Coop Negative List for Textile and Leather

Transcription

1 Coop Negative List for Textile and Leather The Coop Negative List details substances that are restricted or banned in production due to their negative impact on human health and the environment. The Negative List is divided into two parts: Part A - Coop Restricted Substances List in Production (Coop MRSL; limit values for input chemicals, wastewater and sludge) Part B - Coop Restricted Substances List for Products (Coop PRSL) The Negative List (Part A) outlines limit values for the Detox Priority Substances Groups in input chemicals used in a production facility as well as wastewater and sludge discharged during production from that facility. All chemicals used in production processes at a facility must meet these requirements, it is prohibited to use the substances listed intentionally. For each limit, a test method is specified that must be used for laboratory analysis. The Negative List (Part B) deliberately sets limits for finished products as well as for cross contamination of these substances, including when substances are used unintentionally. It contains all substances from Part A in addition to those which Coop considers to ban in the future. Depending on their priority, chemicals may no longer be consciously used (= inclusion in the Coop MRSL) or must be gradually replaced with non-toxic alternatives by a specific date (see priorities). If several product limit values are stated per substance, the following categories are differentiated: A: baby skin contact / B: adult skin contact. For each limit, a test method is specified, that must be used for laboratory analysis of the finished products. Additional Substances to the ZDHC MRSL 1.1 The status of elimination of the restricted chemicals has been defined by Coop's Detox commitment and each chemical group has been prioritized for elimination till the year The priority is highlighted by a colour code in the document for easy identification and implementation by Coop's supply chain: Priority Achieved by Colour Code 1 End of December End of December End of December End of December End of December End of December 2020 Restricted Chemical Group APEOs, PFCs Azo Dyes, Carcinogenic Dyes, Allergenic-Disperse Dyes, Brominated and Chlorinated Flame Retardants, Other Flame Retardants Chlorobenzenes, Chlorotoluenes, Chlorophenols, ganotin Compounds, Toluene, DMFa, DMFu Phthalates, SCCPs Heavy Metals, PAHs, Glycols, Halogenated Solvents, VOCs, Formaldehyde Additional Restricted Chemical Substances The Coop negative list for textiles and leather is a dynamic document that takes account of the latest knowledge from toxicological studies and global legislation, as well as the current technological possibilities, and is accordingly updated on a regular basis. Suppliers are notified of updated documents by Coop Extranet info-mail. Coop suppliers are asked to always use these documents and on that basis implement measures to eliminate hazardous chemicals across the entire supply chain. The supplier must proactively notify Coop if it is currently unable to conform to these requirements. 1/14

2 Part A - Coop Restricted Substances List in Production (Coop MRSL) Input Chemicals Wastewater Sludge CAS Substance Name [µg/l] 1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers Nonylphenol (NP), mixed isomers Octylphenol (OP), mixed isomers Octylphenol ethoxylates (OPEO) Nonylphenol ethoxylates (NPEO) 2. Chlorobenzenes and Chlorotoluenes ,2-dichlorobenzene 1000 ppm Other isomers of mono-, di-, tri-, tetra-, penta- and hexa- chlorobenzene and mono-, di-, tri-, tetra- and penta- chlorotoluene 500 ppm 500 ppm Sum = 200 ppm Liquid chromatographymass spectrometry (LC- MS), gas chromatographymass spectrometry () 1 5 For NP and OP: EN ISO () or EN ISO () or ASTM D7065 () For NPEO& OPEO (1-2 moles) : EN ISO () or ASTM D (LC-MS-MS) For NPEO&OPEO (3-18 moles): With reference to ISO/DIS U. S. EPA 8260B 0.2 (purge and trap method) or U. S. 0.1 EPA 8270D. Reference to ASTM D5369 or EPA 3540C (for extraction) and analysis with reference to EN ISO (for, NP, OP, 1-2 moles NPEO, OPEO) and With reference to ISO/DIS (for NPEO and OPEO (3-18) moles Extraction with reference to EPA 3540C and analysis by EPA 8270D 3. Chlorophenols Tetrachlorophenol (TeCP) Pentachlorophenol (PCP) Sum = 20 ppm ,3,4,5-tetrachlorophenol ,3,4,6-tetrachlorophenol ,3,5,6-tetrachlorophenol chlorophenol ,4-dichlorophenol ,5-dichlorophenol ,6-dichlorophenol ,4,5-trichlorophenol ,4,6-trichlorophenol ,5-dichlorophenol ,3-dichlorophenol Sum = 50 ppm EN ISO Extraction as per US EPA 3510C and quantification as per EPA 8270D or ISO 14154:2005 (using GC-ECD) 0.6 Reference to ASTM D5369, EPA 3540C (For extraction) & EPA 8270D (for analysis) ,4-dichlorophenol chlorophenol chlorophenol ,3,4-trichlorophenol ,3,5-trichlorophenol ,4,5-trichlorophenol 4. Dyes - Azo (Forming Restriced Amines) ,4 -methylene -bis -(2-chloro - aniline) 150 ppm ,4 -methylenedianiline 150 ppm ,4 -oxydianiline 150 ppm chloroaniline 150 ppm ,3 -dimethoxylbenzidine 150 ppm ,3 -dimethylbenzidine 150 ppm methoxy-m-toluidine 150 ppm ,4,5-trimethylaniline 150 ppm ,4 -thiodianiline 150 ppm aminoazobenzene 150 ppm methoxy-m-phenylenediamine 150 ppm ,4 -methylenedi-o-toluidine 150 ppm ,6-xylidine 150 ppm o-anisidine 150 ppm naphthylamine 150 ppm , 3-dichlorobenzidine 150 ppm LC, GC 0.1 With reference to EN & EN U.S. EPA 8270D (Extraction by EPA 3510C) 0.1 U.S. EPA 8270D (Extraction by EPA 3510C) aminodiphenyl 150 ppm 2/14

