Twice-Annual Station Maintenance and Calibration Report CANYONLANDS NATIONAL PARK March 3, 2010

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1 Twice-Annual Station Maintenance and Calibration Report CANYONLANDS NATIONAL PARK March 3, 21 National Park Service Gaseous Pollutant Monitoring Program Prepared by Air Resource Specialists, Inc. under Contract C CALIBRATION SUMMARY Air quality site: Island in the Sky Field Specialist: Dave Meisters Primary Site Operator: Lofton Wiley Backup Site Operator: Kevin Moore All site visit and calibration forms are attached, detailing the pre- and post-maintenance calibrations. Pre-Maintenance Calibration Summary: The ozone analyzer and station reference were both found to be about +6. Maintenance Activity Summary: O 3 The analyzer was found to be +6. The sample pump diaphragm and photometer tubes were installed. Analog output was in need of adjustment; the analyzer displayed a coefficient higher than expected. Both instruments were calibrated. After calibration, the correlation coefficients were back to normal, and no further maintenance was performed. The dryer has failed in the zero air source, as it is indicating desiccant. The compressor s water drop-out bottle leaks air, and the ¼ line is poorly installed; holes have worn through because of the vibration. A replacement Panther with 8 of ¼ tubing (with stainless steel swage lock fittings and tubing tie-downs) will be shipped. WS/WD The cross arm was checked for proper N/S orientation, and it was found to be two (2) degrees low. The sensors were checked for proper orientation and accuracy, and then replaced. Orientation and accuracy checks were repeated for the new sensor, and once the orientation ring was adjusted to correct for a 12 degree offset (probably from the lab rebuild), the final checks passed. The translator was not adjusted. T/ T Calibration checks were performed on the upper and lower temperature sensors at three (3) temperature baths, with very good results. The aspirator fans were found in working condition. The translator was not adjusted. SR A pre-maintenance calibration check of the solar radiation sensor showed that it responded 4 low compared to the reference. The sensor found level and clean. The translator was not adjusted. The post-maintenance side-by-side comparison was recorded. PRECIP The precipitation gauge was reading accurately, and the tipping mechanism was found to be clean and level. No adjustments were necessary. 191 Sharp Point Drive, Suite E Fort Collins, CO 8525 Telephone:

2 WETNESS The wetness sensor, which was exposed in the surrounding snow, was tested and produced expected results. RH The relative humidity sensor was found in good agreement with the reference sensor during pre-maintenance checks. The aspirator fan was in working condition. The sensor was replaced as routine maintenance, and the post-maintenance comparisons are documented. CASTNet Pre-maintenance flow checks passed, and the calibration procedure was not performed. A new diaphragm was installed. Post-Maintenance Calibration Summary: All parameters were within specifications. ADDITIONAL NOTES AND OBSERVATIONS Station Operator The park's law enforcement personnel take turns doing the weekly station visits. They take care to follow SOPs, but often need to perform minimal maintenance due to understaffing. Lofton was able to meet with me to allow access to the shelter and to assist with the meteorological readings during the performance checks. He does a good job and is responsive when problems arise at the site. Monitoring Shelter and Supporting Hardware The 8 ft. x 7 ft. wooden shelter is in poor condition, with bad door seals and many signs of dirt and dust intrusion. The j-box at the base of the tower should be replaced to accommodate for power requirements, and the system should be replaced as well. Bolts are missing from the flow tower unistrut clips (actually, it is doubtful that there ever were bolts because the clips are too small). Fence wire is being used instead, but is not adequate; the tower is loose on the shelter mount. The guy wires on the meteorological tower have rusty wire clamps. 191 Sharp Point Drive, Suite E Fort Collins, CO 8525 Telephone:

