Kaufland Manufacturing Restricted Substances List (MRSL) March 2018

Transcription

1 Kaufland Manufacturing Restricted s List (MRSL) March 2018 The Kaufland MRSL defines the hazardous chemicals which need to be eliminated from the production and products (apparel, footwear and home textiles) till For all chemicals limit values for products, waste water, sludge and input chemicals have been defined. These detection/reporting limits and test methods will be revised - at least yearly, to always reflect best current technology using lowest detection/reporting limits. At any step of the supply chain, responsible handling of chemicals (purchase, and disposal) must be implemented. Kaufland strategy to eliminate hazardous chemicals in the supply chain and improve chemical management will be achieved by strengthening both training and auditing at our suppliers. Kaufland MRSL 定义了 2020 前必须从生产和 ( 服装 鞋类和家用纺织品 ) 中淘汰的危险化学品及其在 和化学原料中的检测方法及检出限 这一 MRSL 将被每年更新一次, 以反映最新的化学品信息和检测技术 供应链的每一步都必须实施有效的化学品管理 ( 购买 使用和处置 ) Kaufland 将通过对供应商的培训和审核来达到在供应链上消除危险化学品和提高化学品管理的目标 Limits 检出限 Waste water/ Sludge/ Textiles / 纺织类 1. Alkylphenols (AP)/Alkylphenol ethoxylate (APEO) 烷基酚 / 烷基酚聚氧乙烯醚 4-(1,1,3,3-Tetramethylbutyl)-phenol (octylphenols) ,4 100 OctylPhenol , Octylphenol ,4 100 Nonylphenol NP various 1 0, Nonylphenol ,4 100 Nonylphenol ,4 100 Nonylphenol , Nonylphenol (branched) ,4 100 Nonylphenol ,4 100 Nonylphenol Ethoxylates NPEO (1-2) various 1 0,4 100 Nonylphenol Ethoxylates NPEO (3-18) various 1 0,4 OP, NP, HpP, 100 (Nonylphenoxy)-polyethylenoxid ,4 PeP sum Nonylphenol, ethoxylated ,4 OP, NP, HpP, PeP, OPEO, 100 (NPEs 3-18) Poly(oxy-1,2-ethanediyl),.alpha.- (nonylphenyl)-.omega.-hydroxy-, branched ,4 NPEO sum Nonylphenol, branched, ethoxylated ,4 100 Isononylphenol-ethoxylate ,4 100 Octylphenol Ethoxylates OPEO (1-2) various 1 0,4 100 Octylphenol Ethoxylates OPEO (3-18) various 1 0,4 100 (OPEs 3-18) alpha-[4-(1,1,3,3- Tetramethylbutyl)phenyl]-w-hydroxypoly(oxy- 1,2-ethandiyl) (SIN List OPEs) ,4 100 DIN EN ISO LC/MS mod, resp. NPEO(1+2): GC/MS DIN EN ISO LC/MS mod, resp. NPEO(1+2): GC/MS organic solvent extract followed by LC-MS or GC- MS analysis Seite 1

2 Waste water/ Sludge/ Textiles / 纺织类 4-tert-Octylphenolethoxylate , tert-Octylphenolethoxylate ,4 100 Heptylphenol various 1 0,4 Pentylphenol various 1 0,4 2. Phthalates / Plasticizers 邻苯二甲酸酯 / 塑化剂 Di-Butyl Phthalate (DBP) ,3 Di(2-Ethyl Hexyl) Phthalate (DEHP) ,3 Benzyl Butyl Phthalate (BBP) ,3 Di-Iso-Nonyl Phthalate (DINP) , ,3 Di-N-Octyl Phthalate (DNOP) ,3 Di-Iso-Decyl Phthalate (DIDP) , ,3 Di-Iso-Butyl Phthalate (DIBP) ,3 < 1000 Di-N-Hexyl Phthalate (DNHP) < 1000 Di-(2-methoxyethyl)phthalate (DMEP) < 1000 Sum 1000 Sum 1000 toluene, GC/MS toluene, GC/MS toluene, GC/MS toluene, GC/MS EN ISO TS 16181; EN 14389; EN ISO TS 16181; EN 14389; Extraction & GC-MS analysis. DHNUP < 1000 DIHP < 1000 DPP Diisopentylphthalte sum 100/1000 < 1000 N-pentyl-isopentylphthalate < ,2-Benzenedicarboxylic acid, dipentylester, branched and linear 1,2-Benzenedicarboxylic acid, dihexylester, branched and linear 1,2-benzenedicarboxylic acid, di-c6-10alkyl esters; 1,2-benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with 0.3% of dihexyl phthalate (CAS ) < / Dicyclohexylphthalate Dinonyl phthalate (DNP) Diethyl phthalate (DEP) Di-n-propyl phthalate (DPRP) Di-iso-octyl phthalate (DIOP) toluene GC/MS toluene GC/MS toluene GC/MS toluene GC/MS toluene GC/MS toluene GC/MS toluene GC/MS toluene GC/MS EN ISO TS 16181; EN 14389; Extraction & GC-MS analysis. EN ISO TS 16181; EN 14389; Extraction & GC-MS analysis. Seite 2