3 CAS Substance Name Input Chemicals Wastewater Sludge [µg/l] Benzidine 150 ppm o-toluidine 150 ppm ,4-xylidine 150 ppm chloro-o-toluidine 150 ppm methyl-m-phenylenediamine 150 ppm o-aminoazotoluene 150 ppm nitro-o-toluidine 150 ppm 5. Dyes - Navy Blue Colourant Not Allocated Component 1: C39H23ClCrN7O12S 2Na Component 2: C46H30CrN10O20S2 3Na 6. Dyes - Carcinogenic or Equivalent Concern LC 50 With reference to DIN (LC-DAD- MS) U.S.EPA 8321B 0.3 ASTM D5369 or US EPA 3540C (For Extraction) Analysis with reference to ISO or EPA 8321B C.I. Direct Black C.I. Direct Blue C.I. Acid Red C.I. Basic Red C.I. Direct Red C.I. Basic Violet C.I. Disperse Blue C.I. Disperse Blue C.I. Basic Blue 26 (with Michler s Ketone > 0.1%) C.I. Basic Green 4 (malachite green chloride) C.I. Basic Green 4 (malachite green oxalate) C.I. Basic Green 4 (malachite green) C.I. Disperse ange C.I. Disperse Yellow C.I. Direct Brown 95 LC 10 With reference to DIN (LC- DAD-MS) Reference to ISO :2014 US EPA 8321B 0.3 ASTM D5369 or US EPA 3540C (For Extraction) Analysis with reference to ISO or EPA 8321B C.I. Solvent Yellow C.I. Solvent Yellow C.I. Solvent Yellow C.I. Basic Violet C.I. Direct Blue C.I. Direct Blue C.I. Acid Red C.I. Acid Violet C.I. Pigment Yellow C.I. Pigment Red Dyes - Disperse (Sensitising) Disperse Yellow Disperse Blue Disperse Blue Disperse Yellow Disperse ange 37/59/ Disperse Brown Disperse ange Disperse Yellow Disperse Red Disperse Red Disperse Red Disperse Blue Disperse Blue Disperse Yellow 49 LC 10 With reference to DIN (LC- DAD-MS) Reference to ISO :2014 US EPA 8321B 0.3 ASTM D5369 or US EPA 3540C (For Extraction) Analysis with reference to ISO or EPA 8321B Disperse Blue Disperse Blue Disperse Yellow Disperse ange Disperse Blue Flame Retardants 3/14

