ZB-5ms GC Columns. Aromatic Compounds

Transcription

1 ZB-5ms GC Columns Enchanced Resolution of Aromatic Compounds

2 ARYLENE MATRIX TECHNOLOGY Traditionally, GC/MS bleed certification had been achieved by incorporating a column s phenyl character into the polymer backbone. These Arylene phases provided similar selectivity to standard phases, but added the stability necessary to reduce bleed. New bonding technologies have allowed companies to produce MS Certified products using non-arylene chemistries, however, selectivity has not always been equivalent. Resolution differences are most commonly observed when analyzing multi-ring aromatics such as PAHs and PCBs. The high molecular weight and rigid bonding, allows certain isomeric configuration to interact better than others. Volts LOW BLEED / FAST CONDITIONING Achieves MS certified bleed level after only 35 minutes! Little to no change in bleed after an additional 30 minutes of conditioning! ms certified Bleed after only 35 min! Passing Bleed Level The Zebron ZB-5ms is the accumulation of more than 5 years of GC column manufacturing experience! We have applied our proprietary Engineered Self Cross-linking (ESC) bonding to an Arylene polymer chemistry and created the new Arylene Matrix Technology. The resulting columns have long lifetime, enhanced selectivity and lower bleed than traditional Arylene products. Try one today and see what Zebron s new Arylene Matrix Technology can do for you! Fig. A Fig. B Application of ESC Bonding Arylene Matrix Technology Traditional Arylene Phase ZB-5ms Peak Skew Sample No min LONG LIFETIME Consistent response after more than 700 samples at ph 2! REPRODUCIBLE RESULTS Column: ZB-5ms Dimensions: 30 meter x 0.25 mm x 0.25 µm GC: HP 5890 Carrier Gas: Hydrogen, 40 C Injection: Split, :00, 250 C,.4 µl Oven Temp: 40 C (isothermal) Detector: 325 C ,4-Dichlorophenol Hexachlorobutadiene Sample:. Decane 2. 2-Ethylhexanoic Acid 3.,6-Hexanediol 4. 4-Chlorophenol 5. Tridecane 6. -Methylnaphthalene 7. -Undecanol 8. Tetradecane 9. Dicyclohexylamine 0. Pentadecane ENGINEERED SELF CROSS-LINKING (ESC) It starts with a careful fractionation of the base polymer resulting in very pure monomodal reactants. After the initial bonding, a second proprietary technique is applied which creates an extensively cross-linked ladder polymer network min Lot 4 Lot 3 Lot 2 Lot

3 OPTIMIZED RUN TIMES EPA Method 8270C : Semivolatile Organic Analysis NON-ARYLENE 5ms vs. Zebron ZB-5ms Column: Standard 5ms Dimensions: 30 meter x 0.25 mm x 0.50 µm Injection: 250 C, µl Carrier Gas: Helium C Oven Program: 50 C (hold 3 min) C/min (Hold 2 min) Detector: 300 C Column: Zebron ZB-5ms Dimensions: 30 meter x 0.25 mm x 0.50 µm Part No.: 7HG-G00-7 Injection: 250 C, µl Carrier Gas: Helium C Oven Program: 50 C (hold 3 min) C/min (Hold 2 min) Detector: 300 C Results in Ret. Time (min) Ret. Time (min). n-nitrosoidimethylamine Pyridine Fluorophenol Benzaldehyde Phenol-d Phenol Aniline bis(2-chloroethyl)ether Chlorophenol-d Chlorophenol ,3-Dichlorobenzene ,4-Dichlorobenzene-d ,4-Dichlorobenzene ,2-Dichlorobenzene-d Benzyl alcohol ,2-Dichlorobenzene Methylphenol Bis(2-chloroisopropyl)ether Acetophenone Methylphenol Methylphenol N-Nitroso-di-n-propylamine Hexachloroethane Nitrobenzene-d Nitrobenzene Isophorone Nitrophenol ,4-Dimethylphenol Bis(2-Chloroethoxy)methane Benzoic Acid ,4-Dichlorophenol Ret. Time (min) Ret. Time (min) 32.,2,4-Trichlorobenzene Naphthalene-d Naphthalene Chloroaniline Hexachlorobutadiene Caprolactam Chloro-3-methylphenol Methylnaphthalene Hexachlorocyclopentadiene ,4,6-Trichlorophenol ,4,5-Trichlorophenol Fluorobiphenyl Biphenyl Chloronaphthalene Nitroaniline Dimethylphthalate ,6-Dinitrotoluene Acenaphthylene Nitroaniline Acenaphthene-d Acenaphthene ,4-Dinitrophenol Nitrophenol Dibenzofuran ,4-Dinitrotoluene Diethylphthalate Fluorene Chlorophenyl-phenylether Nitroaniline ,6-Dinitro-2-methylphenol n-nitrosodiphenylamine Ret. Time (min) Ret. Time (min) 63.,2-Diphenylhydrazine ,4,6-Tribromophenol Bromophenyl-phenylether Hexachlorobenzene Atrazine Pentachlorophenol Phenanthrene-d Phenanthrene Anthracene Carbazole Di-n-butylphthalate Fluoranthene Benzidine Pyrene Terphenyl-d ,3-Dimethylbenzidine Butylbenzylphthalate Benz[a]anthracene ,3-Dichlorobenzidine Chrysene-d Chrysene bis(2-ethylhexyl)phthalate Di-n-octylphthalate Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Perylene-d Indeno[,2,3-cd]pyrene Dibenz[a,h]anthracene Benzo[g,h,i]perylene Good Resolution of the PAH compounds Phenanthrene/Anthracene, Benzo[a]Anthracene/Chrysene, and Benzo[b]fluoranthene/Benzo[k]fluoranthene considering we were able to shorten the run to an 8min run vs. our typical 29 min run. Chris Hollingsworth, Test America, Analytical Testing Corporation