3 Waste water/ Sludge/ Textiles / 纺织类 Di-iso-hexylphthalate DEHA Bis(2-ethylhexyl) adipate , < 1000 DEHT Bis(2-ethylhexyl)ester < 1000 toluene GC/MS toluene GC/MS 3. Brominated and Chlorinated Flame Retardants 溴化及氯化阻燃剂 Polybrominated biphenyls (PBB) ,05 0,3 Monobromo biphenyls (MonoBBs) Various 0,05 0,3 Dibromo biphenyls (DiBBs) - 0,05 0,3 Tribromo biphenyls (TriBBs) - 0,05 0,3 Tetrabromo biphenyls (TetraBBs) - 0,05 0,3 Pentabromo biphenyls (PentaBBs) - 0,05 0,3 Hexabromo biphenyls (HexaBBs) - 0,05 0,3 Heptabromo biphenyls (HeptaBBs) - 0,05 0,3 Octabromo biphenyls (OctaBBs) - 0,05 0,3 Nonabromo biphenyls (NonaBBs) - 0,05 0,3 Decabromo biphenyl (DecaBB) ,05 0,3 Polybrominated diphenyl ethers (PBDEs) various 0,05 0,3 DIN EN ISO MS or HPLC- Monobromo diphenyl ethers (MonoBDEs) - 0,05 0,3 Dibromo diphenyl ethers (DiBDEs) - 0,05 0,3 Tribromo diphenyl ethers (TriBDEs) - 0,05 0,3 Tetrabromo diphenyl ethers (TetraBDE) ,05 0,3 Pentabromo diphenyl ethers (PentaBDE) ,05 0,3 Hexabromo diphenyl ethers (HexaBDE) ,05 0,3 Heptabromo diphenyl ethers (HeptaBDE) ,05 0,3 Octabromo diphenyl ethers (OctaBDE) ,05 0,3 Nonabromo diphenyl ethers (NonaBDE) ,05 0,3 DIN EN ISO MS or HPLC- Seite 3

4 Waste water/ Sludge/ Decabromo diphenyl ether (DecaBDE) ,05 0,3 Tris(2,3-Dibromopropyl)-Phosphate ,5 0,25 Tris(2-Chloroethyl)Phosphate (TCEP) ,05 0,5 Hexabromocyclododecane (HBCDDs) , , , , Textiles / 纺织类 /1000 DIN EN ISO MS or HPLC- Tetrabromo-bisphenol A (TBBPA) ,5 0,25 Bis (2,3-dibromopropyl) phosphate (TRIS) ,25 Tris(1,3-dichloro-2-propyl)phosphate (TDCPP) ,5 0,5 Tris (1-chloro-2-propyl) phosphate (TCPP) ,5 0,5 DIN EN ISO MS or HPLC- 2,2-Bis(bromomethyl)1,3-propanediol ,5 0,5 DIN EN ISO MS or HPLC- Subgroup: Other Flame Retardant TEPA ,5 0,5 Sodium tetraborate Boron trioxide Boric acid total digestion, ICP/MS, for total boron total digestion, ICP/MS, for total boron DIN EN ISO MS or HPLC- For boron and Seite 4

5 Waste water/ Sludge/ Tetraboron disodium heptaoxide, hydrate tbd tbd Limits 检出限 Textiles / 纺织类 Tri-o-cresyl phosphate ,5 0,5 Trixylylphosphate (TXP) tbd tbd Antimony pentoxid (Sb205) tbd tbd Antimony trioxide Amines (associated with Azo dyes) 胺 ( 与偶氮染料相关 ) 4-Aminodiphenyl ,1 0,3 20 Benzidine ,1 0, Chloro-o-Toluidine ,1 0, Naphthylamine ,1 0,3 20 o-aminoazotoluene ,1 0, Amino-4-Nitrotoluene ,1 0,3 20 p-chloroaniline ,1 0,3 20 2,4-Diaminoanisole ,1 0,3 20 4,4 -Diaminodiphenylmethane ,1 0,3 20 3,3 -Dichlorobenzidine ,1 0,3 20 3,3 -Dimethoxybenzidine ,1 0,3 20 3,3 -Dimethylbenzidine ,1 0,3 20 3,3 -Dimethyl-4,4 diaminodiphenylmethane ,1 0,3 20 p-cresidine ,1 0,3 20 4,4 -Methylene-Bis(2-Chloroaniline) ,1 0,3 20 4,4 -Oxydianiline ,1 0,3 20 4,4 -Thiodianiline ,1 0,3 20 sum 20 o-toluidine ,1 0,3 20 2,4-Toluylenediamine ,1 0,3 20 With Reference To EN 14362:1&3 And Followed By Gas Chromatographic Mass Spectrometric (GC-MS) And High Performance Liquid Chromatographic ISO ISO With teference to EN14362:1&3, followed by GC/MS and /or HPLC With teference to EN14362:1&3, followed by GC/MS and /or HPLC With teference to EN14362:1&3, followed by GC/MS and /or HPLC With teference to EN14362:1&3, followed by GC/MS and /or HPLC With Reference To EN 14362:1&3 And Followed By Gas Chromatographic Mass Spectrometric (GC- MS) And High Performance Liquid Chromatographic antimony (total): Microwave followed by ICP-MS analysis. EN & -3 (Textile); ISO & -2 ( Leather). EN & -3 (Textile); ISO & -2 ( Leather). EN & -3 (Textile); ISO & -2 ( Leather). 2,4,5-Trimethylaniline ,1 0,3 20 Seite 5

