Annex 3 List of dyes that generate specific aromatic amines (Informative) October 1, 2015

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Delilah Hubbard
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1 Annex 3 List of dyes that generate specific aromatic amines (Informative) October 1, 2015 e: The following list is made with referring to publicly available information on detection of aromatic amines. However, it is considered possible that other dyes than those mentioned here generate specific aromatic amines. The name of dyes (color index generic name) means a constituent of dyes available in the market and does not indicate a product name. (It is not recommended to use this material as a restricted substance list.) More than one number is given in CAS no. column, as the numbers used are different depending on the documents. The generated primary aromatic amines column is added in this list (updated on October 1, 2015) to indicate the information on the generated primary aromatic amines that was obtained with mainly referring to color index. The verification column indicates the status of verification whether any aromatic amine is generated or not with referring to structural formulas in color index. Verified means completion of verification and not verified means no verification is made, because of no mentioning of structural formulas and others. Added in the remarks column means a dye added this time in the list that has been publicly available. in the remarks column means a dye that has the information on detection of aromatic amine in the name of such dye but does not generate any aromatic amine with applying structural formula. The possible reasons include the case that such dye is mixed with other dyes but sold in the same dye name or that any impure substance (unreacted starting materials, intermediate reactants, etc.) is contained. Dye name (color index generic name) C.I. constitution no. CAS no. Generated primary aromatic amines 2012 version published by JTF Acid Black Table 1 verified Acid Black Acid Black Table 3 verified Acid Black Table 3 verified Acid Black Table 1 verified Acid Black Benzidine, IARC Group 1 1 Table 1 Verified Added Acid Brown Table 3 verified Acid Orange ,4-Xylidine, IARC Group 3 or 2,6-Xylidine, IARC Group 2 1 Table 5 Verified Added Acid Orange ,4-Xylidine, IARC Group 3 or 2,6-Xylidine, IARC Group Table 5 Verified Acid Orange Acid Red o-anisidine, IARC Group 2B 1 1 Table 3 Verified Acid Red o-anisidine, IARC Group 2B 1 1 Table 3 Verified Acid Red ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added Acid Red o-toluidine, IARC Group Table 1 Verified Acid Red ,4-Xylidine, IARC Group Table 5 Verified Acid Red 26: ,4-Xylidine, IARC Group 3 and o-anisidine, IARC Group 1 Table 5 Verified Added Acid Red 26: ,4-Xylidine, IARC Group 3 or 2,6-Xylidine, IARC Group 2 1 Table 5 Verified Added Acid Red o-toluidine, IARC Group 1 1 Table 1 Verified Added Acid Red Aminoazobenzene, IARC Group 2B 1 1 Table 3 Verified Acid Red Acid Red o-aminoazotoluene, IARC Group 2B 1 Table 1 Verified Acid Red ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Acid Red ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Acid Red o-aminoazotoluene, IARC Group 2B 1 1 Table 3 Verified Acid Red 119: Table 1 verified Added Acid Red ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Acid Red ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added Acid Red o-aminoazotoluene, IARC Group 2B 1 1 Table 1 Verified Acid Red o-aminoazotoluene, IARC Group 2B 1 1 Table 3 Verified Eco label SCCNFP Verification Remarks 1

2 Acid Red , Table 1 Verified Acid Red Table 1 verified Acid Red ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added Acid Red o-anisidine, IARC Group 2B 1 1 Table 3 Verified Acid Red o-toluidine, IARC Group Table 1 Verified Acid Red Benzidine, IARC Group 1 1 Table 2 Verified Acid Red Table 3 verified Acid Violet o-anisidine, IARC Group 2B 1 1 Table 3 Verified Basic Brown No.8 2,4-Diaminoanisole, IARC Group 2B 1 Table 2 Verified Basic Brown , Toluylendiamine, IARC Group 2B 1 1 Table 1 Verified Basic Orange Verified Basic Red Table 3 verified Basic Red o-anisidine, IARC Group 2B 1 Table 3 Verified Added Basic Red , Aminoazobenzene, IARC Group 2B 1 1 Table 3 Verified Basic Red Table 3 verified Added Basic Yellow Table 3 verified Added Basic Yellow Table 1 verified Added Direct Black , Direct Black Direct Black Benzidine, IARC Group 1 1 Table 2 Verified Direct Black Direct Black Direct Black ,3 -Dimethoxybenzidine, IARC Group 2B 1 Verified Direct Black verified Direct Black , ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue , ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue Direct Blue ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue , Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue ,3 -Dimethylbenzidine, IARC Group 2B 1 Table 1 Verified Added Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue , ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethylbenzidine, IARC Group 2B 1 Table 2 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue ,3 -Dimethylbenzidine, IARC Group 2B 1 Table 2 Verified Synthetic toluylendiamine, IARC Group 2B Synthetic toluylendiamine, IARC Group 2B 2

