Test Report. Sample Information. Tested according to "ordered" requirements Prints. Submitted Samples

Transcription

1 Page 1 of 9 Test Report Customer: ANKY A/S Contact Person: Sundsvej Herning Report No.: (25415) Denmark Report Version: 1 Morten Dilling Bertelsen Date of Reception: Report Date: Requirements: Sample Description: Tested according to "ordered" requirements Prints Sample Information Date of Order: Sampled By: client Performance Date: No. of orkdays: 10 Nr. 1 Submitted Samples Nr. 2.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

2 Page 2 of 9 Tests required Alkylphenols Azo dyes Chlorinated Paraffines Allergenic disperse dyes Formaldehyde Lead and Cadmium, total content PAH (Polycyclic aromatic hydrocarbons) ph value Phthalates Tinorganic compounds Summary of Test Results Tested according to "ordered" requirements Conclusion Remark The results for ph-value and formaldehyhde for the hite print and the results for chlorinated paraffins, formaldehyde, phvalue and tinorganic compouns for the grey print relates to additional sample material..bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

3 Page 3 of 9 Article No Sample ID Sample description ) Print hite ) Print grey Tested Samples Test Results Tested according to "ordered" requirements Sample Description: 1) Print hite Lab Reference No: Alkylphenols: BVCPS inhouse method, ultrasound extraction ith Methanol ( plastics THF/Methanol), determination using GC-MS, reporting limit: 3 mg/kg / % Nonylphenols (NP) Octylphenols (OP) <3 mg/kg <3 mg/kg Sum of Alkylphenols 10 mg/kg not detected Chlorinated Paraffines: Draft DIN EN ISO (modified), reporting limit: 0.01 % Short chained chlorinated paraffines, C10-C13 <0.01 % Formaldehyde, free in textiles: 64 LFGB B , Formaldehyde release in ater, reporting limit: 5 mg/kg Formaldehyde 16 mg/kg 6.5 mg/kg Determination of PAH: ZEK , reporting limit: 0.2 mg/kg Benzo (a) pyrene 0.5 mg/kg Benzo (e) pyrene 0.5 mg/kg Benzo (a) anthracene 0.5 mg/kg Chrysene 0.5 mg/kg Benzo (b) fluoranthene 0.5 mg/kg Benzo (j) fluoranthene 0.5 mg/kg Benzo (k) fluoranthene 0.5 mg/kg Dibenzo (a,h) anthracene 0.5 mg/kg Naphthalene Acenaphtylene Acenaphtene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Indeno (1,2,3-cd) pyrene Benzo (g,h,i) perylene Cyclopenta (c,d) pyrene Dibenzo (a,e) pyrene Dibenzo (a, i) pyrene Dibenzo (a, l) pyrene.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

4 Continuted\Unseiter Page 4 of 9 Sample Description: 1) Print hite Lab Reference No: Determination of PAH: ZEK , reporting limit: 0.2 mg/kg Dibenzo (a,h) pyrene 1-Methylpyrene Sum 5 mg/kg not detected ph value: DIN EN ISO 3071, variation B ph value Phthalates: DIN EN ISO (modified), extraction ith THF/ACN folloed by GC-MS and/or LC-MS analysis, reporting limit: 50 mg/kg Benzylbutylphthalate (BBP) Dibutylphthalate (DBP) Di(2-ethylhexyl)phthalate (DEHP) Bis(2-methoxyethyl) phthalate (DMEP) 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters (DHNUP) -> determinated as Diundecylphthalate Di-hexylphthalate, branched and linear (DHxP) Di-iso-butylphthalate (DIBP) Di-iso-decylphthalate (DIDP) Di-iso-hexylphthalate (DIHxP) Di-iso-nonylphthalate (DINP) Di-n-hexyl phthalate (DnHP) Di-n-octylphthalate (DNOP) Di-n-pentylphthalate (DnPP) Di-iso-pentylphthalate (DiPP) n-pentyl-iso-pentylphthalate (PiPP) 1,2-Benzenedicarboxylic acid, Di-C6-8-dipentylester, branched and linear Sum of listed Phthalates not detected Tinorganic compounds: DIN EN ISO modified / DIN modified, reporting limit: 0.05 mg/kg Dibutyltin (DBT) 1 mg/kg <0.05 mg/kg Dioctyltin (DOT) 1 mg/kg <0.05 mg/kg Tributyltin (TBT) 0.5 mg/kg <0.05 mg/kg Triphenyltin (TPhT) 0.5 mg/kg <0.05 mg/kg Lead & Cadmium, total content: DIN EN 14602, reporting limit: 1 mg/kg Cadmium (Cd) 50 mg/kg <1 mg/kg Lead (Pb) 90 mg/kg <1 mg/kg.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