6 Waste water/ Sludge/ Limits 检出限 Textiles / 纺织类 o-anisidine ,1 0,3 20 p-aminoazobenzene ,1 0,3 5 2,4-Xylidine ,1 0,3 5 2,6-Xylidine ,1 0,3 5 With Reference To EN14362:1&3 And Followed By Gas Chromatographic Mass Spectrometric (GC-MS) And High Performance Liquid Chromatographic With Reference To EN14362:1&3 And Followed By Gas Chromatographic Mass Spectrometric (GC- MS) And High Performance Liquid Chromatographic EN & -3 (Textile); ISO & -2 ( Leather). Subgroup: Navy Blue Colourant ,1 0,1 not d not d Component 1 (Navy blue) Component 2 (Navy blue) Not Allocated 0,1 0,1 not d not d Subgroup: Carcinogenic dyes 致癌染料 C.I Acid Red ,2 < C.I. Basic Red ,2 < C.I. Basic Violet ,2 < C.I Direct Blue ,2 < C.I Direct Red ,2 < C.I Direct Black ,2 < C.I Disperse Blue ,2 < C.I. Disperse Yellow ,2 < C.I. Disperse Orange ,2 < C.I. Disperse Yellow ,2 < C.I. Disperse Orange ,2 < C.I. Yellow ,2 C.I. Yellow ,2 C.I. Basic Blue ,2 < 50.0 C.I. Basic Violet ,2 C.I. Basic Violet ,2 < 50.0 DIN HPLC DIN 54231, HPLC- DAD-MS DIN HPLC DIN 54231, HPLC-DAD-MS DIN 54231, HPLC-DAD- MS DIN 54231, HPLC-DAD- MS Seite 6

7 Waste water/ Sludge/ Limits 检出限 Textiles / 纺织类 C.I. Direct Brown ,2 < 50.0 C.I. Direct Blue ,2 < 50.0 C.I. Direct Blue ,2 C.I Acid Red ,2 < 50.0 C.I Acid Violet ,2 C.I. Basic Green 4 (malachite green) ,2 < 50.0 Subgroup: Allergenic Disperse Dyes 致敏性分散染料 C.I. Disperse Blue ,2 < C.I. Disperse Blue ,2 < C.I. Disperse Blue ,2 < C.I. Disperse Blue ,2 < C.I. Disperse Blue , ,2 < C.I. Disperse Blue ,2 < C.I. Disperse Blue ,2 < C.I. Disperse Blue ,2 < C.I. Disperse Brown ,2 < C.I. Disperse Orange ,2 < C.I. Disperse Orange ,2 < C.I. Disperse Orange 37/76/ ,2 < C.I. Disperse Red ,2 < C.I. Disperse Red ,2 < C.I. Disperse Red ,2 < C.I. Disperse Yellow ,2 < C.I. Disperse Yellow ,2 < C.I. Disperse Yellow ,2 < C.I. Disperse Yellow ,2 < C.I. Disperse Yellow ,2 < Organotin compounds 有机锡化合物 MBT(Monobutyltin) /2.0 TPhT(Triphenyltin) / 1.0 DOT(Dioctyltin) /2.0 sum 1.0 DBT(Dibutyltin) /2.0 0,05/0,1 DIN 54231, HPLC- DAD-MS DIN 54231, HPLC-DAD-MS DIN 54231, HPLC-DAD- MS Seite 7

8 Waste water/ Sludge/ Textiles / 纺织类 TBT(Tributyltin) / 1.0 0,025 MOT(Monooctyltin) /2.0 DPhT(Diphenyltin) ; /2.0 TeBT(Tetrabutyltin) /2.0 TCyT(TricyclohexylTin) /2.0 TPT(Tripropyltin) NA /2.0 TeET(Tetraethyltin) /2.0 TBTO With Reference to DIN EN17353, followed by GC/MS Analysis. Derivation followed by GC/MS analysis Derivation followed by GC/MS analysis DBTC DBB DMT (Dimethyltin) various /2.0 DPT (Diphenyltin) various /2.0 MT (Methyltin) various TMT (Trimethyltin) various /2.0 TOT (Trioctyltin) various / PFCs (Perfluorocarbon / Polyfluorinated Compounds) 全氟化合物 PFOA ,01 0,001 PFNA ,5 0,001 PFBS or ,5 0,001 4:2 FTOH ,5 0,01 6:2 FTOH ,5 0,01 8:2 FTOH ,5 0,01 10:2 FTOH ,5 0,01 PFHxS ,5 0,001 PFHxA ,5 0,001 PFOS ,01 0,001 POSF ,5 0,01 CEN/TS modified CEN/TS modified Extraction, LC- MS PFOSA ,5 0,01 N-Me-FOSA ,5 0,01 N-Et-FOSA ,5 0,01 N-Me-FOSE alcohol ,5 0,01 N-Et-FOSE alcohol ,5 0,01 Seite 8

