How to Use the Chemical Compatibility Chart. Vials and Closures >> Chemical Compatibility Chart
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1 How to Use the Chemical Compatibility Chart The following chart contains information regarding the expected effects of 7 day direct solvent exposure on materials used for production of vials, caps and septa. Materials commonly used for vials include glass, polypropylene and TPX. Materials commonly used for caps include polypropylene, low density and high density polyethylene, and urea resin. Materials commonly used for septa include PTFE, silicone, natural red rubber, butyl rubber, Viton, polypropylene and polyethylene. PTFE is often laminated onto the sample facing side of a resealable septum to improve solvent exposure characteristics. Laminated septa will generally exhibit greater chemical resistance until the PTFE layer is punctured. Other factors that can affect chemical compatibility are temperature, pressure, whether there is direct contact between the material and the solvent and concentration of the solvent. Solvent mixtures can both increase and decrease chemical attack. In the chart below, the letter rating indicates the general ability of each material to resist chemical attack on direct exposure to the solvent. The number following the rating indicates the highest temperature at which this rating can be considered valid. When evaluating a laminated material, both the rating for the PTFE barrier layer and the secondary material should be examined. In general, the PTFE layer will provide effective protection but extra care is required to avoid breaking through this layer before the initial puncture for sample injection. It is always preferable to select combinations where both layers exhibit some degree of resistance to attack from a specific solvent. This chart is provided as a general guide and to the best of our knowledge this information represents the expected performance of materials used in our products. However, Thermo Fisher Scientific assumes no liability whatsoever for the results obtained under individual circumstances. This chemical resistance chart is to be used as a guide in determining of the suitability of materials only. There is no warranty expressed or implied for a specific purpose. Testing of specific products under your actual conditions is recommended and the final determination of material suitability is the responsibility of the user. Key to Chart on Following Pages E Excellent chemical resistance, low background extractables, recommended G Good chemical resistance, Some background extractable possible, suitable for general analysis F Fair chemical resistance, significant background