IH 2 Technology: Hydrocarbon Fuels from Bio-Waste An Integrated Energy-Environmental solution

Transcription

1 IH 2 Technology: Hydrocarbon Fuels from Bio-Waste An Integrated Energy-Environmental solution Biofuels and Bioenergy: Enablers for Reducing Oil Import Dependence organised by Petrofed, New Delhi, May 2016 Dr. C.S. Laxmi Narasimhan, FRSC General Manager, STCB Dr Alan Del Paggion, VP-Upstream & Renewables, CRI USA Integrated Hydropyrolysis & Hydroconversion IH 2 is a registered trademark of GTI 5/11/2016 1

2 Disclaimer CRI, Criterion and Shell Global Solutions are the trade names of a network of independent technology companies in the Shell Group. Where a company is identified by its trade name or Shell, the reference is used for convenience, or may be used where no useful purpose is served in referring to the company by name. The services and products of these companies may not be available in certain countries or political subdivisions thereof. The information contained in this presentation is provided for general information purposes only and must not be relied on as specific advice in connection with any decisions you may make. No representations or warranties, express or implied, are made by the company or companies presenting these materials or its affiliates concerning the applicability, suitability, accuracy or completeness of the information contained herein and these companies do not accept any responsibility whatsoever for the use of this information. The companies presenting these materials and their affiliates are not liable for any action you may take as a result of you relying on such material or for any loss or damage suffered by you as a result of you taking this action. Furthermore, these materials do not in any way constitute an offer to provide specific services. Copyright 2015 Shell Oil Company. All rights reserved. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical including by photocopy, recording or information storage and retrieval system, without permission in writing from Shell Oil Company or CRI Catalyst Company. 5/11/2016 2

3 IH 2 Technology An Overly Simplified View A highly flexible self-sufficient continuous catalytic thermo-chemical process invented by Gas Technology Institute (GTI) and jointly developed with CRI to which CRI have acquired exclusive license rights. IH 2 technology takes only minutes to achieve what Nature requires millions of Cellulose years to Uses catalysts, hydrogen and heat in proven refinery hardware to cost effectively 1 convert forestry, agricultural and sorted municipal wastes into fungible hydrocarbon transportation fuels petrol, kero and diesel together with char, fertilizer, water and CO USD/gallon FPMC; MM Capex 500 tonne/d standalone tonne/d integrated; No RINs, no credits included Heat 400C +H 2 catalyst But it does her one better by providing refined fuel -H 2 O Molecules Are Identical to Those in Fossil Fuels 5/11/2016 3

4 BROAD RANGE OF FEEDSTOCKS DROP-IN FUELS, BLEND STOCKS IH 2 : the difference Hydrogen can make The IH 2 technology is a catalytic thermochemical process that converts biomass directly to high purity hydrocarbon fuels and/or blend stocks with GHG reductions >65% & High energy content recovery (~70%) in all configurations, and it is cost effective at small scale (<1000 t/d). FEED Municipal Waste (up to 15% plastic) PROCESS SELF-SUFFICIENT IN H 2, LOW CAPITAL COST Feed conditioning sizing, drying & feeding PRODUCTS Distilled Hydrocarbons Biogenic CO 2 Crop Residue Wood/Forest Residue Energy Crops Algae HYDROPYROLYSIS in fluidized bed! Renewable H 2 Separation HYDROTREATING in fixed bed LOW PRESSURE, NO CORROSIVE INTERMEDIATES, COMMERCIAL PROCESS ELEMENTS High Pressure Steam Clean Water Fertilizer BioChar April

5 1 st Stage Reactor Hydropyrolysis Light Gas IH 2 Process (Simplified) MSW Sorting, Drying, Sizing, Pelletisation Renewable H 2 SMR Exports Biogenic CO 2 High Pressure Steam BioChar Hydrocarbon Fuel NH 3 Fertilizer Concentrate S Fertilizer Cyclones Gas Clean Up Sized & Dried/Pelletised Lock Hoppers BioChar Removed 2 nd Stage Reactor Hydroconversion Phase Separation Water Water Clean Up Distillation Gasoline Jet Diesel BioChar 5/11/2016 5

6 Greenfield Process 3D Render 5/11/2016 6

7 1 st Stage Reactor Hydropyrolysis Light Gas Refinery, Hard Assets Integration H 2 SMR Bulk Operations Gas Clean Up Cyclones Sized & Dried Lock Hopper s BioChar Removed 2 nd Stage Reactor Hydroconversion Phase Separation Water Water Clean Up Distillation Gasoline Jet Diesel BioChar 5/11/2016 7

8 Heat LP Steam or Power LP Steam / Power Char Paper Mill, Hard Assets Integration Char Boiler/ Co-Gen Power to grid Wood Yard Handling, storage, chipping, drying, hammer milling LP Steam / Heat Biomass Feedstock Fuel 90 gal/ton MAF 65% gasoline/ 35% diesel Chips Paper Process Digestion, refining, washing, paper machines Multiple uses for low-grade heat or power Paper 5/11/2016 8

9 Sugar Mill, Hard Assets Integration Cane Trash/ Sugar Cane Tops Sugar Cane Sugar Factory Enhanced Energy Integration Sugar Molasses Bagasse Hot water Char Fuels Boiler LP Steam Co-Gen HP Steam Sale to grid 5/11/2016 9