4 CAS Substance Name Input Chemicals Wastewater Sludge [µg/l] Tris(2-chloroethyl)phosphate (TCEP) Decabromodiphenyl ether (DecaBDE) Tris(2,3,-dibromopropyl)8phosphate (TRIS) Pentabromodiphenyl ether (PentaBDE) Octabromodiphenyl ether (OctaBDE) Bis(2,3-dibromopropyl)phosphate (BIS) Tris(1-aziridinyl)phosphine oxide) (TEPA) Polybromobiphenyls (PBB) Tetrabromobisphenol A (TBBPA) Hexabromocyclodecane (HBCDD) 2,2-bis(bromomethyl)-1, propanediol (BBMP) Tris(1,3-dichloro-isopropyl) phosphate (TDCP) Tetrabromodiphenyl ether (TetraBDE) Hexabromodiphenyl ethers (HexaBDE) Heptabromodiphenyl ether (HeptaBDE) Nonabromodiphenyl ether (NonaBDE) Tris(1-chloro-2-propyl)phosphate (TCPP) Sodium tetraborate tbd Boron trioxide tbd Boric acid tbd Antimony trioxide tbd 5 tbd ISO 22032:2006 (for polybdes) and US EPA 527 with quantification by US EPA 8321B ( or LC-MS- MS) 0.25 ASTM D (2008)e1 or EPA 3540C (Standard for extraction) with 1) DIN ISO ) US EPA 527 and U.S. EPA 8321B. tbd tbd tbd tbd Tri-o-cresyl phosphate tbd Short-chain chlorinated Paraffins (SCCP) (C10-C13) 50 ppm EN-ISO BS EN ISO 12010: Reference to ASTM D5369, EPA 3540C & ISO/PRF Glycols Bis(2-methoxyethyl)-ether 50 ppm ethoxyethanol 50 ppm ethoxyethyl acetate 50 ppm Ethylene glycol dimethyl ether 50 ppm methoxyethanol 50 ppm methoxyethylacetate 50 ppm methoxypropylacetate 50 ppm High-performance liquid chromatography (HPLC), LC-MS 50 US EPA 8015 D modified with ENVI-Carb Plus SPE US EPA 8270 (LC-MS) 50 US EPA 8015 D modified with ENVI-Carb Plus SPE US EPA 8270 (LC-MS) Triethylene glycol dimethyl ether 50 ppm 10. Halogenated Solvents ,2-dichloroethane 5 ppm Methylene chloride 5 ppm Trichloroethylene 40 ppm Tetrachloroethylene 5 ppm 1 ISO 10301:1997 US EPA s 524.2, 5030C, 8260 B 0.3 With reference to U.S. EPA 8260C, 5035A, 5021, 8021B & 8260B 11. ganotin Compounds Multiple Dibutyltin (DBT) 20 ppm Multiple Multiple Multiple Multiple Mono-, di- and tri-methyltin derivatives Mono-, di- and tri-butyltin derivatives Mono-, di- and tri-phenyltin derivatives Mono-, di- and tri-octyltin derivatives 5 ppm 5 ppm 5 ppm 5 ppm 12. Polycyclic Aromatic Hydrocarbons (PAHs), low resolution mass spectrometry (LRMS) 0.01 ISO Reference to ASTM D5369, EPA 3540C (for extraction) & DS/EN ISO Benzo[a]pyrene (BaP) 20 ppm Anthracene Pyrene Benzo[ghi]perylene 4/14

5 CAS Substance Name Input Chemicals Wastewater Sludge [µg/l] Benzo[e]pyrene Indeno[1,2,3-cd]pyrene Benzo[j]fluoranthene Benzo[b]fluoranthene Fluoranthene Benzo[k]fluoranthene Acenaphthylene Sum = 200 ppm 1 DIN ( ) US EPA U.S. EPA 8270D and EPA 3510C Chrysene Dibenz[a,h]anthracene Benzo[a]anthracene Acenaphthene Phenanthrene Fluorene Naphthalene, LC 13. Perfluorinated and Polyfluorinated Chemicals (PFCs) Perfluorooctanic acid (PFOA) Perfluorobutanoic acid (PFBA) Perfluoropentanoic acid (PFPA) Perfluorohexanoic acid (PFHxA) Perfluoroheptanoic acid (PFHpA) Perfluorononanoic acid (PFNA) Perfluorodecanoic acid (PFDA) Perfluoroundecanoic acid (PFUnA) Perfluorododecanoic acid (PFDoA) Perfluorotridecanoic acid (PFTrDA) Perfluorotetradecanoic acid (PFTeA) Perfluorooctane sulphonic acid (PFOS) Perfluorobutane sulphonic acid (PFBS) Perfluorohexane sulphonic acid (PFHxS) Perfluoroheptane sulphonic acid (PFHpS) Perfluorodecane sulphonic acid (PFDS) Perfluoro-3,7-dimethyl octanoic acid (PF-3,7-DMOA) 7H-Dodecafluoroheptanoic acid (HPFHpA) 2H,2H-Perfluorodecanoic acid (H2PFDA) 1H,1H,2H,2Hperfluorooctanesulfonate, (H4PFOS 6:2 FTS) Perfluoro-1-octanesulfonamide (PFOSA) N-methylperfluoro-1- octanesulfonamide (N-MeFOSA) N-ethylperfluoro-1- octanesulfonamide (N-EtFOSA) 2-(N-methylperfluoro-1- octanesulfonamido)-ethanol (NMeFOSE) 2-(N-ethylperfluoro-1- octanessulfonamido)-ethanol 1H,1H,2H,2H-Perfluoro-1-hexanol (4:2 FTOH) 1H,1H,2H,2H-Perfluoro-1-octanol (6:2 FTOH) 1H,1H,2H,2H-Perfluoro-1-decanol (8:2 FTOH) 2 ppm LC-MS 0.01 ISO 25101:2009 or DIN (modified) ASTM D5369, EPA 3540C (for extraction) and with reference to CEN/TS (LC-MS-MS) H,1H,2H,2H-Perfluoro-1-dodecanol (10:2 FTOH) H,1H,2H,2H-Perfluorooctylacrylate (6:2 FTAC) H,1H,2H,2H-Perfluorodecylacrylate (8:2 FTAC) H,1H,2H,2H- Perfluorododecylacrylate (10:2 FTAC) 14. Phthalates - including all other esters of ortho-phthalic acid 5/14