extractables possible, for short term use SE Surface effects possible after short exposure, always evaluate suitability before use. C Conditions of exposure can affect compatibility and extractables. Solvent produces noticeable physical effects, use with extreme caution X Not Recommended. Immediate physical failure likely regardless of temperature, high levels of background contaminants likely --- Not tested, No data available ### Numerical values after the compatibility code indicate highest temperature where performance data is available General Chemical Compatibility of Materials used in Chromatography Vials and Closures 1,4-Dioxane E20 F20 G20 G E20 G ,2,4-Trimethylpentane E20 F20 F20 F E20 F Methoxyethanol E20 GE E50 E E20 E Acetaldehyde E20 C20 C20 G20 C20 E20 C20 G20 G20 E Acetamide, Sat. E100 E50 E50 E E50 E50 G20 X E20 E100 Acetic Acid, 5% E100 E50 E50 E50 G20 E100 E50 E20 G20 G20 E50 Acetic Acid, 50% E100 E50 E50 E20 F20 E100 G20 G20 G20 G20 X Acetic Acid, Glacial E20 E20 G20 G20 C20 E20 C20 G20 F20 G20 X Acetic Anhydride E20 G20 E20 C20 X E20 X G20 F20 G20 X Acetone E20 C20 E50 X X E20 X F20 F20 E20 E20 Acetonitrile E20 E20 F20 E50 F20 E20 E20 E20 F20 F20 F20 Acetophenone E20 F20 C20 C20 X E20 X C20 C20 E20 X Acrylonitrile E20 E20 F20 E20 X E20 E20 X X X X Adipic Acid E50 E50 E50 E50 E50 E50 E E20 E50 E50 Alanine E50 E50 E50 E E50 E Allyl Alcohol E20 E20 E20 E E20 E E20 E20 E20 Aluminum Chloride E200 E50 E50 E50 E50 E100 E50 G20 E20 E20 E100 Aluminum Hydroxide SE100 E20 E20 E E100 E20 E20 G20 E50 C
2 Vials and Closures Thermo Scientific Chromatography Columns and Consumables Amino Acids E50 E50 E50 E50 E20 E50 E50 E50 E20 E20 E50 Ammonia (pure) SE100 E50 E50 E50 X E100 E50 E20 X G20 X Ammonia, 25% SE100 E50 E50 E50 C20 E100 E50 E20 X E20 C20 Ammonium Acetate, Sat. E100 E50 E50 E E100 E X Ammonium Chloride E100 E50 E50 E50 E20 E100 E50 E20 E20 E20 E50 Ammonium Glycolate E50 E20 E20 E E50 E Ammonium Hydroxide, 5% SE100 E50 E50 E50 G20 E100 E50 E20 C20 E20 C20 Ammonium Oxalate E100 E20 E20 E E100 E Amyl Alcohol E20 F20 G20 E20 X E20 E20 X E20 E20 F20 Amyl Chloride E100 X C20 F20 C20 E100 X X X X E20 Aniline E50 E20 G20 G20 X E50 E20 X X G20 E20 Aqua Regia SE100 X X X X E100 X X X X G20 Arsenic Acid E20 E50 E50 E50 C20 E20 G20 G20 G20 E20 G20 Benzaldehyde E20 E20 F20 C20 X E20 E20 F20 X E20 X Benzenamine E20 E20 G20 G20 F20 E20 E X X G20 Benzene E20 X X X X E20 X X X X G20 Benzoic Acid, Sat. E50 E20 E50 E50 X E50 E50 G20 X X G50 Benzyl Acetate E20 E20 E20 E E20 E X F20 X Benzyl Alcohol E20 G20 G20 F20 X E20 X F20 X G20 E20 Boric Acid E200 E50 E50 E50 E20 E100 E50 E20 E20 E20 E20 Bromine E20 X X F E20 X X X X G20 Bromobenzene E20 X X X X E20 X X X X F20 