3 Calibration Summary Network: NPS Location: Canyonlands Site: CANY-IS Date: 3/3/1 Last Site Visit: 8/19/9 Parameter Criteria Accuracy Goal Pre-Maintenance Mfg, & Value Calibration Results Post Maintenance Mfg, & Value O 3 Analyzer Average average error <= ± FAIL. PASS Maximum max error <= ± FAIL. PASS TECO 49C TECO 49C Correlation actual r > PASS 1. PASS Intercept actual <= ± 3. ppb 1.4 PASS. PASS Slope actual.95 <= m <= PASS 1. PASS O 3 Reference Average average error <= ± PASS. PASS Maximum max error <= ± PASS. PASS TECO 49C TECO 49C Correlation actual r > PASS 1. PASS Intercept actual <= ± 3. ppb.5 PASS. PASS Slope actual.95 <= m <= PASS 1. PASS CASTNet Flow Flow Rate (low). PASS Flow Rate (target) max error <= ± PASS Tylan FC28SAV-45 AW94322 Flow Rate (high) -.4 PASS Tylan FC28SAV-45 AW94322 Leak Check max error <= ±.3. PASS Precipitation max error <= ± NPS987.2 PASS 158 NPS987 Relative Humidity PRE Sensor ID# 568 max error <= ± 5. Rotronics RH MP61A PASS Rotronics RH MP61A PASS Solar Radiation average error <= ± 5 LiCor Pyranometer PY PASS LiCor Pyranometer PY PASS Delta Temperature max error <= ±.1º C; RM Young <= ±.2º C m=EPA3789.º PASS m=EPA3789 Temperature max error <= ±.2º C; RM Young <= ±.5º C; Rotronics <= ± 1.º C m=????.1º PASS m=???? Wetness Dry response PASS -1 to 1 value dry RM Young to 11 value wet EPA 3883 Wet response 1 PASS RM Young 5811 EPA 3883 Wind Direction Alignment max error <= ± 5º 2º PASS 2º PASS Linearity max error <= ± 3º 176 3º PASS 176 3º PASS NPS9121 NPS9831 Starting Threshold max error <= 6 g-cm; RM Young AQ <= 9 g-cm; RM Young MA <= 3 g-cm, RM Young RE <= 7 g-cm Wind Speed max Wind Speed <5 max error <= ±.2 m/s N/A N/A N/A N/A max Wind Speed >= 5 max error <= ± PASS PASS NPS9153 NPS9846 Starting Threshold max error <=.2 g-cm; RM Young AQ <=.3 g-cm; RM Young MA <= 2.9 g-cm, RM Young RE <=.3 g-cm

4 Calibration Standards Latitude: Operator: Lofton Longitude: Network: NPS Elevation: Location: Site: Date: Last Site Visit: Canyonlands CANY-IS 3/3/21 8/19/29 Parameter Device Manufacturer Model S/N Calibration Date Voltage Fluke /14/22 Voltage Source Calib. Inc. DVC-35A Ozone Transfer Standard TECO 49PS /17/29 Gas Dilution Mass flow ERT Gas Dil Barometric Pressure Barometer/Altimeter AIR AIR-HB-1A 725 1/28/22 High Flow Dry cal BIOS DC /16/21 Low Flow Dry cal BIOS DC2 1/3/24 Precipitation PPT Calibrator 299 1/4/24 Volume (ml): 42 1/5/24 Relative Humidity RH Sensor Visala MHMP45C X8149 1/29/23 Solar Radiation Thermopile LiCor Pyranometer PY128 4/11/23 Multiplier /8/24 Temperature Digital Thermometer Eutechinics /29/23 Torque Gauge RM Young /1/24 Wind Direction Linearity Jig RM Young /11/24 Compass Brunton 56LM /12/24 Wind Speed Torque Disk RM Young 1831 CA 2241 Anemometer Drive RM Young 1881 CA 2241 Volumetric Flow Comments: Lat/Lon confirmed by Garmin GPS

5 OZONE CALIBRATION FORM EQUIPMENT IDENTIFICATION Transfer Standard Analyzer Station Reference TECO TECO TECO 49iPS 49C 49C Span Setting/ O3 Coefficient Zero/ O3 Bkg Sample Freq/ Intensity A/ Lamp Control Frequency/ Intensity B Flow (Lpm)/ Flow A, Flow B / / /.59 Offset Cell Temp / Pressure P=592 / T=19.,52.,66.9 P=615.9 / T=39.7,56.7,7.6 P=61.7 / T=28.9,58.7 STATION TUBING Transfer Standard Analyzer Station Reference OFFSET = ppb OFFSET = ppb OFFSET = ppb Calibration Point Mechanical Setting Conc. Display ZERO 1 1 Pass/ Fail Display Pass/ Fail PASS PASS PASS PASS PASS PASS FAIL PASS FAIL PASS ZERO Target ranges for O3 points are: 3-8, 15-2, 3-35, 4-45 Average : 5.6 FAIL Average : 3.7 PASS Maximum : 7.1 FAIL Maximum : 4.3 PASS LINEAR REGRESSION PLOT RESIDUALS PLOT 5 y = 1.444x R 2 = Analyzer 3 2 Residual Transfer Standard Conc. Regression Concentration Value CALIBRATION TIME From: To: EVENT RESPONSE RESULTS Station Reference Analyzer Response Linear Regression Calibration Point Mechanical Setting Display Recorder () Parameter Analyzer Station Reference ZERO N/A Slope 1.44 PASS 1.32 PASS Precision Span Y Intercept Correlation Coefficient 1.4 PASS.5 PASS 1. PASS 1. PASS Pre-Maint Ozone Comments: Analyzer has new style pump. Both instruments found high and calibrated. Diaphragms and photometer tubes inspected 27627

