Brammer Standard Company, Inc.

Transcription

1 Brammer Stadard Compay, Ic. Certificate of Aalysis BS 3941 Certified Referece Material for AISI Carbo Steel Grade UNS Number G10400 Certified Estimate of Certified Values 3 Certified Estimate of Value 1 Ucertaity 2 Value 1 Ucertaity 2 Al S As Sb C Si Ca S Co Ti Cr V Cu M Mo N Nb Ni O P Pb Iformatioal Values 3,4 B (0.0001) Fe [98.3] Mg (0.0002) Ta (0.0004) W (0.0004) Zr (0.0003) 1 For each elemet, the certified value listed is the preset best estimate of the true value based o the mea of the weighted results of a iterlaboratory testig program. See page 4 for more iformatio o its calculatio. 2 For each elemet, the ucertaity listed is based o a statistical evaluatio of the cotributios of homogeeity ad the iterlaboratory testig program. See page 4 for more iformatio o its calculatio. 3 Values are give i weight percet. Values i brackets are reported by differece. 4 Values i paretheses are ot certified ad are provided for iformatio oly. Trace elemet iformatio values for Bi, Ce, Cl, Ga, Ge, K, Na, ad Z are show o page 4. The requiremets of ISO Guides 31, 34, ad 35 were followed for the preparatio of this Certified Referece Material ad certificate of aalysis. This is a Certified Referece Material as defied by ISO Guide 30. Certificate Number REV Page 1/7

2 BS 3941 * Code for method Certified values listed as weight percet Aalysis * Al * As * C * Ca * Co * Cr * Cu * M Average Std dev H U t-statistic U U Certified Ucertaity Tolerace Aalysis * Mo * N * Nb * Ni * O * P * Pb * S Average Std dev H U t-statistic U U Certified Ucertaity Tolerace Certificate Number REV Page 2/7

3 BS 3941 * Code for method Certified values listed as weight percet Aalysis * Sb * Si * S * Ti * V Average Std dev H U t-statistic U U Certified Ucertaity Tolerace BS 3941 * Code for method Iformatioal values listed as weight percet Aalysis * B * Fe * Mg * Ta * W * Zr [ ] [98.3] Average Std dev H U t-statistic U U (Iformatioal) (0.0001) [98.3] (0.0002) (0.0004) (0.0004) (0.0003) Certificate Number REV Page 3/7

4 For each elemet, i accordace with the requiremets of ISO Guides 34 ad 35, a effort must be made to accout for the effects o the certified value of the ucertaity estimate from homogeeity testig (H) ad the ucertaities of the cotributig laboratories. The average (A) is calculated usig a weighted mea where the reciprocal of the square of each laboratory s combied ucertaity (C ), calculated from its stadard deviatio (S ) ad its ucertaity estimate (U ), is used as the weight (W ) for it s mea (M ). The stadard deviatio (S) is calculated as the square root of the reciprocal of the sum of the weights. U 1 is the combied ucertaity from homogeeity ad labs. U 2 is U 1 multiplied by the coverage factor (95 % t-statistic). U 3 is U 2 divided by the square root of the umber of determiatios (). Thus: C S U 2 2 W 1 C 2 A i 1 W M i1 W S 1 W i1 2 2 U H S U t U U U 2 All but the fial reported values are take to two sigificat figures as determied by each quatity s ucertaity estimate. The fial reported Ucertaity is U 3 rouded to oe sigificat figure ad represets the half width of the 95 % cofidece iterval for the Certified value. The fial reported Certified value is A rouded to the same decimal place as the Ucertaity. The Ucertaity is a measure of the quality of the Certified value. The Tolerace is a measure of the expected performace of a aalysis. This ivolves further expadig the sample ucertaity to iclude istrumet ad operator ucertaity, for those without access to such calculatios. For further iformatio regardig the cofidece iterval for the certified value see ISO Guide 35:2006 sectio 6. BS 3941 * Code for aalytical method Trace aalysis listed as mg/kg (ppm) Aalysis * Bi * Ce * Cl * Ga * Ge * K * Na * Z Aalytical Method Codes: 1 Combustio (ASTM E1019) 7 Photometric 13 Titrimetric 2 Fusio (ASTM E1019) 8 Flame Atomic Absorptio 14 DCP Atomic Emissio 3 Spark Atomic Emissio 9 GF Atomic Absorptio 15 HG Atomic Fluorescece 4 ICP Atomic Emissio 10 X-Ray Fluorescece 16 Differece 5 ICP Mass Spectrometry 11 GD Atomic Emissio 17 Atomic Absorptio Spectrometry 6 Gravimetric 12 GD Mass Spectrometry ICP = Iductively Coupled Plasma GF = Graphite Furace GD = Glow Discharge DCP = Direct Curret Plasma HG = Hydride Geeratio Certificate Number REV Page 4/7