Bromoform E20 X X X --- E20 X Butadiene E20 X X F20 X E20 X X X X E20 Butyl Acetate E20 F20 C20 G20 X E20 G20 X X G20 X Butyl Chloride E20 X F20 X --- E20 X --- X F20 G20 Butyric Acid E20 X X F E20 X X C20 C20 E20 Calcium Chloride E200 E50 E50 E50 E50 E100 E50 E50 E50 E50 E50 Calcium Hydroxide, Conc. SE100 E50 E50 E50 E50 E100 E50 E50 E50 E50 E50 Calcium Hypochlorite, Sat. E20 E20 E20 E20 X E20 E20 G20 C20 G20 C20 Carbazole E20 E20 E20 E E20 E Carbon Disulfide E20 X X X X E20 X X C20 X E20 Carbon Tetrachloride E20 G20 X G20 X E20 F20 C20 C20 X E20 Caustic Potash SE100 E50 E50 E E100 E50 E E20 Caustic Soda, 1% SE100 E50 E50 C E100 E50 E20 E20 E20 F20 Caustic Soda SE100 E50 E50 G E100 G20 G20 G20 E20 F20 Cedarwood Oil E100 X X F20 C20 E100 X SE20 C20 C Cellosolve Acetate E20 F20 E20 E20 X E20 E20 X X G20 X Chlorine Water E20 F20 X G E20 C20 C20 X C20 E20 Chlorine, 10% (Moist) E20 F20 X G E20 C20 C20 X C20 E20 Chlorine, 10% in air E20 F20 C20 F E20 C20 C20 X C20 E20 Chloroacetic Acid E50 E20 E20 E50 X E50 E50 F20 X G20 X Chlorobenzene E20 X X X X E20 X X X X E20 Chloroform E20 X X F20 X E20 F20 F20 X X E20 Chromic Acid, 10% E300 E50 E50 E50 X E100 E50 F20 X F20 G20 Chromic Acid, 20% E300 G20 E50 E50 X E100 E50 C20 X C20 F20 Chromic Acid, 50% E300 G20 G20 E50 X E100 E50 C20 X C20 F20 Chromic:Sulfuric E300 X X X X E100 E50 C20 X C20 F20 Cinnamon Oil E20 X X X --- E20 X Citric Acid, 10% E50 E50 E50 E50 E50 E100 E50 E50 E50 E50 E20 Copper Sulfate E100 E50 E50 E50 G20 E100 E50 E20 F20 E20 E50 Cresol E20 G20 X F20 X E20 X X X X E20 Cyclohexane E20 C20 X F20 G20 E20 F20 C20 C20 X C20 Cyclohexanone E20 F20 G20 F20 X E20 X X X F20 X Cyclopentane E20 F20 F20 F E20 X --- X X X Decahydronapthtalene E20 X F20 E E20 G Decalin E20 X F20 E20 X E20 G20 X X X E
3 Diacetone E20 G20 C20 X X E20 X C20 X F20 X Diacetone Alcohol E20 G20 E20 E20 X E20 X F20 X G20 X Dibutylphthalate E20 C20 G20 F20 X E20 F20 G20 X C20 G20 Diethyl Benzene E20 X X F20 X E20 X X X X E20 Diethyl Ether E20 F20 X F20 G20 E20 X X X X C20 Diethyl Ketone E20 G20 G20 X --- E20 X --- F20 G20 X Diethyl Malonate E20 E20 E20 E E20 E Diethylamine E20 C20 C20 F20 F20 E20 X G20 F20 G20 X Diethylene Dioxide E20 X F20 G E20 G Diethylene Glycol E50 E50 E50 E50 X E50 E50 E20 E20 E20 E20 Diethylene Glycol Ethyl Ether E20 E20 E20 E E20 E Dimethyl Acetamide E20 E20 F20 E E20 F Dimethyl Formamide E20 E20 E20 E E20 E20 G20 C20 G20 X Dimethylsulfoxide (DMSO) E20 E20 E20 E E20 E20 G x Dioxane E20 X F20 G20 X E20 G20 X X G20 X Dipropylene Glycol E100 E50 E50 E E100 E50 G20 E20 E20 E50 Ethyl Acetate E20 C20 F20 E20 X E20 E20 G20 X G20 X Ethyl Alcohol (Absolute) E20 E20 E20 E20 C20 E20 E20 E20 G20 G20 G20 Ethyl Alcohol, 40% E20 E20 E20 E20 F20 