6 POST-MAINTENANCE OZONE CALIBRATION FORM EQUIPMENT IDENTIFICATION Transfer Standard Analyzer Station Reference TECO TECO TECO 49iPS 49C 49C Span Setting/ O3 Coefficient Zero/ O3 Bkg Sample Freq/ Intensity A/ Lamp Control Frequency/ Intensity B Flow (Lpm)/ Flow A, Flow B.59 / / /.59 Offset Cell Temp / Pressure P=592 / T=19.,52.,66.9 P=615.9 / T=39.7,56.7,7.6 P=61.7 / T=28.9,58.7 STATION TUBING Transfer Standard Analyzer Station Reference OFFSET = ppb OFFSET = ppb OFFSET = ppb Calibration Point Mechanical Setting Conc. Display ZERO Pass/ Fail Display Pass/ Fail PASS 4 4. PASS PASS 3 3. PASS PASS 2 2. PASS PASS 1 1. PASS PASS 7 7. PASS ZERO Target ranges for O3 points are: 3-8, 15-2, 3-35, 4-45 Average ABS :. PASS Average ABS :. PASS Maximum :. PASS Maximum :. PASS LINEAR REGRESSION PLOT RESIDUALS PLOT 5 y = x R 2 = Analyzer 3 2 Residual Transfer Standard Conc. Regression Concentration Value CALIBRATION TIME From: To: EVENT RESPONSE RESULTS Station Reference Analyzer Response Linear Regression Calibration Point Mechanical Setting Display Recorder () Parameter Analyzer Station Reference ZERO N/A Slope 1. PASS 1. PASS Precision Span Y Intercept Correlation Coefficient. PASS. PASS 1. PASS 1. PASS Post Maint Ozone Comments: Desiccant pink - Site needs a replacement Panther with 1/4" output elbow and 8' of tubing with 1/4"SS fittings and tie downs. STP at 2.8 / Reference =

7 WETNESS, PRECIPITATION AND BAROMETRIC PRESSURE CALIBRATION FORM Barometric Pressure Reference S/N: 725 Calibration Date: 1/28/2 Precipitation Reference S/N: 299 Calibration Volume: 42 ml Calibration Date: 1/4/4 WETNESS Pre-Maintenance RM Young 5811 Post Maintenance RM Young 5811 EPA 3883 EPA 3883 SENSOR RESPONSE LED (ON/OFF) DRY.17 off PASS WET on PASS DRY WET SENSOR RESPONSE LED (ON/OFF) off on Pre-Maint Wetness Comments: Ground mostly covered in snow. Sensor is exposed and works. Post Maint Wetness Comments: Pre-Maintenance Post Maintenance Calibration Volume Inlet Diameter Reference NPS987 NPS987 9 cc Inlet Diameter 9.66" 9.66" Novalynx RM Young Cal Volume (ml) Designated value in mm PRECIPITATION Cal Volume (ml) Designated value in mm mm mm PASS CC Novalynx RM Young mm mm/tip Pre-Maint Precipitation Comments: Measured smaller volumn of water with on site graduated cylinder. Post Maint Precipitation Comments: BAROMETRIC PRESSURE SENSOR RESPONSE Reference (Volts) (mm Hg) Reference (Volts) (mm Hg) Maximum: Maximum: Pre-Maint Barometric Pressure Comments: Post Maint Barometric Pressure Comments: 27627