4 The added resolution offered by the Arylene Matrix Technology allows run times to be shortened by at least %. 5 min vs. 35 min APP ID , I found the column to have exceptional resolution for Benzo[b]fluoranthene and Benzo[k]fluoranthene. Column: Zebron ZB-5ms Dimensions: 30 meter x 0.25 mm x 0.25 µm Order No.: 7HG-G00- Injection: Split 250 C, µl Carrier Gas: Constant Flow Helium.4 ml/min Oven Program: 40 C for 0.5 min to 220 C at 22 C/min to 325 C at 35 C/min for 3 min Detector: MSD; amu Paul McNamara, Severn Trent Labs - Buffalo EPA Method 8270C Done in 5 minutes! min min. N-Nitrosodimethylamine 2. Pyridine 3. 2-Picoline 4. N-Nitrosomethylethylamine 5. Methyl methanesulfonate 6. N-Nitrosodiethylamine 7. Ethyl methanesulfonate 8. Phenol 9. Aniline 0. Bis(2-chloroethyl)ether. 2-Chlorophenol 2.,3-Dichlorobenzene 3.,4-Dichlorobenzene 4. Benzyl Alcohol 5.,2-Dichlorobenzene 6. 2-Methylphenol 7. Bis(chloroisopropyl)ether 8. N-Nitrosypyrrolidone 9. 3-Methylphenol; 4-Methylphenol 20. N-Nitroso-di-n-propylamine 2. Acetophenone 22. N-Nitrosomorpholine Toluidine 24. Hexachloroethane 25. Nitrobenzene 26. N-Nitrosopiperidine 27. Isophorone Nitrophenol 29. 2,4-Dimethylphenol 30. Benzoic Acid 3. Bis(2-chloroethoxy)methane 32. 2,4-Dichlorophenol 33.,2,4-Trichlorobenzene 34. Naphthalene 35. a,a-dimethylphenylamine Chloroaniline 37. 2,6-Dichlorophenol 38. Hexachloropropene Ret. Time (min) Hexachloro-,3-butadiene 40. N-Nitrosodibutylamine 4.,4-Phenylenediamine Chloro-3-methylphenol 43. Safrole 44. -Methylnaphthalene Methylnaphthalene 46. Hexachlorocyclopentadiene 47.,2,4,5-Tetrachlorobenzene 48. Isosafrole (isomer) 49. 2,4,6-Trichlorophenol 50. 2,4,5-Trichlorophenol 5. Isosafrole (isomer) Chloronaphthalene Nitroaniline 54.,4-Naphthoquinone 55. Dimethyl phthalate 56.,3-Dinitrobenzene 57. 2,6-Dinitrotoluene 58. Acenaphthylene Nitroaniline 60. Acenaphthene 6. 2,4-Dinitrophenol Nitrophenol 63. Pentachlorobenzene 64. 2,4-Dinitrotoluene 65. Dibenzofuran 66. -Naphthalenamine 67. 2,3,4,6-Tetrachlorophenol Naphthalenamine 69. Diethyl Phthalate 70. Fluorene 7. 2-Methyl-5-nitroaniline Chlorophenyl phenyl ether Nitroaniline 74. 4,6-Dinitro-2-methylphenol 75. Diphenylamine 76. Azobenzene Ret. Time (min) ,3,5-Trinitrobenzene 78. Phenacetin Bromophenyl phenyl ether 80. Hexachlorobenzene 8. Pentachlorophenol Aminobiphenyl 83. Pentachloronitrobenzene 84. Dinoseb 85. Phenanthrene 86. Anthracene 87. Dibutyl phthalate Nitroquinoline-n-oxide 89. Methapyriline 90. Isodrin 9. Fluoranthene 92. Benzidine 93. Pyrene 94. Aramite 95. Aramite (isomer) 96. Dimethylaminoazobenzene 97. Chlorobenzilate 98. 3,3-Dimethylbenzidine 99. Benzyl butyl phthalate 00. Kepone 0. 2-Acetylaminofluorene 02. 3,3-Dichlorobenzidine 03. Benz[a]anthracene 04. Bis(2-ethylhexyl) phthalate 05. Chrysene 06. Di-n-octyl phthalate 07. Benzo[b]fluoranthene 08. Benzo[k]fluoranthene 09. Benzo[a]pyrene 0. 3-Methylcholanthrene. Indeno[,2,3-cd]pyrene 2. Dibenz[a,h]anthracene 3. Benzo[g,h,i]perylene Ret. Time (min)