E20 E20 E20 E20 E20 G20 Ethyl Alcohol, 96% E20 E20 E20 E20 C20 E20 E20 E20 G20 G20 G20 Ethyl Benzene E20 X X F20 X E20 X X X X E20 Ethyl Benzoate E20 G20 G20 G E20 C20 X E20 E Ethyl Butyrate E20 C20 F20 G E20 C Ethyl Chloride E20 F20 F20 X C20 E20 F20 X X C20 E20 Ethyl Chloride, Liquid E20 F20 F20 C20 C20 E20 F20 X X C20 E20 Ethyl Cyanoacetate E20 E20 E20 E E20 E Ethyl Lactate E50 E50 E50 E E50 E Ethylene Chloride E20 X X X X E20 X X X C20 G20 Ethylene Glycol E200 E50 E50 E50 E20 E100 E50 E50 E50 E50 E100 Ethylene Glycol Monomethyl Ether E20 G20 E50 E E20 E Ethylene Oxide E20 F20 F20 G20 X E20 C20 C20 X C20 X Fatty Acids E20 E20 E20 E20 C20 E20 E20 G20 C20 C20 G20 Fluorides E20 E50 E50 E E50 E Fluorine E20 X F20 C20 X E20 F20 X X C20 F20 Formaldehyde, 10% E50 E50 E50 E50 X E50 E50 X G20 E20 E20 Formaldehyde, 40% E20 E20 E20 E20 X E20 E20 X G20 E20 G20 Formalin, 10% E20 E20 E20 E E20 E20 G20 G20 E20 E20 Formalin, 40% E20 E20 E20 E E20 E20 G20 G20 E20 E20 Formic Acid, 3% E50 E50 E50 E50 C20 E50 E20 E20 G20 E20 X Formic Acid, 100% E20 E20 E20 E20 X E20 G20 G20 F20 E20 X Formic Acid, 50% E20 E20 E20 E20 X E20 G20 G20 F20 E20 X Formic Acid, 85% E20 E20 E20 E20 X E20 G20 G20 F20 E20 X Freon TF E20 E20 F20 E E20 E20 X C20 X G20 Fuel Oil E20 F20 G20 G20 X E20 F20 X X X F20 Gasoline E20 F20 G20 F20 F20 E20 X X X X E20 Glutaraldehyde E20 E20 C20 E E20 E Glycerine E50 E50 E50 E50 X E50 E50 E20 E20 E20 C20 Glycerol E50 E50 E50 E50 X E50 E50 E20 E20 E20 C20 Hexane E20 G20 F20 G20 G20 E20 X C20 C20 X E20 Hydrazine E20 X X X X E20 X C20 F20 E20 X Hydrobromic Acid, 69% E20 E20 E20 E20 X E20 E20 C20 C20 F20 E20 Hydrochloric Acid, 5% E100 E50 E50 E50 G20 E100 E50 G20 C20 F20 E50 Hydrochloric Acid, 20% E50 E50 E50 E50 C20 E50 E50 C20 C20 F20 E50 Hydrochloric Acid, 35% E20 E20 E20 E20 X E20 E20 X C20 C20 E20 Hydrofluoric Acid, 4% SE100 E20 E20 E20 X E100 E20 X X F20 E20 Hydrofluoric Acid, 48% SE50 E20 E20 E50 X E50 E50 X X F20 G20 Hydrogen Peroxide, 3% E100 E20 E50 E E100 E50 E50 X F20 G
4 Vials and Closures Thermo Scientific Chromatography Columns and Consumables Hydrogen Peroxide, 30% E100 F20 E20 E E100 E50 E20 X C20 G50 Hydrogen Peroxide, 90% E50 F20 E20 E E50 E50 G20 X X G20 Iodine Crystals E20 E20 C20 X --- E20 X E20 C20 F20 E20 Isobutyl Alcohol E20 E20 E20 E20 G20 E20 E20 G20 G20 E20 E20 Isooctane E20 E X X X E20 Isopropyl Acetate E20 G20 G20 E20 X E20 G20 X X F20 X Isopropyl Alcohol, 100% E20 E50 E20 E20 C20 E20 E20 E20 E20 E20 E20 Isopropyl Benzene E20 F20 X F E20 F Isopropyl Ether E20 X X F20 G20 E20 X X X X X Jet Fuel E20 F20 F20 F E20 F20 X X X E20 Kerosene E20 F20 G20 F20 E20 E20 F20 X X X E20 Lacquer Thinner E20 F20 C20 F20 X E20 X X X C20 X Lactic Acid, 3% E50 E50 E20 E50 