5 aboratory ocatio Registrar Accreditatio Brammer Stadard Compay, Ic. Housto, TX A2A 17025, Guide 34 Aalytical Associates Farmigto Hills, MI A2A Dirats aboratories Westfield,MA ACASS Crucible Specialty Metals Syracuse, NY ECO Corporatio St. Joseph, MI A2A Norther Aalytical aboratory, Ic. ododerry, NH PRI/Nadcap Shiva Techologies, Ic. Cicero, NY VHG abs Machester, NH A2A 17025, Guide 34 NS Aalytical Clevelad, OH ACASS aboratory Testig, Ic. Hatfield, PA PRI/Nadcap uvak Ic. Boylsto, MA PRI/Nadcap Evas Aalytical Group iverpool, NY A2A Exova Gledale Heights, Il A2A Istytut Metalurgii Zelaza Gliwice, Polad PCA AB 554 Natioal Aalysis Ceter For Iro Ad Steel Beijig, Chia CNAS Norther Aalytical aboratory, Ic. ododerry, NH PRI/Nadcap A2A = America Associatio for aboratory Accreditatio ACASS = ANSI-ASQ Natioal Accreditatio Board CNAS = Chia Natioal Accreditatio Service Nadcap = Natioal Aerospace ad Defese Cotractors Accreditatio Program PCA = Polish Ceter For Accreditatio PRI =Performace Review Istitute Aalysis: Chemical aalyses were made o solid pieces ad chips prepared by a ed mill from represetative samples for the certified portio of the lot i accordace with ASTM Stadard Practice E1806. The laboratories participatig i the testig followed the requiremets of ISO Stadard Traceability: The followig Certified Referece Materials were used to validate the aalytical data: 11XC4, 11XC8, 12X357; ECO , , , , , , , , , , , , , ; AR 644, 654, 657, 659, 673, 675, 875, 891, 1652, 1653; BAM 039-1, 044-1; BAS 54, 342, 345, 346, 405/1, 434, 455/1, 456/1, 457/1, 458/1, 464/1; BS CSN 2-2, H3C, AS-1, 11A, 12, 13, 14A, 50D, 56H, 61G, 66, 75G, 200-2, 200-4, 718B, 2931A; CKD 162A, 165D, 170H; ECRM 084-1, 85, 085-1, 86, 87, 088-1, 096-1, 097-1, 184-1, 186-1, 191-1; IARM 28G, 57B, 62E, 210C; IMZ 1.22, 1.74/3, 63/1, 74, 112, 114, 119, 187, 202; IPT 43, 208; JSS 169-4, 1706-, 171-4; SRM C1173, 30F, 55D, 101E, 160B, 291, 293, 361, 362, 363, 364, 365, 898, 1249, 1256, 1261A, 1262A, 1263A, 1264, 1264A, 1265A, 1761, 1762, 1763, 1764, 1765, 1766, 1767, 3109A, 3128, 3131A. Homogeeity: This Certified Referece Material (CRM) was tested for homogeeity usig ASTM Stadard Method E826 ad foud acceptable. It was also examied by spark atomic emissio spectrometry ad foud to be compatible with the followig Referece Materials BAM 044-1; BAS 405/1, 455/1, 456/1, 457/1, 458/1; BS AS-1, 11A, 12, 13, 14A, 50D; CKD 165D, 170H; ECRM 085-1, 088-1, 096-1, 097-1, 184-1, 186-1, 191-1; IMZ 1.22, 1.74/3; IPT 43; JSS 169-4, 170-6, 171-4; SRM C1173, 125B, 361, 362, 363, 364, 365, 1256, 1261A, 1262A, 1263A, 1264A, 1265A, 1270, 1761, 1762, 1763, 1764, 1765, 1766, Validity statemet: ISO Guide 31 states that the certificatio should cotai a expiratio date for all materials where istability has bee demostrated or is cosidered possible, after which the certified value is o loger guarateed by the certifyig body. The certificatio of BS 3941 is valid idefiitely. The certificatio is ullified if this CRM is damaged, cotamiated, or otherwise modified. Source: The bar stock for this CRM was produced by Ilad Steel Corporatio, East Chicago, Idiaa. Form: This CRM is machied i the form of a disc, approximately 41 mm i diameter ad 19 mm thick by Brammer Stadard Compay, Ic. Use: This CRM is iteded for use i spark atomic emissio, glow discharge, ad x-ray spectrometric methods of aalysis. Refer to ISO Guide 33 for iformatio about the use of Certified Referece Materials. Certified Area: The etire depth of the CRM may be used. Certificate Number REV Page 5/7

