TFI Report Emission Testing

Transcription

1 TFI Report Emission Testing M1 classification Customer CONICA AG Industriestr Schaffhausen SWITZERLAND Product Industrial flooring Responsible at TFI Dipl.-Ing. Gerd Bittner Tel: Aachen, 04 August 2014 This report includes 2 pages and 5 annex(es). This report is a correction of TFI Report The present document is provided with a qualified electronic signature and is valid without autograph signature. This report only applies to the tested specimens and has been established to the best of our knowledge. Only the entire report shall be reproduced. Under no circumstances, extracts shall be used. Furthermore, we apply the General Terms and Conditions for the Execution of Contracts of the Textiles & Flooring Institute GmbH, also with regard to the order execution.

2 Transaction Test order Order date 7 April 2014 Your reference Emission testing M1 classification of building products Claudia Kribus TFI sample number , , , Date of manufacture --- Date of sample receipt 8 April 2014 Sampling performed by 2 Product Specification cf. annex preparation of test specimen 3 Results customer cf. sampling report Emissions (TVOC 28 days) Formaldehyde Carcinogenic substances Ammonia Odour requirement M1 fulfilled requirement M1 fulfilled requirement M1 fulfilled requirement M1 fulfilled requirement M1 fulfilled 4 Annexes Odour ISO GE Emission testing M1 a E Preparation of test specimen HP ADAM ADAM Sampling report The annexes marked a are based on tests accredited in accordance with EN ISO/IEC Page 2 of 2

3 GE Annex GE Odour ISO Transaction TFI sample number , , , Testing period 14 April May Test Method / Requirements Emission chamber EN ISO :2006 EN ISO :2006 Sensory testing ISO :2012 Determined sensory parameters Deviation - none - stainless steel test chamber volume 0.25 m³ chamber load 0.4 m²/m³ air exchange rate 0.5/h temperature 23 C ± 2 C relative humidity 50 % RH ± 5 % RH air velocity above the sample 0.1 m/s to 0.3 m/s passive sampling using a TEDLAR bag, approx. 200 l comparative scale (6 diffusers) with acetone as reference substance trained test panel members Acceptability scale from -1 to 1 Page 1 of 2

4 GE Results 1 Testing after 28 days Parameter Panelist Individual result Acceptability 1 0,5 2-0,8 3-0,2 4-0,1 5 0,3 6 0,8 7-0,2 8 0,3 9 0,1 10-0,3 11-0,1 12 0,2 13 0,8 14-0,2 15 0,4 16-0,1 17 0,3 18-0,8 19 0,5 20 0,2 21 0,4 Number of panel members Arithmetic mean Standard deviation Result 90 % confidence interval Requirements M1/M2 fulfilled Acceptability yes 1 The test is partially performed by an accredited subcontractor. Page 2 of 2

5 E Annex E Emission Testing M1 after 28 days 1 Transaction TFI sample number , , , Testing period 14 April Mai Test Method / Requirements Emission chamber EN ISO :2006 EN ISO :2006 stainless steel test chamber volume 0.25 m³ area of the test specimen 0.1 m² chamber load 0.4 m²/m³ air exchange rate 0.5/h temperature 23 C ± 2 C relative air humidity 50 % RH ± 5 % RH air velocity above the sample 0.1 m/s to 0.3 m/s The parameter of the chamber measurement correspond to the model room. VOC ISO :2011 EN ISO :2000 Aldehydes and ketones ISO :2011 sampling on Tenax, approx. 5 l, 80 ml/min thermal desorption / gas chromatography / mass spectrometry (TD/GC/MS) Gerstel thermal desorber / cooled injection system, Agilent GC/MS, non-polar capillary column sampling on DNPH cartridges, approx. 50 l, 1000 ml/min solvent desorption / liquid chromatography / diode array detector (HPLC/DAD) Agilent HP 1200 / DAD, C18-column, ternary eluent mixture Ammonia Internal method sampling by absorbing in dilute sulphuric acid using impinger technique approx. 100 L, 1 L/min spectrophotometer Evaluation according to CEN/TS 16516:2013 EN 15251:2007 M1 criteria M1criteriaandtheuseofclassifiedproducts.html AgBB 2012 Deviation - none - Page 1 of 2

6 E Results Parameter Testing after 28 days Result [mg/m²h] Requirements M1 [mg/m²h] fulfilled Total volatile organic compounds within the retention range C6 C < 0.2 yes (TVOC toluene equivalent) 1 Formaldehyde < < 0.05 yes Ammonia < < 0.03 yes Carcinogenic substances < < yes < below determination threshold 1 all compounds > 5 µg/m³ Page 2 of 2

7 HP Annex HP Preparation of test specimen 1 Individual Components Component 1 TFI sample number Date of manufacture 31 March April 2014 Surface of the test specimen ca. 0.1 m² (ca. 38 cm x 26.5 cm) Component 2 TFI sample number CONIFLOOR 540 W, Component A Article number PTA Batch no Date of manufacture ---- Colour white Sample quantity 0,6 kg Packaging polyurethan-truss Component 3 TFI sample number CONIFLOOR 540 W, Component B Article number PTB Batch no Date of manufacture ---- Sample quantity 0,1 kg Packaging tin can Page 1 of 2

