Annex to the Accreditation Certificate D-PL according to DIN EN ISO/IEC 17025:2005

Transcription

1 Deutsche Akkreditierungsstelle GmbH Annex to the Accreditation Certificate D-PL according to DIN EN ISO/IEC 17025:2005 Period of validity: 19 December 2012 to 18 December 2017 (Date of issue: 13 February 2013) Holder of certificate: GBA Gesellschaft für Bioanalytik mbh at these sites Goldtschmidtstraße 5, Hamburg Wiedehopfstraße 30, Gelsenkirchen Flensburger Straße 15, Pinneberg Brekelbaumstraße 1, Hameln Daimlerring 37, Hildesheim Meißner Ring 3, Freiberg Im Emscherbruch 11, Herten Berliner Ring 2, Wolfsburg Tests in the areas of: physical, physico-chemical and chemical analyses of water, sewage, groundwater, surface water, leachate, bottled water, mineral water, bathing water, sewage sludge, sludges, waste, soils, contaminated soils, compost, sediments, foods and commodities, wood, building materials and mixtures, fuels, insulating and waste oil, soil gas, dust, raw materials for pharmaceutical purposes and other pharmaceutical matrices, and chemical products; microbiological analyses of foods and raw materials for pharmaceutical purposes; selected molecular biological analyses of foods; analyses in accordance with the Drinking Water Ordinance, with the exception of the radiological parameters, sampling of untreated water and drinking water; sampling of water, sewage, surface water, water from aquifers, water from stagnant bodies of water, water from mineral and medicinal springs, flowing waters, sludges, sewage sludge, soils and contaminated soils, sediments and waste; Subject module Water, soil and contaminated sites, and waste Abbreviations used: see last page This document is a translation. The definitive version is the original German annex to the accreditation certificate.

2 Table of contents: 1 Environmental analysis (water, waste, soil/contaminated sites, drinking water) (from page 4) 2 Sector for insulating oil analysis (from page 32) 3 Sector for fuel analyses (secondary fuels, fuels, alternative fuels, biofuels) (from page 33) 4 Sector for food and commodity analysis (from page 35) 5 Sector for pharmaceuticals (from page 45) 6 Testing methods for the water subject module (from page 48) 7 Testing methods for the soil and contaminated sites subject module (from page 56) 8 Testing methods for the waste subject module (from page 69) 9 Testing methods in accordance with the Drinking Water Ordinance TrinkwV 2001 (from page 81) The testing methods are marked with the following symbols for the sites at which they are performed: = Hamburg GE = Gelsenkirchen = Pinneberg HM = Hameln HI = Hildesheim = Freiberg HE = Herten WOB = Wolfsburg The testing methods listed and marked with (A) comply with 2 of the agreement of 22 May 2000 between the Oberfinanzdirektion Hannover and the DAP, DACH and DASMIN accreditation bodies for the accreditation of testing laboratories and engineering firms in the context of investigating contaminated areas/areas suspected of being contaminated on federal property. For the sector for the sampling of water at the, GE and HI sites, competence for the full range of the required parameters is confirmed. For the sectors for the analysis of water, soil and soil gas at the and GE sites, competence for a part of the required parameters is confirmed. Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

3 Flexibility: The laboratories are authorised to apply the standardised testing methods listed under sections 1 to 5 (see table of contents), excluding the sampling methods, without the requirement for prior information and consent from the DAkkS, with different versions of the standards. Within the testing areas in the following table, the laboratories at the sites are authorised to freely select the standardised testing methods or their equivalents, without the requirement for prior information and consent from the DAkkS: Matrix Testing type Pinneberg Water, waste, soil/contaminated sites (outside of the subject module) Hamburg Raw materials and solids for the pharmaceutical industry Hamburg Foods Atomic spectrometry, gas chromatography, electrochemistry, gravimetry, measurement analysis, photometry, physical, physicochemical characteristics, sum parameters, ion chromatography Atomic spectrometry, electrochemistry, gravimetry, measurement analysis, sum parameters, non-specific and specific cultivation techniques Atomic spectrometry, gravimetry, photometry, measurement analysis and non-specific and specific microbiological cultivation techniques The testing methods listed are examples. The laboratory has an up-to-date list of all testing methods in the flexible scope of accreditation. Within the testing areas in the following table, the laboratories at the sites are authorised to modify and to further develop and redevelop the testing methods, without the requirement for prior information and consent from the DAkkS: Matrix Testing type Hamburg Raw materials and Gas chromatography solids for the pharmaceutical industry Hamburg Raw materials and HPLC, LC-MS/MS solids for the pharmaceutical industry Hamburg Foods Gas chromatography, HPLC, LC-MS/MS Hamelin Foods Hamelin Water, waste, soil/contaminated sites (outside of the subject module) LC-MS/MS, HPLC-MS/MS concerning analytes and matrices LC-MS/MS, HPLC-MS/MS concerning analytes and matrices The testing methods listed are examples. The laboratory has an up-to-date list of all testing methods in the flexible scope of accreditation. Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

