MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification. 2. Hazards Identification

Transcription

1 MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Manufacturer 1 Product and Company Identification Cutek Extreme Mixture Wood Protection Chemisys International Pty Ltd PO Box 3604 Loganholme QLD 4129 Phone: Hazards Identification Emergency overview Potential short term health effects Routes of exposure Eyes Skin WARNING COMBUSTIBLE LIQUID AND VAPOR HARMFUL IF SWALLOWED CAUSES EYE IRRITATION CAUSES SKIN IRRITATION MAY CAUSE ALLERGIC SKIN REACTION Eye, Skin contact, Skin absorption, Inhalation, Ingestion Causes irritation ACGIH - Threshold Limit Values - Skin Notations Contact with skin can cause irritation and allergic reaction (sensitization) in some individuals May be absorbed through the skin Naphthalene Skin - potential significant contribution to overall exposure by the cutaneous route Inhalation May cause respiratory tract irritation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Potential environmental effects See section 12 May cause stomach distress, nausea or vomiting Aspiration of material into lungs can cause chemical pneumonitis Blood Eyes Kidney Liver Respiratory system Skin Prolonged or repeated exposure can cause drying, defatting and dermatitis Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Ingredient(s) CAS # Percent Phosphoric acid, 2-ethylhexyl ester Distillates (petroleum), hydrotreated light paraffinic Heavy aromatic solvent naphtha (petroleum) Naphtha (petroleum), hydrotreated heavy Naphthalene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Xylene 3 Composition / Information on Ingredients First aid procedures Eye contact Skin contact 4 First Aid Measures Immediately flush with cool water Remove contact lenses, if applicable, and continue flushing for 15 minutes Obtain medical attention if irritation develops or persists Immediately flush with water Wash with soap and water Obtain medical attention if irritation persists Remove and wash contaminated clothing before re-use #23300 Page 1 of 9

2 Inhalation Ingestion Notes to physician General advice If symptoms develop, move victim to fresh air If symptoms persist, obtain medical attention If breathing has stopped, trained personnel should administer CPR immediately Do not induce vomiting If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention This material, if aspirated into the lungs, may cause chemical pneumonitis; treat the affected person appropriately Keep away from sources of ignition No smoking If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Combustible by WHMIS/OSHA criteria Dry chemical Carbon dioxide Foam Water spray Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Do not discharge into lakes, streams, ponds or public waters Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Remove sources of ignition Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use 7 Handling and Storage Use good industrial hygiene practices in handling this material Avoid contact with eyes Avoid contact with skin and clothing Avoid prolonged or repeated skin contact with this material Use only with adequate ventilation Avoid breathing vapors or mists of this product Wash thoroughly after handling Keep out of reach of children Do not store at temperatures above 120 F (49 C) Store in a cool, dry, well-ventilated place away from incompatible materials Keep away from heat, open flames or other sources of ignition #23300 Page 2 of 9

3 Exposure limits Ingredient(s) 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene 8 Exposure Controls / Personal Protection Exposure Limits TWA: 25 ppm TWA: 25 ppm TWA: 25 ppm Distillates (petroleum), hydrotreated light paraffinic Heavy aromatic solvent naphtha (petroleum) Naphtha (petroleum), hydrotreated heavy Naphthalene Phosphoric acid, 2-ethylhexyl ester TWA: 10 ppm STEL: 15 ppm TWA: 10 ppm Xylene Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm Use only under good ventilation conditions or with respiratory protection Wear safety glasses with side shields Rubber gloves Confirm with a reputable supplier first As required by employer code Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using, do not eat, drink or smoke Wash hands before breaks and immediately after handling the product #23300 Page 3 of 9

4 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Melting point Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Solubility (H2O) Viscosity Percent volatile Clear Dark green / Amber Liquid Slight petroleum Liquid C F (80 C) ASTM D C Negligible 17 C Not VOC available 240 gr/l 10 Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials None known Hazardous polymerization does not occur Stable under recommended storage conditions Heat, open flames, static discharge, sparks and other ignition sources Do not mix with other chemicals Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon 11 Toxicological Information Component analysis - LC50 Ingredient(s) 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Distillates (petroleum), hydrotreated light paraffinic Heavy aromatic solvent naphtha (petroleum) Naphtha (petroleum), hydrotreated heavy Naphthalene Phosphoric acid, 2-ethylhexyl ester Xylene LC ppm rat; 3661 mg/l/4h rat 24 Mg/m3/4H rat 215 mg/l/4h rat 590 mg/l/4h rat 6350 mg/l/4h rat #23300 Page 4 of 9

