Product RESTRICTED SUBSTANCES LIST

Transcription

1 Product RESTRICTED SUBSTANCES LIST VERSION JANUARY

2 1.0 Introduction Burberry s Product Restricted Substances List (PRSL) details the chemical restrictions applicable to any finished product or raw material used in either apparel or non-apparel product, including footwear, and which is supplied directly or indirectly to Burberry. It remains the responsibility of Burberry partners to comply with all applicable legislations by each country/state where the partner conducts business in the event such legislation is not covered within this PRSL Burberry retains the right to update the PRSL periodically to include new substances of concern identified by regulatory bodies or voluntary commitments. Burberry Group PLC, London January

3 2.0 Contents 1.0 Introduction Contents Restricted Substances Other Restrictions 10 APPENDIX 1- Analytes 11 AP & APEO incl. isomers 11 Bisphenol-A 11 Chlorinated Paraffins 11 Chlorinated Solvents 11 Chlorobenzenes 11 Chlorophenols 12 Dyes- AZO 13 Dyes- Other 13 Dyes- Disperse 14 Flame Retardants 15 Formaldehyde 15 Heavy Metals 15 N-nitrosamine 15 Organotin Compounds 16 Other Volatile Content 16 Perfluorinated and Polyfluorinated Chemicals 16 Pesticides 17 Phthalates 18 Polycyclic Aromatic Hydrocarbons (PAH) 19 APPENDIX 2 20 Definitions and abbreviations 20 4

4 3.0 Restricted Substances Restricted Substances Infant (<36 months) Limits Test Methods Applicability Kid (36 months 14 Years) Adult Textile Leather Down and Feathers Metal Components Wood Jewellery Plastic (Including Velcro, Synthetic Rubber) Rubber Paper Components AP & APEO incl. isomers* NP/OP mixed isomers OPEO/ NPEO Maximum Contamination Limit SUM= 3ppm Recycled Content Maximum Contamination Limit SUM= 10ppm Recycled Content Maximum Contamination Limit SUM= 25ppm Maximum Contamination Limit SUM= 25ppm Recycled Content Maximum Contamination Limit SUM= 100ppm Recycled Content Maximum Contamination Limit SUM= 250ppm TEXTILE: ISO with GC/MS and LCMS LEATHER: ISO determination with GC/ MS and LCMS ISO/DIS TEXTILE: ISO with LC/MS LEATHER: ISO LC MS MS Bisphenol-A* 50ppm Solvent extraction followed by LCMS Chlorinated Paraffins* ISO modified SCCP C10-C13 Maximum Contamination Limit 50ppm MCCP C14- C17 Maximum Contamination Limit 100ppm If Coated Chlorinated solvent* Not Detected By Headspace GC-MS Chlorobenzenes* Chlorophenols* Not Detected on textile Sum of mono,di and tri chlorophenols < 0.5 ppm Recycled Recycled Content Content Maximum Contamination Limit Maximum Tri SUM= 2.0ppm Contamination Di SUM= 3.0ppm Limit Mono= 3.0ppm Tri SUM= PCP/TeCP = Not Detected 0.2ppm Di SUM= 0.5ppm Mono= 0.5ppm PCP/TeCP= Not Detected PCP, TeCP Not Detected DIN TEXTILE: ISO modified with KOH extraction LEATHER: ISO *Analytes and Detection Limits are listed in Appendix 1 Applicable Not Applicable 5

5 Restricted Substances Limits Test Methods Applicability Infant (<36 months) Kid (36 months 14 Years) Adult Textile Leather Down and Feathers Metal Components Wood Jewellery Plastic (Including Velcro, Synthetic Rubber) Rubber Paper Components Dimethyl formamide (DMFa)* < 1000ppm ISO/TS PU-based Dimethyl fumarate (DMFu)* Not Detected ISO/TS Dyes- Azo* Dyes- Other* Not Detected Recycled Content Maximum Contamination Limit SUM= 20mg/kg Not Detected TEXTILE: EN :2015 P-Aminoazobenzene: EN :2015 LEATHER: ISO :2015 p-aminoazobenzene ISO :2011 DIN Recycled Content Maximum Contamination Limit SUM= 50ppm Dyes- Disperse* Flame Retardants* Formaldehyde* Not Detected Recycled Content Maximum Contamination Limit SUM= 20ppm Not Detected Not Detected DIN GB/T Solvent extraction, GC-MS / GC-NPD / LC-MS < 75ppm TEXTILE: JIS L A LEATHER: ISO Synthetics only Fur only *Analytes and Detection Limits are listed in Appendix 1 Applicable Not Applicable 6