6 CAS Substance Name Input Chemicals Wastewater Sludge [µg/l] Di(ethylhexyl) phthalate (DEHP) Bis(2-methoxyethyl) phthalate (DMEP) Di-n-octyl phthalate (DNOP) Di-iso-decyl phthalate (DIDP) Di-isononyl phthalate (DINP) Di-n-hexyl phthalate (DnHP) Dibutyl phthalate (DBP) Butyl benzyl phthalate (BBP) Dinonyl phthalate (DNP) Diethyl phthalate (DEP) Di-n-propyl phthalate (DPRP) Di-isobutyl phthalate (DIBP) Di-cyclohexyl phthalate (DCHP) Di-iso-octyl phthalate (DIOP) ,2-benzenedicarboxylic acid, di-c7-11-branched and linearalkyl esters (DHNUP) 1,2-benzenedicarboxylic acid,di-c6-8-branched alkyl esters,c7-rich (DIHP) 15. Total Heavy Metals Listed metals are banned from intentional use in textile manufacturing/finishing. Additionally, residual traces of antimony, zinc, copper, nickel, tin, barium, cobalt, iron, manganese, selenium and silver in colourants are expected to comply with the Ecological and Toxicological Association of Dyes and ganic Pigments Manufacturers (ETAD) concentration limits ( Lead (Pb) 100 ppm Cr (III) Tanning agents can be 0.1 monitored for Cr(VI) ISO (ICP- OES) or ISO (ICP-MS) ISO (ICP- OES) or ISO (ICP-MS) ISO or ISO (ICP- OES) or ISO (ICP-MS) EN ISO (Current Chromium (VI) 10 ppm Use) 0.05 ISO ISO/DIS (Draft) 16. Volatile ganic Compounds (VOCs) 0.02 U.S. EPA 7471B 1 U.S. EPA 3051A, 3050B (for digestion) ; analysis by EPA 6011 U.S. EPA 3060A (for digestion) ; With reference to Benzene 50 ppm US EPA ISO C Xylene 500 ppm 15 US EPA 8260 B o-cresol 500 ppm EPA 3540C (For extraction) p-cresol 500 ppm 10 US EPA 8041A 1 & EPA 8270D (for m-cresol 500 ppm analysis) 17. Fat Liquoring Agents Short-chain chlorinated Paraffins (SCCP) (C10-C13) Sum of all phthalates = Inductively coupled Arsenic (As) 50 ppm plasma- 0.1 optical emission 20 ppm spectrometry (ICP Cadmium (Cd) (50 ppm for OES), 0.1 pigments) atomic absorption 4 ppm spectroscopy (AAS) Mercury (Hg) (25 ppm for 0.01 pigments) 10 EN-ISO ) ISO (Scope: DMP, DEP, TPP, DiBP, DBP, BBP, DCHP, DEHP, DOP, DDcP and DUP) 2) U.S. EPA 8270D and EPA 3510C (for extraction) BS EN ISO 12010: Reference to ASTM D5369 or EPA 3540C (For Extraction) and analysis by EPA 8270D U.S. EPA 3051A, 3050B (for digestion) ; analysis by EPA 6011 Reference to ASTM D5369, EPA 3540C & ISO/PRF /14

7 Part B - Coop Restricted Substances List for Products (Coop PRSL) Restriction on Inadmissible Substances in Finished Products 1. Alkylphenols (APs) and Alkylphenol Ethoxylates (APEOs): incl. Isomers P1 2. Chlorobenzenes P3 3. Chlorotoluenes P3 4. Chlorophenols P3 Nonylphenol (NP) & mixed isomers Nonylphenol ethoxylates (NPEOs) Octylphenol (OP) & mixed isomers Octylphenol ethoxylates (OPEOs) , Dichlorobenzenes various 1,2-Dichlorobenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Trichlorobenzenes various 1,2,3-Trichlorobenzene ,2,4-Trichlorobenzene ,3,5-Trichlorobenzene Tetrachlorobenzene ,2,3,4-Tetrachlorobenzene ,2,3,5-Tetrachlorobenzene ,2,4,5-Tetrachlorobenzene Pentachlorobenzene Hexachlorobenzene Chlorotoluene Chlorotoluene Chlorotoluene ,3-Dichlorotoluene ,4-Dichlorotoluene ,5-Dichlorotoluene ,7-6 Dichlorotoluene ,4-Dichlorotoluene ,3,6-Trichlorotoluene ,4,5-Trichlorotoluene α,2,4-trichlorotoluene α,2,6-trichlorotoluene α,3,4-trichlorotoluene α,α,2,6-tetrachlorotoluene α,α,α,2-tetrachlorotoluene α,α,α,4-tetrachlorotoluene ,3,4,5,6-Pentachlorotoluene Benzotrichloride Sum of all <1 Monochlorophenol various 0.5 Dichlorophenols (DiCP) Chlorophenol ,3-Dichlorophenol ,4-Dichlorophenol ,5-Dichlorophenol ,6-Dichlorophenol ,4-Dichlorophenol ,5-Dichlorophenol Chlorophenol Chlorophenol Trichlorophenol (TriCP) Sum of all <0.5 2,4,6-Trichlorophenol ,3,4-Trichlorophenol ,3,5-Trichlorophenol ,3,6-Trichlorophenol ,4,5-Trichlorophenol ,4,5-Trichlorophenol Tetrachlorophenols (TeCP) diverse ,3,4,5-Tetrachlorophenol ,3,4,6-Tetrachlorophenol Sum of all <10 1. For textile articles: ISO/DIS :2016 (NPEO & OPEO) Solvent extraction (NP & OP) 2. For leather and process auxillaries: a) ISO :2015 (1 to 16 moles NPEO and OPEO) b) ISO :2015 (1 to 16 moles NPEO & OPEO + NP & OP) DIN Sum of all <1 DIN LFGB BVL B (2001) (for textiles) and ISO 17070:2015 (for leather) 7/14