5 Component analysis - Oral LD50 Ingredient(s) LD50 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Distillates (petroleum), hydrotreated light paraffinic Heavy aromatic solvent naphtha (petroleum) Naphtha (petroleum), hydrotreated heavy Naphthalene Phosphoric acid, 2-ethylhexyl ester Xylene Effects of acute exposure Eye Skin Causes irritation ACGIH - Threshold Limit Values - Skin Notations 3280 mg/kg rat mg/kg rat 5000 mg/kg rat 7050 mg/kg rat 5000 mg/kg rat 490 mg/kg rat; 533 mg/kg mouse; 1200 mg/day guinea pig 3523 mg/kg rat; 5251 ML/kg mouse Contact with skin can cause irritation and allergic reaction (sensitization) in some individuals May be absorbed through the skin Naphthalene Skin - potential significant contribution to overall exposure by the cutaneous route Inhalation May cause respiratory tract irritation Ingestion Sensitization Chronic effects Carcinogenicity ACGIH - Threshold Limit Values - Carcinogens May cause stomach distress, nausea or vomiting Aspiration of material into lungs can cause chemical pneumonitis Contains a potential skin sensitizer Non-hazardous by WHMIS/OSHA criteria Contains a potential carcinogen Naphthalene A4 - Not Classifiable as a Human Carcinogen Xylene A4 - Not Classifiable as a Human Carcinogen IARC - Group 2B (Possibly Carcinogenic to Humans) Naphthalene Monograph 82 [2002] IARC - Group 3 (Not Classifiable) Xylene Monograph 71 [1999]; Monograph 47 [1989] NTP (National Toxicology Program) - Report on Carcinogens - Reasonably Anticipated to be Human Carcinogens Naphthalene Reasonably Anticipated To Be A Human Carcinogen US - California - Proposition 65 - Carcinogens List Naphthalene carcinogen, initial date 4/19/02 Mutagenicity Non-hazardous by WHMIS/OSHA criteria Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Non-hazardous by WHMIS/OSHA criteria Xylene is considered fetotoxic in humans, based on observations of reduced fetal weight, delayed ossification and persistent behavioural effects in animal studies in the absence of maternal toxicity #23300 Page 5 of 9

6 12 Ecological Information Ecotoxicity Ecotoxicity - Freshwater Algae - Acute Toxicity Data Components of this product have been identified as having potential environmental concerns Heavy aromatic solvent naphtha Hr EC50 Skeletonema costatum: 25 mg/l (petroleum) Naphthalene Hr EC50 Skeletonema costatum: 04 mg/l Ecotoxicity - Freshwater Fish - Acute Toxicity Data 1,2,4-Trimethylbenzene Hr LC50 Pimephales promelas: mg/l [flow-through] 1,3,5-Trimethylbenzene Hr LC50 Pimephales promelas: 348 mg/l Distillates (petroleum), Hr LC50 Oncorhynchus mykiss: >5000 mg/l hydrotreated light paraffinic Heavy aromatic solvent naphtha (petroleum) Hr LC50 Pimephales promelas: 19 mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss: 234 mg/l; 96 Hr LC50 Lepomis macrochirus: 1740 mg/l [static]; 96 Hr LC50 Pimephales promelas: 45 mg/l [flow-through]; 96 Hr LC50 Pimephales promelas: 41 mg/l Naphtha (petroleum), Hr LC50 Pimephales promelas: 2200 mg/l hydrotreated heavy Naphthalene Hr LC50 Pimephales promelas: mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 16 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [static]; 96 Hr LC50 Pimephales promelas: 199 mg/l [static]; 96 Hr LC50 Lepomis macrochirus: mg/l [static] Xylene Hr LC50 Pimephales promelas: 134 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss: mg/l; 96 Hr LC50 Lepomis macrochirus: mg/l [flow-through]; 96 Hr LC50 Lepomis macrochirus: 19 mg/l; 96 Hr LC50 Lepomis macrochirus: mg/l [static]; 96 Hr LC50 Pimephales promelas: Ecotoxicity - Water Flea - Acute Toxicity Data 1,2,4-Trimethylbenzene Hr EC50 Daphnia magna: 614 mg/l 1,3,5-Trimethylbenzene Hr EC50 Daphnia magna: 50 mg/l Distillates (petroleum), Hr EC50 Daphnia magna: >1000 mg/l hydrotreated light paraffinic Heavy aromatic solvent naphtha Hr EC50 Daphnia magna: 095 mg/l (petroleum) Naphtha (petroleum), Hr LC50 Chaetogammarus marinus: 26 mg/l hydrotreated heavy Naphthalene Hr LC50 Daphnia magna: 216 mg/l; 48 Hr EC50 Daphnia magna: 196 mg/l [Flow through]; 48 Hr EC50 Daphnia magna: mg/l [Static] Xylene Hr EC50 water flea: 382 mg/l; 48 Hr LC50 Gammarus lacustris: 06 mg/l Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Other adverse effects 13 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, state/provincial, and local government requirements prior to disposal 14 Transport Information US Department of Transportation (DOT) Not regulated as dangerous goods Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods #23300 Page 6 of 9