9 Waste water/ Sludge/ Textiles / 纺织类 PFBA ,5 0,001 PFPeA ,5 0,001 PFHpA ,5 0,001 PFDA ,5 0,001 PFUnA ,5 0,001 PFDoA ,5 0,001 PFTrA ,5 0,001 PfteA ,5 0,001 PFHpS ,5 0,001 PFDS ,5 0,001 6:2 FTA ,5 0,01 8:2 FTA ,5 0,01 10:2 FTA ,5 0,01 PF-3,7-DMOA ,5 0,001 HPFHpA ,5 0,001 4HPFUnA ,5 0,001 1H, 1H, 2H, 2H-PFOS ,5 0, Chloro benzenes 氯苯 Dichlorobenzenes various ,2-Dichlorobenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Trichlorobenzenes various ,2,3-Trichlorobenzene ,2,4-trichlorobenzene ,3,5-Trichlorobenzene Sum < 1 Tetrachlorobenzene ,2,3,4-tetrachlorobenzene ,2,3,5-tetrachlorobenzene ,2,4,5-tetrachlorobenzene Pentachlorobenzene Hexachlorobenzene Chlorobenzene Seite 9 CEN/TS 15968: modified CEN/TS 15968: modified CEN/TS 15968: modified CEN/TS 15968: modified Extraction, LC- MS Extraction, LC- MS followed by GC- MS analysis.

10 Waste water/ Sludge/ Chloro-Toluenes (solvents and biocides. Production dyes. Chemical Intermediates. Antifelting) 氯甲苯 Textiles / 纺织类 2-chlorotoluene ,02 0,01 3-chlorotoluene ,02 0,01 4-chlorotoluene ,02 0,01 2,3-dichlorotoluene ,02 0,01 2,4-dichlorotoluene ,02 0,01 2,5-dichlorotoluene ,02 0,01 2,6-dichlorotoluene ,02 0,01 3,4-dichlorotoluene ,02 0,01 2,3,6-trichlorotoluene ,02 0,01 2,4,5-trichlorotoluene ,02 0,01 Sum < 1 Benzotrichloride ,02 0,01 Benzyl chloride ,02 0,01 alpha, 2,4-trichlorotoluene ,02 0,01 alpha, 2,6-trichlorotoluene ,02 0,01 alpha, 3,4-trichlorotoluene ,02 0,01 alpha, alpha-dichlorotoluene (Benzalchloride) ,02 0,01 alpha, alpha, 2,6-tetrachlorotoluene ,02 0,01 alpha, alpha, alpha, 2-tetrachlorotoluene ,02 0,01 alpha, alpha, alpha, 4-tetrachlorotoluene ,02 0,01 2,3,4,5,6-pentachlorotoluene ,02 0,01 8. Chlorinated solvents 含氯溶剂 Dichloromethane Chloroform Tetrachloromethane ,1,2-Trichloroethane ,1-Dichloroethane ,2-Dichloroethane Trichloroethylene Perchloroethylene ,1,1-trichloroethane ,1,1,2-Tetrachloroethane ,1,2,2-Tetrachloroethane Seite 10 By Headspace Gas Chromatography Mass Spectrometric (HS GC/MS) Analysis. GC-MS Headspace analysis. DIN MS analysis

11 Waste water/ Sludge/ Textiles / 纺织类 Pentachloroethane ,1-Dichloroethylene Other VOCs 其它挥发性有机化合物 Methyl-ethyl ketone ,3 By Headspace Gas By Headspace Gas Chromatography Chromatography Mass Mass Ethylbenzene ,3 Spectrometric (HS GC/MS) Analysis. Spectrometric (HS GC/MS) Analysis. Xylene ,3 By Headspace Gas By Headspace Gas Chromatography Chromatography Mass Mass Cyclohexanone ethoxyethylacetate ,2,3-trichloropropane Acetophenone , phenyl-2-propanol , methyl-2-pyrrolidone N,N-dimethylacetamide (DMAc) Styrene ,3 Benzene ,3 Toluene ,3 9. Chloro phenols 含氯苯酚 Pentachlorophenols (PCP) / Tetrachlorophenols (TeCP) ,5 2,3,4,5-Tetrachlorophenol Sum 0.05 / 0.5 0,5 2,3,4,6-Tetrachlorophenol ,5 Spectrometric (HS GC/MS) Analysis. Spectrometric (HS GC/MS) Analysis. By Headspace formamide tbd tbd Gas By Headspace Gas N,N-dimethylformamide (DMFa) , /300 Chromatography Chromatography Mass Mass Bis-(2-methoxyethyl) ether Spectrometric (HS GC/MS) Analysis. Spectrometric (HS GC/MS) Analysis. and GC-MS analysis and GC-MS Seite 11

