SEPURAN Green for upgrading biogas efficiently

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1 SEPURAN Green for upgrading biogas efficiently June 03, 2014 Dr. Fabien Cabirol

2 Outline About Evonik and Fibres and Membranes Turning waste water into fuel SEPURAN Green Cartridge System Gas permeation References SEPURAN Green for biogas upgrading References

3 An attractive company One of the global leaders in specialty chemicals AiM: Profitable growth and sustained value creation Main shareholders: RAG-Stiftung, CVC Capital Partners Sales 2013: 12.9 billion Employees as of Dec. 31, 2013: 32,995 Page 3

4 High Performance Polymers is part of our Specialty Materials segment Evonik Fibres in the structure of Evonik Industries Evonik Segments Consumer, Health & Nutrition Resource Efficiency Specialty Materials Services Real Estate Business Units Consumer Specialties Health & Nutrition Inorganic Materials Coatings & Additives Performance Polymers Advanced Intermediates High Performance Polymers Evonik Fibres GmbH

5 Evonik delivers Gas Separation Membrane cartridges via plant-engineering companies Monomers Polymer Membrane Cartridges OEM / Plant Construction End user EVONIK business model

6 EVONIK IN SEA AND ANZ Manila Bangkok Rayong Ho Chi Minh Kuala Lumpur Singapore Jakarta Bekasi Timur Cikarang * portfolio adjusted, excl. exports Regional Head Office Services Sales Production/ R&D Site/Lab Representative Office Melbourne Morrinsville

7 Outline About Evonik and Fibres and Membranes Turning waste water into fuel SEPURAN Green Cartridge System Gas permeation SEPURAN Green for biogas upgrading References

8 Biogas from Palm Oil Mill Effluent POME is a nearly untapped resources with great potential. Biogas from POME is commonly used to produce electricity (feed in tariffs), BUT: The large majority of mills are not within 10km of the grid. Feed in Tariffs can change. Biogas often produced in excess of the electricity need for the mill and surplus is typically flared. Potential for much larger volume of Biogas (EFB) Upgrading to Bio-Methane in addition to electricity generation increases the commercial value of a Biogas project.

9 Biomethane (CBG) Biomethane as direct replacement of Natural Gas or LNG. Feed to Grid (difficult due to lack of infrastructure) Sale to Industrial Parks (if locations of mills suitable) Use within Palm Oil operations (Hydrogen generation)

10 Business Case Model General conditions: Raw biogas 700 Nm³/h (continuous) Upgrading Process 2 stages Raw Biogas Methane 54.3% Upgrading Yield 94% BioMethane composition 98% Project Data: Depreciation Period 15 years Interest Rate 6% Diesel Price Non subsidized (RM 2.8 in MY; IDR 12,400 in ID)

11 Biomethane as natural gas alternative Biogas Plant Upgrading Compression & Storage SEPURAN Industrial Park, Grid, etc CH 4 Production (per Year): 112,800 mmbtu Upgrading/Compression/Storage: CAPEX: MYR 10.5 Million OPEX Yearly: MYR 1.2 Million Total Yearly: MYR 2.3 Million (incl. depreciation) Production Cost: MYR per mmbtu

12 Biomethane (CBG) Biomethane as fuel direct for replacement the plantation of trucks Natural (captive Gas or fleet LNG. use) Feed to Grid (difficult due to lack of infrastructure) Diesel Sale to is Industrial a substantial Parks part (if locations of the Operational of mills suitable) Expenses in the palm oil mill/plantation Use within Palm Oil operations (Hydrogen generation) Partial or full decoupling from diesel price volatility Not convincing Business Case for Malaysia at Today s Natural Gas subsidized price. Proven technology package and readily available technology CBG utilization benefits the mill directly = direct impact Full CBG or Diesel Dual Fuel options

13 Biomethane as Truck Fuel (Captive Use) 100% CBG Trucks Biogas Plant Upgrading CBG Compression and Distribution CBG Trucks SEPURAN Number of Trucks (5 10 tons): 94 Number of Fueling Stations: 2 Upgrading/Compression/Distribution/Conversion: CAPEX: MYR 21 Million OPEX Yearly: MYR 1.9 Million Total Yearly: MYR 4.1 Million CBG Production Cost: MYR 1.58 per Diesel Liter Equivalent Savings: MYR 3.3 Million per Year IRR: 25.2%

14 Biomethane as Truck Fuel (Captive Use) Diesel Dual Fuel Trucks Biogas Plant Upgrading CBG Compression and Distribution Diesel Dual Fuel Trucks SEPURAN Number of Trucks (5 10 tons): 156 Number of Fueling Stations: 2 Ratio CBG/Diesel: 60/40 Upgrading/Compression/Distribution/Conversion: CAPEX: MYR 19.2 Million OPEX Yearly: MYR 1.9 Million Total Yearly: MYR 9 Million (includes Diesel cost) Mixed Fuel (CBG/Diesel) Cost: MYR 2.03 per Liter Savings: MYR 3.5 Million per Year IRR: 27.9%

15 Summary POME to CBG fuel High savings possible (> 1. Mio USD/year) diesel fuel price are likely to increases savings become correspondingly more attractive CBG makes the mill independent from diesel price increases Fuel out of POME will strongly support a green and sustainable image CBG is the most attractive route for the usage of biogas

16 Outline About Evonik and Fibres and Membranes Turning waste water into fuel SEPURAN Green Cartridge System Gas permeation SEPURAN Green for biogas upgrading References

17 SEPURAN Green cartridge system The cartridge system complements the SEPURAN product port folio flexible to different pressure regulations easy membrane replacement reduced replacement costs