8 2,3,5,6-Tetrachlorophenol Pentachlorophenol (PCP) /0.5 4-Chloro-3-methylphenol Azo Dyes (reductively cleavable, carcinogenic arylamines) P2 2,4,5-Trimethylaniline ,4-Diaminoanisole ,4-Toluenediamine ,4-Xylidine ,6-Xylidine Amino-4-nitrotoluene Naphthylamine ,3 -Dichlorobenzidine ,3 -Dimethoxybenzidine ,3 -Dimethyl-4,4 diaminodiphenylmethane ,3 -Dimethylbenzidine ,4 -Diaminodiphenylmethane ,4 -Methylene-bis(2-chloroaniline) ,4 -Oxydianiline ,4 -Thiodianiline Aminobiphenyl Chloro-o-toluidine Benzidine o-aminoazotoluene o-anisidine o-toluidine p-aminoazobenzene p-chloroaniline p-cresidine Carcinogenic Dyes P2 C.I. Disperse Blue mg/l C.I. Disperse ange mg/l C.I. Disperse ange mg/l C.I. Disperse Yellow mg/l Component 1: C39H23ClCrN7O12S 2Na (Navy Blue Colourant) mg/l Component 2: C46H30CrN10O20S2 3Na (Navy Blue Colourant) Not Allocated 5 mg/l C.I. Acid Red mg/l C.I. Direct Black mg/l C.I. Direct Blue mg/l C.I. Direct Red mg/l C.I. Basic Blue mg/l C.I. Basic Green 4 (Malachite Green) mg/l C.I. Basic Red mg/l C.I. Basic Violet mg/l C.I. Direct Brown mg/l C.I. Disperse Yellow mg/l C.I. Solvent Yellow mg/l C.I. Solvent Yellow mg/l C.I. Solvent Yellow mg/l C.I. Solvent Yellow mg/l C.I. Basic Violet mg/l C.I. Direct Blue mg/l C.I. Direct Blue mg/l C.I. Acid Red mg/l C.I. Acid Violet mg/l For textiles: EN :2012 EN :2012 (for 4- Aminoazobenzene) Natural leather : EN ISO :2015 EN ISO :2011 (for 4-Aminoazobenzene) Products for China market: Textiles: GB/T (China Standard: GB18401) Natural leather: GB/T (China Standard: GB20400) DIN 54231:2005 (for all listed colourants) ISO :2014 C.I. Basic Green 4 (malachite green oxalate) mg/l C.I. Basic Green 4 (malachite green chloride) mg/l C.I. Pigment Yellow mg/l C.I. Pigment Red mg/l 7. Allergenic-Disperse Dyes P2 C.I. Disperse Blue mg/l C.I. Disperse Blue mg/l C.I. Disperse Blue mg/l C.I. Disperse Blue mg/l C.I. Disperse Blue mg/l C.I. Disperse Blue mg/l C.I. Disperse Blue ; ; mg/l C.I. Disperse Blue mg/l C.I. Disperse Brown mg/l C.I. Disperse ange mg/l C.I. Disperse ange mg/l C.I. Disperse ange 37/59/ mg/l C.I. Disperse Red mg/l DIN 54231:2005 (for all listed colorants) ISO :2014 8/14