5 IMPROVED RESOLUTION The ZB-5ms Arylene Matrix Technology provides improved resolution of critical isomeric pair. Zebron ZB-5ms vs. J&W DB-5ms EPA Method 60: Polyaromatic Hydrocarbons (PAHs) vs. Dimensions: 30 meter x 0.25 mm x 0.25 µm Injection: Split 250 C, 0.5 µl Carrier Gas: Constant Pressure ml/min 40 C) Oven Program: 40 C (hold 2 min) to C/min, to C/min, to C/min (hold until last peak elutes) Detector: 325 C Sample: EPA 60 2,000 ppm Conditions same for both columns Zebron ZB-5ms Almost 90 % Resolution with Zebron ZB-5ms 7 min Benzo[b]fluoranthene 2. Benzo[k]fluoranthene J&W DB-5ms min % Resolution with J&W DB-5ms. Naphthalene 2. Acenaphthylene 3. Acenaphthene 4. Fluorene 5. Phenanthrene 6. Anthracene 7. Fluoranthene 8. Pyrene 9. Benz[a]anthracene 0. Chrysene. Benzo[b]fluoranthene 2. Benzo[k]fluoranthene 3. Benzo[a]pyrene 4. Indeno[,2,3-cd]anthracene 5. Dibenz[a,h]anthracene 6. Benzo[g,h,i]perylene 7 min. Benzo[b]fluoranthene 2. Benzo[k]fluoranthene min

6 ORDERING INFORMATION Zebron ZB-5ms ID (mm) df (µm) Temp. Limits ( o C) Order No. 0-Meter to 325/350 7CB-G Meter to 325/350 7EG-G00-20-Meter to 325/350 7FD-G to 325/350 7FD-G to 325/350 7FD-G Meter to 325/350 7HG-G to 325/350 7HG-G to 325/350 7HG-G to 325/350 7HM-G to 325/350 7HM-G to 325/350 7HM-G Meter to 325/350 7KG-G to 325/350 7KM-G00- Zebron ZB-5ms GUARDIAN ID (mm) df (µm) Temp. Limits ( o C) Order No. 5-Meter with 0-Meter GUARDIAN to 325/350 7EG-G00--GGC 30-Meter with 5-Meter GUARDIAN to 325/350 7HG-G00--GGA to 325/350 7HG-G00-7-GGA to 325/350 7HM-G00-22-GGA 30-Meter with 0-Meter GUARDIAN to 325/350 7HG-G00--GGC to 325/350 7HG-G00-22-GGC Test Mix Zebron ZB-5ms AG If Zebron does not provide you with equivalent separations as compared to any other GC column of the same phase and comparable dimensions, send in your comparative data within 45 days and keep the Zebron column for FREE! Trademarks Zebron, Arylene Matrix Technology, and Engineered Self Cross-linking (ESC) are registered trademarks of Phenomenex, Inc. Disclaimers J & W is a registered trademark of Agilent Technologies. All comparisons were done using new columns and similar testing conditions. Standard non-arylene 5ms product depicted is the Zebron ZB-5. Subject to Phenomenex Standard Terms and Conditions, which may be viewed at /termsandconditions Phenomenex. All rights reserved. Phenomenex products are available worldwide. For the distributor in your country, contact Phenomenex USA, International Department at international@phenomenex.com. Australia t: f: auinfo@phenomenex.com Canada t: (800) f: (30) info@phenomenex.com Germany t: f: anfrage@phenomenex.com Luxembourg t: +3 (0) f: +3 (0) nlinfo@phenomenex.com Puerto Rico t: (800) 54-HPLC f: (30) info@phenomenex.com Austria t: f: anfrage@phenomenex.com Denmark t: f: dkinfo@phenomenex.com Ireland t: f: eireinfo@phenomenex.com Netherlands t: f: nlinfo@phenomenex.com United Kingdom t: f: ukinfo@phenomenex.com Belgium t: +3 (0) f: +3 (0) beinfo@phenomenex.com France t: f: franceinfo@phenomenex.com Italy t: f: italiainfo@phenomenex.com New Zealand t: f: nzinfo@phenomenex.com All other countries: Corporate Office USA t: (30) f: (30) info@phenomenex.com 686_I_