E20 E50 E20 E20 E20 E20 E20 Lactic Acid, 85% E50 E20 E20 E50 E20 E50 E20 E20 G20 E20 E20 Lead Acetate E50 E50 E50 E50 X E50 E50 X E20 G20 C20 Magnesium Chloride E50 E50 E50 E E50 E50 E20 E20 E20 E20 Mercuric Chloride E20 E20 E20 E E20 E20 E E20 Mercury E20 E20 E20 E20 G20 E20 E20 E20 E20 E20 E20 Methoxyethyl Oleate E50 E20 E20 E E50 E Methyl Acetate E20 G20 E20 C20 X E20 G20 X X F20 X Methyl Alcohol 100% E50 E50 E20 E50 C20 E50 E20 E20 E20 E20 E20 Methyl Ethyl Ketone (MEK) E20 E20 F20 X X E20 X X X G20 X Methyl Isobutyl Ketone (MIBK) E20 G20 C20 X X E20 X X X C20 X Methyl Isopropyl Ketone E20 G20 C20 F20 X E20 X --- X F20 X Methyl-t-Butyl Ether (MTBE) E20 F20 E50 F E20 X F20 X Methylene Chloride (DCM) E20 F20 G20 F20 X E20 X C20 C20 X G20 Mineral Oil E100 F20 E20 F20 E20 E100 C20 E20 X C20 E100 Mineral Spirits E20 F20 E50 F E20 F X X E20 n-amyl Acetate E20 G20 G20 E20 X E20 G20 X X G20 X n-butyl Alcohol E20 E20 E20 E20 G20 E20 E20 G20 E20 E20 E20 n-decane E20 F20 F20 F20 X E20 E20 C20 C20 C20 E20 n-heptane E20 C20 C20 C20 X E20 E20 C20 C20 X E20 n-octane E20 E20 E20 E20 X E20 E20 C20 C20 X E20 Nitric Acid, 10% E20 E50 E20 E20 C20 E20 E20 G20 C20 G20 E20 Nitric Acid, 20% E20 C20 E50 G E20 E C20 F20 E20 Nitric Acid, 50% E20 F20 F20 F E20 G20 C20 X X F20 Nitric Acid, 70% E20 X F20 F E20 G20 X X X C20 Nitrobenzene E20 X F20 X X E20 X X X C20 F20 Nitromethane E20 F20 F20 F20 X E20 X X F20 F20 X o-dichlorobenzene E20 F20 F20 X X E20 F20 X X X E20 Orange Oil E20 G20 C20 G E20 F Oxalic Acid, 10% E20 E20 E20 E20 E20 E20 E20 E20 C20 E20 E20 Ozone E20 F20 E20 C20 G20 E20 C20 E20 C20 G20 F20 p-chloroacetophenone E20 E20 E20 E E20 E p-dichlorobenzene E20 G20 G20 X X E20 F20 X X X E20 Perchloric Acid, Concentrated (70%) E20 C20 C20 C20 X G20 C20 X X F20 G20 Perchloroethylene E20 X X X X E20 X C20 X X E20 Petroleum E100 X G20 C20 G20 E100 X F20 C20 C20 E20 Phenol, 50% E20 X X X X E20 X X X E20 E20 Phenol, Crystals E20 C20 FG G20 X E20 X C20 X E20 E20 Phenol, Liquid E20 X X X X E20 X X X G20 E20 Phosphoric Acid, 5% E100 E50 E50 E50 C20 E100 E50 E20 E20 E20 E20 Phosphoric Acid, 85% SE100 E20 E20 E50 X E100 G20 G20 E20 E20 E20 Picric Acid E20 X E20 X X E20 X X G20 G20 G20 Pine Oil E50 E20 G20 F20 C20 E50 C20 C20 X X E20 Potassium Chloride E300 E50 E50 E50 E20 E100 E50 E50 E50 E50 E
5 Potassium Hydroxide, 10% SE50 E50 E50 C20 C20 E50 E50 E20 E20 E20 C20 Potassium Hydroxide, 30% SE50 E50 E50 E50 C20 E50 E50 E20 E20 E20 X Potassium Hydroxide, Concentrated C100 E50 E50 E50 X E100 E50 E20 E20 E20 X Potassium Permanganate E50 E20 E50 E E50 E50 E E20 Propane Gas E20 X X E E20 X C20 X X E20 Proprionic Acid E20 E20 F20 F E20 F Propylene Glycol E50 E50 E50 E50 E20 E50 E50 E20 E20 E20 E50 Propylene