12 Waste water/ Sludge/ Textiles / 纺织类 2,3,5,6-tetrachlorophenol ,5 Trichlorophenol (TriCP) ,4,6-trichlorophenol ,3,4-trichlorophenol ,3,5-trichlorophenol Sum 0.2 / ,3,6-trichlorophenol ,4,5-trichlorophenol ,4,5-trichlorophenol Dichlorophenols (DiCP) ,3-dichlorophenol ,4-dichlorophenol ,5-dichlorophenol Sum 0.5/3.0 2,6-dichlorophenol , 4-dichlorophenol , 5-dichlorophenol Mono Chlorophenol various / SCCP 短链氯化石蜡 Derivation MS analysis Derivation MS analysis Derivation Derivation MS analysis Derivation MS analysis Derivation MS analysis Derivation Derivation MS analysis ISO Derivation, GC- MS analysis SCCP C Extraction, GC/NCI/MS Extraction, GC/NCI/MS DIN EN ISO 18219, organic solvent, GC- MS/NCI analysis 11. Heavy metals 重金属 Cadmium(Cd) Lead(Pb) (total) 0.2 / 1.0 ; 90 (total) (total) 0,8 90 (total) ISO ISO ISO 105-E04 acid perspiration & ICP analysis. (Extractable) EN Seite 12

13 Waste water/ Antimony (Sb) Sludge/ Mercury(Hg) ,02 Nickel(Ni) Hexavalent Chromium(Cr-VI) Arsenic(As) Chromium(Cr) Copper(Cu) Textiles / 纺织类 / 1.0 / 4.0 not detectable < / / /50 5 0,02 4 not detectable < 3 0,2 3.0 leather: Zinc(Zn) Manganese(Mn) Cobalt (Co) / Beryllium & Beryllium oxide ; tbd tbd Vanadium pentoxide tbd tbd 12. Antioxidants 抗氧化剂 ISO ISO ISO 105-E04 acid perspiration & ICP analysis. ISO 105-E04 acid perspiration & ICP analysis. 2-Mercaptobenzothiazol tbd tbd 10 2,4,6-tri(t-butyl)Phenol tbd tbd 2,6-di-tert-butyl-4-(1-methylpropyl)- hydroxybenzene 2,6-di-tert-butyl-4-(methylthioacetic acid, 2- ethylhexyl ester)-hydroxybenzene ISO or ISO ISO or ISO ISO DIN EN ISO ISO 105-E04 acid perspiration & ICP analysis. (Extractable) tbd tbd tbd tbd 6,6'-di-tert-butyl-4,4'-thiodi-m-cresol tbd tbd 13. Brominated solvents 含溴溶剂 ISO ,2-dibromoethane tbd tbd Seite 13 ISO 105-E04 acid perspiration & ICP analysis.

14 Waste water/ Sludge/ Textiles / 纺织类 1-bromopropane; n-propyl bromide tbd tbd Bromoethane tbd tbd 2-bromopropane tbd tbd (methylenebis(4,1-phenylenazo(1- (3(dimethylamino)propyl)-1,2-dihydro-6-hydroxy-4- methyl-2-oxopyridine-5,3-diyl)))-1,1'-dipyridinium dichloride dihydrochloride Pigment Rot 53:1 (C.I :1); D&C Red No tbd tbd 1,2-dihydro-6-hydroxy-4-methyl-1-[3- (1methylethoxy)propyl]-2-oxo-5-[[4- (phenylazo)phenyl]azo]-3-pyridinecarbonitrile ,2 < 50 1 based on DIN based on DIN Diaminobenzidine [biphenyl-3,3',4,4'- tetrayltetraamine] tbd tbd diaminotoluene tbd tbd development development N,N'-Diacetylbenzidine tbd tbd toluene-2,4-diammonium sulphate tbd tbd 14. Azo dyes that release carcinogenic amines through reduction cleacage (in addition to the priority 11 examples linked to amines listed in EU & Chines regulations) 能释放出致癌胺的 Dyes 染料 based on DIN ,2 < tbd tbd tbd tbd development development D&C Red No tbd tbd Methanaminium, N-[4- [bis[4(dimethylamino)phenyl]methylene]-2,5- cyclohexadien-1-ylidene]-n-methyl-, chloride C.I , C.I. Pigment Black 25, cobalt nickel gray periclase C.I , C.I. Pigment Yellow 157, nickel barium titanium primrose priderite 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3- oxazolidine tbd tbd development development tbd tbd Auramine hydrochloride tbd tbd C.I. Basic Green 4 leuco base ,15 < 50.0 C.I. Basic Green 4 (Malachite Green Chloride) ,15 < 50.0 C.I. Basic Green 4 (Malachite Green Oxalate) ,15 < 50.0 based on DIN C.I. Pigment Brown tbd tbd C.I. Pigment Red 53; D&C Red No tbd tbd development development Pigment Red tbd tbd Dye intermediate 染料中间体 Seite 14 based on DIN based on DIN 54234

