ANALYSIS OF GASOLINE RANGE HYDROCARBONS ON BP1-PONA

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1 PET 01 - PETROLEUM ANALYSIS OF GASOLINE RANGE HYDROCARBONS ON BP1-PONA GASOLINE RANGE HYDROCARBONS Column Part No.: BP1, PONA 50 m x 0.15 mm ID Initial Temp.: 30 C, 5 min hold Rate 1: 2 C/min Temp. 2: 80 C Rate 2: 50 C/min Temp. 3: 120 C Rate 3: 10 C/min Final Temp.: 190 C Detector: FID Sensitivity: 32 x AFS Injection Mode: Split H 2, 40 psi PET 01 Copyright SGE Analytical Science Pty Ltd July Components TIME COMPOUND 4.85 Cyclopentane ,3-Dimethylbutane Methylpentane Methylpentane 6.45 n-hexane ,2-Dimethylpentane 7.60 Methylcyclopentane ,4-Dimethylpentane ,2,3-Trimethylbutane 8.99 Benzene Methyl-3-ethylpentane Methylheptane Methyl-2-ethylcyclopentane Methylheptane cis-2-cis-4-trans-Trimethylcyclopentane Methylheptane trans-4-Dimethylcyclohexane Methyl-cis-2-ethylcyclopentane Methyl-trans-3-ethylcyclopentane Methyl-cis-3-ethylcyclohexane Ethy-1-methycyclopentane trans-2-Dimethylcyclohexane cis-2-trans-4-trans-Trimethylcyclohexane cis-2-trans-4-cis-Trimethylcyclohexane ,4-Dimethylheptane Methylethylhexane Methyloctane Methyloctane Methyloctane o-xylene Methyl-2-propylcyclopentane and 1-Methyl-trans-4-ethylcyclohexane Methyl-cis-4-ethylcyclohexane ,3-Diethylpentane ,3-Dimethylpentane 9.55 Cyclohexane n-octane iso-propylcyclopentane ,2,6-Trimethylheptane ,1,2-Trimethycyclohexane Methylhexane ,3-Dimethylpentane ,1-Dimethylcyclohexane Methylhexane trans-3-Dimethylcyclopentane cis-3-Dimethylcyclopentane Ethylpentane trans-2-Dimethylcyclopentane ,2,4-Trimethylpentane Trimethylhexane ,2,4-Trimethylhexane 24,53 2,4,4-Trimethylhexane ,3,5-Trimethylhexane ,4-Dimethylheptane n-propylcyclopentane cis-2-Dimethylcyclohexane ,1,3-Trimethylcyclohexane ,5-Dimethylheptane n-nonane iso-propylbenzene tert-butylcyclopentane tert-butylbenzene sec-butylcyclopentane Methylnonane n-propylbenzene n-propylcyclohexane m-ethyltoluene n-heptane Methylcyclohexane ,2-Dimethylhexane Ethylcyclopentane ,5-Dimethylhexane ,4-Dimethylhexane ,3-Dimethylheptane ,5-Dimethylheptane ,4-Dimethylheptane ,3,3-Trimethylhexane Ethylbenzene cis-3-cis-5-Trimethylpentane p-ethyltoluene ,3,5-Trimethylbenzene Methylnonane o-ethyltoluene ,6-Dimethyloctane ,2,4-Trimethylbenzene trans-2-cis-4-Trimethylcyclopentane ,3,4-Trimethylpentane trans-2-cis-3-Trimethylcyclopentane ,3,3-Trimethylpentane Toluene ,3-Dimethylhexane ,1,4-Trimethylcyclohexane ,3,4-Trimethylhexane ,3,4-Trimethylhexane m-xylene p-xylene ,3-Dimethylheptane n-decane ,2,3-Trimethylbenzene Methyldecane sec-butylbenzene n-butylbenzene n-undecane

