V 7.0. Restricted Substances List. All Product Divisions AG & TI / All Main Product Groups

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1 Status: Valid from: Valid for: Released Season S19SR All Product Divisions AG & TI / All Main Product Groups Created by: Released by: Team Product Risk Management Head of Product & Vendor Sustainability 2018 HUGO BOSS AG

2 Table of Contents LEGEND / ABBREVIATIONS 3 RESTRICTED SUBSTANCES 4 ACETOPHENONE AND 2-PHENYL-2-PROPANOL 4 ALKYLPHENOL (AP) AND ALKYLPHENOLETHOXYLATES (APEOs), INCLUDING ALL ISOMERS 4 AZO-AMINES 5 BISPHENOL-A 5 CHLORINATED PARAFFINS 6 CHLOROPHENOLS 6 CHLORORGANIC CARRIERS 6 DIMETHYLFORMAMIDE 7 DIMETHYLFUMARATE 7 DYES, FORBIDDEN AND DISPERSE 8 DYES, NAVY BLUE 9 FLAME-RETARDANTS 9 FLUORINATED GREENHOUSE GASES 10 FORMALDEHYDE 10 HEAVY METALS 10 MONOMERS 12 N-NITROSAMINE 13 ORGANOTIN COMPOUNDS 13 ORTHO-PHENYLPHENOL 13 OZONE-DEPLETING SUBSTANCES 13 PERFLUORINATED AND POLYFLUORINATED CHEMICALS (PFCs) 14 PESTICIDES, AGRICULTURAL 14 PHTHALATES 17 POLYCYCLIC AROMATIC HYDROCARBONS (PAHS) 18 VOLATILE ORGANIC COMPOUNDS (VOCs) 19 Page HB_RSL_E_V7.0 2 / 19

3 LEGEND / ABBREVIATIONS AFIRM CADS CAS CEN C.I. DIN EN EPA ISO ISO/TS mg/kg MI ppm pren REACH Reporting limit RSL SVHC Usage ban S19SR w/o µg/cm 2 µg/cm 2 /week The AFIRM Group (Apparel and Footwear International RSL Management Group) is a voluntary association of brands who have the aim to reduce the use and impact of harmful substances in the apparel and footwear supply chain. Therefore the group developed a and a Toolkit to reach the aim. The HUGO BOSS & Product Compliance is based on the AFIRM RSL. Cooperation at DSI (Deutsches Schuhinstitut) Chemical-Abstract-Service; Unique numerical identifiers for chemical elements, compounds, polymers, biological sequences, mixtures and alloys Comité Européen de Normalisation Color Index; Compendium of dyes: In the U.K. the color Index was prepared by the Society of Dyers and Colorists, while in USA it is done by American Association of Textile Chemists and Colorists. Deutsches Institut für Normung European Norm (US) Environmental Protection Agency International Society for Standardization International Society for Standardization/Technical Specification milligram per kilogram Material Information parts per million Draft European Norm Registration, Evaluation, Authorization and Restriction of Chemicals Values equal or higher than this limit have to be documented in the test report s of Very High Concern must not be used intentionally in any production of the product Season: Summer 2019 Spring Summer without microgram per square centimeter microgram per square centimeter per week HB_RSL_E_V7.0 3 / 19

4 RESTRICTED SUBSTANCES Acetophenone ACETOPHENONE AND 2-PHENYL-2-PROPANOL Phenyl-2-propanol 50 ppm each [reporting limit 25 ppm] ALKYLPHENOL (AP) AND ALKYLPHENOLETHOXYLATES (APEOs), INCLUDING ALL ISOMERS Potential breakdown products in EVA foam when using dicumyl peroxide as a crosslinking agent. Extraction in acetone or methanol GC/MS, sonication for 30 minutes at 60 degrees C Nonylphenol (NP), mixed isomers Octylphenol (OP), mixed isomers Total: 100 ppm [reporting limit 10 ppm] APEOs can be used as or found in detergents, scouring agents, spinning oils, wetting agents, softeners, emulsifying/dispersing agents for dyes and prints, impregnating agents, de-gumming for silk production, dyes and pigment preparations, polyester padding and down/feather fillings. Extraction: 1 g sample/20 ml THF, sonication for 60 minutes at 70 C Analysis: EN ISO :2011 Nonylphenol ethoxylates (NPEOs) APs are used as intermediaries in the manufacture of APEOs and antioxidants used to protect or stabilize polymers. Biodegradation of APEOs into APs is the main source of APs in the environment. Octylphenol ethoxylates (OPEOs) Total: 100 ppm [reporting limit 20 ppm] APEOs and formulations containing APEOs are prohibited from use throughout supply chain and manufacturing processes. Because this limit reflects forthcoming EU legislation and was set to provide suppliers with advanced warning and direction for continuous improvement. Textile: EN ISO :2016, determination of AP using LC/MS or GC/MS Leather: EN ISO :2015 HB_RSL_E_V7.0 4 / 19