15 3-amino-9-ethyl carbazole, 9-ethylcarbazol-3- ylamine Waste water/ Sludge/ Textiles / 纺织类 tbd tbd 4,4-isobutylethylidenediphenol tbd tbd 4-amino-3-fluorophenol tbd tbd Anthraquinone tbd tbd anthraquinone, 1-hydroxy tbd tbd Carbazole tbd tbd development development diazomethane tbd tbd Dimethylcarbamoyl chloride tbd tbd quinoline tbd tbd potassium bromate tbd tbd 15. dinitrotoluene 二硝基甲苯 2,4-dinitrotoluene tbd tbd dinitrotoluene (isomer mixture) tbd tbd 2,3-dinitrotoluene tbd tbd 2,6-Dinitrotoluene tbd tbd development development 3,4-dinitrotoluene tbd tbd 3,5-dinitrotoluene tbd tbd 2,5-dinitrotoluene tbd tbd 16. epoxy intermediate (CMR) 环氧中间体 Epichlorohydrin tbd tbd phenyl glycidyl ether; 2,3-epoxypropyl phenyl ether; 1,2-epoxy-3-phenoxypropane tbd tbd 2,2'-bioxirane [1,2:3,4-diepoxybutane] tbd tbd 2,3-epoxypropyltrimethylammonium chloride; EPTAC;Oxiranemethanaminium, N,N,N-trimethyl chloride; Glycydyltrimethylammonium chloride tbd tbd R-1-chloro-2,3-epoxypropane tbd tbd Glycidol [2,3-epoxy-1-propanol] tbd tbd R-2,3-epoxy-1-propanol tbd tbd development development 1,3,5-tris-[(2S and 2R)-2,3-epoxypropyl]-1,3,5- triazine-2,4,6-(1h,3h,5h)-trione tbd tbd oxiranemethanol, 4-methylbenzene-sulfonate, (S) tbd tbd ethylene oxide; oxirane tbd tbd Seite 15

16 Waste water/ Sludge/ Textiles / 纺织类 propylene oxide; 1,2-epoxypropane; methyloxirane tbd tbd styrene oxide; (epoxyethyl)benzene; phenyloxirane tbd tbd 17. fibrous mineral 纤维矿物质 asbestos erionite Glycols 甘醇 nil n - of no n - of no not d polarizing microscope under development Bis(2-methoxyethyl)ether Methoxyethanol tbd 2-Methoxyethyl acetate tbd Ethylene glycol dimethyl ether tbd 2-Ethoxyethanol tbd 2-Ethoxyethyl acetate Extraction, under GC/MS development 1,2-diethoxyethane tbd Ethylene glycol tbd Triethylene glycol dimethyl ether (TEGDME) tbd 2-Methoxypropyl acetate tbd 2-Methoxypropanol tbd 19. Monomers 单体 under development 1,3-Butadiene tbd tbd Acetaldehyde tbd tbd Acrylonitrile tbd tbd Aziridine [Ethyleneimine] tbd tbd aziridine, 2-methyl tbd tbd chloroprene (stabilized); 2-chlorobuta-1,3-diene tbd tbd dimethylsulfamoylchloride tbd tbd Ethyl acrylate tbd tbd Isobutyl nitrite tbd tbd Isoprene tbd tbd development development Methylcarbamate tbd tbd Seite 16

17 Waste water/ Sludge/ Textiles / 纺织类 N-Vinyl-2-pyrrolidinone tbd tbd Propane sultone [1,3-propanesultone; 1,2- oxathiolane 2,2-dioxide] tbd tbd Urethane (Ethyl carbamate) tbd tbd Vinyl bromide tbd tbd Vinyl chloride tbd tbd Acrylamide tbd tbd N-Methylolacrylamide tbd tbd 20. N-nitroso compounds N- 亚硝基化合物 N-Nitrosopiperidine tbd tbd N-Nitrosomethylethylamine tbd tbd N-Nitrosodiethanolamine tbd tbd N-Ethyl-N-nitrosoanilin tbd tbd N-Methyl-N-nitrosoanilin tbd tbd N-Nitrosodi-n-propylamine tbd tbd N-Nitrosodimethylamine tbd tbd development, development, N-Methyl-N'-nitro-N-nitrosoguanidine tbd tbd based on EN based on EN N-Nitrosodiphenylamine tbd tbd N-Nitrosodiethylamine (NDEA) tbd tbd N-Nitrosodi-n-butylamine (NDBA) tbd tbd N-Nitrosopyrrolidine (NPYR) tbd tbd N-Nitrosomorpholine (NMOR) tbd tbd p-nitrosodiphenylamine tbd tbd 21. PAH 多环芳烃 Benzo[a]pyrene (BaP) tbd / 0.5 / 1 0,2 / 0,5 / 1 Benzo[e]pyrene (BeP) tbd / 0.5 / 1 0,2 / 0,5 / 1 Benzo[a]anthracene (BaA) tbd / 0.5 / 1 0,2 / 0,5 / 1 Benzo[b]fluoranthene (BbFA) tbd / 0.5 / 1 0,2 / 0,5 / 1 Benzo[j]fluoranthene (BjFA) tbd / 0.5 / 1 0,2 / 0,5 / 1 Benzo[k]fluoranthene (BkFA) tbd / 0.5 / 1 0,2 / 0,5 / 1 Chrysene (CHR) tbd / 0.5 / 1 0,2 / 0,5 / 1 Dibenzo[a,h]anthracene (DBAhA) tbd / 0.5 / 1 0,2 / 0,5 / 1 Benzo(g,h,i)perylene tbd / 0.5 / 1 0,2 / 0,5 / 1 Seite 17