9 C.I. Disperse Red mg/l C.I. Disperse Red mg/l C.I. Disperse Yellow mg/l C.I. Disperse Yellow mg/l C.I. Disperse Yellow mg/l C.I. Disperse Yellow mg/l C.I. Disperse Yellow mg/l 8. Brominated and Chlorinated Flame Retardants P2 Tris(2-chloroethyl)phosphate (TCEP) Bis(2,3-dibromopropyl)phosphate Tetrabromodiphenyl ether (TetraBDE) Pentabromodiphenyl ether (PentaBDE) Hexabromodiphenyl ethers (HexaBDE) Heptabromodiphenyl ether (HeptaBDE) Octabromodiphenyl ether (OctaBDE) Nonabromodiphenyl ether (NonaBDE) Decabromodiphenyl ether (DecaBDE) Hexabromocyclodecane (HBCDD) , , , , ,2-Bis(bromomethyl)-1,3-propanediol (BBMP) Polybromobiphenyl (PBB) Tetrabromobisphenol A (TBBPA) Tris(1,3-dichloro-isopropyl) phosphate (TDCP) Tris(1-chloro-2-propyl)phosphate (TCPP) Tris(2,3,-dibromopropyl)-phosphate (TRIS) Subgroup: Other Flame Retardants 10 Solvent extraction / GC- MS or LC-MS For China market: GB/T P2 P4 Tris(1-aziridinyl)phosphine oxide) (TEPA) Sodium tetraborate ; ; Boron trioxide Boric acid ; Antimony trioxide (as Sb) Tri-o-cresyl phosphate Short-Chain Chlorinated Paraffins (SCCPs) 10. Glycols P5 Short-chain chlorinated Paraffins (SCCPs) with C10 - C13 Acetone extraction, followed by LC-MS Indirect method for the analysis: Acid digestion ICP-OES / ICP-MS for analysis Extraction following IEC :2015 // LC-MS, -NCI ISO 18219: Ethoxyethanol Methoxyethanol Methoxyethylacetate Methoxypropylacetate Ethylene glycol dimethyl ether (EDGME) Triethylene glycol dimethyl ether Bis(2-methoxyethyl)-ether Ethoxyethyl acetate Halogenated Solvents P5 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethylene ,2-Dichloroethane Chloroform Methylene chloride, Dichloromethane Pentachloroethane Tetrachloroethylene Tetrachloromethane Trichloroethylene ganotin Compounds Mono, Di & Tri-butyltin derivatives Various Sum <0.2 Recommended: Acid digestion/icp-oes or ICP- MS for analysis Textile: Extraction with MeOH // or LC-MS Plastic: 2-Step extraction with THF and MeOH // or LC-MS Methanol extraction followed by Headspace 9/14

10 P3 Mono, Di & Tri-methyltin derivatives Various Sum <0.2 Mono, Di & Tri-phenyltin derivatives Various Sum <0.2 Mono, Di & Tri-octyltin derivatives Various Sum <0.5 Tetraethyltin (TET) Sum <0.5 Tributyltin oxode (TBTO) Sum <0.2 Dibutyltin dichloride (DBTC) Sum <0.2 Dibutyltin hydrogen borate (DBB) Sum <0.2 Tricyclohexyltin Various Sum <0.5 Tripropyltin Various Sum < Polycyclic Aromatic Hydrocarbons (PAHs) P5 Benzo-[a]-pyrene (BaP) Benzo-[a]-anthracene (BaA) Benzo-[b]-fluoranthene (BbFA) Benzo-[e]-pyrene (BeP) Benzo-[j]-fluoranthene (BjFA) Benzo-[k]-fluoranthene (BkFA) Chrysene (CHR) Dibenzo(a,e)pyrene Dibenzo(a,h)pyrene Dibenzo(a,i)pyrene Dibenzo(a,l)pyrene Dibenzo-[a,h]-anthracene (DBAhA) Acenaphthene Acenaphthylene Anthracene Benzo[ghi]perylene Fluoranthene Fluorene Indeno[1,2,3-cd]pyrene Naphthalene Phenanthrene Pyrene Cyclopenta(c,d)pyrene Methylpyrene Total of all PAHs Perfluorinated and Polyfluorinated Carbons (PFCs) P1 Included in sum of all PAH <10 If PAH analysis shows only naphthalene in product, apply limit value as 100 mg/kg for naphthalene Perfluorocarboxylic Acids Perfluorooctanic acid (PFOA) µg/m² Perfluorobutanoic acid (PFBA) Perfluoropentanoic acid (PFPA) Perfluorohexanoic acid (PFHxA) Perfluoroheptanoic acid (PFHpA) Perfluorononanoic acid (PFNA) Perfluorodecanoic acid (PFDA) Perfluoroundecanoic acid (PFUnA) Perfluorododecanoic acid (PFDoA) Perfluorotridecanoic acid (PFTrDA) Perfluorotetradecanoic acid (PFTeA) Perfluoroalkyl Sulfonates (PFSA) Perfluorooctane sulphonic acid (PFOS) µg/m² Perfluorobutane sulphonic acid (PFBS) Perfluorohexane sulphonic acid (PFHxS) Perfluoroheptane sulphonic acid (PFHpS) Perfluorodecane sulphonic acid (PFDS) Polyfluorinated Carboxylic Acids Perfluoro-3,7-dimethyl octanoic acid (PF-3,7- DMOA) H-Dodecafluoroheptanoic acid (HPFHpA) H,2H-Perfluorodecanoic acid (H2PFDA) Polyfluorinated Sulfonates 1H,1H,2H,2H-perfluorooctanesulfonate, (H4PFOS 6:2 FTS) Perfluoralkyl Sulfonamide (FOSA) Perfluoro-1-octanesulfonamide (PFOSA) N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) Perfluorooctane Sulfonamide Ethanol (FOSE) 2-(N-methylperfluoro-1-octanesulfonamido)- ethanol (NMeFOSE) (N-ethylperfluoro-1-octanessulfonamido)- ethanol Fluortelomer Alcohols (FTOH) 1H,1H,2H,2H-Perfluoro-1-hexanol (4:2 FTOH) H,1H,2H,2H-Perfluoro-1-octanol (6:2 FTOH) H,1H,2H,2H-Perfluoro-1-decanol (8:2 FTOH) ISO/TS 16179:2012 (for all listed analytes) AfPS GS 2014:01 PAK Extraction with organic solvent, LC/MS based on CEN/TS /14

