(~~~~~~;.,,ng;stelle. Accreditation. Deutsche Akkreditierungsstelle GmbH

Transcription

1 ~ (~~~~~~;.,,ng;stelle Deutsche Akkreditierungsstelle GmbH Entrusted according to Section 8 subsection1 AkkStelleG in connection with Section 1 subsection 1 AkkStelleGBV Signatory to the Multilateral Agreements of EA, ILAC and IAF for Mutual Recognition Accreditation The Deutsche Akkreditierungsstelle GmbHattests that the testing Iabaratory HuK Umweltlabor GmbH Otto-Hahn-Straße 2, Wenden is competent under the terms of DIN EN 150/IEC 17025:2005 to carry out tests in the following fields: physical, physico-chemical, chemical, microbiological and selected biological investigations of water; chemical, sensory and microbiological investigations in accordance with the Drinking Water Ordinance; sampling of untreated water and drinking water; physico-chemical and chemical investigations of soils, waste products, sludges and sediments as weil as waste for deposit; physico-chemical and chemical investigations of used oils and solid fuels, recovered fuels and solid biofuels; selected methods for chemical investigations of synthetic materials; selected methods for physico-chemical and chemical investigations of slags, ceramic and oxidic raw materials and finished materials, steels, ferrous materials, alloys and metals; selected microbiological methods for the investigation of hygienic conditions; sampling of waste water, cooling water, untreated water, swimming pool and bathing pool water, water from standing waters, aquifers and running waters as weil as sludges; physical, physico-chemical and chemical investigations of water, waste water, ground water, surface water and streaming water, of sludge, sediments, waste, recycling products and recyclable materials; Water, waste and soil and residual waste contamination modules The accreditation certificate shall only apply in connection with the notice of accreditation of with the accreditation number D-PL and is valid until lt comprises the cover sheet, the reverse side ofthe cover sheet and the following annex with a total of 47 pages. Registration number of the certificate: D-PL Berlin, signed Andrea Valbuena Head of Division This document is a translation. The definitive version is the original Germ an accreditation certificate. See notes ove rleaf.

2 Deutsche Akkreditierungsstelle GmbH Office Berlin Spittelmarkt Berlin Office Frankfurt am Main Gartenstraße Frankfurt am Main Office Braunschweig Bundesallee Braunschweig The publication of extracts of the accreditation certificate is subject to the prior written approval by Deutsche Akkreditierungsstelle GmbH (DAkkS). Exempted is the unchanged form of separate disseminations of the cover sheet by the conformity assessment body mentioned overleaf. No impression shall be made that the accreditation also extends to fields beyond the scope of accreditation attested by DAkkS. The accreditation was granted pursuant to the Act on the Accreditation Body (AkkStelleG) of 31 July 2009 (Federal Law Gazette I p. 2625) and the Regulation (EC) No 765/2008 of the European Parliament and of the Council of 9 July 2008 settingout the requirements for accreditation and market surveillance relating to the marketing of products (Official Journal of the European Union L 218 of 9 July 2008, p. 30). DAkkS is a signatory to the Multilateral Agreements for Mutual Recognition of the European co-operation for Accreditation (EA), International Accreditation Forum (IAF) and International Labaratory Accreditation Cooperation (ILAC). The signatories to these agreements recognise each other's accreditations. The up-to-date state of membership can be retrieved from the following websites: EA: ILAC: IAF:

3 Deutsche Akkreditierungsstelle GmbH Annex to the Accreditation Certificate D-PL according to DIN EN ISO/IEC 17025:2005 Period of validity: to Holder of certificate: HuK Umweltlabor GmbH Otto-Hahn-Straße 2, Wenden Tests in the fields: physical, physico-chemical, chemical, microbiological and selected biological investigations of water; chemical, sensory and microbiological investigations in accordance with the Drinking Water Ordinance; sampling of untreated water and drinking water; physico-chemical and chemical investigations of soils, waste products, sludges and sediments as well as waste for deposit; physico-chemical and chemical investigations of used oils and solid fuels, recovered fuels and solid biofuels; selected methods for chemical investigations of synthetic materials; selected methods for physico-chemical and chemical investigations of slags, ceramic and oxidic raw materials and finished materials, steels, ferrous materials, alloys and metals; selected microbiological methods for the investigation of hygienic conditions; sampling of waste water, cooling water, untreated water, swimming pool and bathing pool water, water from standing waters, aquifers and running waters as well as sludges; physical, physico-chemical and chemical investigations of water, waste water, ground water, surface water and streaming water, of sludge, sediments, waste, recycling products and recyclable materials; Water, waste and soil and residual waste contamination modules Abbreviations used: see last page Within Sections 1, 2, 6, 7, 8, 9, 10, 11, 12 and 13 the testing laboratory is entitled to use the standard test methods listed here with different revision levels without requiring previous information and approval of the DAkkS. This document is a translation. The definitive version is the original German annex to the accreditation certificate. 1/47

4 1 Investigations of water, waste water, cooling water, untreated water, swimming pool water and bathing pool water 1.1 Sampling and sample preparation DIN EN ISO (A 4) DIN A DIN ISO (A 14) DIN A DIN EN ISO (A 21) DIN EN ISO (A 31) DIN EN ISO (A 32) Water quality - Sampling - Part 1: Guidance on the design of sampling programmes and sampling techniques Sampling of waste water Water quality - Sampling - Part 5: Guidance on sampling of drinking water from treatment works and piped distribution systems Sampling from running waters Water quality - Sampling - Part 3: Preservation and handling of water samples Water quality - Digestion for the determination of selected elements in water - Part 1: Aqua regia digestion Water quality - Digestion for the determination of elements in water - Part 2: Nitric acid digestion 1.2 Physical and physico-chemical parameters DIN C DIN EN ISO (C 5) DEV C Determination of absorption in the range of the ultraviolet radiation Water quality - Determination of ph Determination of density 1.3 Anions DIN EN ISO 6878 (D 11) Water quality - Determination of phosphorus Period of validity: to Translation - 2/47

5 DIN EN ISO (D 20) DIN EN ISO (D 22) DIN EN ISO (D 25) DIN D DIN EN ISO (D 41) Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 4: Determination of chlorate, chloride and chlorite in water with low contamination Determination of dissolved sulfide by spectrometry Water quality - Determination of chromium(vi) - Method using flow analysis (FIA and CFA) and spectrometric detection 1.4 Cations DIN EN DIN EN ISO (E 12) DIN EN ISO (E 22) DIN EN ISO (E 23) DIN EN ISO (E 29) DIN EN ISO (E 35) DIN EN ISO (E 36) Water quality - Determination of mercury (standard withdrawn) Water quality - Determination of mercury - Method using atomic absorption spectrometry (AAS) with and without enrichment Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP- OES) Water quality - Determination of ammonium nitrogen - Method by flow analysis (CFA and FIA) and spectrometric detection Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of 62 elements Water quality - Determination of mercury - Method using atomic fluorescence spectrometry Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 1: General guidelines Period of validity: to Translation - 3/47

6 1.5 Jointly investigated substances DIN EN ISO (F 26) DIN F DIN EN ISO (F 28) DIN F DIN F DIN F Water quality - Determination of selected phthalates using gas chromatography/mass spectrometry Determination of selected phenols in groundwater and leachate, aqueous eluates and percolates Water quality - Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge - Method using extraction and gas chromatography/mass spectrometry Determination of trihalogen methanes (THM) in bathing water and pool water with headspace-gas chromatography Determination of selected polycyclic aromatic hydrocarbons (PAH) - Method using gas chromatography with mass spectrometric detection (GC-MS) Determination of selected easily volatile organic compounds in water - Method using gas chromatography and mass spectrometry by static headspace technique (HS-GC-MS) 1.6 Gaseous components DIN EN ISO 5814 (G 22) Water quality - Determination of dissolved oxygen - Electrochemical probe method 1.7 Total impact parameters and material parameters DIN H DIN EN ISO 8467 (H 5) DIN H DIN H Determination of total dry residue, filtrate dry residue and residue on ignition Water quality - Determination of permanganate index Water hardness Determination of acid and base-neutralizing capacities Period of validity: to Translation - 4/47