6 Restricted Substances Limits Test Methods Applicability Infant (<36 months) Kid (36 months 14 Years) Adult Textile Leather Down and Feathers Metal Components Wood Jewellery Plastic (Including Velcro, Synthetic Rubber) Rubber Paper Components Heavy Metal Extractable* Arsenic < 0.2ppm Footwear < 1ppm TEXTILE: DIN EN ISO Antimony < 30ppm N/A TEXTILE: DIN EN ISO Cadmium Not Detected TEXTILE: DIN EN ISO Chromium III < 1ppm < 2ppm TEXTILE: DIN EN ISO Chromium VI Not Detected DIN EN ISO Modified Chromium III Chromium VI Banned from use Banned from use N/A TEXTILE: DIN EN ISO < 3ppm DIN EN ISO Modified Chrome Tanned Leather Chrome Tanned Leather Chromium III < 1ppm < 60ppm TEXTILE: DIN EN ISO Other Non-Chrome Tanned Leather Chromium VI Not detected < 3ppm DIN EN ISO Modified Other Non-Chrome Tanned Leather Cobalt < 1ppm N/A TEXTILE: DIN EN ISO Copper < 25ppm N/A TEXTILE: DIN EN ISO Lead < 0.2ppm < 1 ppm TEXTILE: DIN EN ISO *Analytes and Detection Limits are listed in Appendix 1 Applicable Not Applicable 7

7 Restricted Substances Limits Test Methods Applicability Infant (<36 months) Kid (36 months 14 Years) Adult Textile Leather Down and Feathers Metal Components Wood Jewellery Plastic (Including Velcro, Synthetic Rubber) Rubber Paper Components Heavy Metal Extractable* Heavy Metal Release* Heavy Metal Total Content* Nickel < 1ppm N/A TEXTILE: DIN EN ISO Mercury < 0.02ppm < 60 ppm TEXTILE: DIN EN ISO Selenium < 500ppm N/A TEXTILE: DIN EN ISO Nickel Prolonged Skin Contact <0.5 µg/cm 2 /week Body Piercings <0.2 µg/cm 2 /week EN 1811 if coated + EN Arsenic < 1ppm TEXTILE: DIS EN :2015 LEATHER: ISO Cadmium < 40ppm TEXTILE: DIS EN :2015 LEATHER: ISO Lead < 40ppm CPSC-CH-E X (incl Glass coated) < 90ppm CPSC-CH-E Mercury Not Detected TEXTILE: DIS EN :2015 LEATHER: ISO Heavy Metal* Heavy Metal* Lead in Surface Coating/Print Cadmium in Surface Coating/ Print 90ppm 75ppm CPSC-CH-E CPSC-CH-E *Analytes and Detection Limits are listed in Appendix 1 Applicable Not Applicable 8

8 Restricted Substances Limits Test Methods Applicability Infant (<36 months) Kid (36 months 14 Years) Adult Textile Leather Down and Feathers Metal Components Wood Jewellery Plastic (Including Velcro, Synthetic Rubber) Rubber Paper Components N- nitrosamine* Not Detected GB/ /GB GB/T Organotin Compounds* Sum of all < 0.5ppm < 1ppm ISO TS Other Volatile Content* Sum of all < 20ppm By Headspace GCMS Benzene < 5ppm Perfluorinated and Polyfluorinated Chemicals (PFCs)* Long and Short Chain PFCs* Not Detected LC MS and GC MS or LC QQQ and GC/MS/MS Pesticides* Not Detected US EPA 8081B / 8151A Phthalates* CPSC-CH-C Maximum Contamination Limit SUM= < 250ppm per plasticized component Polycyclic Aromatic AfPS-GS Hydrocarbons (PAH)* < 0.5ppm < 1ppm Coating** Vinyl Chloride Monomer* Not Detected GB PVC- coated PVC *Analytes and Detection Limits are listed in Appendix 1 **Coating as per the POP 850/2004 definition and its amendments Applicable Not Applicable 9

