TABLE IV. ORGANIC DERIVATIVES OF AROMATIC HYDROCARBONS a) Liquids. (Listed in order of increasing b.p.)*

Transcription

1 a) Liquids. (Listed in order of increasing b.p.)* point, 'C point, 'C "g DT 1 35 Trimtro Phthic anhy dnde 2.4-Dinitrophenyl sulfenyi ,-* 12' l-ethyl-2-methyl (o-ethyltoluene) 13 le«-butyl * » 17 Benzene Toluene Ethyl 1,4-Xylene 1,3-Xylene 1,2-Xylene Isopropyl (Cumene) n-propyl l-ethyl-3-methyl (m-ethyltoluene) 1-EthyM-methyl (p-ethyltoluene) 1,3,5-Trimethy Ibcnzenc (Mesitylene) 1,2,4-Trimethyl (Pseudocumene) Isobutyl.vcr-Butyl 3-Isopropyl-l-methyl (3-Isopropyltoluene, m- Cymene) , pa 966, pa ,3-rfj 89, 1,3,5 tri 122 2,4-rfi 70 2,4,6-m 37 2,3,5-/n 139 2,4,6-m 183 4,5-rfi 118 2,4,6-/n 109 bp 150' 86, 2,4,6- tn 235 2,4-rfi 62, 2,4,6- tri 124 3,5,6-/«185 bp s , 2,4-d, , 2,4-d, , 2,4-rfi , 2,6-di , , 142 ns Sulfonamide, 156 Oxid» benzoic acid, 121, Sulfonamide, 137 Oxid -» benzoic acid, 121, Sulfonamide, 109 Oxid -Merephthahcacid. >300,subl, Sulfonamide, 147 Oxid» isophthahc acid, 348, h w, Sulfonamide, 137 Oxid -»phthic acid, 206 8, Sulfonamide, 144 Oxid -* benzoic acid, 121 Sulfonamide, 106 Oxid *- benzoic Oxid -» isophthahc acid, 348, h w Oxid -» terephthicacid. >300,subl Oxid -»tnmesic acid, 380, Sulfonamide, 141 Oxid -*phthic acid, Oxid - benzoic acid, 121 Oxid - tnmellitic acid, d Oxid -» benzoic acid, 121 Oxid -* benzoic *Denvative data given in order m p, cryst color, solvent from which crystlized 35

2 point *C ng D; 1 3,5 Trmitro Phthahc anhydride 24-Dl nitrophenyl *~ ' ,2,3-Trimethyl (Hemimellitene) /ranj-propenyl Indane 4-Isopropyl-l-methyl (4-lsopropyltoluene, 4-Cymene) 2-Isopropyl-l-methyl (2 Isopropyltoluene 2-Cymene) 1,3-DiethyI l-methyl-3-propyl (m-propyltoluene) Indent «-Butylbenzenc l-methyl-4-propyl (/>-Propylto!uene) 1,2-Diethyl 1,4-Diethyl l,3-dimethyl-5-ethyl l-methyl-2-propyl (o-propyltoluene) 2, 2-Dimethvl-l-phen\ (propane (Neopentyl) 1,4-Dhnethyl-2-ethyl 2-Methylindane 3-Methyl-2-phenylbulane l-melhylindane 1,3-Dimethyl-4-ethyI 3-w;-ButyI-l-methyl (3-/ev7-Butyltoluene) 1,2-Dimethyl-4-ethyl 1,3-Dimethyl-2-ethyl « to _ " , 2,6-di 54, 2,3,6 in ire 2,4.6-lri 62 2,4,6-rn ,5,6-fn 127 8, 2,S.6-tn , , Oxid * hemimellilicactd, d Sulfonamide, 1 15 Br 2» Tetrabromo, Acid * polymer Br 2 -» Tnbromo, 89 Sulfonamide, Benzarmdodenv, Heat with Pt at Naphthene, 80 3 Br 2 2,5,6-Tnbromo, 94 5, 81 2 Oxid» tnmellitic acid, d Oxid -» hemimelhtieactd, 190-7d 'Derivative data given in order m p, cryst color, solvent from which crystlized 36