7 DIN H DIN H DIN EN ISO 9562 (H 14) DIN EN ISO (H 37) DIN H Determination of the settleable matter by volume in water and waste water Determination of the settleable matter by mass concentration in water and waste water Water quality - Determination of adsorbable organically bound halogens (AOX) Water quality - Determination of phenol index by flow analysis (FIA and CFA) Gravimetric determination of low volatile lipophilic substances after solvent extraction 1.8 Microbiological investigations ISO ISO DIN EN ISO DIN EN ISO 6222 (K 5) DIN EN ISO (K 11) DIN EN ISO (K 12) DIN EN ISO (K 13) DIN EN ISO (K 15) Water quality - Detection and enumeration of Legionella Water quality - Enumeration of Clostridium perfringens - Method using membrane filtration Water quality - Enumeration of Escherichia coli and coliform bacteria - Part 2: Most probable number method Water quality - Enumeration of culturable micro-organisms - Colony count by inoculation in a nutrient agar culture medium (colony counting at 22 C and 36 C) Water quality - Detection and enumeration of Pseudomonas aeruginosa - Method by membrane filtration Water quality - Enumeration of Escherichia coli and coliform bacteria - Part 1: Membrane filtration method for waters with low bacterial background flora Water quality - Detection and enumeration of Escherichia coli and coliform bacteria in surface and waste water - Part 3: Miniaturized method (most probable number) by inoculation in liquid medium Water quality - Detection and enumeration of intestinal enterococci - Part 2: Membrane filtration method Period of validity: to Translation - 5/47

8 DIN EN ISO (K 22) Drinking Water Ordinance Annex 5 I d) bb) 2001 Drinking Water Ordinance Annex 5 I e) 2001 AA-HuK Water quality - Detection and enumeration of Legionella - Part 2: Direct membrane filtration method for waters with low bacterial counts Quantitative determination of cultivatable microorganisms - Determination of colony count by inoculation in a nutrient agar culture (colony counting at 20 C and 36 C) Detection of Clostridium perfringens - Method using membrane filtration: (MCP method) at (44 ± 1) ºC over (21 ± 3) hours Determination of cultivatable microorganisms in aqueous samples - Casting plate method - Surface method 1.9 Test methods for aquatic organisms DIN EN ISO 9408 (L 22) DIN EN ISO (L 52) Water quality - Evaluation of ultimate aerobic biodegradability of organic compounds in aqueous medium by determination of oxygen demand in a closed respirometer Water quality - Determination of the inhibitory effect of water samples on the light emission of Vibrio fischeri (luminescent bacteria test) - Part 2: Method using liquid-dried bacteria 1.10 Selected quick tests with ready-to-use reagents Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK Ammonia cuvette test; Measurement range mg/l NH 4 -N Ammonia cuvette test; Measurement range mg/l NH 4 -N Chromium (III and VI) cuvette test; Measurement range mg/l Chlorine/ozone/chlorine dioxide cuvette test; Measurement range mg/l Cl 2 /O 3 // mg/l ClO 2 Period of validity: to Translation - 6/47

9 Dr. Lange LCI Dr. Lange LCI Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK Dr. Lange LCK CSB cuvette test; Measurement range mg/l O 2 CSB cuvette test; Measurement range mg/l O 2 Chloride cuvette; Measurement range mg/l Cl - Sulfate cuvette; Measurement range mg/l SO 4 2- Sulfide cuvette; Measurement range mg/l S 2- Sulfite cuvette test; Measurement range mg/l SO 3 2- Phosphate cuvette test; Measurement range mg/l PO 4 -P Acid neutralizing capacity cuvette test; Measurement range mmol/l Ks 4,3 Formaldehyde cuvette; Measurement range mg/l H 2 CO 2 Test methods in accordance with the Drinking Water Ordinance - TrinkwV Sampling Procedure DIN EN ISO (A 4) DIN ISO (A 14) DIN EN ISO (A 21) DIN EN ISO (K 19) DIN A DIN A DIN A Title Guidance on the design of sampling programmes and sampling techniques Guidance on sampling of drinking water from treatment works and piped distribution systems Guidance on preservation and handling of water samples Water quality - Sampling for microbiological analysis Sampling from running waters Sampling from barrages and lakes Sampling from running waters Period of validity: to Translation - 7/47

10 Procedure DVWK LAWA AQS Leaflet P-8/ Title Taking and scope of testing of groundwater samples Sampling of groundwater ANNEX 1: MICROBIOLOGICAL PARAMETERS PART I: General requirements for drinking water No. Parameter Procedure 1 Escherichia coli (E. coli) DIN EN ISO (K 12) with Colilert -18/Quanti-Tray 2 Enterococci DIN EN ISO (K 15) Enterolert -DW PART II: Requirements for drinking water intended for consumption from closed containers No. Parameter Procedure 1 Escherichia coli (E. coli) DIN EN ISO (K 12) Enterococci DIN EN ISO (K 15) Pseudomonas aeruginosa DIN EN ISO (K 11) ANNEX 2: CHEMICAL PARAMETERS PART I: Chemical parameters for which as a rule the concentration no longer increases in the distribution network, including the drinking water installation No. Parameter Method 1 Acrylamide n. a. 2 Benzene DIN F Boron DIN EN ISO (E 29) Bromate DIN EN ISO (D 34) Chromium DIN EN ISO (E 29) Cyanide DIN EN ISO (D 6) ,2-Dichlorethane DIN F Fluoride DIN EN ISO (D 20) Nitrate DIN EN ISO (D 20) Active substances in pesticides and biocidal products n. a. 11 Total active substances in pesticides and biocidal products n. a. 12 Mercury DIN EN ISO (E 35) Selenium DIN EN ISO (E 29) Tetrachloroethene and Trichloroethene DIN F Uranium DIN EN ISO (E 29) Period of validity: to Translation - 8/47

11 PART II: Chemical parameters for which the concentration can increase in the distribution network, including the drinking water installation No. Parameter Procedure 1 Antimony DIN EN ISO (E 29) Arsenic DIN EN ISO (E 29) Benzo(a)pyrene DIN F Lead DIN EN ISO (E 29) Cadmium DIN EN ISO (E 29) Epichlorhydrine DIN EN (P 9) Copper DIN EN ISO (E 29) Nickel DIN EN ISO (E 29) Nitrite DIN EN ISO (D 20) Polycyclic aromatic carbohydrates DIN F Trihalogen methanes DIN F Vinyl chloride DIN F ANNEX 3: INDICATOR PARAMETERS Part I: General indicator parameters No. Parameter Procedure 1 Aluminium DIN EN ISO (E 29) Ammonium DIN EN ISO (E 23) Chloride DIN EN ISO (D 20) Clostridium perfringens (including spores) TrinkwV 2001 Anl. 5 I e) 5 Coliform bacteria DIN EN ISO (K 12) Colilert -18/Quanti-Tray 6 Iron DIN EN ISO (E 29) Colour (spectral absorption Hg 436 nm) DIN EN ISO 7887 (C 1-2) Odour DEV B1/2 Part a Taste DEV B1/2 Part a Colony count at 22 C DIN EN ISO 6222 (K 5) Colony count at 36 C TrinkwV 2001 Annex 5 l d) bb) DIN EN ISO 6222 (K 5) TrinkwV 2001 Annex 5 l d) bb) 12 Electrical conductivity DIN EN (C 8) Manganese DIN EN ISO (E 29) Sodium DIN EN ISO (E 29) Total organic carbon (TOC) DIN EN 1484 (H 3) Oxidizability DIN EN ISO 8467 (H 5) Sulfate DIN EN ISO (D 20) Turbidity DIN EN ISO 7027 (C 2) Hydrogen ion concentration DIN EN ISO (C 5) Calcite solubility DIN C (calculation method 3) Period of validity: to Translation - 9/47

