The development of VOCs emission inventory in Thailand Jariya Sukhapan (Ph.D.) Pollution Control Department Thailand
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1 The development of VOCs emission inventory in Thailand Jariya Sukhapan (Ph.D.) Pollution Control Department Thailand Emission inventory development The emission inventory is used to identify significant emission source category for effective formulation of regulations and standards Provide data for integrated evaluation of VOCs emission and ambient monitoring resulted VOCs 1
2 The characteristics of emission inventory Based year : 2005 Area : Thailand Pollutants : VOCs Source categories : stationary point sources, mobile sources Temporal resolution : tonnes/year The selection of VOCs 44 VOCs compounds according to the analysis method of US.EPA TO 14 3 additional compounds Formaldehyde Acetaldehyde Ethylene oxide VOCs 2
3 Summary of VOCs inventory development Phase 1 st 2 nd 3 rd No. of VOCs to be studied No. of VOCs to be selected Level of data collected National level (import, export, production, consumption) Specific to source sector (questionaire, estimated by EF) Door to door survey Source testing data From 1 st phase : Benzene VOCs 3
4 VOCs consumption ( ) VOCs 1) VOCs used in high volumes Vinyl chloride 1,2-Dichloroethane Benzene Toluene p-xylene Styrene Acrylonitrile Butadiene Range of consumption volume (tonnes/year) 106, , , , , , , , ,347 1,022,834 44, ,518 92, , , ,036 VOCs consumption ( ) VOCs 2) VOCs used in lower volumes Chloroform Trichloroethylene Ethyl benzene Dichloromethane Tetrachloroethylene Benzyl chloride p-dichlorobenzene Formaldehyde Ethylene oxide Range of consumption volume (tonnes/year) ,797 7, ,276 10,907 1,069 1, VOCs 4
5 VOCs consumption ( ) 3) VOCs that are disappearing from the market Carbon tetrachloride 1,2-Dibromoethane Acetaldehyde VOCs Range of consumption volume (tonnes/year) Toxicity Criteria of selecting VOCs compounds carcinogenicity, Inhalation chronic toxicity Possibility of exposure Amount presented in the environment Production and import volume in 2005 toxicity Detected values in ambient monitoring VOCs 5
6 l 2 nd Phase inventory 20 selected VOCs are Vinyl chloride 1,2-dichloroethane Benzene Benzyl chloride Ethylbenzene Carbontetrachloride Toluene Acrylonitrile Dichloromethane Trichloroethylene p-xylene 1,3-butadiene Tetrachloroethylene 1,2-dibromoethane Styrene Acetaldehyde p-dichlorobenzene Ethylene oxide Chloroform Formaldehyde VOCs 6
7 2 nd Phase inventory Activity data was collected and multiplied with EF from US.EPA FIRE data base Also used US.EPA L&E report and Japanese PRTR as the reference for judging the potential sources in Thailand Example of FIRE data base VOCs 7
8 Example of Benzene PRTR From 2 nd phase : Benzene emission sources Mainly from the mobile source Gasoline storage and transportation 16% Other sources 1% Industrial combustion source 6% Mobile source 77% Total emission = 2,048.1 ton/year VOCs 8
9 From 2 nd phase : Trichloroethylene emission sources Mainly from the industrial process Conveyorized vapor degreasing (uncontrol) 6% Conveyorized vapor degreasing (control) 12% Open-top vapor degreasing (uncontrol) 14% Open-top vapor degreasing (control) 1% Cold solvent cleaning (control) 50% Cold solvent cleaning (uncontrol) 17% Total emission = 5,090 ton/year From 2 nd phase : Toluene emission sources Mainly from the industrial process Gasoline storage 1% Dryer of synthetic rubber production, uncontrol 4% Belt filter press of sew age treatment plant 1% Vehicle 16% Total emission = 22,200 ton/year Surface coating w ith paint, uncontrol 78% VOCs 9
10 From 2 nd phase : Ethylbenzene emission sources Mainly from vehicles NG fired cogen.turbine 8% Asphalt production 3% Ex.Boiler (Pulvarized lignite) tangential fired, control Ex.Boiler in electric 1% gen.(bituminous coal),control 0% Total emission = 106 ton/year Vehicle 88% From 2 nd phase : Dichloromethane emission sources Mainly from the industrial process Cold solvent cleaning/stripping,uncontrol 5% Conveyorized vapor degreasing, uncontrol 1% Open top degreasing, uncontrol 1% Polyurethane products, foaming agent used, act.carbon adsorption control 7% Cold solvent cleaning/stripping, act.carbon adsorption control 18% Conveyorized vapor degreasing 21% Total emission = 4,360 ton/year Surface coating of automobile,uncontrol 26% Cold solvent cleaning/stripping,control 21% VOCs 10
11 From 2 nd phase : Tetrachloroethylene emission sources Mainly from the industrial process Cold solvent cleaning/stripping (uncontrol) 11% Dry cleaning (condenser control) 4% Open-top vapour degreasing, uncontrol 13% Dry cleaning (carbon adsorption control) 72% Total emission = 765 ton/year From 2 nd phase : Acetaldehyde emission sources Mainly from the vehicles Furniture manufacturing 30% Sewage treatment 2% Organic Acid manufacturing 0% Vehicle 68% Total emission = 1,000 ton/year VOCs 11
12 VOCs to be studied intensively in 3 rd Phase Vinyl Chloride Ethylene dichloride Benzene Trichloroethylene Tetrachloroethylene Dichloromethane Data supporting for the development of emission Control strategies Benzene VOCs Trichloroethylene Tetracholoroethylene Dichloromethane Vinyl chloride 1,2 Dichloroethane Benzene/Gasoline storage tank Gas station Combustion in Industries Dry Cleaning Type of Factory Degreasing facility and other related facilities Chemical / PVC Production VOCs 12
13 Special thanks Pollution Control Department, Thailand Japan International Cooperation Agency U.S.Environmental Protection Agency Maptaput IEAT Thank You VOCs 13
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