5 AZO-AMINES Aminobiphenyl Benzidine Chlor-o-toluidine Naphthylamine o-aminoazotoluene Amino-4-nitrotoluene p-chloraniline ,4-Diaminoanisole ,4 -Diaminodiphenylmethane ,3 -Dichlorobenzidine ,3 -Dimethoxybenzidine ,3 -Dimethylbenzidine ,3 -dimethyl-4,4 -diaminodiphenylmethane p-cresidine ,4 -Methylen-bis(2-chloraniline) ,4 -Oxydianiline ,4 -Thiodianiline o-toluidine ,4-Toluylendiamine ,4,5-Trimethylaniline ,4 Xylidine ,6 Xylidine Methoxyaniline (= o-anisidine) p-aminoazobenzene BISPHENOL-A Bisphenol-A (BPA) 20 ppm each [reporting limit 5 ppm] - limits corresponding to AFIRM 1 ppm [reporting limit 1 ppm] Azo dyes and pigments are colorants that incorporate one or several azo groups (-N=N-) bound with aromatic compounds. Thousands of azo dyes exist, but only those which degrade to form the listed cleavable amines are restricted. Azo dyes that release these amines are regulated and should no longer be used for dyeing of textiles. Used in the production of epoxy resins, polycarbonate plastics, flame retardants and PVC. Prohibited from use in food and drink containers, and items intended to come into contact with oral cavity. Textile: EN ISO Leather: EN ISO :2015 p-aminoazobenzene: Textile: EN ISO :2017 Leather: EN ISO :2011 Sample preparation: Extraction: 1 g sample/20 ml methanol, sonication for 60 minutes at 70 C. : DIN EN ISO :2011 (mod) HB_RSL_E_V7.0 5 / 19

6 CHLORINATED PARAFFINS Short-chain chlorinated Paraffins (SCCP) (C10-C13) 1000 ppm [reporting limit 100 ppm] Medium-chain chlorinated Paraffins (MCCP) (C14-C17) CHLOROPHENOLS ,3,4-Trichlorophenol ,3,5-Trichlorophenol ,3,6-Trichlorophenol ,4,5-Trichlorophenol ,4,6-Trichlorophenol ,4,5-Trichlorophenol ,3,4,5-Tetrachlorophenol (TeCP) ,3,4,6-Tetrachlorophenol (TeCP) ,3,5,6-Tetrachlorophenol (TeCP) Pentachlorophenol (PCP) CHLORORGANIC CARRIERS Chlorotoluene Chlorotoluene Chlorotoluene ,3-Dichlorotoluene ,4-Dichlorotoluene ,5-Dichlorotoluene ,6-Dichlorotoluene ,4-Dichlorotoluene ,3,6-Trichlorotoluene ,4,5-Trichlorotoluene ,3,4,5-Tetrachlorotoluene ,3,4,6-Tetraclorotoluene ,3,5,6-Tetrachlorotoluene 1000 ppm [reporting limit 100 ppm] 0,5 ppm each Total: 1 ppm [reporting limit 0,2 ppm] May be used as softeners, flame retardants or as fat liquoring agents in leather production. Also used as plasticizer in polymer production. Chlorophenols are polychlorinated compounds used as preservatives or pesticides. Pentachlorophenol (PCP) and Tetrachlorophenol (TeCP) are sometimes used to prevent mold and kill insects when growing cotton and when storing/transporting fabrics. PCP and TeCP can also be used as preservatives in print pastes. Chlorobenzenes and Chlorotoluenes (chlorinated aromatic hydrocarbons) can be used as carriers in the dyeing process of polyester or wool/polyester fibers. They can also be used as solvents. Combined CADS 1 / ISO 18219:2015 method V1:06/17 (extraction by ISO 18219:2015 and analysis by GC-NCI-MS) 1 M KOH extraction, hours at 90 C, derivatization and analysis 64 LFGB B or DIN EN ISO 17070:2015 DIN 54232: CADS test method: Determination of SCCP and MCCP in different matrices by use of GC-ECNI-MS V8_final_ published on the AFIRM website HB_RSL_E_V7.0 6 / 19