2 PET 01 - PETROLEUM PET 01 Copyright SGE Analytical Science Pty Ltd July 2008

3 PET 02 - PETROLEUM ANALYSIS OF MICROCRYSTALLINE WAX ON BPX5 MICROCRYSTALLINE WAX Column Part No.: BPX5, 0.25 µm film 12 m x 0.32 mm ID Initial Temp: 120 C, 1 min 10 C/min Final Temp: Detector: Sensitivity: Injection Mode: 375 C 20 min FID 30 x AFS On-Column H 2, 10psi. Notes: It is recommended to use cool on-column injection to ensure no loss of high molecular weight fraction. Components 1. C30 2. C40 3. C50 4. C60 PET 02 Copyright SGE Analytical Science Pty Ltd July 2008

4 PET 03 - PETROLEUM ANALYSIS OF FURNACE OIL IN PENTANE ON BP5 FURNACE OIL IN PENTANE Column Part No.: BPX5, 0.25 µm film 12 m x 0.32 mm ID Initial Temp: 100 C, 2 min 10 C/min Final Temp: Detector: Sensitivity: Injection Mode: 350 C, 20 min FID 40 x AFS On Column H 2, 10 psi. Components 1. n-c10 2. n-c17 3. Pristane 4. n-c18 5. Phytane PET 03 Copyright SGE Analytical Science Pty Ltd July 2008

5 PET 06 - PETROLEUM ANALYSIS OF POLYWAX 655 & REFINERY LUBRICATION OIL ON HT5 POLYWAX 655 & REFINERY LUBRICATION OIL Column Part No.: HT5, 0.1 µm 6 m x 0.53 mm ID Initial Temp.: 50 C 10 C/min Final Temp.: 480 C, 15 min Detector: FID Sensitivity: 40 x AFS Injection Mode: On-Column Hydrogen, 20 ml/min Solvent: CS 2 POLYWAX 655 REFINERY LUBRICATION OIL PET 06 Copyright SGE Analytical Science Pty Ltd July 2008

6 PET 07 - PETROLEUM ANALYSIS OF LEADED PETROL ON BPX5 LEADED PETROL Column Part No.: BPX5, 0.25 µm film 30 m x 0.25 mm ID Initial Temp.: -20 C, 1 min Rate 1: 4 C/mn Temp. 2: 40 C Rate 2: 8 C/min Final Temp.: 150 C Detector: FID Sensitivity: 10 x AFS Injection Mode: Split H 2, 10 psi Components 1. iso-butane 2. n-butane 3. iso-pentane 4. n-pentane 5. 2,2-Dimethylbutane 6. 2,3-Dimethylbutane 7. 2-Methylpentane 8. 3-Methylpentane 9. n-hexane 10. Benzene Methylhexane 12. 2,3 Dimethylpentane Methylhexane 14. 2,2,4-Trimethylpentane 15. n-heptane 16. Toluene 17. 2,3-Dimethylhexane 18. Ethylbenzene 19. m-xylene 20. p-xylene 21. o-xylene 22. n-propylbenzene Methyl-3-ethylbenzene Methyl-4-ethylbenzene 25. 1,3,5- Trimethylbenzene Methyl-2-ethylbenzene 27. 1,2,4- Trimethybenzene 28. 1,2,3-Trimethylbenzene 29. Naphthalene Methylnaphthalene Methylnaphthalene PET 07 Copyright SGE Analytical Science Pty Ltd July 2008

7 PET 08 - PETROLEUM ANALYSIS OF POLYWAX 1000 ON HT5 POLYWAX 1000 Column Part No.: HT5, 0.15 µm 12 m x 0.53 mm I.D. (Aluminium Clad) Initial Temp.: 200 C Program 10 C/min. Final Temp.: 480 C H 2, 5 psi Detector: F.I.D. Sensitivity: 32 x AFS Injection Mode: Split Solvent CS 2 Notes: On-column injection is recommended for all analyses where hydrocarbons above C 50 are to be analysed. PET 08 Copyright SGE Analytical Science Pty Ltd July 2008

8 PET 11 - PETROLEUM ANALYSIS OF CRUDE OIL AND WAX MIXTURES ON HT5 CRUDE OIL AND WAX MIXTURE Column Part No.: HT5, 0.1 µm 12 m x 0.22 mm I.D. (Aluminium Clad) Initial Temp.: 35 C Program 10 C/min. Final Temp.: 480 C H 2, 15 psi Detector: F.I.D. Sensitivity: 32 x AFS Injection Mode: Split Notes: HT5 is the best column for the analysis of hydrocarbons C 10 - C 70. PET 11 Copyright SGE Analytical Science Pty Ltd July 2008