9 4.0 Other Restrictions REACH Regulation 1907/2006 Candidate List Annex XIV Burberry expects its global partners supplying Burberry PLC directly or indirectly with products and/or raw materials, to comply with the requirements set under REACH. This includes restrictions under Annex XVII, authorization and information Duty. In addition to the substances restricted in REACH Annex XVII, the REACH Regulation has other requirements for substances in articles. Evaluation and Authorization is required for substances of very high concern (SVHC), which are detailed in Annex XIV of the REACH Regulation 1907/2006. This list is updated periodically and can be found on 10

10 APPENDIX 1 Analytes AP & APEO incl. isomers Nonylphenol PPM PPM PPM PPM PPM Octyphenol PPM PPM PPM Nonylphenol ethoxylates (NPEOs) PPM PPM PPM PPM PPM Octylphenol ethoxylates (OPEOs) PPM PPM PPM Bisphenol-A Bisphenol-A PPM Chlorinated Parrafins SCCP PPM MCCP (C14-C17) PPM Chlorinated Solvents 1,2-Dichloroethane PPM Methylene chloride PPM Tetrachloroethene PPM Trichloroethene PPM Chlorobenzenes Chlorobenzene PPM 1,2-Dichlorobenzene PPM 1,3- Dichlorobenzene PPM 1,4- Dichlorobenzene PPM 1,2,4- Trichlorobenzene PPM 1,2,3- Trichlorobenzene PPM 1,3,5- Trichlorobenzene PPM 1,2,3,4- Tetrachlorobenzene PPM 1,2,3,5- Tetrachlorobenzene PPM 1,2,4,5- Tetrachlorobenzene PPM Pentachlorobenzene PPM Hexachlorobenzene PPM 2-Chlorotoluene PPM 11

11 Chlorobenzenes (continued) 3-Chlorotoluene PPM 4-Chlorotoluene PPM 2,3-Dichlorotoluene PPM 2,4-Dichlorotoluene PPM 2,5-Dichlorotoluene PPM 2,6-Dichlorotoluene PPM 3,4-Dichlorotoluene PPM 2,3,6-Trichlorotoluene PPM 2,4,5-Trichlorotoluene PPM 2,3,4,5-Tetrachlorotoluene PPM 2,3,5,6-Tetrachlorotoluene PPM Pentachlorotoluene PPM Chlorophenols 4-Chloro-3-methylphenol PPM 2-Chlorophenol PPM 3-chlorophenol PPM 4-chlorophenol PPM 2,3-dichlorophenol PPM 2,4-Dichlorophenol PPM 2,5-Dichlorophenol PPM 2,6-Dichlorophenol PPM 3,4-dichlorophenol PPM 3,5-dichlorophenol PPM Trichlorophenol mixed isomers PPM 2,4,5-Trichlorophenol PPM 2,4,6-Trichlorophenol PPM 2,3,4-Trichlorophenol PPM 2,3,5-Trichlorophenol PPM 2,3,6-Trichlorophenol PPM 3,4,5-Trichlorophenol PPM Tetrachlorophenol (TeCP) mixed isomers PPM 2,3,4,6-Tetrachlorophenol PPM 2,3,4,5-Tetrachlorophenol PPM 2,3,5,6-Tetrachlorophenol PPM Pentachlorophenol (PCP) PPM DMFa PPM DMFu PPM 12