7 CHLORORGANIC CARRIERS, continued Pentachlorotoluene ,3-Dichlorobenzene ,4-Dichlorobenzene ,2,3-Trichlorobenzene ,2,4-Trichlorobenzene ,3,5-Trichlorobenzene ,2,3,4-Tetrachlorobenzene ,2,3,5-Tetrachlorobenzene Total: 1 ppm [reporting limit 0,2 ppm] Chlorobenzenes and Chlorotoluenes (chlorinated aromatic hydrocarbons) can be used as carriers in the dyeing process of polyester or wool/polyester fibers. They can also be used as solvents. DIN 54232: ,2,4,5-Tetrachlorobenzene Pentachlorobenzene Hexachlorobenzene ,2-Dichlorobenzene 10 ppm [reporting limit 1 ppm] DIMETHYLFORMAMIDE Dimethylformamide (DMFa) 500 ppm [reporting limit 50 ppm] DMFa is a solvent used in plastics, rubber, and polyurethane (PU) coating. Water-based PU does not contain DMFa and is therefore preferable. CEN ISO/TS 16189:2013 DIMETHYLFUMARATE Dimethylfumarate (DMFu) 0,1 ppm [reporting limit 0,05 ppm] DMFu is an anti-mold agent used in sachets in packaging to prevent the buildup of mold, especially during shipping. CEN ISO/TS 16186:2012 HB_RSL_E_V7.0 7 / 19

8 DYES, FORBIDDEN AND DISPERSE C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue 35A C.I. Disperse Blue 35B C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Brown C.I. Disperse Orange C.I. Disperse Orange C.I. Disperse Orange / / C.I. Disperse Orange 37/76/ C.I. Disperse Orange C.I. Disperse Red 1 50 ppm each [reporting limit 15 ppm] Disperse dyes are a class of water-insoluble dyes that penetrate the fiber system of synthetic or manufactured fibers and are held in place by physical forces without forming chemical bonds. Disperse dyes are used in synthetic fiber (e.g. polyester, acetate, polyamide). Restricted disperse dyes are suspected of causing DIN 54231: C.I. Disperse Red C.I. Disperse Red 17 allergic reactions or of being carcinogenic and are prohibited from use for dyeing of textiles C.I. Disperse Red C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Acid Red C.I. Basic Red 9 HB_RSL_E_V7.0 8 / 19