4 1 Environmental analysis (water, waste, soil/contaminated sites, drinking water) Testing type: Atomic spectrometry (ICP-MS, ICP-OES, AAS) DIN EN 1483 (E12) DIN EN ISO AbfKlärV 1992 Appendix LAGA guideline SM 1/ LAGA guideline SM 2/ DIN EN ISO (E22) (A) and DIN ISO Determination of mercury Method using atomic absorption spectrometry Replaces (A) Determination of mercury using AFS Dev.: microwave digestion with aqua regia or nitric acid Replaces DIN EN (E35) Heavy metals: Cd, Cr, Cu, Hg, Ni, Pb, Zn Dev.: measurement using ICP-MS Heavy metals dev.: determination using ICP-OES (withdrawn directive) Heavy metals using ICP-OES Cd, Cr, Cu, Hg, Ni, Pb, Zn (withdrawn directive) Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES): Al, Ba, Be, B, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Se, Sn, Te, Ti, V, Zn Dev. for solids: determination from aqua regia or microwave digestion: As, B, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, P, Pb, Sb, Sn, Te, Ti, V and Zn; additionally Te and Tl Soil quality Determination of trace elements in extracts of soil by inductively coupled plasma atomic emission spectrometry (ICP-AES) WA, SE, SW, GW, EL WA, SS, DW, SO, WO SS, SL WA, EL WS, SL WA, SE, SW, GW, EL, AC, DW SO, SL, SED, BW DIN EN ISO (E29) E DIN EN Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Part 2: Determination of 62 elements: Dev.: here only for Al, As, B, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Hg, Mg, Mn, Mo, Na, Ni, Pb, Sb, Se, Sn, Sr, Tl, Zn, U only for drinking water Sludge, treated biowaste and soil Determination of trace elements using inductively coupled plasma mass spectrometry (ICP-MS) WA, SE, SW, GW, DW, EL, AC SO, SL, SED, SM, SS VGB-M 701 Serial no. 02 and Sodium, potassium and magnesium as minor constituents of gypsum after aqueous extraction and measurement using ICP-OES and conversion to the corresponding oxides GY Testing type: Gas chromatography (GC-FID, GC-ECD, GC-NPD, GC-MSD, GC-AED, GC-TCD, GC-MS/MS) Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

5 method SOP no method HI- MA-M method HI- MA-M DIN EN ISO DIN F (A) DIN ISO and (draft) HLUG, Contaminated sites handbook Vol. 7, Part VDI 3865 sheet n-alkanes C1-C4 and n-alkenes C1-C4 GA GE (Methane, ethane, ethylene, propane, propene, carbon dioxide, carbon monoxide) using GC-FID and TCD Alkanes, volatile C1 to C5 using GC-FID WA HI Alkanes, volatile C1 to C5 using GC-FID GA HI Water quality Determination of selected polybrominated diphenyl ethers in sediment and sewage sludge Method using extraction and gas chromatography/mass spectrometry: Polybrominated diphenyl ether (PBDE), polybrominated biphenyls (PBB), tetrabromobisphenol-a (TBBP-A), hexabromocyclododecane (HBCD), tribromoanisole (TBA) Dev.: liquid/liquid extraction with water samples, additional matrices (biota, polymers and materials): ultrasonic extraction, other internal standards Determination of benzene and some of its derivatives using gas chromatography using headspace analysis (HS-GC) BTEX: benzene and some of its derivatives, naphthalene, monochlorobenzene and dichlorobenzene by GBA-: in addition, SMFAB and Aliphatics C5-C10 Dev.: analysis also using GC-MSD. for soil and waste: elutriation with water Soil quality Gas chromatographic quantitative determination of volatile aromatic and halogenated hydrocarbons and selected ethers Static headspace method (BTEX/V) Replaces: HLUG, Contaminated sites handbook Vol. 7, Part BTEX/ V: benzene and some of its derivatives using GC-MS after overcoating with methanol Measurement of organic soil pollutants Gas chromatographic determination of volatile organic compounds in addition to other solvents in soil gas after adsorption at activated carbon and desorption with organic solvents WA, SO, SL, SED, PO, BIO, MAT WA, SE, SW, GW, DW, SO, WS, GA SO, SL, SED SO GA, HI GE, GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

6 VDI 2100 sheet method HI-MA-M U E DIN F DIN ISO (A) ISO DIN EN F DIN ISO (A) Determination of gaseous compounds in ambient air Determination of indoor air pollutants Gas chromatographic determination of organic compounds Active sampling by accumulation on activated charcoal Solvent extraction Dev.: determination of BTEX/V (benzene and some of its derivatives, as well as volatile halogenated hydrocarbons and C3 aromatics) using GC-MSD after method adjustment (tube type, internal standards, GC column) BTEX, V and C3 aromatics in air samples; determination from HS vials Determination of organochlorine pesticides, polychlorobiphenyls and chlorobenzene in water Method using gas chromatography and mass spectrometric detection (GC-MS) after liquid-liquid extraction Dev. measurement also using GC-MS/MS Determination of organochlorine pesticides and polychlorinated biphenyls Gas chromatographic method with electron capture detection (chlorobenzenes, organochlorine pesticides and PCBs) Dev.: analysis using GC-MSD Dev: processing of sludge or sediment from freezedried samples Water quality determination of short-chain chlorinated paraffins (SCCP) in water method using gas chromatography-mass spectrometry (GC- MS) and negative chemical ionisation (NCI) Dev.: additional determination of MCCPs, modular clean-up, modified quantification, GC-MSD detector, additional matrices (soil, sediment, material) Water quality Gas chromatographic determination of some selected chlorophenols in water using GC-MSD Dev: in addition, phenol, cresols and xylenols are also determined, as well as triclosan and bisphenol A in Replaces E-DIN EN Soil quality Determination of selected chlorophenols Gas-chromatographic method with electroncapture detection Dev. : determination using GC-MS GA GA, SO WA, SE, SW, GW, DW, EL SO, SL, SED WA, SW, GW, DW, SO, SED, MAT WA, SW, GW, DW SO HI, HI, HI, HI Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

