Resin Solubility Chart

Transcription

1 Resin Solubility Chart

2 Viscosity Conversions (For Newtonian 25 C, D = 1) Ford Cup Zahn Zahn Zahn #4 #2 #3 #4 Gardner Krebs Centipoise (sec) (sec) (sec) (sec) Holdt Stormer 1 A A A A A A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Z Z Z Z Z Z-6

3 Temperature Conversion C = 5/9 ( F) 32 F = 9/5 ( C)+32 C F C F C F C F C F C F C F C F C F C F

4 Resin Suppliers Resin Name Resin Type Supplier Elvax 40 W Ethylene/Vinyl Acetate DuPont Walsroder E 560 Cellulose Nitrate Dow Wolff Cellulosics Eastman CAB Cellulose Acetate Butyrate Eastman Eastman CAP Cellulose Acetate Propionate Eastman Eastman CA Cellulose Acetate Eastman CK 2400 Phenolic Georgia Pacific Resins Eastotac H-130 Hydrocarbon Eastman Reactol 1717A Ketone Aldehyde Lawter International Butvar B-76 Polyvinyl Butyral Eastman Paraloid B-66 Acrylic Dow Elvacite 2010 Acrylic Lucite International Inc. Cymel 303 Melamine Cytec Desmodur N-100 Isocyanate Bayer Versamid 115 Polyamide Cognis Paphen PKHH Phenoxy Phenoxy Specialties Ucar VYHH Vinyl Chloride/Vinyl Acetate Dow Epon 1001F Epoxy Momentive Epon 1007F Epoxy Momentive

5 Eastman Products for the Coatings Industry Cellulose Acetate Butyrate CAB CAB CAB CAB CAB CAB CAB CAB CAB BP CAB CAB-38l-20 BP CAB CAB CELLULOSE ESTERS Cellulose Acetate CA S CA CA CA CA Cellulose Acetate Propionate CAP CAP CAP PLASTICIZERS Eastman 168 Eastman TOTM Eastman DOA Eastman 425 Eastman Triacetin Admex Eastman TXIB Benzoflex Eastman NPG Glycol Eastman TMPD Glycol CHDM Glycol HPHP Glycol Benzoic Acid RESIN INTERMEDIATES 1,4-CHDA-HP DMCD AAEM Purified Terephthalic Acid TBAA Isophthalic Acid SPECIALTY PRODUCTS CP Eastman Advantis 510W Eastman Optifilm enhancer 400 CP AP Eastman Optifilm enhancer 300 CP Eastman Optifilm Additive OTI200 CP Eastman Sustane SAIB Eastek Polymer Dispersion CP Eastman Sustane SAIB-90 Eastman AQ Polymers CP Velate 368 CP 310W Velate 375 CP 347W CP 349W AAA DMAA EAA EASTMAN SOLUS PERFORMANCE ADDITIVES