3 n o D; 1 35 Trimtro deriva Phthahc anhy dnde deriva 24 Di nttro phenyl deriva Phenylpentane l-ethyl-3-isopropyl 2-Methyl-2-phenylbutane 4-(m-Butyl-l-methyl (4-tert Bulyltoluene) f-ethyl-2-isopropyl 2-Phenylpentane 1,2-Dimethyl-3-ethyI 3-jer-Butyl-l-methyl (3-5?c-Butyltoluene) 3-Isobutyl-l-methvl (3-Isobutyltoluene) /-2-Methyl-l-phenylbutane 1,3-Dimethyl-5-isopropyl 2-Phenyl-cK-2-butene 4-Isobutyl-l-methyl (p Isobutvltoluene) 2-se c-butyl-1 -methyl (2-sec Butvltoluene) 2-Isobutyl-l-methyl (o-isobutyltoluene) 1,4-Dimethyl-2-isopropyl l-ethyl-4-isopropyl </,/-2-Metbyl-l-phenvlbulane 1,2,3,5-Tetramethyl (Isodurene) 3-Methyl-l-phenylbutane (Isopentyl)!,3-Dimethyl-2-isopropyl 1,3-Dlmethyl-4-isopropyl 3-Methylindene 4-.str-Butyl-l-methylbeim>ne (/j-jec-butyltoluene) " " I , or -. 2bdi di di mono di rfi di Benzamidodenv, Ben?dmidodenv Ben.7amido Oxid >-hemimelhtieacid d Oxid Mrtmesic acid, Benzamido 126 *Denvative data given in order m p, cryst color, solvent from which crystlized 37

4 point, "C point *C n20 "D Df 1 3,5- Trmitro Phthic anhydride 24-Di mtrophenyl ;frt*Butyl-l-niethyl (2-w-Butyltoluene) 3,5-Diethyl-l-methyl (3,5-Diethyltoluene) 2-Butyl-l-methyl (2-Butyltoluene) l-ethyl-3-propyl l,2-dimethyl-4-isopropyl , ,4,6-m ,2-Dimethyl-3-isopropyl l-ethyl-2-propyl 1,3-Di-isopropyl 1,2-Diethyl-4-methyl 1,2-Di-isopropyl l,4-dimethyl-2-propyl 1,23,4-Tetramethyl (Prehnitene) l-ethyl-4-propyl 3-Butyl-l-methyl (m-butyltoluene), 2,4-Diethyl-l-methyl (2,4-Diethyltoluene) n-pentyl 3-Methyl-3-phenylpentane 1 ^-Dimethyl-5-rerr-butyl l,3-dimethyl-4-propyl 1,2-Diethyl-3-methyl 4-Butyl-l-methyl (4-Butyltoluene) 2,5-Diethyl-l-methyl (2,5-Diethyltoluene) 1,23.4-TeIrahydronaphthene (Tetrahn) 1,3-Diethyl-2-propyl 2,6-Dielhyl-l-methyl (2,6-Diethyltoluene) 1,2-Dimethyl-4-propyl l,3-dimethyl-5-propyl 2-Methyl-3-phenylpentane 4-/m-Butyl- 1 ^-dimethyl 1,4-Di-isopropyl 1,2-Dimethyl-3-propyl I IS ,6-di , 2-ProH 5,6-di 176 2,4,6-rr; 107 (one form). 114 (another form) 5J-di 95 2,5,6-f/v 112, 101-2, 2,4-d, Benzamido, CI 2-5,6,7,8- Tetrachloro, 172 Derivative data given in order m p, cryst color, solvent from which crystlized 38

5 point, "C point, 'C n r? Df 13,5 Trimlro deriva Phthahc anhydride 2,4-Dinitrophenyl /('rt-buly l-4-ethy I rf,/-3-phenylhexane 2-Elhyl-l,3,5-trimethyl 3-Ethyl-4-isopropyl-l-methyl 5-Ethyl-l,2,4-trimethyl 6-Ethyl-l,2.4-trimethyl 2-Phenylhexane 2-Methyl-l-phenylpentane 4-Isopropyl-l-propyl 1,3-Dipropyl 5-Ethyl-l,2,3-trimelhvl 3-Ethyl-l,2,4-irimethyl 1,2,4-1 ciethy I 1,3,5-Triethyl 2-Methyl-l,2,3,4-tetrahydronaphthene (2 Methyltetrm) 1 -Methyl-1,2,3.4-lelrahydronaphthene(l-Methyltetrahn) 4-Elhyl-l,2,3-trimethyl 1,4-Dipropyl 3-Methyl- 1 -phenylpentane 2-Propyl-13,5-trimethyl l,l-dimethyl-l,2,3,4-tetrahydronaphthene (1,1- Dimethyltetrm) 3-(m-Butyl-l-isopropyl l-methyl-3-pentyl (3-Pentyltoluene) 4-/?r(-Butyl-l-isopropyl 2-Methyl-2-phenylhexane 2,4- l)i-isopropy 1-1 -methyl (2,4-Di-isopropyltoluene) 3-Methyl-3-phenylhexane n-hexyl 3-Phenylheptane 2,6-Di-isopropyl-l-methyl (2,6-Di-isopropyltoluene) > " 09137' X S ,6-di 94 5, 4,6-di lll. 3,6-A 87 8, 5,6-d 79 80, 2,4,6-»« Ar-x, x- di A-di 178 2,4-rfi ,6-Dibromo, 60-1, acet 2,4,6-Tnbromo, 105 'Derivative data given in order m p, cryst color, solvent from which crystlized 39