18 Waste water/ Sludge/ Textiles / 纺织类 Indeno(1,2,3-cd)pyrene tbd / 0.5 / 1 0,2 / 0,5 / 1 Acenapthylene tbd 1 Acenaphthene tbd 1 Fluorene tbd 1 Phenanthrene tbd 1 Pyrene tbd 1 Sum 1,0 / 10 / 50 Sum 1,0 / 10 / 50 an organic solvent MS analysis Anthracene tbd 1 Fluoranthene tbd 1 Naphthalene / 2.0 / 10 1,0 / 2,0 / 10 Cyclopenta[cd]pyrene tbd tbd Dibenzo[a,e]pyrene tbd tbd Dibenzo[a,h]pyrene tbd tbd Sum 24 PAH 5.0 Dibenzo[a,i]pyrene tbd tbd / 10 Dibenzo[a,l]pyrene tbd tbd 1-Methylpyrene tbd tbd Sum 18 PAH Sum 24 PAH not in scope not in scope not in scope not in scope Sum 1,0 /10 / 50 Sum 5.0 / 10 Sum 0,2/1,0 /10 / 50 Benzo[b]naphtho[2,1-d]thiophene tbd tbd Polycyclic Aromatic Compounds (PACs) tbd tbd 9,10-Benzophenanthren tbd tbd Anthracene oil, Coal tar pitch tbd tbd Anthracene oil tbd tbd Anthracene oil, anthracene paste tbd tbd Anthracene oil, anthracenelow tbd tbd Anthracene oil, anthracene paste, anthracene fraction tbd tbd Anthracene oil, anthracene paste, distn. Lights tbd tbd 22. Petroleum distillates & related chemicals 石油馏分及其相关化合物 extracts, petroleum, light naphthenic distillate solvent n - of no AfPS GS 2014:01 PAH AfPS GS 2014:01 PAH Seite 18

19 distillate aromatic extract extracts, petroleum, light paraffinic distillate solvent extracts, petroleum, heavy naphthenic distillate solvent distillates, petroleum, chemically neutralized middle solvent-dewaxed heavy paraffinic petroleum distillates benzin naphtha pitch petroleum naphtha hydrotreated light straight run (petroleum) distillates (petroleum), hydrotreated (mild) heavy naphthenic (9ci); hydrotreated heavy paraffinic petroleum distillates (mineral oil) distillates (petroleum), solvent-refined (mild) heavy paraffinic (9ci) distillates (petroleum), solvent-refined (mild) light paraffinic (9ci) Waste water/ Sludge/ n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no n - of no Textiles / 纺织类 development development Seite 19

20 aromatic naphtha, type aromatic petroleum derivative solvent petrolatum Bitumen Coal Tar oil respirable particles 可吸如性粉尘 Waste water/ Sludge/ n - of no n - of no n - of no n - of no n - of no Textiles / 纺织类 Aluminium oxide (particles of respirable size) tbd tbd Silica (particles of respirable size) ; ; tbd tbd development development Titanium dioxide (particles of respirable size) tbd tbd 24. s 溶剂 1,4-Dioxane tbd tbd Cyclododecane tbd tbd Ethanol tbd tbd Furan tbd tbd hexamethylphosphoramide (HEMPA) tbd tbd development development Methanol tbd tbd Methyl isobutyl ketone tbd tbd Nitrilotriacetic acid tbd tbd N-methylformamide tbd tbd 25. Others 其它 (2-chloroethyl)(3-hydroxypropyl)ammonium chloride tbd tbd (4-ethoxyphenyl)(3-(4-fluoro-3- phenoxyphenyl)propyl)dimethylsilane tbd tbd (BHA) Butylated hydroxyanisole tbd tbd Seite 20

21 1-(2-amino-5-chlorophenyl)-2,2,2-trifluoro- 1,1ethanediol,hydrochloride, containing <0,1 % 4- chloroaniline (EC No ) 2-butyryl-3-hydroxy-5-thiocyclohexan-3-ylcyclohex-2-en-1-one Waste water/ Sludge/ Textiles / 纺织类 tbd tbd tbd tbd 2-nitroanisole tbd tbd 2-nitronaphthalene tbd tbd development development 2-Nitropropane tbd tbd 2-nitrotoluene tbd tbd 4,4'-Methylenbis(N-(1-methylpropyl)benzolamin) tbd tbd 4-Nitrobiphenyl tbd tbd 5-Nitroacenaphthene tbd tbd 7-methoxy-6-(3-morpholin-4-yl-propoxy)-3Hquinazolin-4-one Containing 0.5 % formamide (EC No ) tbd tbd AEEA [2-(2-aminoethylamino)ethanol] tbd tbd Dimethyl fumarate (DMFu) not in scope not in scope Aniline ,1 0, ,1 not in scope not in scope ISO/TS 16186, followed by GC/MS, followed by GC/MS Azobenzene tbd tbd Carbon black tbd tbd chloro-n,n-dimethylformiminium chloride tbd tbd Colchicine tbd tbd Diazoaminobenzene tbd tbd Formaldehyde tbd tbd 75/300 20/75 EN ISO ; DIN EN ISO Hydrazine tbd tbd hydrazobenzene tbd tbd hydroquinone (1,4-Dihydroxybenzene) tbd tbd methoxyacetic acid tbd tbd Methylazoxymethanol acetate tbd tbd development development Michler's base (N,N,N',N'-tetramethyl-4,4'- methylendianiline) tbd tbd N-(2-Naphthyl)anilin tbd tbd Seite 21