12 No. Parameter Procedure 21 Tritium n. a. 22 Total reference dose n. a. Part II: Special requirements for drinking water in drinking water installation systems Parameter Procedure Legionella spec. ISO ,DIN EN ISO (K22) Parameters not included in Annexes 1 to 3 of the Drinking Water Ordinance of 2001 Further periodic investigations Parameter Procedure Calcium DIN EN ISO (E 29) Potassium DIN EN ISO (E 29) Magnesium DIN EN ISO (E 29) Acid neutralizing capacity DIN H The accreditation is not a substitute for the recognition or approval procedure of the responsible authority in accordance with Article 15, Section 4 of the Drinking Water Ordinance. 3 List of test methods for the WATER module LAWA Stand: Subarea 1: Sampling and general parameters Parameter Procedure WW SW GW Sampling of waste water Sampling of running waters DIN A 11: DIN A 11: DIN A 15: DIN A 15: Sampling of aquifiers DIN A 13: Sampling of standing waters DIN A 12: Homogenisation of samples DIN A 30: Temperature DIN C 4: ph value DIN C 5: DIN C 5: Conductivity (25 C) DIN EN 27888: (C 8) Odour DIN EN 1622: (B 3) Annex C Colour DIN EN ISO 7887: (C 1) Section 2 Turbidity DIN EN ISO 7027: (C 2) Oxygen DIN EN 25814: (G 22) Redox potential DIN C 6: Period of validity: to Translation - 10/47

13 Subarea 2: Photometry, ion chromatography and mass analysis Parameter Procedure WW SW GW UV absorption at 254 nm (SAC 254) DIN C 3: UV absorption at 436 nm (SAC 436) DIN EN ISO 7887: (C 1) Ammonium nitrogen DIN EN ISO 11732: (E 23) DIN EN ISO 11732: (E 23) DIN E 5: DIN EN ISO 14911: (E 34) Nitrite nitrogen DIN EN 26777: (D 10) DIN EN ISO : (D 19) DIN EN ISO : (D 20) DIN EN ISO : (D 20) DIN EN ISO 13395: (D 28) Nitrate nitrogen DIN EN ISO : (D 19) DIN EN ISO : (D 20) DIN EN ISO : (D 20) DIN EN ISO 13395: (D 28) DIN / 9-3: DIN D 29: Total phosphorus DIN EN 1189: (D 11) DIN EN ISO 6878: (D 11) DIN EN ISO : (D 45) DIN EN ISO : (D 46) Orthophosphate DIN EN ISO : (D 19) DIN EN ISO : (D 20) DIN EN 1189: (D 11) DIN EN ISO 6878: (D 11) DIN EN ISO : (D 45) DIN EN ISO : (D 46) Fluoride (dissolved and total) DIN D 4: DIN EN ISO : (D 19) DIN EN ISO : (D 20) Chloride DIN D 1: DIN EN ISO : (D 19) DIN EN ISO : (D 20) DIN EN ISO : (D 20) DIN EN ISO : (D 25) DIN EN ISO 15682: (D 31) Period of validity: to Translation - 11/47

14 Parameter Procedure WW SW GW Sulfate Cyanide (easily released) Cyanide (total) Chromium VI DIN EN ISO : (D 19) DIN EN ISO : (D 20) DIN EN ISO : (D 20) DIN D 5: DIN D 13-2: DIN D 14-2: DIN EN ISO 14403: (D 6) DIN D 7: DIN D 13-1: DIN D 14-1: DIN EN ISO 14403: (D 6) DIN D 7: DIN D 24: DIN EN ISO : (D 22), Section 5 (dissolved chromate) Sulfide (easily released) DIN D 27: Subarea 3: Elemental analysis Parameter Procedure WW SW GW Aluminium Arsenic Lead DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN EN ISO 12020: (E 25) DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) DIN EN ISO 11969: (D 18) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) DIN E 6: DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 16: DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) Period of validity: to Translation - 12/47

15 Parameter Procedure WW SW GW Cadmium Calcium Chromium Iron Potassium Copper DIN EN ISO 5961: (E 19) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 16: DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 3: DIN EN ISO 7980: (E 3a) DIN EN ISO : (E 29) DIN EN ISO 14911: (E 34) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN EN 1233: (E 10) DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 1: DIN E 32: DIN EN ISO 15586: (E 4) DIN E 13: DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN EN ISO : (E 29) DIN EN ISO 14911: (E 34) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 7: DIN E 16: DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) Period of validity: to Translation - 13/47

16 Parameter Method WW SW GW Manganese Sodium Nickel Mercury Zinc Boron Magnesium DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN EN ISO : (E 29) DIN E 33: DIN EN ISO 15586: (E 4) DIN EN ISO 14911: (E 34) DIN E 14: DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN EN ISO : (E 29) DIN EN ISO 14911: (E 34) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 11: DIN EN ISO : (E 29) DIN E 16: DIN EN ISO 15586: (E 4) DIN EN 1483: (E 12) DIN EN 1483: (E 12) DIN EN 12338: (E 31) DIN EN 13506: (E 35) DIN EN 17852: (E 35) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 8-1: DIN E 16: DIN EN ISO : (E 29) DIN EN ISO 15586: (E 4) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN D 17: DIN EN ISO : (E 29) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) DIN E 3: DIN EN ISO 7980: (E 3a) DIN EN ISO : (E 29) DIN EN ISO 14911: (E 34) Period of validity: to Translation - 14/47

17 Parameter Method WW SW GW Phosphorus Subareas 4/5: Group and sum parameters DIN EN ISO : (E 29) DIN EN ISO 11885: (E 22) DIN EN ISO 11885: (E 22) Parameter Procedure WW SW GW Biological oxygen requirement (BOR 5 ) Chemical oxygen requirement (COR) Phenol index (with and without distillation) Suspended materials DIN EN : (H 51) DIN EN : (H 52) DIN H 41: DIN H 44: DIN ISO 15705: (H 45) DIN H 16: DIN EN ISO 14402: (H 37) DIN H 2: DIN EN 872: (H 33) Acid-base neutralizing capacity DIN H 7: Total organic carbon (TOC) DIN EN 1484: (H 3) Dissolved organic carbon (DOC) DIN EN 1484: (H 3) Total bound nitrogen (TN b ) Adsorbable organically bound halogens (AOX) Subarea 6: Gas chromatographic methods DIN ENV 12260: (H 34) DIN EN 12260: (H 34) DIN EN ISO : (H 36) DIN EN 1485: (H 14) DIN EN ISO 9562: (H 14) DIN H 22: Parameter Procedure WW SW GW Volatile halogenated hydrocarbons Benzene and derivatives (BTEX) Organochloride pesticides (OCP) Polychlorinated biphenyls (PCB) DIN EN ISO 10301: (F 4)* DIN EN ISO 15680: (F 19) DIN F 9: * DIN EN ISO 15680: (F 19) DIN EN ISO 6468: (F 1)* DIN F 2: * DIN EN ISO 6468: (F 1)* DIN F 2: * DIN F 3: Period of validity: to Translation - 15/47

18 Parameter Method WW SW GW Mono/dichlorobenzenes Tri- to hexachlorobenzene DIN EN ISO 10301: (F 4)* DIN EN ISO 15680: (F 19) DIN EN ISO 6468: (F 1)* DIN F 2: * Chlorophenols DIN EN 12673: (F 15) Organic phosphorus and organic nitrogen compounds DIN EN ISO 10695: (F 6) * Polycyclic aromatic hydrocarbons (PAH)** DIN F 39: Hydrocarbon index DIN EN ISO : (H 53) * mass spectroscopic detection is permitted ** Subarea 6 is also completely fulfilled when PAH is analysed according to a procedure of Subarea 7 Subarea 7: HPLC methods n. a. Subarea 8: Microbiological methods n. a. Subarea 9.1: Biological methods and biotests (Part 1) Parameter Procedure WW SW GW Fish egg test Luminescent bacteria inhibition test Subarea 9.2: Biological methods and biotests (Part 2) n. a. DIN T 6: DIN EN ISO 15088: (Part 6) DIN L 34: in conjunction with DIN L 34-1: DIN EN ISO : (L 34-2) DIN EN ISO : (L 52) DIN EN ISO : (L 51) Period of validity: to Translation - 16/47