12 Dyes- Azo 4,4 -methylene-bis-(2-chloro-aniline) PPM 4,4 -methylenedianiline / 4,4 -diaminodiphenylmethane PPM 4,4 -oxydianiline PPM 4-chloroaniline / p-chloraniline PPM 3,3 -dimethoxylbenzidine PPM 3,3 dimethylbenzidine PPM 6-methoxy-m-toluidine / p-cresidine PPM 2,4,5 trimethylanilline PPM 4,4 -thiodianiline PPM 4- aminoazobenzene / p- Aminoazobenzene PPM 4- methoxy-m-phenylenediamine / 2,4- Diaminoanisol PPM 4,4 methylenedi-o-toluidine / 3,3 -dimethyl-4,4 diamino-diphenyl-methane PPM 2,6-xylidine PPM o-anisdine / 2-methoxyaniline PPM 2-naphthylamine PPM 3, 3-dichlorobenzidine PPM 4-aminodiphenyl PPM Benzidine PPM o-toluidine PPM 2,4-xylidine PPM 4-chloro-o-toluidine-m PPM 4-methyl phenylenediamine / 2,4-toluylendiamine PPM o-aminoazotoluene PPM 5-nitro-o-toluidine / 2-amino-4-nitrotoluol PPM Dyes- Other NAVY BLUE Navy Blue incl C39H23CICrN7012S C46H30CrN10O20S PPM DYES- BASIC Direct Brown PPM Direct Black PPM Direct Blue PPM Direct Red PPM DYES- DIRECT C.I. Basic Violet 3 with 0,1 % of Michler s ketone (EC No ) PPM 13

13 Dyes- Disperse Disperse Blue PPM Disperse Blue PPM Disperse Blue PPM Disperse Blue PPM Disperse Yellow PPM Disperse Yellow PPM Disperse Yellow PPM Disperse Yellow PPM Disperse Orange PPM Disperse Red PPM Disperse Red PPM Disperse Brown PPM C.I. Disperse Blue PPM C.I. Disperse Blue PPM C.I. Disperse Blue PPM C.I. Disperse Blue PPM C.I. Disperse Orange PPM C.I. Disperse Orange PPM C.I. Disperse Orange PPM C.I. Disperse Orange PPM C.I. Disperse Red PPM C.I. Disperse Yellow PPM C.I. Acid Red PPM C.I. Basic Red PPM C.I. Basic Green PPM C.I. Basic Green PPM C.I. Basic Green PPM C.I. Basic Violet PPM C.I. Basic Blue PPM 14

14 Flame Retardants Tris(2-chloroethyl)phosphate (TCEP) PPM Decabromodiphenyl ether (DecaBDE) PPM Tris(2,3,-dibromopropyl)- phosphate (TRIS) PPM Pentabromodiphenyl ether (PentaBDE) PPM Octabromodiphenyl ether (OctaBDE) PPM Bis(2,3-dibromopropyl)phosphate (BIS) or (BBP) PPM Tris(1-aziridinyl)phosphine oxide (TEPA) PPM Polybromobiphenyls (PBB) PPM Tetrabromobisphenol A (TBBPA) PPM Hexabromocyclodecane (HBCDD) PPM 2,2-bis(bromomethyl)-1,3-propanediol (BBMP) PPM Tris(1,3-dichloro-isopropyl) phosphate (TDCP) PPM Bis (2,3-dibromopropylether) of tetrabromobisphenol (BDBPT) PPM Formaldehyde Fomaldehyde PPM Heavy Metals Arsenic Various Antimony Various Cadmium Various Chromium III Various Chromium VI PPM Cobalt Various Copper Various Lead Various Lead Various Nickel Various Mercury Various Selenium Various N-nitrosamine N-nitrosodimethylamine (NDMA) PPM N-nitrosodiethylamine (NDEA) PPM N-nitrosodipropylamine (NDPA) PPM N-nitrosodibutylamine (NDBA) PPM N-nitrosopiperidine (NPIP) PPM N-nitrosopyrrolidine (NPYR) PPM N-nitrosomorpholine (NMOR) PPM N-nitroso N-methyl N-phenylamine (NMPhA) PPM N-nitroso N-ethyl N-phenylamine (NEPhA) PPM 15