Oxide E20 E20 E20 E20 E20 E20 E20 G20 E20 G20 E20 Pyridine E20 E20 F20 X X E20 X X X F20 X Resorcinol, Sat. E20 E20 E20 E20 C20 E20 E Salicylaldehyde E20 E20 E20 E E20 E E20 Salicylic Acid, Powder E50 E50 E50 E50 E20 E50 E50 E20 E20 E20 E20 Salicylic Acid, Sat. E50 E50 E20 E50 E20 E50 E50 E20 E20 E20 E20 sec-butyl Alcohol E20 E20 E20 E E20 E Silicone Oil E100 E50 E50 E E100 E20 G20 E20 E20 E50 Silver Acetate E50 E50 E50 E E50 E Silver Nitrate E20 E20 E20 E20 E20 E20 E20 E20 E20 E20 E20 Skydrol LD4 E100 E20 E20 E20 F20 E100 G20 C20 X G20 C20 Sodium Acetate, Sat. E50 E50 E50 E50 E20 E50 E50 X G20 G20 E20 Sodium Carbonate E100 E50 E50 E50 E20 E100 E50 E20 E20 E20 E20 Sodium Dichromate E50 E50 E50 E E50 E50 G20 C20 E20 E20 Sodium Hydroxide, 1% F100 E50 E50 C20 E20 E100 E50 E20 E20 E20 G20 Sodium Hydroxide, 10% SE100 E50 E50 E50 G20 E100 E50 E20 E20 E20 C20 Sodium Hydroxide, Concentrated (50%) SE100 E50 E50 E50 G20 E100 E50 E20 E20 E20 C20 Sodium Hypochlorite, 15% E20 F20 E50 E20 X E20 F20 E20 X G20 E20 Stearic Acid E50 E50 E50 G20 E20 E50 E50 E20 X G20 E20 Stearic Acid, Crystals E50 E50 E50 E50 E20 E50 E50 E20 X G20 E20 Sulfur Dioxide, Liquid E20 X X F E20 X E20 C20 F20 C20 Sulfur Dioxide, Wet or Dry Gas E50 E50 E50 E E100 X E20 C20 G20 F20 Sulfuric Acid, 6% E100 E50 E50 E50 G20 E100 E50 F20 E20 E20 E20 Sulfuric Acid, 20% E100 E50 E50 E50 F20 E100 E50 C20 E20 E20 E20 Sulfuric Acid, 30% G100 E50 E50 E50 C20 E100 E50 C20 G20 E20 E20 Sulfuric Acid, 60% SE100 G20 E20 E20 X E100 E20 X X X E20 Sulfuric Acid, 98% SE100 F20 G20 F20 X E100 G20 X X X C20 Tartaric Acid E20 E20 E20 E20 F20 E20 E20 E20 C20 G20 E20 tert-butyl Alcohol E20 E20 E20 E20 X E20 E20 G20 E20 E20 E20 Tetrahydrofuran (THF) E20 G20 C20 F20 X E20 F20 X X X X Thionyl Chloride E20 X X X X E20 X X X X X Tincture of Iodine E50 E50 X G E50 X G20 C E20 Toluene E20 X C20 X X E20 F20 X X C20 F20 Tributyl Citrate E20 G20 G20 E E20 G Trichloroacetic Acid E20 G20 E20 F20 X E20 F20 X C20 F20 C20 Trichloroethane E20 X X X X E20 X X X X G20 Trichloroethylene E20 X X X X E20 X X X X G20 Triethylene Glycol E50 E50 E50 E E50 E E20 E20 E20 Tripropylene Glycol E100 E50 E50 E E100 E Tris Buffer, Solution E100 E20 E20 E20 E20 E100 E20 E20 G20 E20 E20 Trisodium Phosphate E100 E50 E50 E50 E20 E100 E50 E20 E20 E20 E20 Turpentine E20 F20 F20 F20 E20 E20 F20 X X X E20 Undecyl Alcohol E20 E20 E20 E E20 F Urea E50 E50 E20 E50 E20 E50 E50 E20 E20 E20 E20 Vinylidene Chloride E20 X X F E20 X Xylene E20 X X F20 C20 E20 X X X X G20 Zinc Chloride, 10% E100 E50 E50 E50 E20 E100 E50 E20 E20 E20 E20 Zinc Stearate E50 E50 E50 E E50 X Zinc Sulfate, 10% E50 E50 E50 E50 E20 E50 E50 E20 G20 E20 E
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