7 AltholzV App in conjunction with DIN EN F CEN TR (BAM method) method - MA-M method -MA-M DECHEMA e.v DIN EN ISO H (A) DIN ISO (A) DIN EN Determination of selected chlorophenols (chlorophenols, PCP, phenols, cresols, xylenols) Dev: in addition, triclosan and bisphenol A are determined, additional determination in COM and MAT SO, WO, SED, COM, MAT Chlorophenols and alkylphenols using GC-MSD WO HI Glycols (ethylene-, diethylene-, triethylene- and propylene glycol) in water and soil using GC-MSD Determination of selected heterocyclic compounds according to the Kora list, in water and eluates using GC-MSD Water quality Determination of hydrocarbon index Part 2: Method using solvent extraction and gas chromatography GBA-: additional analysis after petrol pack Soil quality Gas chromatographic determination of content of hydrocarbon in the range of C 10 to C 40 GBA-: additional analysis after petrol pack Characterisation of waste Determination of hydrocarbon content in the range of C10 to C40 by gas chromatography (GC-FID) SO, WA WA EL WA, SE, SW, GW, HI, GE SO, SL, SED WS, SO, HI, GE, HI, GE LAGA guideline KW/ DIN EN ISO (P 10) DIN EN ISO F (A) incl. DIN F DIN EN ISO F Hydrocarbons in waste using GC-FID WS, HI, GE Water quality Determination of six complexing agents, EDTA, NTA and others Gaschromatographic method (GC-MSD) Dev.: additional matrices (soil and cleaning agents) after aqueous eluate creation Water quality determination of volatile halogenated hydrocarbons gas chromatographic method or GC-MSD Dev.: additional matrices (solids and air) Gas chromatographic determination of a number of monocyclic aromatic hydrocarbons, naphthalene and several chlorinated compounds using purgeand-trap and thermal desorption WA, SO, CA WA, SE, SW, GW, DW, SO, SL, SED, WS, GA WA, HI, GE GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

8 method -MA-M DIN ISO DIN F Contaminated sites handbook Vol. 7, part DIN EN ISO DIN EN ISO Nonylphenol standard horizontal method HI-MA-M U DIN EN ISO F (A) method -MA-M Musk compounds in water and solids using GC-MSD WA, SO, BIO, SED, CA Gas chromatographic determination of the content SO GE of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons Thermal desorption after blowing out and collecting on an adsorbent Determination of selected nitroaromatic WA compounds by gas chromatography (GC-MSD) Nitroaromatics by GC-MSD SO Water quality Determination of selected alkylphenols Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection Dev.: in addition, octylphenols and ethoxylate are determined Dev.: extraction with hexane and other clean-up Water quality Determination of selected alkylphenols Part 2: Gas chromatographic mass spectrometric determination of alkyl phenols, their ethoxylates and bisphenol A for non-filtered samples using solid-phase extraction and derivatisation; Deviation: here only for alkylphenols and their ethoxylates; only used for measurement, other internal standards, additional analytes: OP3EO and NP3EO Soils sludges and treated bio-waste Organic constituents- Nonylphenols (NP) and nonylphenolmono- and diethoxylates by gas chromatography with mass selective detection (GC-MS) Dev.: only used for extraction Determination of organic acids (C1-C5) in water after derivatisation using GC Water quality Determination of selected organic nitrogen and phosphorous compounds Gas chromatographic method (GC-MSD) pesticides SWE- EPA, neutral reprocessing (GC method 2) Dev.: for SO: extraction in an ultrasonic bath and enrichment through concentration Organophosphorous flame retardants: TCPP, TCEP, TDCP after solvent extraction and measurement by GC-MS WA, SW, SE, DW, GW, FW SO, SL, SED SO, SL, SED WA, SL WA, SW, GW, DW, SO WA, SW, GW, BUI HI Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

9 DIN LUA NRW leaflet 1 (A) 1994 DIN ISO DIN EN E DIN EN ZEK Jointly determinable substance groups (group F) Part 39: Determination of selected polycyclic aromatic hydrocarbons (PAH) Method using gas chromatography with mass spectrometric detection (GC-MS)(F 39) PAH: 16 polycyclic aromatic hydrocarbons according to EPA/TVO incl. methylnaphthalene and benzo[e]pyrene using GC-MSD Dev: processing of sludge or sediment from freezedried samples Soil quality Determination of polycyclic aromatic hydrocarbons (PAH) Gas chromatographic method with mass spectrometric detection (GC-MS) Dev: different solvent mixture Characterisation of waste Determination of polycyclic aromatic hydrocarbons (PAH) in waste using gas chromatography mass spectrometry (GC- MSD) Dev.: different solvent mixture Sludge, treated biowaste and soil Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC)) Harmonised method for the determination of polycyclic aromatic hydrocarbons (PAH) in polymers WA, DW, SE, EL, GE SO, SL, SED SO, SL, SED WS, SO, SL, FU WS, BW, SO, SL, FU, SED PO, GE, GE, HI DIN EN ISO 6468-F (A) DIN F Water quality Determination of certain organochlorine insecticides, polychlorinated biphenyls and chlorobenzenes Gaschromatographic method after liquid-liquid extraction (PCB: 6 polychlorinated biphenyls according to Balschmitter using GC-MSD: PCB 28, PCB 52, PCB 101, PCB 138, PCB 153, PCB 180) Dev.: additionally PCB 118, measurement with GC- MSD or GC-MS/MS Gas chromatographic determination of polychlorinated biphenyls (using GC-MSD or ECD) WA, SE, SW, GW, DW, EL WA, DW, HI, HI, GE EPA EPA 8260 B DIN ISO (A) Purge + Trap measurement of purgeable organic compounds in water by capillary column gas chromat./mass spectr. Volatile organic compounds by gas chromat./mass spectr. Soil quality Determination of organochlorine pesticides and polychlorinated biphenyls using GC (PCB: polychlorinated biphenyls according to Balschmitter: PCB 28, PCB 52, PCB 101, PCB 138, PCB 153, PCB 180, as well as: PCB 118 ) WA SM SO, BUI, JS, SL, SED GE GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