15 Organotin Compounds Dibutilyn (DBT) Multiple PPM Dimethyltin (DMT) Multiple PPM Monobutylin (MBT) Multiple PPM Monooctylin (MOT) Multiple PPM Dioctylin (DOT) Multiple PPM Tricyclohexyltin (TCyHT) Multiple PPM Trioctylin (TOT) Multiple PPM Tripropyltin (TPT) Multiple PPM Trimethyltin (TMT) Multiple PPM Triphenyltin (TPhT) Multiple PPM Tetrabutylin (TebT) PPM Tributyltin (TBT) Multiple PPM Monomethylin (MMT) Multiple PPM Monophenyltin (MPT) Multiple PPM Diphenyltin (DPT) Multiple PPM Other Volatile Content Analyte Cas number Required Detection Limit Benzene PPM Xylene PPM o-cresol PPM p-cresol PPM m-cresol PPM Toluene PPM Perfluorinated and Polyfluorinated Chemicals 2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (EtFOSE) µg/m2 Perfluoro-3,7-dimethylotanoic Acid (PF-3,7-DMOA) µg/m2 1H,1H,2H,2H- Perfluorooctylacrylate (6:2 FTA) µg/m2 1H,1H,2H,2H- Perfluorododecylacrylate (10:2 FTA) µg/m2 Perfluoroundecanoic acid (PFUdA) µg/m2 1H,1H,2H,2H- Perfluorooctanesulphonic acid (1H,1H,2H,2H-PFOS) µg/m2 1H,1H,2H,2H- Perfluorodecylacrylate (8:2 FTA) µg/m2 Perfluorododecanoic acid (PFDoA) µg/m2 N-methylperfluoro-1-octanesulfonamide (MeFOSA) µg/m2 Perfluorooctanoic acid (PFOA) µg/m2 perfluorodecanoic acid (PFDA) µg/m2 2H,2H,3H,3H- Perfluoroundecanoic Acid (H4PFUnA) µg/m2 perfluorononanoic acid (PFNA) µg/m2 Perfluorotetradecanoic acid (PFTeA) µg/m2 N-ethylperfluoro-1-octanesulfonamide (EtFOSA) µg/m2 perfluoroundecanoic acid (PFUnA) µg/m2 1H,1H,2H,2H-Perfluoro-1-Decanol (8:2 FTOH) µg/m2 16

16 Perfluorinated and Polyfluorinated Chemicals (continued) perfluorotridecanoic acid (PFTrA) µg/m2 perfluorooctane sulfonamide (PFOSA) µg/m2 1H,1H,2H,2H-Perfluoro-1-Dodecanol (10:2 FTOH) µg/m2 Perfluorooctane sulfonate (PFOS) Multiple 1µg/m2 7H-Dodecanefluoroheptane Acid No CAS available 1µg/m2 2H,2H-Perfluorodecane Acid No CAS available 1µg/m2 1H,1H,2H,2H-Perfluoorooctanesulphonic acid No CAS available 1µg/m2 Perfluorocyclobutane- c-c4f µg/m2 7H-dodecafluoroheptanoate (HPFHpA) µg/m2 1H,1H,2H,2H-Perfluoro-1-Hexanol (4:2 FTOH) µg/m2 Perfluoropentanoic acid (PFPA) µg/m2 Perfluoro-n-hexanoic acid (PFHxA) µg/m2 Perfluoropentane - C5F µg/m2 Perfluorohexane sulphonates (PFHxS) µg/m2 Perfluorobutanoic acid (PFBA) µg/m2 Perfluorobutane (PFBS) µg/m2 Perfluoroheptanoic acid (PFHpA) µg/m2 Perfluoro-1-heptanesulfonic acid (PFHpS) µg/m2 1H,1H,2H,2H-Perfluoro-1-Oktanol (6:2 FTOH) µg/m2 N-Methylheptadecafluorooctane sulfonamidoethanol (N-Me-FOSE) µg/m2 Pesticides 2-(2,4,5-trichlorophenoxy) propionic acid, its salts and compounds PPM 2,4,5-trichlorophenoxyacetic acid PPM Aldrin PPM Chlordane PPM Dichloro-diphenyl-dichloro ethane (DDD) PPM Dichloro-diphenyl-dichloro ethylene (DDE) PPM Dichloro-diphenyl-trichloro ethane (DDT) PPM Dieldrin PPM Endrine PPM Epoxy-heptachlorine PPM Hexachlorobenzene PPM Pentachlorobenzene PPM Tetrachlorobenzene PPM Hexachlorocyclohexane (HCH, all isomers) except gammahexachlorocyclohexane PPM Isodrin PPM Kelevane PPM Kepone (Chlordecone) PPM Lindane PPM Methoxychlor PPM Mirex PPM 17