19 4 SOIL AND RESIDUAL WASTE CONTAMINATION MODULE Status: 20 October 2000 Investigated area 1: Solid matter - inorganic parameters Parameter investigated Procedure Method Sampling Manual drillings DIN Sheet 1; 1964 Sampling for the investigation of surfaces suspected of or known to contain waste contamination Sampling for the investigation of natural, close-to-natural and cultural sites Occupational safety for sampling Driving core probing Samples in undisturbed stratification On site E DIN ISO Section 8.5.6; DIN 4021, E DIN ISO Section 8.3; DIN 19672, Part 1; 1968 E DIN ISO ; Pedological Mapping Manual 4th edition, 1994, reprint 1996 VDLUFA Methods Manual Volume 1 E DIN ISO ; ZH 1/183: 1997 Particle size distribution Finger test in the field # 4th edition, 1994, reprint 1996 Pedological Mapping Manual DIN : Laboratory Sample pre-treatment, sample preparation DIN ISO 11464; Dry matter Field-fresh or air-dried soil samples DIN ISO 11465; Organic carbon and total carbon following dry Air-dried soil samples DIN ISO 10694; combustion ph value (CaCl 2 ) Field-fresh or air-dried soil samples, c(cacl 2 ): 0.01 mol/l DIN ISO 10390; Particle size distribution Bulk density Aqua regia extract 1) Sieving, dispersion, pipette analysis 2) Sieving, dispersion, araeometer method Drying of a soil sample of suitable volume at 105 C, reweighing From crushed samples (particle size < 150 µm) E DIN ISO 11277; DIN ; DIN 18123; E DIN ISO 11277; E DIN ISO 11272; DIN ; DIN ISO 11466; Period of validity: to Translation - 17/47

20 Parameter investigated Procedure Method Ammonium nitrate extract DIN 19730: Arsenic (As) Extraction with aqua regia ICP - AES DIN EN ISO 11885; ICP - MS DIN ; ET AAS analogous to E DIN ISO 11047; Hydride AAS DIN EN ISO 11969; Cadmium (Cd) Extraction with aqua regia AAS E DIN ISO 11047; ICP AES DIN EN ISO 11885; ICP - MS DIN ; Chromium (total) Extraction with aqua regia AAS E DIN ISO 11047; ICP AES DIN EN ISO 11885; ICP - MS DIN ; Chromium (VI) Extraction with phosphatebuffered aluminium sulfate Spectral photometry DIN 19734; solution Copper (Cu) Extraction with aqua regia AAS E DIN ISO 11047; ICP AES DIN EN ISO 11885; ICP - MS DIN ; Nickel (Ni) Extraction with aqua regia AAS E DIN ISO 11047; ICP AES DIN EN ISO 11885; ICP - MS DIN ; # For occupational safety reasons not applicable for contaminated surfaces. Period of validity: to Translation - 18/47

21 Parameter investigated Procedure Method Lead (Pb) Extraction with aqua regia AAS E DIN ISO 11047; ICP - AES DIN EN ISO 11885; ICP - MS DIN ; Thallium (Tl) AAS E DIN ISO 11047: ICP-AES (ICP-MS possible) DIN EN ISO 11885: Mercury (Hg) AAS cold vapour technique DIN EN 1483; Extraction with aqua regia Reduction with Sn(II) chloride or Drying temperature may not NaBH4 exceed 400 C Zinc (Zn) Extraction with aqua regia AAS E DIN ISO 11047; ICP - AES DIN EN ISO 11885; ICP - MS DIN ; Cyanide E DIN ISO 11262; Investigated area 2: Solid matter - organic parameters Parameter investigated Procedure Method Sampling Manual drillings DIN Sheet 1; 1964 Sampling for the investigation of surfaces suspected of or known to contain waste contamination Sampling for the investigation of natural, close-to-natural and cultural sites Occupational safety for sampling Driving core probing Samples in undisturbed stratification On site Particle size distribution Finger test in the field E DIN ISO Section 8.5.6; DIN 4021, E DIN ISO Section 8.3; DIN 19672, Part 1; 1968 E DIN ISO ; Pedological Mapping Manual 4th edition, 1994, reprint 1996 VDLUFA Methods Manual Volume 1 E DIN ISO ; ZH 1/183: 1997 Pedological Mapping Manual 4th edition, 1994, reprint 1996 E DIN ; Period of validity: to Translation - 19/47

22 Parameter investigated Procedure Method Laboratory Sample pre-treatment, sample preparation E DIN ISO 14507; Dry matter Field-fresh or air-dried soil samples DIN ISO 11465; Organic carbon and total carbon following dry Air-dried soil samples DIN ISO 10694; combustion ph value (CaCl 2 ) Field-fresh or air-dried soil samples, c(cacl 2 ): 0.01 mol/l DIN ISO 10390; Particle size distribution Bulk density Polycyclic aromatic hydrocarbons (PAH) 16 PAH (EPA) Benzo(a)pyrene Notice: Acenaphthylene cannot be determined by fluorescence detector Hexachlorobenzene Pentachlorophenol 1) Sieving, dispersion, pipette analysis 2) Sieving, dispersion, araeometer method Drying of a soil sample of suitable volume at 105 C, reweighing 1) Soxhlet extraction with acetone/toluene or acetone/ cyclohexane, chromatographic clean-up 2) Extraction with tetrahydrofuran or acetonitrile 3) Extraction with acetone, added from petroleum ether, removal of acetone, chromatographic clean-up of petroleum ether extract, assimilation in acetonitrile 4) Extraction with a water/acetone/petroleum ether mixture in the presence of NaCl Extraction with an acetone/cyclohexane mixture or acetone/petroleum ether mixture, if necessary chromatographic clean-up following the removal of acetone Soxhlet extraction with heptane or acetone/heptane (50:50); derivatization with acetic acid anhydride E DIN ISO 11277; DIN ; DIN 18123; E DIN ISO 11277; E DIN ISO 11272; DIN ; GC MS Leaflet No1 des LUA NRW, 1994 HPLC-UV/DAD/F* Leaflet No. 1 of the LUA -NRW, 1994* HPLC - UV/F E DIN ISO 13877, GC - MS, HPLC - UV/DAD/F VDLUFA Methods Manual, Volume VII, Contamination Site Manual Volume 7, LfU Hessen GC - ECD, GC - MS E DIN ISO 10382; GC - ECD, GC - MS E DIN ISO 14154; Period of validity: to Translation - 20/47

23 Parameter investigated Procedure Method 1) Extraction with petroleum GC - ECD, GC - MS ether or acetone/petroleum E DIN ISO 10382; ether mixture, Aldrin, DDT, HCH mixture chromatographic clean-up GC - ECD, GC - MS 2) Extraction with a VDLUFA Methods Manual water/acetone/petroleum Volume VII, ether mixture Polychlorinated biphenyls (PCB) Extraction with heptane or acetone/petroleum ether, chromatographic clean-up Soxhlet extraction with heptane, hexane or pentane, chromatographic clean-up of AgNO 3 / silica gel column Extraction with a water/acetone/petroleum ether mixture in the presence of NaCl Investigated area 3: Solid matter, dioxins and furans n. a. Investigated area 4: Groundwater, seepage water and surface water Parameter investigated Sampling DIN EN ISO 25667, Part 2 E DIN ISO 10382: DIN : VDLUFA Methods Manual Volume VII, Method DIN ; Federal/Regional Water Consortium (LAWA): Sampling of groundwater Groundwater Directive, Part 3; AQS Leaflet P 8/2; German Water Resources Management and Land Improvement Association (DVWK): DVWK Regulations 128/92 DVWK Leaflet 245/1997 Sampling of seepage water No standard procedure currently available Sampling of surface water (running waters) DIN ; AQS Leaflet P 8/3; Sampling of surface water (standing waters) DIN ; Temperature DIN ; ph value DIN ; Oxygen content DIN EN 25814; Electrical conductivity DIN EN 27888; Period of validity: to Translation - 21/47

24 Parameter investigated Elution procedure 1 (soil saturation extract) Elution procedure 2 (modified S4 procedure) Elution procedure 3 (column or lysimeter test) Antimony (Sb) Arsenic (As) Lead (Pb) Cadmium (Cd) Chromium (Cr), total Chromium (Cr VI) Cobalt (Co) Copper (Cu) Molybdenum (Mo) Nickel (Ni) Method Laboratory According to Federal Soil Protection and Contamination Ordinance (BBodSchV) standards (Annex 1, 3.1.2) DIN ; in conjunction with the procedural specifications of the BBodSchV (Annex 1, 3.1.2) No standard procedure currently available; Possibilities for performing in column or lysimeter tests according to the most recent state of analytics must be proven ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; Hydride - AAS E DIN ; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; Hydride - AAS DIN EN ISO 11969; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS E DIN ; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS DIN EN ISO 5961; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS DIN EN 1233; Spectral photometry DIN ; Ion chromatography DIN EN ISO ; ICP - AES on the basis of DIN EN ISO 11885; AAS DIN ; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS DIN ; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS DIN ; Mercury Hg) AAS cold vapour technique DIN EN 1483; Selenium (Se) ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS DIN ; Period of validity: to Translation - 22/47