9 PET 15 - PETROLEUM ANALYSIS OF POLYWAX 500 AND C 4 -C 20 N-PARAFFINS ON HT5 Column Part No.: HT5, 0.5 µm film 10 m x 0.53 mm ID Initial Temp: 10 C, 1 min 10 C/min Final Temp: 410 C, 5 min He, 20 ml/min Solvent: CS 2 PET 15 Copyright SGE Analytical Science Pty Ltd July 2008

10 PET 16 - PETROLEUM ANALYSIS OF POLYWAX 655 ON A 6 M X 0.53 MM ID HT5 Column Part No.: HT5, 0.1 µm film 6 m x 0.53 mm ID (aluminium clad) Initial Temp: -20 C, 1 min 10 C/min Final Temp: 430 C, 5 min He, 20 ml/min Solvent: CS 2 PET 16 Copyright SGE Analytical Science Pty Ltd July 2008

11 PET 17 - PETROLEUM GASOLINE SAMPLE ON THICK FILM BPX5 Column Part No.: BPX5, 3.0 µm 25 m x 0.32 mm ID Initial Temp.: 35 C, 5 min Rate 1: 5 C/min Final Temp.: 340 C, 5 min Detector: FID, 360 C Injector Mode: Split, 100:1, 240 C He, 10 psi Injection Volume: 0.1 µl Components 1. C5 2. C8 PET 17 Copyright SGE Analytical Science Pty Ltd July 2008

12 PET 18 - PETROLEUM ANALYSIS OF POLYWAX 655 ON MEGABORE BPX1 Column Part No.: BPX1, 0.1 µm 5 m x 0.53 mm ID Initial Temp: 40 C 15 C Final Temp: 420 C, 5 min Detector Temp: 440 C Carrier: He, 10 ml/min Instrument: HP 6890 Solvent: CS 2 Components 1. C20 2. C40 3. C60 4. C80 5. C100 PET 18 Copyright SGE Analytical Science Pty Ltd July 2008

13 PET 19 - PETROLEUM REFERENCE GAS OIL MT-60 ON A MEGABORE BPX1 Column Part No.: BPX1, 0.1 µm 5 m x 0.53 mm ID Initial Temp: 40 C 15 C Final Temp: 420 C, 5 min Detector Temp: 440 C Carrier: He, 10 ml/min Instrument: HP 6890 Components DEGREES DIFFERENCE ( F) IBP 0.6 5% % % % % % % % % % % 0.2 FRP 0.3 PET 19 Copyright SGE Analytical Science Pty Ltd July 2008

14 PET 20 - PETROLEUM CS2 BLANK SIMDIS ON A 5 M 0.53 MM ID BPX1 COLUMN Column Part No.: BPX1, m x 0.53 mm ID Initial Temp: 40 C 15 C Final Temp: 420 C, 5 min Detector Temp: 440 C Carrier: He, 10 ml/min Instrument: HP 6890 PET 20 Copyright SGE Analytical Science Pty Ltd July 2008

15 PET 21 - PETROLEUM HYDROCARBON STANDARD ON A THICK FILM BPX5 COLUMN Column Part No.: BPX5, 3.0 µm 25 m x 0.32 mm ID Initial Temp.: 35 C, 5min Rate 1: 5 C/min Final Temp.: 340 C, 5 min Detector: FID, 360 C Injector Mode: Split, 100:1, 240 C He, 10 psi Injection Volume: 0.1 µl Components 1. C5 2. C8 3. C15 4. C20 PET 21 Copyright SGE Analytical Science Pty Ltd July 2008