17 Pesticides (continued) Perthane PPM Quintozene PPM Strobane PPM Telodrin PPM Toxaphene PPM Halogenated biphenyls, including Polycholorinated biphenyl (PCB) Multiple 0.2 PPM Various Halogenated terphenols, including Polychlorinated terphenyl (PCT) Multiple 0.2 PPM Various Halogenated naphthalenes Multiple 0.2 PPM Various Halogenated diarylalkanes Multiple 0.2 PPM Halogenated diphenyl methanes, including Multiple 0.2 PPM - Monomethyl-dibromo-diphenyl methane PPM - Monomethyl-dichloro-diphenyl methane PPM - Monomethyl-tetrachloro-diphenyl methane PPM Phthalates Di(ethylhexyl) phthalate (DEHP) PPM Bis(2-methoxyethyl) phthalate (DMEP) PPM Di-n-octyl phthalate (DNOP) PPM Di-iso-decyl phthalate (DIDP) PPM Di-isononyl phthalate (DINP) PPM Di-n-hexyl phthalate (DnHP) PPM Dibutyl phthalate (DBP) PPM Benzyl butyl phthalate (BBP) PPM Dinonyl phthalate (DNP) PPM Diethyl phthalate (DEP) PPM Di-n-propyl phthalate (DPRP) PPM Di-isobutyl phthalate (DIBP) PPM Di-cyclohexyl phthalate (DCHP) PPM Di-iso-octyl phthalate (DIOP) PPM 1,2-benzenedicarboxylic acid, di-c7-11 branched and linearalkyl esters (DHNUP) PPM 1,2-benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) PPM Dipentyl phthalate (DPP) PPM N-pentyl-isopentylphthalate (NPIPP) PPM Diisopnetyl phthalate (DIPP) PPM 1,2- Benzenedicarboxylic acid, dipentylester, branched and linear PPM Dimethyl phthalate (DMP) PPM 18

18 Polycyclic Aromatic Hydrocarbons (PAH) Benzo[a]pyrene (BaP) PPM Anthracene PPM Pyrene PPM Benzo[ghi]perylene PPM Benzo[e]pyrene PPM Indeno[1,2,3-cd]pyrene PPM Benzo[j]fluoranthene PPM Benzo[b]fluoranthene PPM Fluoranthene PPM Benzo[k]fluoranthene PPM Acenaphthylene PPM Chrysene PPM Dibenz[a,h]anthracene PPM Benzo[a]anthracene PPM Acenaphthene PPM Phenanthrene PPM Fluorene PPM Naphthalene PPM Acenapththene PPM Vinyl Chloride Monomer Vinyl Chloride Monomer PPM 19

19 APPENDIX 2 Definitions and abbreviations PPM Detection Limit Prolonged Skin Contact CAS number Infant Kid Adult Global Partner N/A Components Other non-chrome tanned leather Jewellery Part Per Million, equivalent of mg/kg Lowest limit value which can be detected by the selected test method. Below this limit the report will mention Not Detected Items which have the possibility to have direct skin contact e.g. lining in outerwear Unique numerical identifiers assigned by Chemical Abstracts Service to every chemical substance All products intended for children under the age of 36 months or 100cm height All products intended for children from 36 months up to the age of 14 years All products intended for people starting from the age of 16 years old A company who supplies Burberry directly or indirectly with stock items Not applicable Amongst others; mother of pearl, horn, corozo(nut), straw Leathers with other tanning methods such as synthetic and vegetable tanning Amongst others; glass, Swarovski, precious stones 20