9 / / DYES FORBIDDEN AND DISPERSE, continued C.I. Basic Green C.I. Basic Violet C.I. Basic Violet C.I. Basic Blue C.I. Direct Black C.I. Direct Blue C.I. Direct Red C.I. Direct Brown Dimethylaminoazobenzene (Solvent Yellow 2) C.I. Solvent Blue ,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol DYES, NAVY BLUE 50 ppm each [reporting limit 15 ppm] Component 1: C39H23ClCrN7O12S.2Na 50 ppm each Not allocated Component 2: C46H30CrN10O20S2.3Na [reporting limit 15 ppm] FLAME-RETARDANTS Pentabromodiphenyl ether (PentaBDE) Octabromodiphenyl ether (OctaBDE) Decabromodiphenyl ether (DecaBDE) various All other Polybrominated diphenyl ether (PBDE) Tetrabromobisphenol A (TBBP A) Polybromobiphenyls (PBB) Hexabromocyclododecane (HBCDD) ,2-bis(bromomethyl)-1,3-propanediol (BBMP) Tris(1,3-dichloro-isopropyl) phosphate (TDCPP) Trixylyl phosphate (TXP) Tris(2,3,-dibromopropyl) phosphate (TRIS) Tris(1-aziridinyl)phosphine oxide) (TEPA) Tris(2-chloroethyl)phosphate (TCEP) Bis(2,3-dibromopropyl) phosphate (BDBPP) 10 ppm each [reporting limit 5 ppm] Disperse dyes are a class of water-insoluble dyes that penetrate the fiber system of synthetic or manufactured fibers and are held in place by physical forces without forming chemical bonds. Disperse dyes are used in synthetic fiber (e.g. polyester, acetate, polyamide). Restricted disperse dyes are suspected of causing allergic reactions or of being carcinogenic and are prohibited from use for dyeing of textiles. Navy blue colorants are regulated and are prohibited from use for dyeing of textiles. (Index ) Flame-retardant chemicals, including the entire class of organohalogen flame retardants, should no longer be used. DIN 54231:2005 DIN 54231:2005 EN ISO :2016 EN ISO :2016 HB_RSL_E_V7.0 9 / 19

10 FLUORINATED GREENHOUSE GASES See Regulation (EC) No 842/2006 for a complete list: 0,1 ppm each [reporting limit 0,1 ppm] Sample preparation: Purge and trap thermal desorption or SPME : GC/MS FORMALDEHYDE Formaldehyde Adults and children: 75 ppm Babies: 16 ppm [reporting limit 16 ppm] Used in textiles as an anti-creasing and anti-shrinking agent, often also in polymeric resins. Although very rare in apparel & footwear, composite wood materials, e.g. particle board and plywood, must comply with existing California forthcoming US formaldehyde emission requirements (40 CFR 770). Suppliers are advised to refer to brand-specific requirements for these materials. Textile, wood, paper: JIS L A (Japan Law 112) or EN ISO :2011 Leather: ISO :2008 with ISO :2008 confirmation method in case of interferences. HEAVY METALS Antimony (Sb) 30 ppm [reporting limit 3 ppm] Found in or used as a catalyst in polymerization of polyester, flame retardants, fixing agents, pigments and alloys. Textiles: DIN EN : Arsenic (As) 0,2 ppm [reporting limit 0,1 ppm] Total: 100 ppm [reporting limit 10 ppm] Arsenic and its compounds can be used in preservatives, pesticides and defoliants for cotton, synthetic fibers, paints, inks, trims and plastics. Textiles: DIN EN :2016 Total: Textiles: DIN EN :2016 2: Barium (Ba) 1000 ppm [reporting limit 100 ppm] Barium and its compounds can be used in pigments for inks, plastics, surface coatings, as well as in dyeing, mordant, filler in plastics, textile finish and leather tanning. Textiles: DIN EN : Cadmium (Cd) 0,1 ppm [reporting limit 0,05 ppm] Total: 40 ppm [reporting limit 5 ppm] Cadmium compounds are used as pigments (especially in red, orange, yellow and green); as a stabilizer for PVC; and in fertilizers, biocides and paints. Textiles: DIN EN :2016 Total: Textiles, plastics, metal: DIN EN :2016 2:2017 HB_RSL_E_V / 19

11 HEAVY METALS, continued Chromium (Cr) Textiles: 2 ppm Leather footwear for babies: 60 ppm Chromium compounds can be used as dyeing additives, dye-fixing agents, colorfastness after-treatments, dyes for wool, silk and polyamide (especially dark shades) and leather tanning. Textiles: DIN EN : Chromium VI Leather: 3 ppm [reporting limit 3 ppm] Knitted textiles for babies: 0,5 ppm Though typically associated with leather tanning, Chromium VI also may occur in the dyeing of wool (after the chroming process). Textiles: DIN EN :2016 with EN ISO if Cr is detected Leather: EN ISO and EN ISO :2017 for confirmation in case the extract causes interference Cobalt (Co) Adults: 4 ppm Children/babies: 1 ppm Cobalt and its compounds can be used in alloys, pigments, dyestuff and the production of plastic buttons. Textiles: DIN EN : Copper (Cu) Adults: 50 ppm Children/babies: 25 ppm [reporting limit 5 ppm] Copper and its compounds can be found in alloys and pigments and in textiles as an antimicrobial agent. Textiles: DIN EN : Lead (Pb) Adults and children: 1 ppm Babies: 0,2 ppm [reporting limit 0,1 ppm] Total: 90 ppm [reporting limit 10 ppm] May be associated with plastics, paints, inks, pigments, surface coatings and metal components. Textile: DIN EN :2016 Total: Non-metal: CPSC-CH-E Metal: CPSC-CH-E Lead in paint and surface coating: CPSIA Section CFR 1303 HB_RSL_E_V / 19