18 Characteristics of the SEPURAN Green Cartridge System Investment for casing just once, afterwards only replacement of aacartridges necessary Easy assembly and disassembly due to low own weight of 10 kg Fast and flexible replacement of modules by reason of new adapter and lug system Pre-built rack system possible. Therefore fast connection because of elimination of piping between each and every module Fast construction of container due to easy assembly of pre-built racks Up to 200 cartridge systems in one 40 ft. container possible

19 Outline About Evonik and Fibres and Membranes Turning waste water into fuel SEPURAN Green Cartridge System Gas permeation SEPURAN Green for biogas upgrading References

20 Illustration of a gas separation process in a hollow fibre membrane Mode of operation of a membrane module for gas separation Relative permeation rates of various gases

21 A CO 2 /CH 4 selectivity of >50 is our USP for a successful process layout Performance indicators for Evonik Membranes in Biogas upgrading FAST H 2 O >400 CO O N CH Mixture Selectivity* CO 2 /CH 4 50 O 2 /N 2 9 CO 2 /N 2 30 SLOW * Selectivity = Permeability Compound A / Permeability Compound B

22 Outline About Evonik and Fibres and Membranes Turning waste water into fuel SEPURAN Green Cartridge System Gas permeation SEPURAN Green for biogas upgrading References

23 The membrane removes CO 2 and dries the biogas at the same time Process steps of biogas upgrading with SEPURAN Green Membranes Raw Biogas Desulphurisation H 2 O Removal Filter Compressor Condensate separation CO 2 Removal Biomethane

24 Evonik s Multi Step Biogas Upgrading Process with SEPURAN Green is a game changer! For the first time membrane technology can offer complete separation!

25 Outline About Evonik and Fibres and Membranes Turning waste water into fuel SEPURAN Green Cartridge System Gas permeation SEPURAN Green for biogas upgrading References

26 10 Nm³/h Pilot Plant in Neukirchen a. d. Vöckla, Austria

27 Evonik Pilot Unit Penglai, China Seite 27

28 Evonik Pilot Unit Evonik s own unit for testing purpose In operation since 02/2011 First reference in Europe Now shipped to China to be first reference in Asia Commissioning in 09/2013 in Penglai, China Demonstrating the application of biomethane production through hollow fibre membrane technology Seite 28

29 Results of the pilot plant in Neukirchen confirm the expectations since 02/2011

30 Biogas-Upgrading plants in different sizes can be referenced in the EU market >20 plants in: Germany, France, UK, Swizerland, Norway, Sweden, Korea, etc... Zeven, Germany Capacity: 250 m³/h Start-up date: 10/2012 Köckte, Germany Capacity: 700 m³/h Start-up date: 09/2013 Poundbury, UK Capacity: 650 m³/h Start-up date: 10/2012 Sachsendorf 1, Germany Capacity: 150 m³/h Start-up date: 10/2012 Prattln, Switzerland Capacity: 210 m³/h Start-up date: 10/2012 Neukirchen, Austria Capacity: 10 m³/h Start-up date: 2/2011 Sachsendorf 2, Germany Capacity: 700 m³/h Start-up date: 10/2013

31 Reference list of upgrading plants supplied with SEPURAN Green (end 2013) Size (Nm³/h raw gas) Quantity 10 Nm³/h < Nm³/h Sorted by country Austria (2), China (2), Germany (1), Italy (1), Netherlands (2), Thailand (1), United Kingdom (1), USA (1) France (3), Germany (2), Norway (1), Spain (1), Swizerland (1) 500 < Nm³/h Germany (3), United Kingdom (1) > 1000 Nm³/h 5 United Kingdom (5)

32 Envitec biogas-upgrading plant in Sachsendorf, Germany Envitec is now offering SEPURAN technology globally. EVONIK CONFIDENTIAL Site Capacity Sachendorf, Germany 150 Nm³/h Start-Up 10/2012 Product use Substrate Engineering company Plant operator Gas grid Energy crops Envitec Envitec

33 Sachsendorf EnviThan plant start up protocol Start-up within 16 min.

34 Sachsendorf EnviThan plant typical results Biomethane Concentration

35 700 Nm³/h biogas plant, Köckte Germany Source: Envitec

36 DMT biogas-upgrading plant in Poundbury, UK EVONIK CONFIDENTIAL Site Poundbury, UK Capacity 650 Nm³/h Start-Up 10/2012 Substrate Food waste Product use Gas grid Engineering company DMT Plant operator JV Energen Source:

37 Poundbury UK Start up and operation summary In operation since Oct 2012 Processes 650 Nm 3 /h of biogas Very fast start up biomethane injection quality reached within several minutes CH 4 in biomethane 97% up to 99% to reduce propane addition (and its costs) CH 4 loss < 0.5% Energy consumption: kwh/nm 3 biogas Very Low staff and maintenance costs No significant down time except planned maintenance Source: DMT

38 Evonik is a leading supplier of biogas upgrading membranes Advantages of the Evonik membrane process with SEPURAN Green Simple to operate, low maintenance Simple to operate, low maintenance Simple to operate, low maintenance Very low downtime and manpower requirement Methane slip (loss) is tunable from a few % to <0.5% depending on project requirements High methane yield > 99% possible Highest energy efficiency (<0.2 kwel/nm 3 crude biogas, <0.4 kwel/nm 3 biomethane) No additional ancillary materials Easily regulated for changes in flow rate or composition Easily scalable (10 Nm 3 /h to > 2000 m³/h)

39 Thank you for your attention!

40 Question/Comments:

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