10 E DIN EN ASU L DIN S (A) LUA NRW Leaflet AltholzV 2002 Appendix IV no in conjunction with DIN S NIOSH NIOSH OSHA PV VDI 2464 sheet ISO in line with DEV-F33 (Blueprint) 52nd delivery 2002 Dev: processing of sludge or sediment from freezedried samples after Soxhlet extraction and clean-up with silica gel (in accordance with DIN F3) Measurement using GC-MS or MS/MS, additional matrices Sludge, treated biowaste and soil Determination of polychlorinated biphenyls (PCB) by gas chromatography-mass spectrometry (GC-MS) Analysis of foods Modular multi-method for the determination of pesticide residues in foods (PAH and PCB: 16 polycyclic aromatic hydrocarbons, according to EPA; 6 polychlorinated biphenyls according to Balschmitter, in addition: PCB 118; tetra- to hexachlorobenzenes and organochlorine pesticides after processing and measurement using GC-MSD) Dev.: clean-up in accordance with 64 LB L /1-4 Determination of 6 polychlorinated biphenyls (PCB) Dev. : sediments are freeze-dried and extracted for 8h using Soxhlet, measurement by GC- MS Dev. GE: drying at 105 C, 3h Soxhlet extraction, implementation in conjunction with LUA leaflet 6 (1996) PCB: 6 polychlorinated biphenyls using GC-MSD or ECD PCB 28, PCB 52, PCB 101, PCB 138, PCB 153, PCB 180 PCB: 6 polychlorinated biphenyls using GC-MSD or ECD PCB 28, PCB 52, PCB 101, PCB 138, PCB 153, PCB 180 PAH and PCB: polycyclic aromatic hydrocarbons, according to EPA and 6 polychlorinated biphenyls according to Balschmitter, after adsorption on PU foam XAD-2 or Florisil and measurement using GC- MSD Water quality Determination of dioxin-like polychlorinated biphenyls Method using gas chromatography/mass spectrometry (Determination of WHO-PCB: PCB 77, PCB 81, PCB 105, PCB 114, PCB 118, PCB 123, PCB 126, PCB 156, PCB 157, PCB 167, PCB 169, PCB 189) using GC-MSD Dev.: additional matrices (solids) after Soxhlet WS, BW, SO, SL, FU, SED BIO SO, SS, SED SO, HI, GE GE WO, SO, SL, WS, HI, GE GA WA, SW, SE, DW, GW, FW, SO, SL, SED Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

11 in line with AbfKlärV 1992 in line with VDI 3499 sheet DIN EN DIN EN DIN EN VDI 2464 sheet DEV-F33 (Blueprint) 52nd delivery 2002 DIN S VDI 3499 sheet DIN EN ISO DIN F (A) extraction in accordance with DIN ( ) Determination of PCBs and related products Part 1: Separation and determination of selected PCB congeners by gas chromatography (GC) using an electron capture detector (ECD) Dev.: measurement using GC-MS Determination of PCBs and related products Part 2: Calculation of polychlorinated biphenyl (PCB) content; dev.: measurement using GC-MS Characterisation of waste Determination of selected polychlorinated biphenyls (PCB) in solid waste by using capillary gas chromatography with electron capture or mass spectrometric detection Measurement of emissions Indoor air measurement Measurement of polychlorinated biphynyls (PCBs) GC/MS method for PCB 28, 52, 101,138, 153, 180; adsorption PU foam Determination of polychlorinated dibenzodioxins (PCDD) and polychlorinated dibenzofuranes (PCDF) PCDD/F: 17 polychlorinated dibenzodioxins and dibenzofurans using GC-MSD Determination of polychlorinated dibenzodioxins (PCDD) and polychlorinated dibenzofurans (PCDF) (S 24) Emission measurement Determination of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) Dev.: determination in other matrices (filter dust, boiler ash, slag) using GC-MS Petroleum products and used oils Determination of PCBs and related products Part 3: Determination and quantification of the content of polychlorinated terphenyls (PCT) and polychlorinated benzyl toluenes (PCBT) by gas chromatography (GC) using an electron capture detector (ECD) Dev.: measurement using GC-MS, liquid/liquid extraction with water samples, additional matrices (solids): ultrasonic extraction Determination of selected phenols Part 2: Method by derivatisation and gas chromatography Dev.: analysis using GC-MSD Determination of phenoxyalkyl carbonic acids by gas chromatography and mass-spectrometric detection after solid-liquid-extraction and OIL OIL WS GA WA SL, SED DU, SM, GE GE SO, WO, WA, OIL WA, SW, SE, DW, GW, FW WA, SW, SE, DW, GW, FW Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

12 derivatisation DIN EN ISO (F20) DIN EN ISO (F 26) E DIN method GE-MA-M U method -MA-M DIN F (A) Supplementary instruction f. calibr. and quantity. in analysis of hydrocarbons in SMFAB samples DIN P DIN EN ISO (F 13) Water quality Determination of selected phenoxyalkanoic herbicides, including bentazones and hydroxybenzonitriles as well as clopyralid and Quinmerac by gas chromatography and mass spectrometric detection after solid-liquid extraction and derivatisation GBA: pesticides in accordance with Swedish EPA, method 1, acidic work-up Dev. for soil: extraction in an ultrasonic bath and enrichment through concentration Replaces DIN , Water quality Determination of selected phthalates using gas chromatography / mass spectrometry Dev.: liquid-liquid extraction Soil quality Determination of selected phthalates in sludge, sediment, solid waste and soil after extraction and determination using gas chromatography mass spectrometry (GC-MS) Dev.: additional analytes: Dimethyl, diethyl-, dipropyl-, diisobutyl-, dipentyl-, butyl benzyl, dicyclohexyl-, dioctyl-, diisononyl-, diisodecyl phthalate Dev.: additional matrix: Commodity Oxygen, nitrogen, carbon monoxide, carbon dioxide and methane in soil gas, landfill gas and gases using GC-FID and TCD Screening (GC-MS), qualitative and semiquantitative orientation analysis after extraction of solids with n-hexane, acetone or n-hexane/acetone (50:50, v:v) Gas chromatographic determination of low volatile halogenated hydrocarbons GBA HI: only chlorobenzenes: tri- to hexachlorobenzene GBA GE: in combination with DIN T1 (PCB only) WA, SO, DW WA SO, SL, SED, WS, COM GA SO, SED, SL WA, DW SMFAB after liquid extraction using GC-MSD WA, SO Determination of vinyl chloride (chloroethene) by headspace gas chromatography Water quality Determination of selected organotin compounds Gas chromatographic GE WA, DW, SO, GA HI WA, SW, SE, DW, GW, FW, HI, GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