6 Cautio: As with ay bar material, avoid spark atomic emissio spectrometric burs i the ceter of the CRM (5 mm radius), as some segregatio may be preset. Sample Preparatio: For best aalytical results, use the same method for preparig the aalytical surface o all referece materials as used for productio specimes. Avoid overheatig the sample durig surface preparatio. Cautio: CRM cotais sigificat isoluble soft metal iclusios. Surface smearig may occur. Spark atomic emissio spectrometers may require exteded preburs to compesate. Certificate Number: The uique idetificatio umber for this certificate of aalysis is REV You may obtai iformatio o revisios of certificates from the iteret at Safety Notice: A Safety Data Sheet (SDS) is ot required for this material. This material will ot release or otherwise result i exposure to a hazardous chemical, uder ormal coditios of use. Iquiries cocerig this Referece Material should be directed to: Brammer Stadard Co., Ic. Phoe: (281) Web: Befer Road Housto, Texas USA Fax: (281) cotact@brammerstadard.com Revisio: This certified referece material was origially certified as a referece material o May 31,1995. Additioal iterlaboratory testig was performed. O, Sb, S, ad Ti have bee chaged from iformatioal to certified. Revised values for all elemets except Cu, Mg, P, Pb, ad S, are preseted. Iformatioal values for B, Fe, Ta, W, ad Zr are provided. All trace data are preseted i mg/kg (ppm). A umber of trace elemets have bee added. Brammer Stadard Compay, Ic., is accredited by the America Associatio For aboratory Accreditatio (A2A) to ISO Guide 34 as a Referece Material Producer for the productio of Certified Referece Materials ad Referece Materials (Certificate Number ) Brammer Stadard Compay's Chemical aboratory is accredited by A2A to ISO Stadard (Certificate Number ) By Certificate Number 10539, the Quality System of Brammer Stadard Compay, Ic., is registered to ISO 9001:2008 by Natioal Quality Assurace (NQA), U.S.A. The scopes of accreditatio are listed o the website: Refereces: Versios used were those available at the time of testig ad characterizatio E826 E1019 E1806 Stadard Practice for Testig Homogeeity of a Metal ot or Batch i Solid Form by Spark Atomic Emissio Spectrometry Stadard Test Methods for Determiatio of Carbo, Sulfur, Nitroge, ad Oxyge i Steel, Iro, Nickel, ad Cobalt Alloys by Various Combustio ad Fusio Techiques Stadard Practice for Samplig Steel ad Iro for Determiatio of Chemical Compositio ISO Stadard 17025:2005 Geeral requiremets for the competece of testig ad calibratio laboratories Certificate Number REV Page 6/7

7 ISO Stadard 9001:2008 Quality Maagemet Systems - Requiremets ISO Guide 30:1992 Terms ad defiitios used i coectio with referece materials amedmet ISO Guide 31:2015 Referece materials - Cotets of certificates ad labels ISO Guide 33:2000 Uses of certified referece materials ISO Guide 34:2009 Geeral requiremets for the competece of referece material producers ISO Guide 35:2006 Referece Materials - Geeral ad statistical priciples for certificatio ASTM documets available from ASTM, 100 Barr Harbor Dr., West Coshohocke, Pa ISO Guides ad Stadards available from Global Egieerig - Other useful documets available from NIST, U.S. Departmet of Commerce, Gaithersburg, MD NIST Special Publicatio , Hadbook for SRM Users NIST Special Publicatio 829, Use of NIST Stadard Referece Materials for Decisios o Performace of Aalytical Chemical Methods ad aboratories Certified by: o August 23, Beau R. Brammer Certificate Number REV Page 7/7