6 Resin Solubility Chart a,b ESTERS ETHYLENE/ CELLULOSE CELLULOSE VINYL CELLULOSE ACETATE ACETATE CELLULOSE ROSIN KETONE ACETATE NITRATE BUTYRATE PROPIONATE ACETATE TERPENE ESTER PHENOLIC HYDROCARBON ALDEHYDE EVAPORATION Walsroder Eastman Eastman Eastman Reactol RATE Elvax 40 W E 560 CAB CAP CA CK 2400 Eastotac H A SOLVENT (n-buoac=1) 20 Wt% 8 Wt% 8 Wt% 20 Wt% 10 Wt% 40 Wt% 40 Wt% 40 Wt% 60 Wt% 50 Wt% Methyl Acetate 6.0 I I I Ethyl Acetate (85% 88%) 4.2 I I I Ethyl Acetate, Urethane Grade 4.1 I I 9 18 I 42 Dimethyl Carbonate 3.2 I PS PS 20 I Isopropyl Acetate 3.0 I I I I 65 t-butyl Acetate 2.8 I PS I I 304 n-propyl Acetate 2.3 I I I 48 Isobutyl Acetate 1.4 I PS I I 108 n-propyl Propionate 1.2 I I n-butyl Acetate 1.0 I PS I n-butyl Propionate 0.5 PS I I p-amyl Acetate 0.4 I I I I Isobutyl Isobutyrate 0.4 I 100 I I I Hexyl Acetate 0.2 I PS I I 306 Pentyl Propionate 0.18 PS 60 I I I Heptyl Acetate 0.08 I 65 I I I Ethylhexyl Acetate 0.03 I 90 I I I I EG Diacetate 0.02 I I I 340 I Methyl Soyate 0.01 I I I I I 511 PS I Dibasic Esters I PS I 140 I I 651 Propylene Carbonate <0.005 I I PS I KETONES Acetone 6.3 I I I 10 PS 6 Methyl Ethyl Ketone 3.8 I I 9 18 PS 9 Methyl n-propyl Ketone g 2.3 I PS I PS 9 18 PS 15 Methyl Isobutyl Ketone 1.6 I PS I PS 28 Methyl Isoamyl Ketone 0.5 I PS I Methyl n-amyl Ketone 0.4 I PS I Cyclohexanone 0.3 I Diisobutyl Ketone 0.2 I 46 I I I PS Diacetone Alcohol 0.12 I I I 620 I 453 Eastman C-11 Ketone 0.02 I 72 I I I Isophorone 0.02 I I I 837 GLYCOL ETHERS h Eastman PM Solvent 0.7 I I I I EG Methyl Ether 0.47 I I I I 100 I EG Ethyl Ether 0.3 I PS I I I PG tert-butyl Ether 0.3 I 150 I I I I I PG Propyl Ether 0.2 I 95 I I I I I Eastman EP Solvent 0.2 I 86 PS I I I I PG Butyl Ether 0.08 I 110 I I I I I Eastman EB Solvent 0.06 I 100 I I I I I DPG Methyl Ether 0.02 I I I I I Eastman DM Solvent 0.02 I I PS I I 420 I Eastman DE Solvent 0.02 I I I I I Eastman DP Solvent 0.01 I 130 PS I I I I EG Hexyl Ether 0.01 I 120 I I I I Eastman DB Solvent I 200 PS I I I I Eastman EEH Solvent i I I I I I PG Phenyl Ether I I I I I GLYCOL ETHER ESTERS h Eastman PM Acetate 0.4 I I I I EG Ethyl Ether Acetate 0.2 I I I I Eastman EB Acetate 0.03 I PS I I I DPG Methyl Ether Acetate <0.01 I PS I I I Eastman DE Acetate I PS I I Eastman DB Acetate I I I I ETHER ESTER Eastman EEP Solvent 0.12 I I I I ESTER-ALCOHOL Eastman Texanol Ester Alcohol I 1115 PS I I I 1550 I I ALCOHOLS Methyl Alcohol 3.5 I 19 I I I I I 26 I 11 Ethyl Alcohol (Anhy) Formula C (SDA 3A) 1.7 I 28 I I I I I 35 I 24 Isopropyl Alcohol 1.7 I I I I I I I 150 I 92 n-propyl Alcohol 1.0 I I I I I I I 100 I 67 tert-butyl Alcohol 0.9 I I I I I I I 2350 I 749 sec-butyl Alcohol 0.9 I I I I I I I 310 I 159 Isobutyl Alcohol 0.6 I I I I I I I 410 I 209 n-butyl Alcohol 0.5 I I I I I I I 120 I 93 p-amyl Alcohol 0.3 I I I I I I 150 I I Cyclohexanol 0.05 I I I I I I 6700 I I PS 2-Ethylhexanol 0.01 I I I I I HYDROCARBONS Toluene I I I I VM&P Naphtha 1.6 I I I I I I 23 Xylene I I I I Aromatic I I I I SPECIALTY SOLVENTS Methylene Chloride I I Tetrahydrofuran PS ,1,1-Trichloroethane I PS I I Nitropropane 1.1 I PS I I I Parachlorobenzotrifluoride 0.9 PS I I I I PS 5295 PS N,N-Dimethyl Formamide 0.2 I I I 48 I N-Methyl-2-Pyrrolidone 0.04 I I I RESINS* VINYL POLYVINYL CHLORIDE/ BUTYRAL ALKYD POLYESTER ACRYLIC UREA MELAMINE ISOCYANATE POLYAMIDE PHENOXY VINYL ACETATE EPOXY Butvar Paraloid Elvacite Cymel Desmodur Versamid Paphen Ucar Epon Epon B-76 Thermoset e B N f PKHH VYHH 1001F 1007F 10 Wt% 65 Wt% c 65 Wt% d 70 Wt% 40 Wt% 20 Wt% 75 Wt% 50 Wt% 50 Wt% 75 Wt% 75 Wt% 25 Wt% 10 Wt% 50 Wt% 40 Wt% PS NA 1600 I PS NA 1600 I NA 1700 I PS PS 7 NA PS I NA 2150 I I I I NA 2840 I I I I NA 1500 I NA 2950 I PS I NA PS I I 117 I PS 6 NA PS PS NA 2200 I NA 2250 I I I I NA 3300 I I I I I NA 3290 I I I NA 4250 I I I NA 4100 I I 350 I I I NA 6400 I PS I I I I NA I I I I I 33 NA I I I I NA I 6000 PS I PS PS 21 NA PS PS I PS I I I I I I I I I 43 I I NA I I I I I NA I PS NA I I NA I I NA I I 1250 PS I NA I I I NA I I NA I I I NA I I NA I I NA PS I NA I PS NA PS I NA I I NA I I I NA I I 1750 I I NA 969 > I I PS PS PS PS PS PS I PS I NA I I I I I I I 18 9 NA I I I I I I NA I I I I I I I NA I I I I I I NA I I I I I PS I NA I I I I PS I NA I I I I I I NA I I I I I I NA I I I I 980 I I NA 6100 I I I I I I NA I I I I I NA I I I I I I I I I I I 1700 I 685 I I I I I I I I I I I I I I I I I I I I I I I 30 I j I I I 1550 I I I I I PS I I I I I = Completely Insoluble. NA = Solvent not applicable for use with this resin. PS = Partially Soluble Resin/solvent combinations form heterogeneous solutions with varying degrees of solution haze. Eastman products shown in red. a These are typical properties and Eastman makes no representation that the material in any particular shipment will conform to the listed properties. b Resin solubility expressed in cp (mpa s), Brookfield 25 C. c Alkyd resin 75 wt% solids in 90/10 wt% MPK/n-Butyl acetate blend. The alkyd was then diluted to 65 wt% solids with solvent shown. The final solvent blend was a 56/6/38 (wt%) blend of MPK/n-Butyl acetate/solvent shown. d Polyester resin 85 wt% solids in PM acetate. The polyester was then diluted to 65 wt% solids with the solvent shown. The final blend was a 35/65 (wt%) blend of PM acetate/solvent shown. e Acrylic resin 80 wt% solids in MAK. The acrylic resin was then diluted to 70 wt% solids with the solvent shown. The final solvent blend was a 58/42 (wt%) blend of MAK/solvent shown. f As supplied in the United States. g MPK is not on EPA s HAPs list, but it can contain as much as 10 vol% of MIBK, which is on this list. h EG = Ethylene Glycol PG = Propylene Glycol DPG = Dipropylene Glycol i Eastman EEH is a blend of EEH, DEH, and TEH. j Initially soluble but gelled after short period of time.

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