13 method DIN EN ISO in conjunction with E DIN LMBG 64 LB L method -MA-M method HI-MA-M U Soil quality Determination of selected organotin compounds Gas-chromatographic method (GC- FPD) Identification and quantification of organotin compounds in solids (soils, sediments, waste): withdrawn Analysis of foods Gas chromatographic determination of organotin compounds in fish and mussels (Determination of mono-, di-, tri- and tetrabutyltin, mono- and diooctyltin, tricyclohexyltin, mono-, diand triphenyltin using GC-FPD in biota) Organotin compounds using GC-FPD in passive collectors and adsorber materials Determination of furan, thiophene, 3- methylthiophene and 2,5-dimethylthiophene (heterocyclic compounds) in water using headspace gas chromatography SO, SL, SED BIO PASSIVE ADSORB WA EL HI Testing type: HPLC (HPLC-DAD, HPLC-UV, HPLC-FLD, LC-MS/MS) method HM-MA-M U method HI-MA-M U method HI-MA-M U method HM-MA-M U Acrylamide using LC-MS/MS DW HM Determination of aldehydes in water and eluates WA, EL HI Determination of aldehydes in solids (incl. formaldehyde) Pharmaceutical substances using LC-MS/MS SO GW, SW, DW, SO, SED HI HM method HM-MA-M U method HM-MA-M U method HM-MA-M U Determination of selected LAS in detergents (solid and liquid) Determination of selected LAS in water Determination of selected LAS in solids DE, CA WA, SW, DW, GW SO, SS, SL HM HM HM Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

14 06 DIN EN ISO F DIN ISO ISO method HM-MA-M methods HM-MA-M-U method HM-MA-M LUA NRW leaflet DIN ISO Determination of certain explosives and related compounds using HPLC-DAD Soil quality Determination of selected explosives Part 1: Method using high-performance liquid chromatography (HPLC) with UV detection Dev. Measurement using LC-MS/MS Glyphosate, glufosinate, AMPA and amitrole after derivatisation with FMOC and measurement Dev. using LC-MS/MS Determination of selected heterocyclic compounds in water using LC-MS/MS WA, EL, SO SO WA, SW, DW, GW Oestrogens using LC-MS/MS GW, SW, DW HM Determination of polynuclear aromatic hydrocarbons using HPLC-UV/DAD/FLD WA HM HM HM HM SO, WS, AS, MIR HI DIN EN ISO DIN EN ISO (F 12) method HM-MA-M U DIN (F 35) DIN F DIN S Determination of 15 polycyclic aromatic hydrocarbons (PAH) in water by HPLC with fluorescence detection after liquid-liquid extraction (replaces: DIN F ) Determination of selected plant treatment agents Method using high performance liquid chromatography with UV detection after solid-liquid extraction Dev. HM: LC-MS/MS in conjunction with HM-MA-M U 2-4 WA, SE, SW, GW, DW HI WA, SW, GW, SO HM Determination of PSM in solids using LC-MS/MS SO, SED HM Determination of selected phenoxyalkyl carbonic acids and further acid plant treatment agents Method using high performance liquid chromatography and mass spectrometric detection (HPLC-MS/MS) Determination of selected polyfluorinated compounds (PFC) in water Method using high performance liquid chromatography and mass spectrometric detection (HPLC-MS/MS) after solidliquid extraction Determination of selected polyfluorinated compounds (PFC) in sludge, compost and soil Method using high performance liquid WA, SW, DW, GW WA, SW, DW, GW SL, SED SS, SO HM HM HM Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

15 chromatography and mass spectrometric detection (HPLC-MS/MS) method HM-MA-M X-ray contrast medium using LC-MS/MS WA, GW, SW, DW HM Individual testing methods of electrochemistry DIN D (A) DIN D (A) VGB-M 701 serial no. 02 and DIN EN G (A) DIN G DIN EN Testing type: Gravimetry Determination of fluoride GBA: also in acids Determination of total inorganic bound fluoride after digestion and distillation; GBA: also in eluates Fluoride from soda extract using ion-selective electrode Determination of dissolved oxygen; electrochemical method (also on-site) Oxygen saturation index (withdrawn standard) Determination of water by automatic Karl Fischer titration (IEC 60814:1997); WA, SE, GW, DW, AC SE, EL, AC GY, CC, DU WA, SW, GW, DW WA, SW, SE, DW, GW, FW SM, IO, OIL, HE,, GE, HM,, HE DIN VGB-M 701 serial no DIN S DIN EN ISO Moisture content and dry residue (withdrawn WO, HI, GE, standard) HM, Moisture content at 40 C. GY Determination of dry residue by freezing and preparation of the freeze dried mass of sludge Dev.: also from biota samples Soil quality Pre-treatment of samples by freezedrying for subsequent analysis SL, SED, BIO SO DIN EN DIN Characterisation of waste Determination of loss on ignition in waste, sludge and sediments Methods of soil investigations for agricultural water engineering Chemical laboratory tests Part 3: Determination of the loss on ignition and the residue of soil after ignition WS, SL, SED SO, GE, GE, Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

16 DIN DIN EN (S 3a) MA-M VGB M701 serial no DIN H (A) DIN ISO (A) DIN EN DIN S2 and S DIN EN S2a DIN ISO DIN DIN S DIN H Bundesgütegemeinschaft Kompost e.v. Methodenbuch zur Analyse (Federal Compost Association methods book for the analysis of compost), Chapter IV A Soil Investigation of soil samples Determination of ignition loss Characterisation of sludges Determination of the loss on ignition of dry mass Silicon dioxide, aqua regia insoluble SO SS, SL DU, CC, GY Sieve residue at 32 µm GY Determination of total dry residue, filtrate dry residue and residue on ignition Soil quality Determination of dry matter and water content on a mass basis Gravimetric method Characterisation of waste Calculation of dry matter by determination of dry residue or water content Dry residue and loss on ignition (withdrawn standard) Characterisation of sludges Determination of dry residue and water content WA, SW, SE, DW, GW, FW SO, BW, WS WS, HI, GE, HI, GE,, HI, GE,, GE SO, SL, HI, GE, SO, SL, SS, HI, GE, Soil quality Determination of dry bulk density SO, GE Soil Investigation of soil samples Determination of density of soil Part 2: Field tests (withdrawn standard) Determination of leachability by water (steam method) Determination of total dry residue, filtrate dry residue and residue on ignition (H 1) Plant compatibility in the seed planting experiment with spring barley SO SO SO, WS SO GE, HI, GE,, HI, GE GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