5 Page 5 of 9 Sample Description: 2) Print grey Lab Reference No: Azo dyes/arylamines (other materials): EN :2012, LFGB 64 B & -4 ( BVL B & -4); reporting limit: 10 mg/kg Azo dyes/arylamines 20 mg/kg not detected Alkylphenols: BVCPS inhouse method, ultrasound extraction ith Methanol ( plastics THF/Methanol), determination using GC-MS, reporting limit: 3 mg/kg / % Nonylphenols (NP) Octylphenols (OP) <3 mg/kg <3 mg/kg Sum of Alkylphenols 10 mg/kg not detected Chlorinated Paraffines: Draft DIN EN ISO (modified), reporting limit: 0.01 % Short chained chlorinated paraffines, C10-C13 <0.01 % Formaldehyde, free in textiles: 64 LFGB B , Formaldehyde release in ater, reporting limit: 5 mg/kg Formaldehyde 16 mg/kg 5.5 mg/kg Determination of PAH: ZEK , reporting limit: 0.2 mg/kg Benzo (a) pyrene 0.5 mg/kg Benzo (e) pyrene 0.5 mg/kg Benzo (a) anthracene 0.5 mg/kg Chrysene 0.5 mg/kg Benzo (b) fluoranthene 0.5 mg/kg Benzo (j) fluoranthene 0.5 mg/kg Benzo (k) fluoranthene 0.5 mg/kg Dibenzo (a,h) anthracene 0.5 mg/kg Naphthalene Acenaphtylene Acenaphtene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Indeno (1,2,3-cd) pyrene Benzo (g,h,i) perylene Cyclopenta (c,d) pyrene Dibenzo (a,e) pyrene Dibenzo (a, i) pyrene Dibenzo (a, l) pyrene Dibenzo (a,h) pyrene 1-Methylpyrene Sum 5 mg/kg not detected.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

6 Page 6 of 9 Sample Description: 2) Print grey Lab Reference No: ph value: DIN EN ISO 3071, variation B ph value Phthalates: DIN EN ISO (modified), extraction ith THF/ACN folloed by GC-MS and/or LC-MS analysis, reporting limit: 50 mg/kg Benzylbutylphthalate (BBP) Dibutylphthalate (DBP) Di(2-ethylhexyl)phthalate (DEHP) Bis(2-methoxyethyl) phthalate (DMEP) 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters (DHNUP) -> determinated as Diundecylphthalate Di-hexylphthalate, branched and linear (DHxP) Di-iso-butylphthalate (DIBP) Di-iso-decylphthalate (DIDP) Di-iso-hexylphthalate (DIHxP) Di-iso-nonylphthalate (DINP) Di-n-hexyl phthalate (DnHP) Di-n-octylphthalate (DNOP) Di-n-pentylphthalate (DnPP) Di-iso-pentylphthalate (DiPP) n-pentyl-iso-pentylphthalate (PiPP) 1,2-Benzenedicarboxylic acid, Di-C6-8-dipentylester, branched and linear Sum of listed Phthalates not detected Tinorganic compounds: DIN EN ISO modified / DIN modified, reporting limit: 0.05 mg/kg Dibutyltin (DBT) 1 mg/kg <0.05 mg/kg Dioctyltin (DOT) 1 mg/kg <0.05 mg/kg Tributyltin (TBT) 0.5 mg/kg <0.05 mg/kg Triphenyltin (TPhT) 0.5 mg/kg <0.05 mg/kg Allergenic disperse dyes: DIN 54231, 64 LFGB B , reporting limit: 15 mg/kg Allergenic disperse dyes 50 mg/kg not detected Lead & Cadmium, total content: DIN EN 14602, reporting limit: 1 mg/kg Cadmium (Cd) 50 mg/kg <1 mg/kg Lead (Pb) 90 mg/kg <1 mg/kg.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

7 Page 7 of 9 All services provided by are subject to our current Terms and Conditions. The test result relates only to the tested item. Without the ritten consent of excerpts of this report shall not be reproduced. Tests not covered by the laboratory's testing spectrum may be subcontracted to an accredited laboratory. The accreditation relates to competences stated on the accreditation certificate. If nothing else has been agreed on samples are stored for 3 months. All tested parameters are listed in the appendix. The testing of mixed samples is carried out at the customer's explicit request and may imply a deviation from the testing standard. Please note the folloing: results for mixed samples that are belo the limit may exceed the limit if the samples contained in the mixed sample are tested individually. In these cases separate testing of the samples is recommended. Performance Date: Total Run Time: 10 Dr. Tim Lubinus Analytical Testing Specialist No results printed beyond this point in the report Azo dyes/arylamines (other materials) Detailed Method Descriptions EN :2012, LFGB 64 B & -4 (BVL B & -4), detection of the use of certain azo colorants in textiles accessible ith or ithout extraction, reduction by dithionit, detection of certain amines by GC-MS and/or LC-DAD-MS, reporting limit: 10 mg/kg Chlorinated Paraffines Draft DIN EN ISO (modified), ultrasound extraction ith n-hexane, 60 min, 60, GC-MS / NCI analysis, quantification: C10 - C13, 55.5% Cl content and C14 - C17, 52% Cl content, reporting limit: 0.01 % Allergenic disperse dyes DIN 54231, 64 LFGB B , ultrasound extraction ith Methanol, determination by LC-DAD-MS, reporting limit: 15 mg/kg Formaldehyde, free in textiles 64 LFGB B , Formaldehyde release in ater, derivatisation ith Acetylacetone, determination by photometry, reporting limit: 5 mg/kg Lead & Cadmium, total content DIN EN 14602, total metal content, microave digestion ith salpetric acid/hydrochloric acid, determination using ICP, reporting limit: 1 mg/kg Determination of PAH ZEK , ultrasound extraction ith Toluene, determination ith GC-MS (SIM), reporting limit: 0.2 mg/kg Tinorganic compounds DIN EN ISO modified / DIN modified, ultrasound extraction ith Ethanol / Diethyldithiocarbamate, derivatisation ith Tetraethylborate, determination using GC-MS, reporting limit: 0.05 mg/kg.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

