AC Reformulyzer M3. 75 Minutes Full Gasoline Analysis. Compliance with ASTM D 6839, EN and ISO Self Explanatory Operation

Transcription

1 AC Reformulyzer M3 75 Minutes Full Gasoline Analysis Compliance with ASTM D 6839, EN and ISO Self Explanatory Operation Integrated Diagnostics ONE WORLD ONE COMPANY ONE TEAM

2 2 AC Analytical Controls pioneered, developed and optimized the AC Reformulyzer application, which is used globally by nearly all refineries. The latest generation Reformulyzer Mark 3 (M3) provides complete identification and quantification of all hydrocarbon types, oxygenates, and carbon number distribution with numerous features, including the following: Full gasoline analysis in 75 minutes in compliance with ASTM D 6839, EN 14517, IP 566 and ISO Easy to use Self explanatory operation providing: - intuitive user interface - automated validation thru quality control samples with the integrated diagnostic tool - analysis simulation program Automated conditioning programs for columns and traps Available on the Agilent Technologies 7890A All flows and pressures are fully controlled electronically Large installed base: major oil companies, R&D labs, independent labs and government agencies Easy parts replacement thru the use of dedicated connectors Columns and traps with extended lifetime AC User Group enables users to share technical knowledge and optimize performance A global network of AC certified support engineers commissions the system on-site in one day

3 75 Minutes Full Gasoline Analysis The Reformulyzer M3 analysis is based on a multi-dimensional column switching technique. After sample introduction, a set of columns and traps separates the sample into different hydrocarbon groups. The multi-dimensional technique determines carbon number distribution for each group, e.g., Paraffins, Olefins, Naphthenes, Aromatics or Oxygenates. Incorporated Standard Test Methods The Reformulyzer M3 complies with accepted international standard test methods, including: ASTM D 5443, (D 6293), D 6839 IP 382, (526), 566 UOP 870 ISO Reports Fuel Specifications EN228 now includes the EN ISO (Multidimensional GC, Reformulyzer) as Referee Method for Hydrocarbon content (Olefins & Aromatics), Benzene, Oxygenates and Oxygen content. It therefore replaces FIA (EN15553) for Hydrocarbon content, EN12177 for Benzene and EN1601 for Oxygenates. 3 AC Reformulyzer M3 analysis of gasoline in 75 minutes

4 Analysis Simulation Program Self-explanatory operation Training Tool AC developed the Reformulyzer M3 Analysis Simulation Program to train users in the multi-dimensional technique. The program demon strates sample separation through various columns and traps integrated into the software. 4 The simulation program shows the analysis sequence step-by-step. Simultaneously the elution pattern can be observed in the chromatogram. System Maintenance All traps have dedicated connectors for easy parts replacement.

5 Integrated Diagnostic Tool Automates validation AC has developed a set of quality control (QC) samples and an integrated diagnostic tool to validate the Reformulyzer M3 s performance. After analysis of the QC samples, the diagnostic tool reports validation and statistical data for: a specific analysis a series of analyses over a longer period The diagnostic tool will automatically mark results outside specification limits. You will find these marked results in the on-screen report. The diagnostic tool also advices on possible causes for components exceeding the limits and reviews data for trend recording. Analysis viewer Quality Control Samples Besides the gravimetric PIONA standards, AC offers a set of quality control samples that covers most light petroleum streams: Reformer feed Reformate FCC naphtha Gasoline containing MTBE Oxygenates free gasoline Gasoline containing Ethanol Gasoline containing ETBE & Ethanol 5 AC Reformulyzer M3 on-screen report The diagnostic tool also advices on possible causes for components exceeding the limits. Special filtering options AC Reformulyzer M3 Diagnostic Tool