12 HEAVY METALS, continued Mercury (Hg) 0,02 ppm [reporting limit 0,02 ppm] Total: 0,5 ppm [reporting limit 0,1 ppm] Mercury compounds can be present in pesticides and as contaminants in caustic soda (NaOH). They could also occur in paints. Textile: DIN EN :2016 Total: Textiles, plastics, metal: DIN EN :2016 2: Nickel (Ni) 1 ppm [reporting limit 0,1 ppm] Release (metal parts): Prolonged skin contact: 0,5 µg/cm²/week Pierced part: 0,2 µg/cm²/week [reporting limit 0,1 µg/cm²/week] Nickel and its compounds can be used for plating alloys and improving corrosion-resistance and hardness of alloys. They can also occur as impurities in pigments and alloys. Textile: DIN EN :2016 Release EN 12472:2005+A1:2009 and EN 1811: Selenium (Se) MONOMERS Styrene 500 ppm [reporting limit 50 ppm] 500 ppm [reporting limit 50 ppm] May be found in synthetic fibers, paints, inks, plastics and metal trims. Styrene is a precursor for polymerization and may be present in various styrene-copolymers like plastic buttons. Textiles: DIN EN :2016 GC/MS 120 C for 45 minutes; -or- Extraction in Methanol GC/MS, sonication for 60 minutes at 60 C Vinyl Chloride 1 ppm [reporting limit 1 ppm] Vinyl Chloride is a precursor for polymerization and may be present in various PVC material like prints, coatings, flip flops and synthetic leather. EN ISO 6401:2008 HB_RSL_E_V / 19

13 N-NITROSAMINE N-nitrosodimethylamine (NDMA) N-nitrosodiethylamine (NDEA) N-nitrosodipropylamine (NDPA) N-nitrosodibutylamine (NDBA) N-nitrosopiperidine (NPIP) N-nitrosopyrrolidine (NPYR) N-nitrosomorpholine (NMOR) N-nitroso N-methyl N-phenylamine (NMPhA) N-nitroso N-ethyl N-phenylamine (NEPhA) ORGANOTIN COMPOUNDS Dibutyltin (DBT) Dioctyltin (DOT) Monobutyltin (MBT) Tricyclohexyltin (TCyHT) Trimethyltin (TMT) Trioctyltin (TOT) Tripropyltin (TPT) 0,5 ppm each 1 ppm each [reporting limit 0,1 ppm] Tributyltin (TBT) 0,5 ppm each Triphenyltin (TPhT) [reporting limit 0,1 ppm] ORTHO-PHENYLPHENOL Ortho-phenylphenol (OPP) OZONE-DEPLETING SUBSTANCES See Regulation (EC) No 1005/2009 for a complete list: ppm [reporting limit 100 ppm] 5 ppm [reporting limit 5 ppm] Can be formed as by-product in the production of rubber. Class of chemicals combining tin and organics such as butyl and phenyl groups. Organotins are predominantly found in the environment as antifoulants in marine paints, but they can also be used as biocides (e.g. antibacterials), catalysts in plastic and glue production and heat stabilizers in plastics/rubber. In textiles and apparel, organotins are associated with plastics/rubber, inks, paints, metallic glitter, polyurethane products and heat transfer material. OPP can be used for its preservative properties in leather or as a carrier in dyeing processes. Ozone-depleting substances have been used as a foaming agent in PU foams as well as a dry-cleaning agent and are prohibited from use. GB/T : determination using GC/MC with LC/MS/MS verification if positive. Alternatively, LC/MS/MS may be performed on its own. pren 19577:2017 CEN ISO/TS 16179: M KOH extraction, hours at 90 C, derivatization and analysis 64 LFGB B or DIN EN ISO 17070:2015 GC/MS headspace 120 C for 45 minutes HB_RSL_E_V / 19

