 3,800/1,500 8,300 / 5,000 9,900 / 6, / / / / / / 25 - / - - / - 18 / > 50 9 / > / / 6 2,800 / 1,000 3,400 / 1,200 7,200 / 3,500 9,300 / 5, / / / / 80 NB / NB 60 / - 60 / / / / / / / / / / / 3, / 3, / 2, / 2, / / / / / / / / DISCLAIMER: Values have been established by standard tests. The data should be considered as a guide and not as binding minimum values. Because may factors affect processing or applications, we recommend that individual tests are performed to determine the suitability of the product use. 21

22 Promyde Polyamide 6 Weight Reduction PHYSICAL PROPERTIES CONDITIONS TEST METHOD UNIT Density 23 ºC ISO 1183 g/cm 3 Viscosity Number 25 ºC ISO 307 cm 3 /g Moisture absorption 23 ºC/50% r.h. ISO 62 % Water absorption 23 ºC/saturation ISO 62 % Flammability 1.5 mm UL-94 Class Glow wire flammability index 1.5 mm IEC ,12 ºC Glow wire ignitability temperature 1.5 mm IEC ,12 ºC PROCESSING CONDITIONS Melt Volume rate 275 ºC / 5 kg ISO 1133 cm 3 /10min Melt temperature, injection moulding ºC Mould temperature ºC Mould Shrinkage longitudinal % transversal % MECHANICAL PROPERTIES (dry/cond.)* Tensile modulus 23 ºC, 1 mm/min ISO 527-1/-2 MPa Tensile strength 23 ºC, 50 mm/min ISO 527-1/-2 MPa Elongation at yield 23 ºC, 50 mm/min ISO 527-1/-2 % Elongation at break 23 ºC, 50 mm/min ISO 527-1/-2 % Flexural modulus 23 ºC, 2 mm/min ISO 178 MPa Flexural strength 23 ºC, 2 mm/min ISO 178 MPa Charpy unnotched impact strength 1) 23 ºC -30 ºC ISO 179/1eU kj/m 2 Charpy notched impact strength 23 ºC -30 ºC ISO 179/1eU kj/m 2 THERMAL PROPERTIES Melting temperature (DSC) 10 ºC/min ISO 3146 ºC Heat Deflection Temperature (HDT) 1,8 MPa 0,45 MPa ISO 75-1/-2 ºC Thermal coefficient of linear ºC long. expasion ºC transv. ISO / /k ELECTRICAL PROPERTIES (dry/cond.)* Dielectric constant 1MHz ISO Dissipation factor 1MHz ISO Volume resistivity ISO Ω.m Surface resistivity ISO Ω Comparative tracking index ISO WEIGHT REDUCTION B30 NC100 B30 P2 G25 WR B300 P2 NF B300 P2 G16 HB M , V-2 HB HB HB / / ,000 / 2,000 7,600 / 5,700 5,100 / 3,200 9,200 / 5, / / 90 90/ / / 25 - / - - / - - / / > / / / 6.5 3,500 / 1,400 6,500 / 4,500 4,600 / 2,300 8,000 / 4, / / / / - NB / NB 75 / / / / / / / / / / / 2, / 2, / 2, / / / / / / ) NB: No break. * dry = dry as moulded / cond. = conditioned according to ISO

23 Promyde Polyamide 66 POLYAMIDE 66 A30 P2 G15 A30 P2 G30 A30 P2 G40 A30 P2 G HB HB HB HB ,500 / 3,500 9,500 / 7,500 13,000 / 8,500 17,000 / 11, / / / / / - - / - - / - - / / / / / 3.5 4,500 / 2,500 9,000 / 6,500 12,000 / 7,500 16,000 / 10, / / / / / / / / / / / / / / / / / / / / DISCLAIMER: Values have been established by standard tests. The data should be considered as a guide and not as binding minimum values. Because may factors affect processing or applications, we recommend that individual tests are performed to determine the suitability of the product use. 23

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Polyamide 6 for Injection Moulding

Polyamide 6 for Injection Moulding Promyde is a trademark of NUREL 1 NUREL Engineering Polymers Excellence in Polymerization Recent technical advancements in NUREL polymerization processes have enabled