8 HP Production Production period 11 April April 2014 Produced by Specimen Area of the specimen 1st Layer Nominal quantity to be applied 150 g/m 2 Actual quantity applied 150 g/m 2 Textiles & Flooring Institute GmbH testing laboratory, industrial flooring in stainless steel tub elasticated, low-emission boarding 6+2.5mm 0.1 m², approx. 38 cm x 26.5 cm Mixing ratio component A : component B = 6:1 Mixing Application technique Date of application Deviation - none - 3 Conditioning agitation and repotting roller and brush 11 April 2014, 8:50 a.m. Conditioning period 11 April April 2014 (3 days) Temperature 23 C ± 2 C Relative air humidity Deviation - none - 50 % rh ± 5 % rh Page 2 of 2

9 ADAM xls gefundene Substanzen Detected substances Emissionen nach 28 Tagen Emission after 28 days Kommentar Comment CAS-No. RT [min] Retentionsbereich Retention range C i SER i Zuordnung Classification R i lfd. Nr [µg/m³] [µg/m²h] [canc./nik/o.nik] [carc./lci/no LCI] Data to be entered only via the button "enter/delete results" Ethylacetat ,70 VVOC a 2 3 3, Essigsäure ,30 VOC a 2 6 7, , Triethylamin ,60 VOC a , , Propylenglykol ,90 VOC a 2 2 2, , Toluol ,10 VOC a 1 4 5, , Butylacetat ,90 VOC a 2 3 3, , Methoxy-1-methylethylacetat ,20 VOC a 2 2 2, , Cyclohexanon ,90 VOC a , , Ethylenglykol-monobutylether ,10 VOC a , , Neopentylglykol ,80 VOC b 3 7 8, , ,4-Butandiol ,00 VOC a , , andere Alkylbenzole 12,60 VOC a 2 2 2, , ,2,3-Trimethylbenzol ,70 VOC a 2 1 1, , N,N-Dimethylcyclohexanamin ,00 VOC c ,50 ohne NIK 0 1,2,4-Trimethylbenzol ,40 VOC a 2 6 7, , Propylenglykol-di-acetat ,00 VOC b 3 2 2, , Ethyl-1-hexanol ,10 VOC a 1 3 3, , Dipropylenglykol ,10 VOC a 2 3 3, , ,3,5-Trimethylbenzol ,20 VOC a 2 1 1, , Nicht identifizierte Komponente 14,30 VOC c 3 2 2,50 ohne NIK 0 N-Methyl-2-pyrrolidon ,50 VOC a , , Nicht identifizierter Carbonsäureester 14,60 VOC c 3 1 1,25 ohne NIK 0 n-undecan ,90 VOC a 1 7 8, , Alkenyl. Benzol 17,30 VOC c 3 2 2,50 ohne NIK 0 Alkenyl. Benzol 17,50 VOC c 3 3 3,75 ohne NIK 0 Alkenyl. Benzol 17,70 VOC c 3 5 6,25 ohne NIK 0 n-dodecan ,40 VOC a , , Phenoxypropanol ,60 VOC c ,00 ohne NIK 0 n-tridecan ,80 VOC a , , Alkenyl. Benzol 24,80 VOC c 3 3 3,75 ohne NIK 0 Alkenyl. Benzol 25,10 VOC c 3 4 5,00 ohne NIK 0 BHT ,30 VOC a 1 5 6, , Nicht identifizierter Carbonsäureester 25,90 VOC c 3 2 2,50 ohne NIK 0 Alkenyl. Benzol 26,20 VOC c 3 1 1,25 ohne NIK 0 Nicht identifizierte Komponente 29,10 SVOC c 3 1 1,25 ohne NIK 0 Nicht identifizierte Komponente 29,30 SVOC c 3 3 3,75 ohne NIK 0 Nicht identifizierte Komponente 30,00 SVOC c 3 6 7,50 ohne NIK 0 Formaldehyd ,20 VVOC d 1 0 0, Quantifizierung Quantification Identifikation Identification Daten nur über den Button "Messergebnisse eingeben/löschen" in diese Tabelle eintragen compounds after 28d Serial number ADAM_2012_08_3 Legende legend VVOC = < C6 VOC = C6 - C16 SVOC = C16 - C a = substanzspezifisch substance-specific b = substanzähnlich substance-like c = Toluoläquivalent toluene equivalent d = DNPH = Klasse 1 class 1 2 = Klasse 2 class 2 3 = Klasse 3 class 3

10 ADAM xls Chromatogram after 28 days Abundance TIC: [BSB1] D\ data.ms 1.7e e e e e e e+07 1e Time--> chromatogram 28d

11 ADAM xls Photo of the test specimen photo

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