8 CASTNET FLOW CHECK FORM High Flow Standard (BIOS) Reference S/N: 1461 Cell #: Calibration Date: 2/16/1 MFC Date PREVIOUS LINEAR REGRESSION FLOW CALIBRATION LINEAR REGRESSION 3/3/1 Tylan Tylan MFC Display Set Point FC28SAV-45 FC28SAV-45 Slope AW94322 AW94322 Intercept PUMP IDENTIFICATION Standard Temp. and Pressure (STP) TEMP PRESSURE (mmhg) Thomas Thomas CAB18 17CAB18 N/A N/A FLOW CHECK ITEM PRE MAINTENANCE ITEM AS FOUND AS LEFT Vacuum 21 inhg 21 Full Scale Flow (Operating) Zero.6.6 MFC Flow Value (Operating) Flow Target BIOS SLPM SENSOR RESPONSE ACTION BIOS (SLPM) MFC Display Rotometer Flow Flow Value (SLPM) MFC VOLTS DC Target Flow Points 1.5 SLPM 3. SLPM SLPM PASS/FAIL Zero (pump off) N/A N/A Leak Test N/A N/A.237 PASS Point 1 (low) to to PASS Point 2 (target) PASS Point 3 (high) to to PASS Max Flow Test PASS Calibration Required? Point 1 (low) *Note: A calibration is required if the difference between the transfer. NOT REQUIRED standard and the value is greater than +/- 2. MFC Zero/Leak Test Diff:.2 Point 2 (target) at the target setting or greater than +/- 2.5 at either the low 1.6 NOT REQUIRED or high point. Leak Present? NO Point 3 (high) *Note: A leak is present if the difference -.4 NOT REQUIRED between the zero and leak test value is greater than.1 SENSOR RESPONSE ACTION BIOS (SLPM) MFC Display Rotometer Flow Flow Value (SLPM) MFC VOLTS DC Target Flow Points 1.5 SLPM 3. SLPM SLPM PASS/FAIL Zero (pump off) N/A N/A Leak Test N/A N/A Point 1 (low).75 to to 2.25 Point 2 (target) Point 3 (high) 2. to to 4. Max Flow Test Pre-Maint CASTNet Flow Comments: Post Maint CASTNet Flow Comments: 27627

9 CASTNET FLOW CALIBRATION FORM High Flow Standard (BIOS) Reference S/N: 1461 Cell #: Calibration Date: 2/16/1 MFC Tylan FC28SAV-45 AW94322 Tylan FC28SAV-45 AW94322 PUMP IDENTIFICATION Standard Temp. and Pressure (STP) TEMP PRESSURE (mmhg) Thomas Thomas CAB18 17CAB18 N/A N/A CASTNET FLOW CALIBRATION RESULTS ACTION BIOS (SLPM) MFC Display Flow Value (SLPM) MFC VOLTS DC Target Flow Points Linear Regression 1.5 SLPM 3. SLPM Parameter MFC MFC VOLTS DC Zero (pump off) Slope Leak Test Point Y Intercept Correlation Coefficient Point Point MFC Set Point Zero/FS Set Point Point s 3. s Zero Full Scale Point MFC Volts DC BIOS SLPM Pre-Maint CASTNet Flow Comments: Post Maint CASTNet Flow Comments: 27627

10 SOLAR RADIATION CALIBRATION FORM Solar Radiation Reference S/N: PY128 Reference Factor: 95.64(W/m2) Calibration Date: 4/11/3 SOLAR RADIATION LiCor Pyranometer PY46778 LiCor Pyranometer PY46778 Translator TRANSLATOR CARD SETTING (W/m2) Zero.1 (W/m2) Span 1396 SENSOR RESPONSE HOUR (W/m2) T.STD HOUR (W/m2) T.STD 12: : 13: 13: : 14: 15: 15: 16: 16: 17: 17: Average : -4 Average : -5 : PASS : PASS Pre-Maint Solar Radiation Comments: Post Maint Solar Radiation Comments: 27627