8 Page 8 of 9 Alkylphenols Octylphenols (OP) ( ) Nonylphenols (NP) ( ) Azo dyes/arylamines (other materials) 4,4'-Methylene-bis-(2-chloro-aniline) ( ) 4,4'-Diaminodiphenylmethane ( ) 4,4'-Oxydianiline ( ) 4-Chloroaniline ( ) 3,3'-Dimethoxybenzidine ( ) 3,3'-Dimethylbenzidine ( ) p-cresidine ( ) 2,4,5-Trimethylaniline ( ) 4,4'-Thiodianiline ( ) 2,4-Diaminoanisole ( ) Aniline ( ) 3,3'-Dimethyl-4,4'-diaminodiphenylmethane ( ) 2,6-Xylidine ( ) o-anisidine ( ) 2-Naphtylamine ( ) 3,3'-Dichlorobenzidine ( ) 4-Aminobiphenyl ( ) Benzidine ( ) o-toluidine ( ) 2,4-Xylidine ( ) 4-Chloro-o-toluidine ( ) 2,4-Toluenediamine ( ) o-aminoazotoluene ( ) 5-Nitro-o-toluidine ( ) 1,4-Phenylenediamine ( ) Chlorinated Paraffines Short chained chlorinated paraffines, C10-C13 (-) Allergenic disperse dyes Disperse Yello 1 ( ) Disperse Blue 35 ( ) Disperse Blue 102 ( / ) Disperse Blue 106 ( ) Disperse Yello 39 ( ) Disperse Orange 37 / 76 / 59 ( ) Disperse Bron 1 ( ) Disperse Blue 1 ( ) Disperse Blue 3 ( ) Disperse Orange 1 ( ) Disperse Yello 3 ( ) Disperse Red 11 ( ) Disperse Red 1 ( ) Disperse Red 17 ( ) Parameters & CAS No. Disperse Blue 7 ( ) Disperse Blue 26 ( ) Disperse Yello 49 ( ) Disperse Blue 124 ( ) Disperse Yello 23 ( ) Disperse Yello 9 ( ) Disperse Orange 3 ( ) Disperse Orange 149 ( ) Formaldehyde, free in textiles Formaldehyde ( ) Lead & Cadmium, total content Lead (Pb) ( ) Cadmium (Cd) ( ) Determination of PAH Anthracene ( ) Pyrene ( ) Dibenzo (a, i) pyrene ( ) Dibenzo (a,h) pyrene ( ) Benzo (g,h,i) perylene ( ) Dibenzo (a, l) pyrene ( ) Dibenzo (a,e) pyrene ( ) Benzo (e) pyrene ( ) Indeno (1,2,3-cd) pyrene ( ) Benzo (j) fluoranthene ( ) Benzo (b) fluoranthene ( ) Fluoranthene ( ) Benzo (k) fluoranthene ( ) Acenaphtylene ( ) Chrysene ( ) 1-Methylpyrene ( ) Cyclopenta (c,d) pyrene ( ) Benzo (a) pyrene ( ) Dibenzo (a,h) anthracene ( ) Benzo (a) anthracene ( ) Acenaphtene ( ) Phenanthrene ( ) Fluorene ( ) Naphthalene ( ) Phthalates Di(2-ethylhexyl)phthalate (DEHP) ( ) Bis(2-methoxyethyl) phthalate (DMEP) ( ) Di-n-octylphthalate (DNOP) ( ) Di-n-pentylphthalate (DnPP) ( ) Di-iso-decylphthalate (DIDP) ( ) Di-iso-nonylphthalate (DINP) ( ) Di-iso-pentylphthalate (DiPP) ( ).bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com

9 Page 9 of 9 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters (DHNUP) -> determinated as Diundecylphthalate ( , ) Di-hexylphthalate, branched and linear (DHxP) ( ) Di-iso-hexylphthalate (DIHxP) ( ) 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) ( ) n-pentyl-iso-pentylphthalate (PiPP) ( ) Di-iso-butylphthalate (DIBP) ( ) Dibutylphthalate (DBP) ( ) Di-n-hexyl phthalate (DnHP) ( ) 1,2-Benzenedicarboxylic acid, Di-C6-8-dipentylester, branched and linear ( ) Benzylbutylphthalate (BBP) ( ) Tinorganic compounds Dioctyltin (DOT) (-nonexistent-) Dibutyltin (DBT) ( ) Tributyltin (TBT) ( ) Triphenyltin (TPhT) ( ).bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com