3 Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 Verified Direct Blue Verified Direct Blue Verified Direct Blue verified Direct Blue Table 5 Verified Added Direct Blue , ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue verified Direct Blue Table 1 verified Direct Blue Table 1 verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue Direct Blue Table 1 verified Direct Blue Table 1 Direct Blue , ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 Verified Direct Blue verified Direct Blue Benzidine, IARC Group 1 1 Table 2 Verified Direct Blue ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Blue ,3 -Dimethoxybenzidine, IARC Group 2B 1 Table 1 Verified Added Direct Brown Direct Brown 1: Direct Brown , Direct Brown , Direct Brown Direct Brown , Direct Brown , Direct Brown Direct Brown Direct Brown Benzidine, IARC Group 1 1 Table 2 Verified Direct Brown Benzidine, IARC Group 1 1 Table 2 Verified Direct Brown Direct Brown Benzidine, IARC Group 1 1 Table 2 Verified Direct Brown Direct Brown Direct Brown Benzidine, IARC Group 1 1 Table 2 Verified Direct Brown Direct Brown Direct Brown verified Direct Brown Direct Brown Benzidine, IARC Group 1 1 Verified Direct Brown verified Direct Brown ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Brown Table 1 verified Added 3

4 Direct Brown verified Direct Green Direct Green Direct Green , Direct Green 8: Table 1 verified Direct Green Benzidine, IARC Group 1 Table 2 Verified Direct Green 21:1 Table 2 verified Added Direct Green Benzidine, IARC Group 1 1 Table 2 Verified Direct Green ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Orange Benzidine, IARC Group 1 Table 2 Verified Direct Orange Benzidine, IARC Group 1 1 Table 2 Verified Direct Orange ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Orange ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Orange , Direct Orange ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Orange Benzidine, IARC Group 1 1 Table 2 Verified Direct Orange Benzidine, IARC Group 1 1 Table 2 Verified Direct Orange Verified Direct Orange Benzidine, IARC Group 1 1 Table 2 Verified Direct Orange o-toluidine, IARC Group Table 1 Verified Direct Red , Direct Red ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red ,3 -Dimethoxybenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red , Direct Red , Direct Red Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red , ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red o-anisidine, IARC Group 2B 1 1 Table 3 Verified Direct Red o-anisidine, IARC Group 2B 1 1 Table 3 Verified Direct Red Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Direct Red ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Direct Red No.10 3,3 -Dichlorobenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red o-toluidine, IARC Group Table 1 Verified Direct Red ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Red o-toluidine, IARC Group 1 and o-anisidine, IARC Group 1 1 Table 3 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red Benzidine, IARC Group 1 1 Table 2 Verified Direct Red ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added 4

5 Direct Red ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added Direct Red ,4-Xylidine, IARC Group 3 or 2,6-Xylidine, IARC Group 2 1 Table 5 Verified Added Direct Red ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added Direct Violet , Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Direct Violet Verified Direct Violet Direct Violet ,3 -Dimethoxybenzidine, IARC Group 2B 1 Table 1 Verified Added Direct Violet ,4-Xylidine, IARC Group 3 1 Table 5 Verified Added Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Violet , Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Table 2 Verified Direct Violet Benzidine, IARC Group 1 1 Verified Direct Yellow Direct Yellow Benzidine, IARC Group 1 1 Table 2 Verified Direct Yellow Direct Yellow ,3 -Dimethylbenzidine, IARC Group 2B 1 1 Table 1 Verified Direct Yellow verified Direct Yellow verified Disperse Orange Table 1 verified Added , Disperse Orange , 1 1 Table 3 verified Disperse Red Aminoazobenzene, IARC Group 2B 1 1 Table 3 Verified Disperse Red Table 1 Verified Disperse Yellow Aminoazobenzene, IARC Group 2B 1 1 Table 3 Verified Disperse Yellow Aminoazobenzene, IARC Group 2B 1 1 Table 3 Verified Disperse Yellow Aminoazobenzene, IARC Group 2B 1 1 Table 3 Verified Disperse Yellow Table 1 verified Added Solvent Orange , ,4-Xylidine, IARC Group 3 1 Table 5 Solvent Red Aminoazobenzene, IARC Group 2B 1 Table 3 Verified Solvent Red Aminoazobenzene, IARC Group 2B 1 Table 3 Verified Mordant Yellow ,4 -Thioianiline, IARC Group 2B Table 1 Verified Added Mordant Red Table 1 verified Added Referable information [As of October 1, 2015] (1) Names of dyes are found in the 2014 version of the EU Eco Label Textile Restricted Substance List. (2) A wide range of names of azo colorants and their generated primary aromatic amines can be found in "The safety review of the use of certain azo-dyes in cosmetic products by the Scientific Committee on Cosmetic Products and Non-food Products Intended for Consumers, adopted by the SCCNFP during the 19th plenary meeting of 27 February, 2002". (3) Information on azo pigments is publicly disclosed by ETAD. 5

6 (4) (Informative) Names of dyes that generate primary aromatic amines are found in the 2014 controlled substances list of Levi Strauss & Co. (5) (Informative) Names of dyes that generate primary aromatic amines are found in the 2014 Azo Dyes and Pigments: Banned Arylamines of Marks and Spencer 6

Test Report. No. SHAHG Date: 12 Dec Page 1 of 7.

Test Report. No. SHAHG Date: 12 Dec Page 1 of 7. Test Report No SHAHG1624457402 Date: 12 Dec 2016 Page 1 of 7 #DOYOURSPORTS GMBH NOBELSTRAßE 12 IN 41189 MÖNCHENGLADBACH-GERMANY The following sample(s) was/were submitted and identified on behalf of the