10 Product Quality Evolution via New Catalysts Catalysts alone improve product fuel quality from wood at Lab Scale Total Liquid Product 1 st Gen Catalysts Total Liquid Product 2 nd Gen Catalysts Gas/Jet/Diesel Product 3 rd Gen Catalysts Jet/Diesel Product 4 th Gen Catalysts Hydrocarbon Hydrocarbon Water Water 4Q09 R5 3Q10 R25 2Q12 R60+ 1Q14 R100 10

11 Feed and Products Agri & MSW 5/11/

12 Products from 4 th Generation Catalysts Finished gasoline (left), Finished diesel (middle) and water product (right) all produced using CRI 4 th Generation catalyst systems 5/11/

13 Current IH 2 Process Fuel Quality US - Gasoline Meets ASTM D b 86 Octane w/ E10 S < 10-ppm Fully renewable RBOB EU Petrol EN 228: Petrol Jan 2009 RON 87 vs 95 S ~10-ppm Blend Stock World-wide Civil Jet Fuel Grade Meets global Jet A-1 specs analyzed to date S < 2-ppm Freezing Point BDL No napthalenes Low aromatics SPK Ability to allow aromatics US - Diesel Meets ASTM D Cetane Number 44 S < 10-ppm EU Diesel EN 590:2009+A1:2010 Cetane Number 48 S <15-ppm Blend Stock 5/11/

14 Focus Karnataka Through Examples Agricultural Waste Example: *7.9 Million tonnes/a Municipal Waste Example *1.56 million tonnes/a Total waste for all districts wt% 0.6 million tonnes/a total biomass component 28wt% Bagasse Rice Cotton Ragi+Jowar Maize Others 2.1 million tonnes/a transportation fuel 0.16 million tonnes/a transportation fuel * TERI Report 2012IB09 14

15 Focus India Through Examples Agricultural Waste Example: *199 Million tonnes/a Municipal Waste Example *60 million tonnes/a wt% Bagasse Rice Cotton Wheat Maize Others 55.7 million tonnes/a transportation fuel 36.6 million tonnes/a 28wt% 10.3 million tonnes/a transportation fuel *Internal Shell Report

16 Reduce GHG emissions & Dependency on Petroleum imports CASE I- CURRENT STATUS CO 2 + Toxic gases 200 million tonnes of waste biomasswastefully incinerated in India Generates large CO 2, and other pollutants 80 million tonnes per year imported CASE II- IH 2 OUTLOOK Potential to reduce petroleum imports by four times Potential to produce 60 million tonnes per year Reduced CO 2 emissions Date 5/11/ million tonnes per year imported 16

17 Positive Impact for India Swatch Bharat, Energy Independence & Make in India IH 2 process provides farmers, municipalities and the energy sector with a cost effective means to: Meet growing energy demands with local resources Reduce overall dependence on imported energy Meet policy obligations Create jobs 1, stimulate domestic investment Stimulate foreign investment Create distributed rural fuel production or Liquify biomass for centralized upgrading Monetize urban/rural wastes Reduce carbon footprint and reduce particulates 2 1 In addition to direct jobs created on site, up to another one hundred indirect jobs could be created in the area of feedstock cultivation, harvesting, transport, fuel transport, sales and equipment manufacturing as most clients will purchase hardware locally. 2 Converting wastes directly to CO 2 versus landfilling where a portion will produce CH4 a 20x more potent GHG. Also, converting agri residues to fuel vs burning in field reduces particulates. 17

18 Road Map to Deployment in India Create / enhance biomass pre-treatment facilities at source for shipment Sorting, drying, sizing and pelletization Demonstration of IH 2 Technology Q Commercial scale IH 2 Technology tonne/day - subsequently When technology is proven, transition to local fabrication Make in India Biomass feed stock diversity marketing and management Talent Development: Engineers/ Scientists (Chemists, Biologists)/ Plant Technicians will be required to take forward this technology for a variety of applications 5/11/

19 Dollars Risked Status India is the home for the Shell demonstration unit and a contender for first commercial deployment of IH 2 technology. CRI is also deploying in North America, Northern and Western Europe, ANZAC, SE Asia and China Prove the Reliability & Profitability Prove the Engineering & Hardware 2,000L/day 3D IH ,000L/day 3D IH 2-500tpd 0.02L/day Bangalore EE 2 nd Stage Test Prove the Science 1L/week Bangalore MBU 20L/day Chicago IH 2-50 Pilot Plant Scale 5/11/

20 IH 2-50 C4+ Liquids Production /11/2016 Total

21 Architect s View of NTC Bengaluru 5/11/

22 IH 2 5 tonne/day Process Demo (Simplified) Goals of NTCB Showcase Plant Technology demonstration Continuous technology improvement Generating fuel for trials and certification 5/11/

23 Alliance Partners Process design, process assurance, intellectual property rights, MBU (0.5kg/hr semi continuous) and IH 2-50 pilot (50kg/d continuous) scale testing. Experimental fluidization dynamics, cold flow modeling, solids handling. Exclusive FEED provider for the IH 2 process at commercial scale. Supplier of reformer technology for 1000 tonne/day and above. Suppliers of wood yard technology and biomass drying/sizing Exclusive FEED provider for the IH 2 process at 5mt/d feed and below. Turnkey provider of Bangalore MBU and EEFB units, GTI IH Supplier of reformer technology for 500 tonne/day plants and below Hydrocarbon fuel specifications, qualifications, process safety and design considerations, demonstration unit funding and site host, etc Financial support. Engine testing partner to perform required emissions and engine testing Solids handling experts, lock hopper designs Regulatory agency for D-code pathways, emissions guidelines, etc. Consent needed prior to sale of IH 2 fuels in US. LCA support, Prof Shonnard 5/11/

24 Thank You! 5/11/