17 Testing type: Measurement analysis DIN E in conjunction with AbfKlärV 1992 BGBl. S. 912, App. 1 AbfKlärV 1992 BGBl. I S. 912, App. 1 in conjunction with Federal Compost Association methods book for the analysis of compost, Chapter III, B /09 DIN DIN DIN EN (A1) (A2) (draft) VGB-M 701 serial no Federal Compost Association methods book for the analysis of compost, Chapter III, B VDLUFA book of methods on soil analysis Vol. I, A DIN Determination of ammonia-nitrogen (E 5) Dev.: also from soil Basic active substances Assessment of water, soils and gases for their aggressiveness to concrete Part 2: Sampling and analysis of water and soil samples: Smell, ph, potassium-permanganate consumption, Hardness (dev. using ICP-OES), Magnesium (dev. using ICP-OES), Ammonium (dev. using CFA), Sulphate and chloride (dev. using IC), lime solubility as Heyer marble test, sulphide Assessment of water, soils and gases for their aggressiveness to concrete Part 2: Sampling and analysis of water and soil samples: Acidity according to Baumann-Gully, sulphate and chloride (Dev. after aqueous elution using IC), sulphide Concrete part 1: Specification, performance, production and conformity WA, SW, SE, GW, FW, SO SO, SED, SS, BW WA, SW, SE, GW, FW SO WA, SO Calcium as calcium oxide, complexometric GY Carbonate according to Scheibler SO, SED, GE Carbonate according to Scheibler SO, SED, GE Carbonate content (withdrawn standard) SO Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

18 LAGA CN/ in conjunction with ISO and Determination of total cyanide (withdrawn directive) SO, WS TL Streu 2003 edition Ferrocyanide (anti-caking agent) DS HI DIN H DIN D DIN EN ISO 8467 (H5) DIN H Water hardness (H 6) Dev.: measurement of Ca and Mg using ICP Carbon dioxide chemistry: Calculation of dissolved carbon dioxide (free carbon dioxide), carbonate and bicarbonate ion (withdrawn standard) Water quality Determination of permanganate index Determination of acid and base-neutralizing capacities (H 7) WA, DW WA WA, DW WA, SW, GW, GE, HI, GE, DIN CEN/TS Leaching behaviour test Acid and base WS neutralisation capacity test -MA-M 8-38 Acidity (HCl) by titration using sodium hydroxide AC DEV H 12 Nitrogen (total), calculation WA, DW GE DIN ISO Soil quality Determination of total nitrogen Modified Kjeldahl method SO, BW, SED, BIO VDLUFA book of methods Dev.: also from biota samples on soil analysis Vol DIN H Swedish standard SS Nitrogen (bound); Method after reduction with Devarda's alloy and catalytic digestion Dev.: also from soil, sediment (withdrawn standard) WA, SE, SO, SED DIN EN (H11) Water quality determination of Kjeldahl nitrogen; method after mineralisation with selenium WA, SW, SE, DW, GW, FW VGB-M 701 serial no Sulphur dioxide (SO2) as calcium sulphite hemihydrate, titrimetically with iodine GY DIN EN Characterisation of sludges Determination of SL SS Kjeldahl nitrogen TL Streu 2003 edition Thawing substance DS HI DEV-D15 ASTM D Thiosulphate (withdrawn DEV-regulation) Estimation of the permanganate consumption (SOD) in soil according to ASTM D WA, SW, SE, DW, GW, FW SO HI Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

19 Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

20 Testing type: Photometry DIN C DIN E (A) DIN EN ISO (E 23) (A) DIN EN ISO (G4) DIN D (A) DIN EN ISO (D 40) DIN EN DIN ISO E DIN EN ISO DIN EN ISO (D6) DIN EN ISO DIN D (A) DIN D LAGA guideline. CN 1/ DIN E DIN EN ISO 7887 (C 1) (A) Determination of absorption in the range of the UV radiation, Spectral absorptions coefficient Determination of ammonia-nitrogen Water quality Determination of ammonium nitrogen Method by flow analysis (CFA) and spectrometric detection Water quality Determination of free chlorine and total chlorine Part 2: Colorimetric method using N,N-diethyl-1,4-phenylenediamine, for routine control purposes Deviation: also in acids Photometric determination of chromium(vi) using 1,5-diphenylcarbonohydrazide (D 24) Water quality Determination of chromium(vi) Photometric method for weakly contaminated water Characterisation of waste and soil Determination of Chromium(VI) in solid material by alkaline digestion and ion chromatography with spectrophotometric detection Soil quality Determination of total cyanide and easily liberatable cyanide Continuous-flow analysis method Cyanide (total and easily liberatable) using continuous flow analysis (CFA) Replaces DIN EN ISO 14403, Determination of cyanides Replaces DIN D13: Replaces DIN D14: Determination of cyanides in drinking water, weakly contaminated groundwater and surface water: Cyanide (total and easily liberatable) after separation process (withdrawn standard) Cyanide, total and easily liberatable (withdrawn directive) WA, SW, SE, DW, GW, FW WA, SW, SE, DW, GW, FW WA, SW, GW, EL, DW WA, AC WA, DW DW GW SW SO SO, GE, GE WA, SW, GW, EL WA, SW, GW, SE, DW WA, DW, GW, SW Determination of iron WA, DW Water quality Examination and determination of colour WS WA, SW, GW, HI, GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