11 15. Phthalates P4 16. Heavy Metals 1H,1H,2H,2H-Perfluoro-1-dodecanol (10:2 FTOH) Fluorotelomer Acrylates (FTAC) 1H,1H,2H,2H-Perfluorooctylacrylate (6:2 FTAC) 1H,1H,2H,2H-Perfluorodecylacrylate (8:2 FTAC) 1H,1H,2H,2H-Perfluorododecylacrylate (10:2 FTAC) Butyl benzyl phthalate (BBP) ,2-Benzenedicarboxylic acid, di-c7-11- branched and linear alkyl esters (DHNUP) Di-(2-methoxyethyl) phthalate (DMEP) Di(ethylhexyl) phthalate (DEHP) Dibutyl phthalate (DBP) ,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) Di-isobutyl phthalate (DIBP) Di-iso-decyl phthalate (DIDP) , Di-isononyl phthalate (DINP) , Di-n-hexyl phthalate (DnHP) Di-n-octyl phthalate (DNOP) Di-isopentyl phthalate (DIPP) Di-n-propyl phthalate (DPRP) ,2-benzenedicarboxylic acid, dipentyl ester, branched and linear Di-iso-octyl phthalate (DIOP) Dinonyl phthalate (DNP) N-pentyl-isopentylphthalate (NPIPP) Di-cyclohexyl phthalate (DCHP) Diethy phthalate (DEP) Dipentyl phthalate (DPP) Dihexylphthalate, branched + linear ,2-benzenedicarboxylic acid, di-c6-10-alkyl esters;1,2-benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with 0.3% of dihexyl phthalate Dimethyl phthalate (DMP) Diisohexyl phthalate Total Digestion Metal Content 500 each and Sum of all phthalates <1000 Lead (Pb) Various 40 1) CPSC-CH-C (Mandatory for US market for determination of phthalates in childeren toys and childcare articles) 2) ISO (For textile) 3. ISO/TS 16181:2011 (For footwear materials) Total lead content: CPSC-CH-E (metals) CPSC-CH-E (coating) CPSC-CH-E (Nonmetal polymeric material)/ ISO (leather) Cadmium (Cd) Various 50 Total cadmium : EN 1122 P5 Arsenic (As) Various 10 Mercury (Hg) Various 0.5 Extractable Metal Content Antimony (Sb) Arsenic (As) Various 0.2 Barium (Ba) Cadmium (Cd) Various 0.1 Chromium (Cr; total) Cobalt (Co) Copper (Cu) Lead (Pb) Various 0.2 Mercury (Hg) Various 0.02 Zinc (Zn) Tin (Sn) ISO (Leather) / EN (textiles) / Microwave Digestion followed by ICP-MS Microwave digestion with H202/HNO3 followed by EN ISO :2014 ISO (leather) / pren (others) 11/14