6 6 Wide Range of Report Options Hydrocarbon type concentrations by carbon number in weight% and liquid volume% Oxygenated component concentrations in weight% and liquid volume% as specified by EN 228 Benzene, Total Aromatics, Total Olefins and Total Saturates in liquid volume%; Oxygen in weight%, Oxygenates in liquid volume% The AC Reformulyzer M3 offers several options to report hydrocarbon types and oxygenates and add special calculations. Density in g/ml, kg/m3 and lb/gal Average molecular weight RON/MON calculation for the PIONA mode C:H:O ratio and Calorific Value Excellent LIMS connectivity: upload the results directly to your LIMS or manually after approval Operator Acquired On Processed On Sample Name SampleGroup Sample Type Instrument Method Analysis Conditions AC Reformulyzer M3 report options reformulyzer 048 Winterspec : C:\Chem32\1\DATA\D1002\048 Winterspec4.d : Admin Vial : 104 : 2/17/2010 1:30:25 PM Inj Volume : 0,1 μ l : 2/17/2010 1:30:29 PM : : 048 Winterspec : Winterspec EtOH/ETBE : Winterspec ETBE Reference Name : 048 Gasoline N lot 004 : Winter02 Reference Number : C A 3.4 EthAlcSep 110 B 5.3 OlefinSep1 100 E 2.5 OlefinSep2 150 Normalized weight percent results C-nr Naph. Paraf. Cycl Ol. Olef. Arom. Oxyg. Total Poly Total Normalized volume percent results C-nr Naph. Paraf. Cycl Ol. Olef. Arom. Oxyg. Total Poly Total Oxygenates results Oxygenate Wt% LV% O2% ETBE Ethanol Total EN / ASTM D 6839 Benzene Total Aromatics Total Olefins Total Oxygenates Total Saturates Total Oxygen 0.81 LV% LV% LV% LV% LV% 1.89 Wt% Excellent LIMS connectivity Report of a Winterspec analysis

7 AC User Group Optimizes analyzer performance Reformulyzer users can join the AC User Group. AC organizes interactive meetings periodically that allow users to share and exchange technical knowledge. An important part of the user group is the Performance Monitoring Program (PMP), a regular round robin anonymous testing program that helps labs verify their analyzer s precision. Results are processed anonymously; AC reports the statistical values and offers suggestions for improving precision. The 2009 PMP test consisted of 4 samples: three gasolines, one high olefinic FCC naphtha. One gasoline contained a relative high ethanol concentration, exceeding the current Fuel specifications limits to prepare the analyzer for possible future market developments. 7 AC Users Group Meeting Performance Monitoring Program samples

8 AMERICAS UNITED STATES PAC Corporate Headquarter 8824 Fallbrook Drive Houston, TX USA Phone: TEST or Fax: EMEAI GERMANY Badstrasse 3-5, P.O. Box 1241 DE Lauda-Königshofen Germany Phone: +49 (0) Fax: +49 (0) FRANCE BP VERSON CARPIQUET Cedex France Phone: +33 (0) Fax: +33 (0) THE NETHERLANDS Innsbruckweg AG Rotterdam The Netherlands Phone: +31 (0) Fax: +31 (0) RUSSIA & CIS Shabolovka street, 34, Bldg , Moscow, Russia Phone: Fax: UAE Villa#8/1, Street#9 Al Karama District P.O.Box Abu Dhabi, United Arab Emirates Phone: Fax: ASIA SINGAPORE 61, Science Park Road #03-09/10 The Galen Singapore Science Park III Singapore Phone: Fax: Features & Benefits of AC Reformulyzer M3 Full gasoline analysis in 75 minutes in compliance with ASTM D 5443, (D 6293), D 6839, IP 382, (526), 566, UOP 870 and ISO European gasoline specifications (EN 228) include the EN ISO (multidimensional GC, Reformulyzer ) as referee method for Hydrocarbon content (Olefins and Aromatics), Benzene, Oxygenates and Oxygen content. Analysis simulation program to support ease of operation Automated validation thru quality control samples with the integrated diagnostic tool Available on the Agilent Technologies 7890A Easy parts replacement thru the use of dedicated connectors Automated conditioning programs for columns and traps Large installed base: major oil companies, R&D labs, independent labs and government agencies Report options include hydrocarbon type and oxygenate concentrations by carbon number and special calculations Excellent LIMS connectivity: upload the results directly to your LIMS or manually after approval AC User Group allows users to share and exchange technical knowledge A global network of AC certified support engineers commissions the system on-site in one day One year hardware and application warranty includes free helpdesk Optional on-line remote support by LAN connection is available CHINA Rm.1003, Sunjoy Mansion No.6 RiTan Rd. ChaoYang District, Beijing P.R. China Phone: ext 370/371/372/373/375 Fax: THAILAND 25 Floor, M. Thai Tower, All seasons place 87 Wireless Road, Lumpini Phatumwan Bangkok Thailand Phone : Fax : SOUTH KOREA World Vision Building # Youido-dong, Youngdeungpoku Seoul Korea Phone: Fax: copyright by PAC L.P. All Rights Reserved