21 DIN P method -MA-M DIN D (A) And DIN EN ISO (D 28) (A) DIN EN (D 10) (A) EN ISO (H 37) (A) DIN H DIN EN ISO 6878 (D 11) DIN EN ISO (D46) DIN EN ISO (H36) DIN D (A) DIN D VGB M701 serial no Determination of hydrazine WA, SW, SE, DW, GW, FW Iodine, iodide AC Photometric determination of nitrate WA, DW Water quality Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection Water quality Determination of nitrite; spectrometric method Water quality Determination of phenol index by flow analysis (FIA and CFA) Determination of phenol index after distillation and colouring extraction using 4-Aminoantipyrine Dev.: soil/waste samples after suspension in phenol-free water quantification by CFA Water quality Determination of phosphorus Ammonium molybdate spectrometric method Water quality Determination of orthophosphate and total phosphorus contents by flow analysis (FIA and CFA) Part 2: Method by continuous flow analysis (CFA) Water quality Determination of nitrogen Part 1: Determination of nitrogen using oxidative digestion with peroxodisulfate Photometric determination of dissolved sulphide WA, SW, GW, SE, EL, DW WA, SW, GW, SE, DW WA, SE, SW, GW, EL WA, SO, DU WA, SE, SW, GW, SS WA, SW, SE, DW, GW, FW WA, SE, SW WA, SW, SE, DW,, GE GW, FW Determination of easily liberated sulphide WA, SE, SW, GE Degree of whiteness GY Federal Compost Association methods book for the analysis of compost, Chapter IV A Stability of the nitrogen cycle of organic materials Dev: measurement of ammonium with CFA and measurement of nitrate with IC SO GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

22 Testing type: Physical and physicochemical characteristics DIN EN ISO C Water quality Determination of alkalinity Part 1: Determination of total and composite alkalinity WA, SW, SE, DW, GW, FW DIN C Calculation of the calcite saturation of water WA, SW, SE, DW, GW, FW, GE, HM DEV C 9 DIN Determination of density Deviation: also from dust, mixed salts, waste Soil Investigation of soil samples Uniaxial compression test (withdrawn standard) WA, DU, CC, WS SO, WS GE DIN EN ISO 7887-C (A) DIN DIN ISO (A) Water quality Examination and determination of colour (withdrawn standard from 1994) Vane testing Dimensions of apparatus, mode of operation, evaluation (withdrawn standard) Soil quality Determination of the specific electrical conductivity WA, DW SO, WS SO, GE GE, HI, GE, DIN EN C (A) DIN C DIN ISO (A) Water quality Determination of electrical conductivity (also on site) Soil quality Determination of ph-value (C 5) (also on site) (withdrawn standard) Soil quality Determination of ph-value (H 2 O, CaCl 2, KCl) (withdrawn standard) WA, SW, GW, EL, DW WA, SW, GW, EL, DW SO, BW, WS, HI, GE, HM,, HI, GE, HM,, HI, GE, DIN EN (S 5) in conjunction with AbfKlärV 1992 Appendix VGB-M 701 serial no DIN C BioAbfV 1998 Appendix 3 DIN C Characterisation of sludge Determination of phvalue (H 2 O) Replaces DIN S SS, SL ph-value GY, HI, GE, Determination of redox potential WA, GW, HI, GE, HM, Salt content, calculation as potassium chloride after measurement of conductivity Determination of temperature (C 4) (also on site) BW WA, SW, GW, DW, HI, GE, HI, GE, HM, Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

23 DIN EN ISO 7027 (C 2) (A) method GE-MA-M with DIN Part 1( ) + Part 2 ( ) Water quality Determination of turbidity (also on site) Determination of dynamic viscosity using rotation viscometer WA, DW OIL solutions, viscous liquids, HI HE Testing type: Sum parameters DIN H2-2/ DIN EN DIN EN 872 (H 33) DIN H DIN S DIN EN 1485 (H 14) DIN EN ISO 9562 (H 14) DIN (H 22) DIN EN 1899 (H 51) DIN H (A) DIN ISO (H 45) DIN H DIN S (A) Determination of filterable matter and the residue on ignition (H 2) Determination of total dissolved solids (TDS) in water and eluates Determination of suspended solids Method by filtration through glass fibre filters (withdrawn standard) Determination of the settleable matter by volume in water and waste water (H 9); Volume GE, HM, with a sample volume of 2 l Determination of adsorbed organically bound halogens (AOX) AOX: adsorbable organically bound halogens, method: batch test and column method (withdrawn standard) Water quality Determination of adsorbable organically bound halogens (AOX) Replaces method H14: and Determination of dissolved adsorbable organically bound halogens in salt-loaded water after solid-phase extraction (SPE-AOX)(H 22) Determination of biochemical oxygen demand after n days (BSB n ) Part 1: Dilution and seeding method with allylthiourea acid addition Determination of the chemical oxygen demand (COD), in the range above 15 mg/l Water quality Determination of the COD: chemical oxygen demand index (ST-COD), cuvette test Determination of extractable organically bound halogens; : also from acids Dev.: combustion in oxygen flow (withdrawn standard) Determination of strippable and extractable organically bound halogens (S 17) WA, SE, SW WA, EL WA, SW, SE, DW, GW, FW WA, SW, SE, DW, GW, FW SS, SL WA, SE, SW, GW, EL WA, SE, SW, GW, EL, HI, GE,, HI, GE, HI, HI, GE, HM, GE GE WA, SE, SW, GW GE WA, SE WA, SE WA, SE, SW WA, AC SO, SL, GE, GE, HI, GE, GE, GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