12 Chromium, hexavalent, Cr(VI) Various 3 Nickel (Ni) Selenium (Se) Releasable Metal Content (from sundries & jewellery) Extractable Cr VI in leather: ISO ing is to be performed after ageing (ageing condition 24 hours at 80'C and 20% RH) Nickel is generally tested for releasable metal content. Recommended to add limit and test method for Nickel release. Nickel (Ni) μg/cm²/week 0.2 μg/cm²/week (pierced part) For metallic parts without a surface coating or plating, test in accordance with method EN For metallic parts with a surface coating or plating, perform EN 12472, then test in accordance with method EN Volatile ganic Compounds (VOCs) 2-Ethoxyethylacetate P5 Benzene Bis-(2-methoxyethyl) ether Xylene Methyl-ethyl ketone P3 Toluene Ethylbenzene P5 Styrene Cyclohexanone ,2,3-Trichloropropane Acetophenone P3 N,N-Dimethylformamide (DMFa) ISO/TS 16189: Methyl-2-pyrrolidone Extraction with MeOH // 2-Phenyl-2-propanol /10 P5 N,N-Dimethylacetamide (DMAc) o-cresol m-cresol p-cresol Various Substances Textile: Extraction with MeOH // Add head space for Benzene, Xylene, Toluene, etylbenzenes, Styrene, Cyclohexanone, 1,2,3-Trichloropropane, N,N-Dimethylacetamide (DMAc) Extraction with MeOH // Headspace Extraction with KOH // GC- MS Textile: ISO JISL A (Japan law 112) P5 Formaldehyde /75 P6 19. Biocides Glyoxal and other short chain aldehydes (monoand di-aldehydes up to C6) & Various 100 Bisphenol A Polychlorinated biphenyls (PCB) Various 1 Polychlorinated terphenyls (PCT) Various 1 P3 Dimethyl fumarate (DMFu) Natural Leather: Products for markets other than China: ISO Products for China market: GB/T Extraction with MeOH // HPLC Solvent extraction /GC- MS or LC-MS Solvent extraction /GC- MS or LC-MS method for footwear: ISO/TS 16186: /14

13 P6 Triclosan Octylisothiazolinone Chloromethylisothiazolinone Methylisothiazolinone ,2-Benzisothiazolin-3-one o-phenylphenol (OPP) /100 Solvent extraction, derivatisation followed by analysis Solvent extraction / GC- MS, LCMS for confirmation Textiles: Extraction with KOH, derivatization and testing on method for leather: ISO 13365: Nitrosamines P6 N-Nitrosodimethylamine (NDMA) N-Nitrosodiethylamine (NDEA) N-Nitrosodi-n propylamine (NDPA) N-Nitrosodi-n-butylamine (NDBA) N-Nitrosopiperidine (NPIP) N-Nitrosopyrrolidine (NPYR) N-Nitrosomorpholine (NMOR) N-Nitroso-N-methyl-N-phenylamine (NMPhA) N-Nitroso-N-ethyl-N-phenylamine (NEPhA) EN 12868:1999 (It is applicable for rubber articles) GB/T (described in GB "Rubber shoes healthy and safety specification and GB "Children s Canvas Rubber Footwear") 21. Pesticides P6 Aldrin Captafol Chlordane DDT o,p'-ddt Dieldrin Endrin Heptachlor Hexachlorobenzene α-hexachlorocyclohexane ß-Hexachlorocyclohexane δ-hexachlorocyclohexane ,4,5-Trichlorophenoxyacetic acid ,4-Dichlorophenoxyacetic acid Chlordimeform Ethyl-4,4'-dichlorobenzilate Dinoseb Monocrotophos Pentachlorophenol Toxaphene Methamidophos Methyl parathion Parathion Phosphamidon Lindane ,4 -DDD (Dichlorodiphenyldichloroethane) ,4 -DDD (Dichlorodiphenyldichloroethane) Diazinon Propetanfos Chlorfenvinphos Dichlofenthion Chlorpyrifos Fenchlorphos Diflubenzuron Triflumuron Cypermethrin Deltamethrin Fenvalerate Cyhalothrin Flumethrin Azinphos methyl Azinphos ethyl Bromophos-ethyl Carbaryl Coumaphos Cyfluthrin DEF (1,2,4-Tributyl phosphortrithioate) ,4 -DDE (1,1-Dichloro-2,2-bis(4- chlorophenyl)ethene) ; Sum of all <0.5 / Sum of all <1 U.S. EPA s: 8081 A / 8151 A / 8141 A / 8270 C 13/14

14 22. Isocyanates P6 Dichlorprop Dicrotophos Dimethoate Endosulfan, α Endosulfan, ß Esfenvalerate Heptachloroepoxide Isodrin Kelevan Kepone Malathion Methyl-4-chlorophenoxyacetic acid (MCPA) MCPB Mecoprop Mirex Methoxychlor Perthane Phosdrin/Mevinphos Profenophos Quinalphos Strobane Telodrin Trifluralin Diphenylmethane diisocyanates (MDI) Various 50 Hexamethylene diisocyanate (HDI) Isophorone diisocyanate (IPDI) Tetramethylxylene diisocyanate (TMXDI) Toluene diisocyanate (TDI) Napthylene-1,5,diisocyanate (1,5-NDI) Unreacted / Free Monomers Solvent extraction / P6 Acrylamide /1 Acrylonitrile Butyl acrylate Butyl methacrylate Ethyl acrylate Ethyl methacrylate Methyl methacrylate Extraction with MeOH / HPLC Multiple headspace / Solvent extraction / 14/14