14 PERFLUORINATED AND POLYFLUORINATED CHEMICALS (PFCs) Perfluorooctane Sulfonate (PFOS) ) and related substances Perfluorooctanoic Acid (PFOA) and related substances PESTICIDES, AGRICULTURAL 2-(2,4,5-trichlorophenoxy) propionic acid, its salts and compounds; 2,4,5-TP ,4,5-trichlorophenoxyacetic acid, its salts and compounds; 2,4,5-T ,4-dichlorophenoxy-acetic acid, its salts and compounds; 2,4-D Aldrine Azinophosmethyl Azinophosethyl Bromophos-ethyl Captafol Carbaryl Chlorbenzilat Chlordane Chlordimeform Chlorfenvinphos Chlorthalonil Coumaphos Cyfluthrin Cyhalothrin Cypermethrin S,S,S-Tributyl phosphorotrithioate (Tribufos) Deltamethrin o,p-dichlorodiphenyl-dichloroethane (o,p-ddd) 1 µg/m 2 each [reporting limit 1 µg/m 2 ] 0,5 ppm each - limits corresponding to AFIRM PFOA and PFOS may be present as unintended byproducts in long-chain and short-chain commercial water, oil and stain repellent agents. PFOA may also be used in polymers like polytetrafluoroethylene (PTFE). Long-chain PFC technology is restricted from use with a 25 ppb limit on PFOA and its salts and a 1000 ppb total limit on PFOA-related substances in all materials. See commission Regulation (EU) 2017/1000. This is effective 4 July RSL limits will be revised in a subsequent update. May be found in natural fibers (primarily cotton). CEN/TS 15968:2014 Natural fibers: ISO / DIN F2 or EPA 8081 / EPA 8151A or BVL L : HB_RSL_E_V / 19

15 PESTICIDES; AGRICULTURAL; continued p,p-dichlorodiphenyl-dichloroethane (p,p-ddd) o,p-dichlorodiphenyl-dichloroethylene (o,p-dde) p,p-dichlorodiphenyl-dichloroethylene (p,p-dde) o,p-dichlorodiphenyl-trichloroethane (o,p-ddt) p,p-dichlorodiphenyl-trichloroethane (p,p-ddt) Diazinone Dichlofluanide Dichloroprop Dicofol Dicrotophos Dieldrine Dimethoate Dinoseb, its salts and acetate Endosulfan DTTB (4,6-Dichloro-7 (2,4,5-trichloro-phenoxy) -2- Trifluoro methyl benz imidazole) Endosulfan I (alpha) 0,5 ppm each May be found in natural fibers (primarily cotton). Natural fibers: ISO / DIN F2 or EPA 8081 / EPA 8151A or BVL L : Endosulfan II (beta) Endrine Esfenvalerate Ethylenedibromid Ethylparathione; Parathion Fenvalerate ; ; Halogenated biphenyls, including Polychlorinatedbiphenyl (PCB) Halogenated terphenols, including polychlorinated terphenyl (PCT) Halogenated naphthalenes, including polychlorinated naphthalenes (PCNs) Halogenated diarylalkanes HB_RSL_E_V / 19

16 ; ; PESTICIDES; AGRICULTURAL; continued Halogenated diphenyl methanes, including Monomethyl-dibromo-diphenyl methane, Monomethyl-dichloro-diphenyl methane, and Monomethyl-tetrachloro-diphenyl methane Heptachlor Heptachloroepoxide a-hexachlorocyclohexane with and without Lindane b-hexachlorocyclohexane with and without Lindane g-hexachlorocyclohexane with and without Lindane Hexachlorobenzene Isodrine Kelevane Kepone Lead hydrogen arsenate Lindane Malathione MCPA MCPB Mecoprop 0,5 ppm each May be found in natural fibers (primarily cotton). Natural fibers: ISO / DIN F2 or EPA 8081 / EPA 8151A or BVL L : Metamidophos Methoxychlor Mirex Monocrotophos Parathion-methyl Pentachloroanisole Phosdrin/Mevinphos Perthane Propethamphos Profenophos Quinalphos Quintozene Strobane HB_RSL_E_V / 19