25 Parameter investigated Zinc (Zn) Tin (Sn) Cyanide, total Cyanide (CN - ), easily released Fluoride (F - ) Method ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; AAS DIN ; ICP - AES on the basis of DIN EN ISO 11885; ICP - MS DIN ; Spectral photometry DIN ; E DIN EN ISO 14403; Spectral photometry DIN ; Fluoride-sensitive electrode DIN ; Ion chromatography DIN EN ISO ; BTEX GC - FID DIN ; (take account of matrix loading) Volatile halogenated carbohydrates GC - ECD DIN EN ISO 10301; Aldrin GC - ECD, GC MS possible DIN ; DDT GC - ECD, GC MS possible DIN ; Phenols GC - ECD ISO DIS ; Chlorophenols GC - ECD, GC - MS E DIN EN 12673; Chlorobenzenes GC - ECD, GC MS possible DIN ; Polychlorinated biphenyls GC - ECD, GC - MS DIN ; (PCB): 6 PCB Congeners (No. 28, 52, 101, 138, 163, E DIN ; acc. to Ballschmiter) 16 PAH (EPA) HPLC - F DIN ; Naphthalene GC - FID, GC - MS DIN ; Mineral oil carbohydrates Extraction with petroleum ether; Gas chromatographic determination according to ISO/TR 11064; Investigated area 5: Soil air, landfill gas n. a. Investigated area 6: Wet and dry deposition n. a. Investigated area 7: Forest soil investigations n. a. Investigated area 8: Investigations for the evaluation of the terrestrial ecotoxicity of harmful substances n. a. Period of validity: to Translation - 23/47

26 5 List of test methods for the WASTE MODULE LAGA status: August 2012 Investigated area 1: Sewage sludge Subarea/ Parameter 1.1 Sampling Annex 1 AbfKlärV Basis/ Method Sewage Sludge Ordinance (AbfKlärV) 1.2 Heavy metals Article 3 Section 5 AbfKlärV Aqua regia digestion Lead (from aqua regia digestion) Cadmium (from aqua regia digestion) Chromium (from aqua regia digestion) Copper (from aqua regia digestion) Nickel (from aqua regia digestion) DIN (01.83) DIN EN (04.01) DIN EN (01.03) DIN (05.81) DIN (03.88) DIN E 6 (07.98) DIN ISO (05.03) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) DIN (07.80) DIN (03.88) DIN ISO (05.03) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) DIN EN ISO 5961 (E 19) (05.95) DIN (06.85) DIN (03.88) DIN EN 1233 (E 10) (08.96) DIN ISO (05.03) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) DIN (03.88) DIN E 7 (09.91) DIN ISO (05.03) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) DIN (03.88) DIN E 11 (09.91) DIN ISO (05.03) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) Period of validity: to Translation - 24/47

27 Subarea/ Parameter Mercury (from aqua regia digestion) Zinc (from aqua regia digestion) Basis/ Method DIN (07.80) DIN EN 1483 (E 12) (07.07) DIN EN ISO (E 35) (04.08) DIN (10.80) DIN (03.88) DIN E 8 (10.04) DIN ISO (05.03) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) 1.3 Adsorbed organically bound halogens AOX (from dry residue) DIN S 18 (11.89) 1.4 Physical parameters, nutrients Article 3 Section 5 AbfKlärV Dry residue Organic substances as ignition loss (from dry residue) ph value Aqua regia digestion DIN S 2 (11.85) DIN EN (S 2a) (02.01) DIN S 3 (11.85) DIN EN (S 3a) (02.01) DIN (09.81) DIN (07.09) DIN EN (S 5) (06.98) DIN (01.83) DIN EN (04.01) DIN EN (01.03) Annex 1 AbfKlärV Akaline substances as CaO Calculated as % CaO = (50-x-2y) 1 1,402 Ammonium nitrogen (NH 4 -N) DIN E 5 (10.83) DIN (02.77) Distillation method Total nitrogen (N tot. ) DIN ISO (05.97) DIN EN (01.01) Phosphorus (P 2 O 5 ) (from aqua regia digestion) DIN S 12 (11.86) DIN (03.88) DIN EN ISO 6878 (D 11) (09.04) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) Period of validity: to Translation - 25/47

28 Subarea/ Parameter Potassium (K 2 O) (from aqua regia digestion) Magnesium (MgO) (from aqua regia digestion) Persistent harmful organic substances 1.5 Polychlorinated biphenyls (PCB) 1.6 Polychlorinated dibenzodioxins/furans (PCDD/PCDF) Basis/ Method DEV E13 (5th Delivery 68) DIN (03.88) DIN E 13 (07.92) DIN ISO (E 27) (08.96) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) DIN (09.82) DIN (03.88) DIN E 3 (03.02) DIN EN ISO 7980 (E 3a) (07.00) DIN EN ISO (E 22) (09.09) DIN EN ISO (E 29) (02.05) Article 3 Section 6 AbfKlärV Annex 1, No AbfKlärV DIN S 20 (01.96) Annex 1 No AbfKlärV DIN S 24 (10.00) 1 Correction to AbfKlörV, Annex 1, Section 1.3.2, No. VI; this source gives an incorrect formula for calculation. Investigated area 2: Soil n. a. Investigated area 3: Biowaste n. a. Investigated area 4: Old oil, liquid dielectric n. a. Investigated area 5: Waste for disposal n. a. Investigated area 6: Wood waste n.a. Period of validity: to Translation - 26/47

29 6 Investigation of soils and oil eluates 6.1 Sample pre-treatment and sample preparation ISO DIN ISO DIN EN DIN ISO DIN ISO DIN EN DIN EN DIN EN DIN EN DIN DIN DIN Soil quality - Microwave-assisted extraction of the aqua regia soluble fraction for the determination of elements Soil quality - Determination of dry matter and water content on a mass basis - Gravimetric method (standard withdrawn) Sludge, treated biowaste, soil and waste - Calculation of dry matter fraction after determination of dry residue or water content Soil quality - Extraction of trace elements soluble in aqua regia (standard withdrawn) Soil quality - Extraction of trace elements from soil using ammonium nitrate solution Soil improvers and growing media - Extraction of calcium chloride/dtpa (CAT) soluble nutrients Sludge, treated biowaste, soil and waste - Determination of loss on ignition Sludge, treated biowaste and soil - Digestion of aqua regia soluble fractions of elements Sludge, treated biowaste and soil - Guidance for sample pretreatment Leaching of solid materials - Batch test for the examination of the leaching behaviour of organic substances at a liquid to solid ratio of 2 l/kg Leaching of solid materials - Percolation method for the joint examination of the leaching behaviour of inorganic and organic substances Leaching of solid materials - Batch test for the examination of the leaching behaviour of inorganic substances at a liquid to solid ratio of 2 l/kg Period of validity: to Translation - 27/47

30 DIN Investigation of solids - Pre-treatment, preparation and processing of samples for chemical, biological and physical investigations 6.2 Physical and physico-chemical parameters DIN ISO DIN ISO DIN ISO DIN EN ISO DIN EN Soil quality - Determination of ph (standard withdrawn) Soil quality - Determination of the specific electrical conductivity Soil quality - Determination of particle size distribution in mineral soil material - Method by sieving and sedimentation Soil quality - Determination of dry bulk density Sludge, treated biowaste and soil - Determination of ph 6.3 Total impact parameters and material parameters DIN ISO DIN ISO DIN ISO DIN EN DIN EN DIN EN Soil quality - Determination of organic and total carbon after dry combustion (elementary analysis) (standard withdrawn) Soil quality - Determination of nitrate nitrogen, ammonium nitrogen and total soluble nitrogen in air-dry soils using calcium chloride solution as extractant Soil quality - Determination of total sulfur by dry combustion Sludge, treated biowaste, soil and waste - Determination of total organic carbon (TOC) by dry combustion Sludge, treated biowaste and soil - Determination of adsorbable organically bound halogens (AOX) Sludge, treated biowaste and soil - Determination of total nitrogen using the dry combustion method Period of validity: to Translation - 28/47