16 PET 22 - PETROLEUM UNLEADED GASOLINE ON BPX5 Sample Description: Pure Unleaded Gasoline Column Part No.: BPX5, 0.25 µm film 30 m x 0.25 mm ID Components 1. Benzene 2. Toluene 3. Ethylbenzene 4. m, p - Xylene 5. o - Xylene Sample Introduction: Split / Splitless Injector Temp.: 240 C Injection Volume: 0.1 µl Autosampler Syringe: 0.5 µl Removable Needle Part No Septa: Auto-Sep T Part No Injection Type: Split Purge On Time: NA Purge On (Split) Vent: 200 ml/min Split Ratio: 149 to 1 Liner Type: FocusLiner single taper Part No Pressure/Flow Values: Constant Flow: Pressure: Column Flow: Linear Velocity: Oven Parameters: Initial Temp.: Initial Time: Rate 1: Final Temp. 1: Hold Time: Run Time: Detector Parameters: Detector Type: Helium On 13.6 psi 1.34 ml/min 30 cm/sec at 25 C 25 C 1 min 30 C/min 240 C 1 min 9.17 min FID at 280 C PET 22 Copyright SGE Analytical Science Pty Ltd July 2008

17 PET 24 - PETROLEUM STANDARD MIX FOR HIGH TEMPERATURE SIMULATED DISTILLATION (HTSD) ON BPX1 Column Part No.: BPX1, 0.1 µm Dimensions: 5 m x 0.53 mm ID Initial Temp.: 40 C 15 C/min Final Temp.: 420 C, 5 min Detector Temp.: 440 C He, 10 ml/min Instrument: HP 6890 Separation Systems Injector Initial Temp.: 40 C 15 C/min Final Temp.: 420 C, 5 min PET 24 Copyright SGE Analytical Science Pty Ltd July 2008

18 PET 25 - PETROLEUM RETENTION TIME HYDROCARBON STANDARD ON BPX1 Column Part No.: BPX1, 0.9 µm film 10 m x 0.53 mm ID Initial Temp.: 40 C 10 C/min Final Temp.: 390 C, 10 min Detector Temp: 400 C He, 20 ml/min Instrument: HP 6890 Separation Systems Injector Final Temp: 390 C,10min Initial Temp.: 80 C 10 C/min PET 25 Copyright SGE Analytical Science Pty Ltd July 2008

19 PET 26 - PETROLEUM STANDARD FOR D2887 ON BPX1 Column Part No.: BPX1, 2.65 µm film 10 m x 0.53 mm ID Initial Temp.: 40 C 15 C/min Final Temp.: 350 C, 10min Detector Temp.: 400 C He, 20 ml/min Instrument: HP 6890 Separation Systems Injector Initial Temp.: 80 C 15 C/min Final Temp.: 350 C, 10 minr PET 26 Copyright SGE Analytical Science Pty Ltd July 2008

20 PET 27 - PETROLEUM ANALYSIS OF POLYWAX 1000 ON AN ALUMINIUM CLAD HT5 Column Part No.: HT5, µm film 5 m x 0.53 mm ID Initial Temp.: 40 C, 1 min 10 C/min Final Temp.: 450 C, 10 min He, 20 ml/min Solvent: CS 2 C 60 C 70 C 50 C 80 C 90 C 100 C 40 C 110 C 120 C 30 PET 27 Copyright SGE Analytical Science Pty Ltd July 2008 Minutes C

21 PET 27 - PETROLEUM ANALYSIS OF POLYWAX 1000 ON AN ALUMINIUM CLAD HT5 Column Part No.: HT5, µm film 5 m x 0.53 mm ID Initial Temp.: 40 C, 1 min 10 C/min Final Temp.: 450 C, 10 min He, 20 ml/min Solvent: CS 2 C 60 C 70 C 50 C 80 C 90 C 100 C 40 C 110 C 120 C 30 PET 27 Copyright SGE Analytical Science Pty Ltd July 2008 Minutes C

炭化水素 - 直鎖炭化水素炭化水素 - 炭化水素及びアルコール類

炭化水素 - 直鎖炭化水素炭化水素 - 炭化水素及びアルコール類炭化水素 - 直鎖炭化水素 Column : Equity-, 0 m x 0. mm ID, 0. µm Cat. No. : 0-U Column : Equity-, 0 m x 0. mm ID, 0. µm Cat. No. : 09-U Oven : 0 ( min), /min to ( min) Inj.: Track oven Det. : FID, Carrier gas: Helium,.