24 (draft) Deviation for GE: only extractable organically bound halogens DEV H 22 Decaying ability (withdrawn standard) DIN Humus content (withdrawn standard) DIN EN Characterisation of waste Halogen and sulphur content Oxygen combustion in closed systems and determination methods DIN H LAGA KW/04 Point AbfAblVO Appendix 4 no. 2.3 DIN H DIN EN (H 23) VGB-B 401, sheet DIN EN (H 34) method -MA-M DIN EN 872 (H 33) DIN EN 1484 (H 3) (A) DIN EN DIN ISO Federal Compost Association methods book for the analysis of compost, Chapter IV B WA SO WS, GE Gravimetric determination of low volatile lipophilic WA, SE, SO, WS, HI, GE substances after solvent extraction (H 56) Dev. for soil, waste: solid-liquid extraction, in also with various solvents Lipophilic substances, total extractable WS, SO, CS, HI, GE Lipophilic substances, total extractable WS, HI, GE Determination of phenol index Determination of methylene blue and bismut active substances (H 23) (withdrawn standard) WA, SW, SE, DW, GW, FW WA Residual carbon content SO, WS GE Water quality Determination of nitrogen Determination of bound nitrogen (TNb) following oxidation to nitrogen oxides Oxygen consumption in sediments according to requirements of the BfG Water quality Determination of suspended solids Method by filtration through glass fibre filters Water analysis Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) Characterisation of waste Determination of total organic carbon (TOC) in waste, sludges and sediments Soil quality Determination of organic and total carbon after dry combustion (elementary analysis) Content of germinable seeds and plant parts capable of budding WA, SE, SW SED WA, SW, SE, DW, GW, FW WA, SE, SW, GW, EL, DW WS, SL, SED SO BW GE HE GE GE, HI, GE, GE, GE GE Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

25 Individual testing methods of aquatic toxicity tests Dep V 2009 Appendix 4 no DIN EN ISO 9888 (L 25) DIN L Dep V 2001 Appendix 4 no in conjunction with DIN S DIN EN ISO Breathability over 4 days (AT 4) WS GE Water quality Determination of aerobic biodegradability of organic substances in aqueous medium Static test (Zahn-Wellens method) Determination of the tolerance of Daphnia to the toxicity of waste water by way of a dilution series (L 30) Gas formation rates in fermentation test over 21 days (GB 21) Water quality Determination of the inhibitory effect of water samples on the light emission of Vibrio fischeri, Part 2: Method using liquid-dried bacteria WA, SE WA, SE WS WA GE GE GE GE Individual testing methods of non-specific cultivation techniques DIN EN ISO 6222 (K5) TrinkwV 2001, Annex 5 Part 1 d) bb) Quantitative determination of culturable microorganisms Determination of colony count by inoculation in a nutrient agar culture medium Quantitative determination of culturable microorganisms Determination of colony count by inoculation in a nutrient agar culture medium (Colony count at 22 C and 36 C) DW, SW, GW DW, SPW, HM, WOB Testing type: Specific cultivation method TrinkwV 2001, Annex 5 Part 1 e) Colilert -18/ Quanti- Tray UBA (German Federal Environment Agency) communication, Bundesgesundheitsblatt 49, 2006, p ff Detection of Clostridium perfringens using membrane filtration (mcp-agar at 44 +/-1 C over 21 +/-3 hours) Detection of Escherichia coli and coliform bacteria using finished reagents DW DW, SPW, WOB, HM Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

26 DIN EN ISO (K 12) DIN EN ISO (K 15) DIN EN ISO (K 22) UBA recommendation DIN EN ISO DIN EN ISO (K 11) Water quality Detection and enumeration of Escherichia coli and coliform bacteria; Part 1: Membrane filtration method Water quality Detection and enumeration of intestinal enterococci; Part 2: Membrane filtration method Detection of Legionella in drinking water and bathing water Water quality Detection and enumeration of Legionella Part 2: Direct membrane filtration method with low bacterial count Water quality Detection and enumeration of Pseudomonas aeruginosa Method by membrane filtration DW, SPW, GW DW, SW, GW DW, SPW DW, SPW DW, SPW, WOB, WOB, WOB, WOB, WOB Testing type: Sampling of water and other applicable documentation for sampling DIN A Sampling of waste water Replaces DIN A SE, LE, GE, HI, HM DIN A (A) DIN EN ISO (K 19) DIN A (A) DIN A DIN ISO DIN A (A) DIN EN ISO (S 1) Sampling from aquifers GW, GE, HM, HI, Sampling for microbiological analysis WA, HI, GE, HM,, WOB Sampling from stagnant bodies of water SW, DW, GE, HM,, HI Sampling of drinking water and untreated water WA, DW, HI, GE, (withdrawn standard) HM, Water quality sampling part 5: Guidance on sampling of drinking water from treatment works and piped distribution systems WA, DW, HI, GE, HM, Sampling from flowing waters FW, DW, GE, HM,, HI Water quality Sampling Part 13: Guidance on SL, SS, GE, HI sampling of sludges (withdrawn standard) Replaces DIN S Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89

27 DIN S DIN A DIN ISO DIN EN ISO DIN Sampling of sediments using soil core sampler, box SED, GE, gripper, Van-Veen soil sampler, downpipe HM, HI Sampling of water from mineral springs and spas WA, DW, GE, HM, HI Soil quality Sampling Part 2: Guidance on sampling SO techniques Geotechnical investigation and testing Sampling SO methods and groundwater measurements Part 1: Technical principles for execution Replaces DIN 4021: Soil Exploration by excavation and borings, as well SO as sampling: Sampling in the investigation of areas with suspected contamination and contaminated sites (ramming core sampling) (withdrawn standard) Other applicable documentation Federal Compost Association methods book for the analysis of compost, Chapter IV A DIN A DIN EN ISO (A 4) DIN EN ISO (A21) incl. Corr. 1, (A, B) (draft) ISO F-UB Leaflet 4, quality assurance LAWA AQS leaflet P 3/ Gaseous phytotoxins in the seed planting experiment with cress Pre-treatment, aliquotation and homogenisation of non-homogeneous water samples Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques Replaces DIN EN : Replaces DIN EN : Guidance on the preservation and handling of water samples Guidance on sampling of groundwater (withdrawn standard) WA, SW, SE, DW, GW, FW WA, DW WA, SW, SE, DW, GW, FW WA, DW GE, GE, HM,, HI, GE,, GE, HM,, HI, GE, HM,, HI Sampling of ground water GW, DW, HI Waste water digestion SE HI Period of validity: 19 December 2012 to 18 December 2017, Date of issue: 13 February /89