31 E DIN Standard draft Investigation of solids - Determination of organic, elemental and inorganic carbon content using temperature differentiation 6.4 Anions DIN ISO DIN EN Soil quality - Determination of total cyanide and easily liberatable cyanide - Continuous-flow analysis method Characterisation of waste and soil - Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection (Deviation: Determination by ICP-OES and photometry) 6.5 Cations DIN ISO DIN ISO DIN EN ISO (E 12) DIN CEN/TS DIN CEN/TS DIN CEN/TS DIN CEN/TS Soil quality - Determination of mercury in aqua regia soil extracts with cold-vapour atomic spectrometry or cold-vapour atomic fluorescence spectrometry (Deviation for solid matter: Thermal extraction and determination with AAS) Soil quality - Determination of trace elements in extracts of soil by inductively coupled plasma - atomic emission spectrometry (ICP-AES) Water quality - Determination of mercury - Method using atomic absorption spectrometry (AAS) with and without enrichment (Deviation for solid matter: Direct thermal extraction) Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma optical emission spectrometry (ICP-OES) Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma mass spectrometry (ICP-MS) Sludge, treated biowaste and soil - Determination of mercury - Part 1: Cold-vapour atomic absorption spectrometry (CV-AAS) Sludge, treated biowaste and soil - Determination of mercury - Part 2: Cold-vapour atomic fluorescence spectrometry (CV-AFS) Period of validity: to Translation - 29/47

32 6.6 Organic parameters ISO DIN ISO DIN ISO DIN ISO DIN ISO DIN EN ISO Water quality - Determination of selected monovalent phenols - Part2: Method by derivatization and gas chromatography Soil quality - Determination of organochlorine pesticides and polychlorinated biphenyls - Gas-chromatographic method with electron capture detection (Deviation: Determination by GC-MS) Soil quality - Determination of some selected chlorophenols - Gaschromatographic method with electron-capture detection (Deviation: Determination by GC-MS) Soil quality - Determination of content of hydrocarbon in the range C10 to C40 by gas chromatography Soil quality - Determination of polycyclic aromatic hydrocarbons (PAH) - Gas chromatographic method with mass spectrometric detection (GC-MS) Soil quality - Gas chromatographic determination of volatile aromatic and halogenated hydrocarbons and selected ethers - Static headspace method 7 Investigation of waste, sludge, sediments, recycling products, recyclable materials, Road materials, used oils and waste eluates 7.1 Sampling and sample preparation DIN EN ISO (S 1) DIN EN DIN EN Water quality - Sampling - Part 13: Guidance on sampling of sludges Characterization of waste - Leaching; Compliance test for leaching of granular waste materials and sludges - Part 1: One stage batch test at a liquid to solid ratio of 2 l/kg with particle size below 4 mm (with or without size reduction) Characterization of waste - Leaching; Compliance test for leaching of granular waste materials and sludges - Part 2: One stage batch test at a liquid to solid ratio of 10 l/kg with particle size below 4 mm (with or without size reduction) Period of validity: to Translation - 30/47

33 DIN EN DIN EN (S 7a) DIN EN DIN EN V DIN CEN/TS DIN S LAGA PN TP Gestein-StB Part Characterization of waste - Leaching; Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with limited size reduction) Characterization of sludges - Determination of trace elements and phosphorus - Aqua regia extraction methods Characterization of waste - Microwave assisted digestion with hydrofluoric (HF), nitric (HNO3) and hydrochloric (HCl) acid mixture for subsequent determination of elements in waste Characterization of waste - Digestion for subsequent determination of aqua regia soluble portion of elements in waste Characterization of waste - Leaching behaviour tests - Up-flow percolation test (under specified conditions) Determination of leachability by water Procedural Directive for physical, chemical and biological investigations in connection with the recycling/elimination of waste materials according to LAGA PN 98 - Basic rules for sampling solid, air- and water-tight wastes and disposed materials Modified S4 method of DEV 7.2 Physico-chemical parameters DIN EN DIN EN (S 3a) DIN EN (S 2a) DIN EN Sludge, treated biowaste and soil - Determination of ph Characterization of sludges - Determination of the loss on ignition of dry mass (standard withdrawn) Characterization of sludges - Determination of dry residue and water content Characterization of waste - Determination of total organic carbon (TOC) in waste, sludges and sediments Period of validity: to Translation - 31/47

34 DIN EN DIN EN DIN EN DIN EN DIN EN DIN CEN/TS DepV No Characterization of waste - Calculation of dry matter by determination of dry residue or water content Characterization of sludges - Settling properties - Part 1: Determination of settleability (Determination of the proportion of sludge volume and sludge volume index) Characterization of waste - Determination of loss on ignition in waste, sludge and sediments Characterization of sludges - Determination of calorific values Characterization of waste - Determination of total dissolved solids (TDS) in water and eluates Characterization of waste - Determination of gross calorific value and calculation of net calorific value Biological degradability of the dry residue from the original substance - Breathability determined over four days by laboratory testing (AT 4 ) 7.3 Inorganic parameters DIN EN DIN EN Characterization of waste - Halogen and sulfur content - Oxygen combustion in closed systems and determination methods Characterization of waste and soil - Determination of elemental composition by X-ray fluorescence 7.4 Organic parameters DIN EN DIN EN DIN EN Characterization of waste - Determination of hydrocarbon content in the range of C10 to C40 by gas chromatography Characterization of waste - Determination of hydrocarbon content by gravimetry Characterization of waste - Determination of selected polychlorinated biphenyls (PCB) in solid waste by using capillary gas chromatography with electron capture or mass spectrometric detection Period of validity: to Translation - 32/47

35 DIN EN DIN S DIN S DIN S Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography - mass spectrometry (GC/MS) Determination of the organically bound halogens amenable to extraction (EOX) Determination of adsorbed organically bound halogens (AOX) Determination of 6 polychlorinated biphenyls (PCB) 7.5 Investigation of waste materials for disposal according to the Landfill Ordinance LAGA PN DepV Annex 4 No. 2 and No DIN DIN EN DIN EN DIN DIN C Procedural Directive for physical, chemical and biological investigations in connection with the recycling/elimination of waste materials according to LAGA PN 98 - Basic rules for sampling solid, air- and water-tight wastes and disposed materials Sampling of waste materials for disposal Investigation of solids - Pre-treatment, preparation and processing of samples for chemical, biological and physical investigations Characterization of waste - Digestion for subsequent determination of aqua regia soluble portion of elements in waste Characterization of waste - Leaching; Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with limited size reduction) (extended by: Eluate investigations of coarse-particle road construction materials) Leaching of solid materials - Percolation method for the joint examination of the leaching behaviour of inorganic and organic substances Determination of ph value (standard withdrawn) Period of validity: to Translation - 33/47

36 DIN EN (C 8) DIN EN DIN EN DIN EN DIN EN DIN EN ISO (D 20) DIN EN ISO (E 22) DIN EN ISO (E 12) E DIN standard draft DIN EN DIN EN 1484 (H 3) DIN EN ISO DIN EN ISO (H 37) DIN EN Water quality - Determination of electrical conductivity Characterization of waste - Calculation of dry matter by determination of dry residue or water content Characterization of waste - Determination of total dissolved solids (TDS) in water and eluates Characterization of waste - Determination of loss on ignition in waste, sludge and sediments Characterization of sludges - Determination of calorific values Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) Water quality - Determination of mercury - Method using atomic absorption spectrometry (AAS) with and without enrichment (Deviation for solid matter: Direct thermal extraction) Investigation of solids - Determination of organic, elemental and inorganic carbon content using temperature differentiation Characterization of waste - Determination of total organic carbon (TOC) in waste, sludges and sediments Water analysis - Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) Water quality - Determination of total cyanide and free cyanide using flow analysis (FIA and CFA) - Part 2: Method using continuous flow analysis (CFA) Water quality - Determination of phenol index by flow analysis (FIA and CFA) Characterization of waste - Determination of hydrocarbon content by gravimetry Period of validity: to Translation - 34/47