7 15 Regulatory Information Canadian federal regulations Canada - CEPA - High Priority Chemicals as Identified by DSL Categorization Naphthalene Batch 1, published February 3, 2007 Canada - CEPA - Schedule I - List of Toxic Substances Canada - WHMIS - Ingredient Disclosure List 1,2,4-Trimethylbenzene % 1,3,5-Trimethylbenzene % Naphthalene % WHMIS status Controlled WHMIS classification WHMIS labeling This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Class B - Division 3 - Combustible Liquid, Class D - Division 2A, 2B Occupational Safety and Health Administration (OSHA) 29 CFR hazardous Yes chemical US Federal regulations US - CAA (Clean Air Act) Hazardous Air Pollutants (isomers and mixtures) US - CAA (Clean Air Act) - HON Rule - Organic HAPs US - CAA (Clean Air Act) - HON Rule - SOCMI Chemicals Naphthalene Group IV Xylene Group I US - CAA (Clean Air Act) - Reactivity Factors for VOCs in Aerosol Coatings 1,2,4-Trimethylbenzene G Ozone/g VOC Reactivity Factor 1,3,5-Trimethylbenzene G Ozone/g VOC Reactivity Factor Naphthalene G Ozone/g VOC Reactivity Factor Xylene G Ozone/g VOC Reactivity Factor US - CAA (Clean Air Act) - Volatile Organic Compounds (VOCs) in SOCMI US - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Naphthalene Lb final RQ; 454 kg final RQ Xylene Lb final RQ; 454 kg final RQ US - CERCLA/SARA - Section Emission Reporting 1,2,4-Trimethylbenzene % de minimis concentration Naphthalene % de minimis concentration Xylene % de minimis concentration US - CWA (Clean Water Act) - Hazardous Substances US - CWA (Clean Water Act) - Priority Pollutants US - CWA (Clean Water Act) - Toxic Pollutants CERCLA (Superfund) reportable quantity Naphthalene: Xylene: Phosphoric acid: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR #23300 Page 7 of 9

8 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Section 302 extremely hazardous substance No Section 311 hazardous chemical Yes Clean Water Act (CWA) State regulations Hazardous substance Priority pollutant Toxic pollutant US - California - 8 CCR Section Director's List of Hazardous Substances 1,2,4-Trimethylbenzene Present US - California - Proposition 65 - Carcinogens List Naphthalene carcinogen, initial date 4/19/02 US - Illinois - Toxic Air Contaminant Carcinogens Naphthalene IARC 2B Carcinogen; NTP Anticipated Carcinogen US - Illinois - Toxic Air Contaminants 1,2,4-Trimethylbenzene Present US - Louisiana - Reportable Quantity List for Pollutants Naphthalene Lb final RQ; 454 kg final RQ Xylene Lb final RQ; 454 kg final RQ US - Massachusetts - Right To Know List 1,2,4-Trimethylbenzene Present Distillates (petroleum), Carcinogen; Extraordinarily hazardous hydrotreated light paraffinic US - Michigan - Critical Materials List Xylene Lb Annual usage threshold (all isomers) US - Minnesota - Hazardous Substance List 1,2,4-Trimethylbenzene Present (including all isomers) US - New Jersey - Right to Know Hazardous Substance List 1,2,4-Trimethylbenzene sn ,3,5-Trimethylbenzene sn 1929 Naphthalene sn 1322 Xylene sn 2014 US - New York - Reporting of Releases Part List of Hazardous Substances Naphthalene Lb RQ (air); 1 lb RQ (land/water) Xylene Lb RQ (air); 1 lb RQ (land/water) US - North Carolina - Control of Toxic Air Pollutants Xylene mg/m3 (chronic toxicants); 65 mg/m3 (acute irritants) US - Pennsylvania - RTK (Right to Know) List 1,2,4-Trimethylbenzene Environmental hazard Naphthalene Environmental hazard Xylene Environmental hazard US - Rhode Island - Hazardous Substance List WARNING: This product contains a chemical known to the State of California to cause cancer 1,2,4-Trimethylbenzene Toxic 1,3,5-Trimethylbenzene Toxic Naphthalene Toxic; Flammable Xylene Toxic (skin); Flammable (skin) #23300 Page 8 of 9

9 Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Severe Serious Moderate Slight Minimal LEGEND HMIS/NFPA Disclaimer Effective date Expiry date Health 16 Other Information Flammability Physical Hazard Personal Protection * X Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 01-Jan Jan-2016 Prepared by Dell Tech Laboratories Ltd (519) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z4001/Z Standard Yes #23300 Page 9 of 9