11 TEMPERATURE, DELTA TEMPERATURE AND RELATIVE HUMIDITY CALIBRATION FORM Reference Thermometer S/N: 342 Calibration Date: 1/29/3 Relative Humidity Reference S/N: X8149 Calibration Date: 1/29/3 TEMPERATURE / DELTA TEMPERATURE Temperature Delta Temp. Translator Pre-Maintenance m=???? 2m=EPA3789 EPA3628 Post Maintenance m=???? 2m=EPA3789 EPA3628 BATH TEMP TEMPERATURE SENSOR RESPONSE Δ TEMPERATURE SETTING PRE- TRANSLATOR CARD RESPONSE TEMPERATURE Δ TEMPERATURE PASS.. PASS Zero PASS.. PASS Span PASS.. PASS Maximum :.1 PASS Maximum :. PASS SENSOR RESPONSE POST TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE Zero Span Maximum : Maximum : Pre-Maint Temperature Comments: Post Maint Temperature Comments: RELATIVE HUMIDITY Pre-Maintenance Rotronics RH MP61A Post Maintenance Rotronics RH MP61A SENSOR RESPONSE SENSOR RESPONSE HOUR T.STD HOUR T.STD 1: PASS 1: 11: PASS 11: 12: PASS 12: 13: 13: PASS 14: 14: 15: 15: Average ABS :.7 PASS Average ABS :. PASS Maximum : 1. PASS Maximum :. PASS Screen dirty/clogged on RH pre-maintenance sensor? (check one): Yes No Pre-Maint Relative Humidity Comments: Post Maint Relative Humidity Comments: 27627

12 WIND DIRECTION CALIBRATION FORM To Landmark #1: 124 Degrees True From Landmark #1: 34 LM Description: rock formation To Landmark #2: 178 Degrees True From Landmark #2: 358 LM Description: Crossarm Declination: 11 Degrees Wind Direction Reference S/N: Calibration Date: 1/12/4 WIND DIRECTION WIND DIRECTION ALIGNMENT Land Mark Reference Degrees Degrees (degrees) (degrees) To PASS 124 PASS NPS9121 NPS9831 From 1 34 PASS 33-1 PASS Translator To PASS PASS From PASS 358 PASS Card Setting WIND DIRECTION TRANSLATOR CARD Average : 1 PASS Average : 1 PASS PRE POST Maximum : 2 PASS Maximum : 2 PASS Zero.. WIND DIRECTION LINEARITY Span Check Point Oscillator Frequency (Hz) = Data Logger Should Read (degrees) Degrees (degrees) Degrees PASS 58 2 PASS PASS PASS WIND DIRECTION STARTING THRESHOLD PASS 33-3 PASS PRE POST PASS PASS Torque gm-cm Torque gm-cm PASS 241 PASS PASS PASS Wind direction starting threshold accuracy goal: <= 6 g-cm 7 36 PASS PASS PASS 15 1 PASS Average : 1 PASS Average : 1 PASS Maximum : 3 PASS Maximum : 3 PASS Pre-Maint Wind Direction Comments: Post Maint Wind Direction Comments: 27627

13 WIND SPEED CALIBRATION FORM Wind Speed Reference S/N: CA 2241 Calibration Date: WIND SPEED WIND SPEED TRANSLATOR CARD Card PRE POST Setting Zero.2.2 NPS9153 NPS9846 Span Translator Oscillator Frequency (Hz) = Data Logger Should Read WIND SPEED STARTING THRESHOLD PRE POST Torque gm-cm Torque gm-cm Wind speed starting threshold accuracy goal: <=.2 g-cm Motor Speed (rpm) RM Young Met One WIND SPEED WIND SPEED PASS PASS PASS PASS N/A PASS PASS PASS PASS 4 N/A 2.48 N/A 7 N/A N/A Maximum ABS (use if Wind Speed <5): Maximum ABS (use if Wind Speed >=5):.4 PASS.4 PASS FOR REFERENCE ESC Met Card ESC Analog Input Card CSI 23X Instruction P3 M/S Output RMY Gray Prop RMY Black Prop Aluminum Cups Lexan Cups WSP High Input WSP Low Input WSP High Output (E.U.'s) WSP Low Output (E.U.'s) WSP High Input WSP Low Input WSP High Output (E.U.'s) WSP Low Output (E.U.'s) Config. Multiplier Offset Hz 5 m/s m/s 1V V 5 m/s m/s Hz Hz 5 m/s m/s 1V V 47.8 m/s m/s m/s m/s 1(or 5)V V 5 m/s m/s Pre-Maint Wind Speed Comments: Post Maint Wind Speed Comments: 27627

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