37 DIN EN LAGA KW/ DIN EN ISO DIN F DIN ISO DIN EN DepV Annex 4 No Characterization of waste - Determination of hydrocarbon content in the range of C10 to C40 by gas chromatography Extractable lipophilic substances in the original substance Soil quality - Gas chromatographic determination of volatile aromatic and halogenated hydrocarbons and selected ethers - Static headspace method Determination of benzene and some of its derivatives by gas chromatography (Deviation for soils: Extraction with methanol) Soil quality - Determination of polycyclic aromatic hydrocarbons (PAH) - Gas chromatographic method with mass spectrometric detection (GC-MS) Characterization of waste - Determination of selected polychlorinated biphenyls (PCB) in solid waste by using capillary gas chromatography with electron capture or mass spectrometric detection Biological degradability of the dry residue from the original substance - Breathability determined over four days by laboratory testing (AT 4 ) 7.6 investigations in accordance with LAGA Directive M20 DIN ISO DIN EN DIN ISO DIN ISO Soil quality - Determination of ph (standard withdrawn) Sludge, treated biowaste and soil - Determination of ph Soil quality - Extraction of trace elements soluble in aqua regia (standard withdrawn) Soil quality - Determination of mercury in aqua regia soil extracts with cold-vapour atomic spectrometry or cold-vapour atomic fluorescence spectrometry Period of validity: to Translation - 35/47

38 DIN EN DIN ISO DIN EN ISO 7887 (C 1) DIN EN ISO 7027 (C 2) DIN EN ISO (D 20) DIN EN ISO (C 5) DIN EN ISO (E 23) DIN EN ISO (E 22) DIN EN ISO (E 12) DIN EN ISO (H 37) DIN EN ISO DIN EN ISO E DIN standard draft Sludge, treated biowaste, soil and waste - Calculation of dry matter fraction after determination of dry residue or water content Soil quality - Determination of total cyanide and easily released cyanide - Continuous-flow analysis method Water quality - Examination and determination of colour Water quality - Determination of turbidity Water quality - Determination of dissolved anions by liquid chromatography of ions - Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate Water quality - Determination of ph Water quality - Determination of ammonium nitrogen - Method by flow analysis (CFA and FIA) and spectrometric detection Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) Water quality - Determination of mercury - Method using atomic absorption spectrometry (AAS) with and without enrichment (Deviation for solid matter: Direct thermal extraction) Water quality - Determination of phenol index by flow analysis (FIA and CFA) Water quality - Determination of total cyanide and free cyanide using flow analysis (FIA and CFA) - Part 2: Method using continuous flow analysis (CFA) Soil quality - Gas chromatographic determination of volatile aromatic and halogenated hydrocarbons and selected ethers - Static headspace method Investigation of solids - Determination of organic, elemental and inorganic carbon content using temperature differentiation Period of validity: to Translation - 36/47

39 DIN EN 1484 (H 3) DIN EN DIN EN DIN EN DIN EN DIN EN DIN EN DIN EN (C 8) DIN F DIN S DIN S DIN S Water analysis - Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) Characterization of waste - Leaching; Compliance test for leaching of granular waste materials and sludges - Part 4: One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with limited size reduction) Characterization of waste - Digestion for subsequent determination of aqua regia soluble portion of elements in waste Characterization of waste - Determination of hydrocarbon content in the range of C10 to C40 by gas chromatography Characterization of waste - Calculation of dry matter by determination of dry residue or water content Characterization of waste - Determination of selected polychlorinated biphenyls (PCB) in solid waste by using capillary gas chromatography with electron capture or mass spectrometric detection Characterization of waste - Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography - mass spectrometry (GC/MS) Water quality - Determination of electrical conductivity Determination of benzene and some of its derivatives by gas chromatography (Deviation for soils: Extraction with methanol) Determination of leachability by water Determination of the organically bound halogens amenable to extraction (EOX) Determination of 6 polychlorinated biphenyls (PCB) Period of validity: to Translation - 37/47

40 7.7 Selected methods for the investigation of used oils DIN EN ISO DIN EN ISO DIN EN ISO DIN EN DIN EN DIN DIN Determination of flash point - Pensky-Martens closed cup method Determination of flash/no flash - Rapid equilibrium closed cup method Petroleum products - Determination of water - Coulometric Karl Fischer titration method Petroleum products and used oils - Determination of PCBs and related products - Part 1: Separation and determination of selected PCB congeners by gas chromatography (GC) using an electron capture detector (ECD) (Deviation: Determination by GC-MS) Petroleum products and used oils - Determination of PCBs and related products - Part 2: Calculation of polychlorinated biphenyl (PCB) content Testing of petroleum products - Determination of boiling range distribution - Gas chromatography method Testing of petroleum products - Method for sample preparation - Part 1: Microwave incineration 8 Selected investigations of fuels 8.1 Selected investigations of solid fuels DIN DIN DIN DIN Solid fuels - Determination of contents of trace elements - Part 1: General rules, sampling and sample preparation; Preparation of samples for the analysis (dissolution method) Solid fuels - Determination of contents of trace elements - Part 2: ICP-OES Testing of solid fuels - Sampling and sample preparation - Part 3: Sample preparation Testing of solid fuels - Determination of the bulk density of solid fuels Period of validity: to Translation - 38/47

41 DIN DIN DIN ASTM D DIN DIN DIN DIN DIN DIN DIN DIN DIN DIN Testing of solid fuels - Determination of the water content and the moisture of the analysis sample Testing of solid fuels - Determination of ash content Testing of solid fuels - Determination of volatile matter content Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis Testing of solid fuels - Determination of fluorine content Solid mineral fuels - Determination of sulfur content - Part 3: Instrumental methods Testing of solid fuels - Determination of chlorine content Testing of solid fuels - Determination of chemical composition of fuel ash - Part 10: X-ray fluorescence analysis (RFA) Testing of solid fuels - Determination of chemical composition of fuel ash - Part 11: Determination by inductively coupled plasma emission spectrometry (ICP-OES) Testing of solid fuels - Determination of fusibility of fuel ash Testing of solid fuels - Determination of total carbon, hydrogen and nitrogen - Instrumental methods Testing of solid mineral fuels - Proximate analysis and calculation of fixed carbon Testing of solid and liquid fuels - Determination of gross calorific value by the bomb calorimeter and calculation of net calorific value - Part 1: Principles, apparatus, methods Testing of solid and liquid fuels - Determination of gross calorific value by the bomb calorimeter and calculation of net calorific value - Part 2: Method using isoperibol or static jacket calorimeter Period of validity: to Translation - 39/47

42 8.2 Selected methods for the investigation of solid recovered fuels DIN EN DIN CEN/TS DIN EN ASTM D DIN EN DIN CEN/TR DIN EN DIN EN DIN EN DIN EN DIN EN DIN EN Solid recovered fuels - Determination of calorific value Solid recovered fuels - Determination of bulk density Solid recovered fuels - Determination of the content of volatile matter Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis Solid recovered fuels - Determination of ash content Solid recovered fuels - Methods for the determination of ash melting behaviour by using characteristic temperatures Solid recovered fuels - Methods for the determination of carbon (C), hydrogen (H) and nitrogen (N) content Solid recovered fuels - Methods for the determination of sulphur (S), chlorine (Cl), fluorine (F) and bromine (Br) content Solid recovered fuels - Method for the determination of the content of major elements (Al, Ca, Fe, K, Mg, Na, P, Si, Ti) Solid recovered fuels - Methods for the determination of the content of trace elements (As, Ba, Be, Cd, Co, Cr, Cu, Hg, Mo, Mn, Ni, Pb, Sb, Se, Tl, V and Zn) Solid recovered fuels - Determination of moisture content using the oven dry method - Part 3: Moisture in general analysis samples Solid recovered fuels - Methods for the determination of biomass content Period of validity: to Translation - 40/47

43 8.3 Selected investigations of solid biofuels DIN EN DIN EN DIN EN DIN EN DIN EN DIN EN DIN EN ASTM D DIN EN DIN EN DIN EN V DIN CEN/TS Solid biofuels - Determination of moisture content - Oven dry method - Part 1: Total moisture - Reference method Solid biofuels - Determination of moisture content - Oven dry method - Part 3: Moisture in the general analysis sample Solid biofuels - Determination of ash content Solid biofuels - Determination of calorific value Solid biofuels - Determination of bulk density Solid biofuels - Determination of total content of carbon, hydrogen and nitrogen - Instrumental methods Solid biofuels - Determination of the content of volatile matter Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis Solid biofuels - Determination of total content of sulfur and chlorine Solid biofuels - Determination of major elements - Al, Ca, Fe, Mg, P, K, Si, Na and Ti Solid biofuels - Determination of minor elements - As, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Sb, V and Zn Solid biofuels - Method for the determination of ash melting behaviour - Part 1: Characteristic temperatures method 9 Selected methods for the investigation of slags, ceramic and oxidic raw materials and finished materials DIN EN ISO Monolithic (unshaped) refractory products - Part: Sampling for testing Period of validity: to Translation - 41/47