22 Waste water/ Sludge/ Textiles / 纺织类 N,N-(dimethylamino)thioacetamide hydrochloride tbd tbd N,N'-Bis-(1-ethyl-3-methylpentyl)-1,4- benzendiamin tbd tbd N,N-di-2-naphthyl-benzen-1,4-diamin (Diafen NN) tbd tbd N-[6,9-dihydro-9-[[2-hydroxy- 1(hydroxymethyl)ethoxy]methyl]-6-oxo-1H-purin-2- yl]acetamide tbd tbd O-isobutyl-N-ethoxy carbonylthiocarbamate tbd tbd o-phenylphenate, sodium tbd tbd o-phenylphenol ,5 0,025 20/50 Derivation MS analysis Derivation MS analysis Phenolphthalein tbd tbd Phenylhydrazine tbd tbd phenylhydrazine hydrochloride ; ISO tbd tbd phenylhydrazinium sulphate (2:1) tbd tbd potassium 1-methyl-3-morpholinocarbonyl-4-[3- (1methyl-3-morpholinocarbonyl-5-oxo-2-pyrazolin- 4-ylidene)-1-propenyl]pyrazole-5-olate containing < 0.5 % N,N-dimethylformamide (EC No ), tbd tbd Pyridine tbd tbd tetrahydrothiopyran-3-carboxaldehyde tbd tbd Thioacetamide tbd tbd Thiourea tbd tbd Toluene diisocyanate (1,3-) tbd tbd development development toluene diisocyanate (2,4-) tbd tbd Trimethyl phosphate tbd tbd Diethyl sulfate tbd tbd Dimethyl sulfate tbd tbd Benzophenone tbd tbd benzophenone, 4,4'-bis(dimethylamino)- [Michler's ketone] tbd tbd Cycloheximide tbd tbd Seite 22

23 Waste water/ Sludge/ Textiles / 纺织类 Dichlorophene [2,2'-Methylenbis(4-chlorophenol)] tbd tbd Metam sodium tbd tbd Safrole [5-allyl-1,3-benzodioxole] tbd tbd Bisphenol A tbd tbd borate, zinc salt total digestion, ICP/MS, for total boron total digestion, ICP/MS, for total boron Bis(chloromethyl)ether tbd tbd 2-chloro-6-fluoro-phenol tbd tbd dimethyldithiocarbamate, Potassium salt tbd tbd dimethyldithiocarbamate, Sodium salt tbd tbd Disodium ethylenebis(n,n'-dithiocarbamate) tbd tbd 1,2-Dimethylhydrazine tbd tbd 1,1-Dimethylhydrazine (UDMH) tbd tbd development development dinitrobenzenes tbd tbd 2-ethylhexyl diphenyl phosphate tbd tbd Carbendazim (N-2-benzimidazolecarbamic acid methyl ester) tbd tbd Carbon disulfide tbd tbd Ethylene thiourea tbd tbd Hexachlorobutadiene ,3 N-methylacetamide tbd tbd By Headspace Gas Chromatography Mass Spectrometric (HS GC/MS) Analysis. under development By Headspace Gas Chromatography Mass Spectrometric (HS GC/MS) Analysis. under development perboric acid, sodium salt ; ; ; ; ; ; ; 5 1 total digestion, ICP/MS, for total boron total digestion, ICP/MS, for total boron Seite 23

24 Diazene-1,2-dicarboxamide [C,C`-azodi(formamide), ADCA] Waste water/ Sludge/ Textiles / 纺织类 tbd tbd Triglycidylisocyanurate (TGIC) tbd tbd N-(1,4-Dimethylpentyl)-N'-phenyl-benzen-1,4- diamin tbd tbd Diethanolamine tbd tbd musk xylene tbd tbd 2-(2H-Bensotriazol-2-yl)-4,6-bis(1,1- dimetylpropyl)fenol 2-(2H-benzotriazol-2-yl)-4-(1,1,3,3- tetramethylbutyl)-phenol 2-(2 -Hydroxy-3,5 -di-tert.butylphenyl)- benzotriazole 2,4-Di-tert-butyl-6-(5-chlorobenzotriazole-2- yl)phenol (UV 327) 2-(2H-benzotriazole-2-yl)-4-(tert-butyl)-6(secbutyl)phenol (UV 350) tbd tbd Extraction, GC/MS development development tbd tbd tbd tbd tbd tbd tbd tbd 3-(4-methylbenzylidene) camphor tbd tbd Extraction, GC/MS Extraction, GC/MS Extraction, GC/MS Definition tbd to be determined not applicable Banned substances will not be d in the production of Kaufland articels Phase out of chemical is ongoing. Timeline for a ban has to be defined. Seite 24