17 PESTICIDES; AGRICULTURAL; continued Telodrine Toxaphene Tolylfluanide Trifluarline 0,5 ppm each May be found in natural fibers (primarily cotton). Natural fibers: ISO / DIN F2 or EPA 8081 / EPA 8151A or BVL L : PHTHALATES Di-Iso-nonylphthalate (DINP) Di-n-octylphthalate (DNOP) Di(2-ethylhexyl)-phthalate (DEHP) Diisodecylphthalate (DIDP) Butylbenzylphthalate (BBP) Dibutylphthalate (DBP) Diisobutylphthalate (DIBP) Di-n-hexylphthalate (DnHP) Diethylphthalate (DEP) 500 ppm each Total ppm [reporting limit 50 ppm] Esters of ortho-phthalic acid (phthalates) are a class of organic compound commonly added to plastics to increase flexibility. They are sometimes used to facilitate the molding of plastic by decreasing its melting temperature. Phthalates can be found in: Flexible plastic components (e.g., PVC) Print pastes Adhesives Plastic buttons Plastic sleevings Polymeric coatings Sample preparation: CPSC-CH-C : Textile: GC-MS, EN ISO 14389:2014 Leather: GC-MS Dimethylphthalate (DMP) di-n-pentyl phthalate (DPENP) dicyclohexyl phthalate (DCHP) The listed phthalates are those most commonly used and regulated across industry sectors. Find more information about additional phthalates on the REACH SVHC list, which is updated frequently. HB_RSL_E_V / 19

18 POLYCYCLIC AROMATIC HYDROCARBONS (PAHS) Acenaphthene Acenaphthylene Anthracene Benzo(g,h,i)perylene Fluorene Fluoranthene Indeno(1,2,3-cd)pyrene Naphthalene** Phenanthrene Pyrene Benzo(a)anthracene No individual restriction Total: 10 ppm [reporting limit 0,2 ppm] PAHs are natural components of crude oil and are common residues from oil refining. PAHs have a characteristic smell similar to that of car tires or asphalt. Oil residues containing PAHs are added to rubber and plastics as a softener or extender and may be found in rubber, plastics, lacquers and coatings. PAHs are often found in the outsoles of footwear and in printing pastes for screen prints. PAHs can be present as impurities in Carbon Black. They also may be formed from thermal decomposition of recycled materials during reprocessing AFPS GS Benzo(a)pyrene Benzo(b)fluoranthene Benzo(e)pyrene Benzo(j)fluoranthene Benzo(k)fluoranthene 1 ppm each Child care articles: 0,5 ppm each [reporting limit 0,2 ppm] **Naphthalene: Dispersing agents for textile dyes may contain high residual naphthalene concentrations due to the use of low-quality naphthalene derivatives (e.g. poor-quality naphthalene sulphonate formaldehyde condensation products) Chrysene Dibenzo(a,h)anthracene HB_RSL_E_V / 19

19 VOLATILE ORGANIC COMPOUNDS (VOCs) Benzene 5 ppm [reporting limit 5 ppm] Carbon Disulfide Carbon tetrachloride Chloroform Cyclohexanone ,1,1- Trichloroethane ,2-Dichloroethane ,1-Dichloroethylene Dimethylacetamide (DMAC) Ethylbenzene Pentachloroethane Total: 1000 ppm [reporting limit 20 ppm each] These VOCs should not be used in textile auxiliary chemical preparations. They are also associated with solvent-based processes such as solvent-based polyurethane coatings and glues/adhesives. They should not be used for any kind of facility cleaning or spot cleaning. For general VOC screening: GC/MS headspace 45 minutes at 120 degrees C. For DMAC: DIN CEN ISO/TS 16189: ,1,1,2- Tetrachloroethane ,1,2,2- Tetrachloroethane Tetrachloroethylene (PER) Toluene ,1,2- Trichloroethane Trichloroethylene Xylenes (meta-, ortho-, para-) HB_RSL_E_V / 19