44 DIN EN ISO DIN EN ISO DIN EN ISO DIN EN ISO DIN EN DIN EN DIN EN DIN EN DIN DIN Supplementary sheet DIN Chemical analysis of refractory products by X-ray fluorescence (XRF) - Fused cast-bead method Chemical analysis of silicon-carbide-containing raw materials and refractory products - Part 1: General information and sample preparation Chemical analysis of silicon-carbide-containing raw materials and refractory products - Part 2: Determination of loss on ignition, total carbon, free carbon and silicon carbide, total and free silica and total and free silicon Chemical analysis of silicon-carbide-containing raw materials and refractory products - Part 3: Determination of nitrogen, oxygen and metallic and oxidic constituents Advanced technical ceramics - Methods of test for ceramic powders - Part 3: Determination of the oxygen content of nonoxides by thermal extraction with a carrier gas Methods of test for dense shaped refractory products - Part 1: Determination of bulk density, apparent porosity and true porosity Methods of test for dense shaped refractory products - Part 18: Determination of bulk density of granular materials by the water method with vacuum Products and systems for the protection and repair of concrete structures - Test methods - Determination of chloride content in hardened concrete Testing of oxidic raw materials and basic materials - General bases of work for the X-ray fluorescence method (XRF) Testing of oxidic raw materials and basic materials - General bases of work for the X-ray fluorescence method (XRF) - General survey on disintegration methods referred to groups of materials for the determination of test specimens for XRF Testing of ceramic raw and finished materials - Part 2: Sampling of ceramic raw materials Period of validity: to Translation - 42/47

45 DIN DIN DIN DIN DIN DIN Testing of ceramic raw and finished materials - Preparation of samples for the determination of change of mass during drying and for chemical analysis (standard withdrawn) Testing of oxidic raw materials and materials - Determination of change in mass on ignition Testing of oxidic raw and basic materials for ceramic, glass and glazes - Determination of fluoride content Determination of solid state density - Part 2: Gas pycnometry Particle size analysis; sieve analysis; general principles Particle size analysis; sieve analysis; procedure 10 Selected methods for the investigation of steels, alloys and metals ISO ISO ISO Ferroalloys; Sampling and sieve analysis Ferrolalloys; Sampling and sample preparation for chemical analysis - Part 1: Ferrochromium, ferrosilicochromium, ferrosilicon, ferrosilicomanganese, ferromanganese Ferroalloys; Sampling and sample preparation for chemical analysis - Part 2: Ferrotitanium, ferromolybdenum, tungsten, ferroniobium, ferrovanadium Further applicable documents: ISO 3713 Ferroalloys; Sampling and preparation of samples; General rules ISO ISO Direct reduced iron Determination of metallic iron - Bromine-methanol titrimetric method Iron ores: Determination of acid-soluble iron(ii) content; titrimetric method Period of validity: to Translation - 43/47

46 ISO ISO DIN EN ISO (E 22) DIN EN DIN EN DIN EN DIN DIN Steel and iron - Determination of total carbon and sulfur content - Infrared absorption method after combustion in an induction furnace (routine method) (matrix modification / extension: Carbon and sulfur determinations in metals, oxides, ferroalloys, waste materials and in products and flux materials in the steel and iron industry) Steel and iron - Determination of nitrogen content - Thermal conductimetric method after fusion in a current of inert gas (routine method (matrix modification/extension: Nitrogen determinations in metals, oxides, ferroalloys, waste materials and in products and flux materials in the steel and iron industry) Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (matrix modification: Determination of elements in scrap metals, metals, ferroalloys, and in products and flux materials in the steel and iron industry) Chemical analysis of ferrous materials - Determination of oxygen in steel and iron - Part 1: Sampling and preparation of steel samples for oxygen determination Chemical analysis of ferrous materials - Determination of oxygen content in steel and iron - Part 2: Infrared method after fusion under inert gas (matrix modification/extension: Oxygen determinations in metals, oxides, ferroalloys, waste materials and in products and flux materials in the steel and iron industry) Characterization of waste - Calculation of dry matter by determination of dry residue or water content (matrix modification: Scrap metals, metals, ferroalloys, and in products and flux materials in the steel and iron industry) Testing of solid mineral fuels - Determination of total carbon, hydrogen and nitrogen - Instrumental methods (matrix modification/extension: Hydrogen determinations in metals, oxides, ferroalloys, waste materials and in products and flux materials in the steel and iron industry) Determination of solid state density - Part 2: Gas pycnometry Period of validity: to Translation - 44/47

47 DIN DIN Iron Works Laboratory Manual, Volume 2, Part 2, 2nd edition 1998, p Iron Works Laboratory Manual, Volume 5, 1st edition 1997, p. 56 Particle size analysis; sieve analysis; general principles Particle size analysis; sieve analysis; procedure Determination of total carbon and sulfur content in steel by the infrared absorption spectroscopic method Sampling of ferroalloys and filler metals Further applicable documents: DIN X-ray spectrometry - X-ray emission and X-ray fluorescence analysis (XRF)- Part 1: Definitions and basic principles DIN X-ray spectrometry - X-ray emission and X-ray fluorescence analysis (XRF) - Part 2: Definitions and basic principles for measurements, calibration and evaluation of results 11 Selected investigations of further chemical products DIN Testing of plastics; determination of the percentage of styrene in reaction moulding materials based on unsaturated polyester resins; gas chromatography method 12 Determination of surface colony counts and colony counts in rinsing media DIN Annex C.3 DIN Annex C.3 Food hygiene - Commercial dishwashing with multi-tank transport dishwashers - Hygiene requirements, procedure testing Bioindicators, mountings and inserts Food hygiene - Commercial dishwashing with one-tank dishwashers Hygiene requirements, type testing Procedure and testing Period of validity: to Translation - 45/47

48 DIN Loose-leaf collection of BEHR'S VERLAG Section: B Determination of surface colony count on fitment and utensils in food areas - Part 3: Semiquantitative method with culture media laminated taking up equipment (squeeze method) Quality assurance of cleaning, disinfection and technical hygiene - Requirements, testing methods, documentation, references; test rhythms and bioindicators 13 Microbiological investigations of membrane filters and nutrients (Agar) BIA 9420: BIA Workbook of the IFA, 30th delivery IV/03 BIA 9430: BIA Workbook of the IFA, 32.nd delivery IV/04 Method for the determination of airborne mould concentrations at the workplace (Deviation: Analytics only) Method for the determination of airborne bacterial concentrations at the workplace (Deviation: Analytics only) Period of validity: to Translation - 46/47

49 Abbreviations used: AA-HuK-xxx ASTM BIA DepV, Annex 4 DEV DIN EN HfdE IEC IFA ISO LAGA TP Gestein-StB Hausverfahren (in-house procedure) American Society for Testing and Materials Berufsgenossenschaftliches Institut für Arbeitssicherheit (German Statutory Industrial Accident Institution) Deponieverordnung (Verordnung über Deponien und Langzeitlager); Vorgaben zur Beprobung (Probenahme, Probenvorbereitung und Untersuchung von Abfällen und Deponieersatzbaustoffen) (Waste Disposal Ordinance (ordinance for landfill sites and longterm storage); Specifications for sampling (sampling, sample preparation and investigation of waste materials and substitute building materials for landfill sites) Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung (Standard German method for the investigation of water, waste water and sludge) Deutsches Institut für Normung e. V. (German Standards Institute) Europäische Norm (European standard) Handbuch für das Eisenhüttenlaboratorium (Manual for iron work laboratories) International Electrotechnical Commission Institut für Arbeitsschutz der Deutschen Gesetzlichen Unfallversicherung (Institute for Occupational Safety of the German Accident Insurances) International Organization for Standardization Länderarbeitsgemeinschaft Abfall (Regional Consortium for Waste Materials) Technische Prüfvorschriften für Gesteinskörnungen im Straßenbau (Technical test specification for aggregates in road works) Period of validity: to Translation - 47/47