6 point, *C point "C nzo "D Df 1 35 Trmitro Phthdhc anhy dride 2,4 Di nitro phenyl Propyl-I,2,4-trimethyl 6-Mefhyl-l,2,3,4-tetrahydronaphthene (6- Methyltetrm) 2,2-Dimethyl-l,2,3,4-tetrahydronaphthene (2 2 Dimethyltetrm) 2-Phenylheptane 5-Methyl-l,2,3,4-tetrahydronaphthene (5- Methyltetrahn) 2-Ethyl-l,23,4-tetrahydronaphthene (2-EthylteIrm) Cyclohexyl l-ethyl-l,2,3,4-tetrahydronaphthene ( 1 -Ethyltetrm) 2,5-Dimethyl-I,2,3,4-tetrahydronaphthene (2,5- Dimethyltetrin) 2,8-Dimethyl-l,23,4-tetrahydronaphthene (2,8- Dimethyltetrm) 2,7-Dimethyl- 1,2,3,4-retrahydronaphthene (2,7- Dimethyltetrm) 2,6-Dimethyl-l,2,3,4-tetrahydronaphthene (2,6- Dimethyltetrm) l,4-di-«r-butyl 1,5-DimetHyl-l,2,3,4-tetrahydronaphlhene (1,5 Dimethyltetrm) 3-Ethyl-3-pheny(hexane 6-Ethyl-l,2,3,4-«etrahydronaphthene (6 Ethyltetrm) 2-Methyl-l-phenyl-l-bulene 5-Ethyl-l,2,3,4-tetrahydronaphthene (5-Ethvltetrm) n-heptyl 1-Methylnaphthene 5,6-Dimethyl-l,2,3,4-tetrahydronaphthene (5,6 Dimethyltetrm) 6,7-Dimethyl-l,2,3,4-Ietrabydronaphtbene (6,7- Dimethyltetrm) 5,7-Dimethyl-J,23,4-tetrahydronaphthene (5,7 Dimethyltetrm) '" S , or - red, , 71, 4,5-rfi 143 5,8 di Oxid -tnmellitic acid d sit, Styphnate, 135, Oxid > melo phamc acid, Heating with Sat 320 1,3-Dimethylnaphthene, b p 263 * Derivative data given in order m p, cryst color, solvent from which crystlized 40

7 "S D{ i 35 Tnmtro Phlhic anhy dride 2,4- Di mtro phenyl ,8-Dimethyl-l,2,3,4-tetrahydronaphthene (5.8- Dimethyltetrdlin) 2-Ethylnaphthene 1-Ethylnaphthene 1,7-Dimethylnaphthene 1,6-Dimethylnaphthene 1,3-Dimethylnaphthenc n-octyl (! -Phenyloctane) 1-Allylnaphthene l-isopropylnaphthene 1,4-Dimethy Inaphlhene 1,1-Diphenylethane 2-Isopropylnaphthene!-Propylnaphthene 1-Propylnaphthene 1,3,7-Trimethylnaphthene l-isopropyl-7-methylnaphthene (Apocadene) n-nylhenzene ( 1 -Phenylnonane) 2-Butylnaphthene -r<77-butylnaphthene -frrt-butylnaphthene -Butylnaphlhene , a)268 2 b) , , I , or, , or, me 93 5, , or , or, 102, or, 71 3, or -, , 104 5, or , 2- PrOH , , me , 24-dl 2 Heating with Sat 230"^ 1,4-Dimethylnaphthene, b p 268 Styphnate, Styphnate 1113, Styphnate, 143 Styphnate, 122 Styphnate, 117 8, w -me, 2,4,7- Tnmtrofluorenone denv, 142 5, or Dimer Tetrabromo, Styphnate, or me Oxtd > benzophenone, 49 Styphnate 1515 or me jl Styphnate, 166 (163-4),, 4-Sulfonamide, Meic anhydride " 3- (4-nylbenzoyl) acrylic acid, 82 3 'Derivative data given in order m p, cryst color, solvent from which crystlized 41

8 point, 'C point, "C "8 Df 1,3,5- Trimtro Phthahc anhydride 2,4- Dinitrophenyl ,5-Benzindane (1,2-Cyclopentanonaphthene) n-decyl (1-Phenyldecane) 1 -Pentylnaphthene 2-Pentylnaphthene n-undecylbenzenc («-Hendecyl, 1-Phenylundecane) l-hexylnaphthene 2-Hexylnaphthene n-dodecyl ( 1 -Phenyldodecane) 1-Heptylnaphthene 2-Heptylnaphthene Tridecyl ( 1 -Phenyltndecane) 1-Octylnaphfhene 2-Octylnaphthene 1-nylnaphthene 2-nylnaphIhene 1 -Decylnaphthene forms stable -05, metastable , 74, , 2,4,7-Tnnitrofluorenonedenv, Sulfonamide, Sulfonamide,5 * Derivative data given in order m p, cryst color, solvent from which crystlized 42