MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Manufacturer LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 1 Product and Company Identification Ultra Low Sulphur Diesel Mixture Fuel Irving Oil Refining GP Box 1260 Saint John, NB E2L 4H6 CA Phone: (506) Refinery: (506) Emergency Phone: (CHEMTREC) Health * 1 Flammability 2 Physical Hazard 0 Personal Protection B 2 Hazards Identification Emergency overview Potential short term health effects Routes of exposure Eyes Skin WARNING COMBUSTIBLE Containers may explode when heated CONTAINS MATERIAL WHICH MAY CAUSE CANCER EYE AND SKIN IRRITANT May cause chronic toxic effects Contains a potential teratogen Eye, Skin contact, Skin absorption, Inhalation, Ingestion Causes irritation Causes irritation ACGIH - Threshold Limit Values - Skin Notations Skin - potential significant contribution to overall exposure by the cutaneous route Skin - potential significant contribution to overall exposure by the cutaneous route Diesel Fuel No Skin - potential significant contribution to overall exposure by the cutaneous route (listed under Diesel fuel) Inhalation Ingestion Target organs Chronic effects Signs and symptoms Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness) Harmful if swallowed May cause stomach distress, nausea or vomiting Blood Eyes Kidney Liver Respiratory system Skin Prolonged or repeated exposure can cause kidney damage Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent Diesel Fuel No < 01 < 01 < 01 < 01 #19038 Page 1 of 10 Issue date 28-Sep-2009

2 Composition comments First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice *Fuel oil is a complex mixture of hydrocarbons Its exact composition depends on the source of the crude oil from which it was produced and the refining methods used Fuel oil contains hundreds of individual organic chemicals This section identifies only some of the well-known chemical constituents *Sulphur: <8 ppm *Hydrogen sulphide: Nil 4 First Aid Measures Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists Flush with cool water Wash with soap and water Obtain medical attention if irritation persists If symptoms develop, move victim to fresh air If symptoms persist, obtain medical attention If breathing has stopped, trained personnel should administer CPR immediately Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention Symptoms may be delayed Keep away from sources of ignition No smoking If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Combustible by WHMIS/OSHA criteria Vapors may travel to a source of ignition and flash back Containers may explode when heated Carbon dioxide Dry chemical Foam Container may explode in heat of fire Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back Firefighters should wear full protective clothing including self contained breathing apparatus Cool containers with flooding quantities of water until well after fire is out May include and are not limited to: Oxides of carbon Oxides of nitrogen Polycyclic aromatic hydrocarbons (PAHs) Aromatic hydrocarbons Not expected to be sensitive to mechanical impact Vapor: Yes 6 Accidental Release Measures Personal precautions Methods for containment Methods for cleaning up Other information Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use Keep unnecessary personnel away #19038 Page 2 of 10 Issue date 28-Sep-2009

3 Handling Storage Exposure limits Ingredient(s) Diesel Fuel No 2 7 Handling and Storage Use good industrial hygiene practices in handling this material Non-sparking equipment Explosion-proof ventilation Intrinsically safe electrical equipment Ground and bond containers when transferring material Have clean emergency eye wash and shower available in work area Keep out of reach of children Containers should be vented and equipped with a flame arrester May be stored at ambient temperatures Keep away from heat, open flames or other sources of ignition Shipping: Stable during transport May be transported hot 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV TWA: 05 ppm STEL: 25 ppm OSHA-PEL TWA: 1 ppm STEL: 5 ppm Ceiling: 25 ppm ACGIH-TLV TWA: 02 mg/m3 OSHA-PEL TWA: 02 mg/m3 ACGIH-TLV TWA: 10 ppm STEL: 15 ppm OSHA-PEL TWA: 10 ppm ACGIH-TLV TWA: 100 mg/m3 OSHA-PEL Not established ACGIH-TLV TWA: 20 ppm Skin: 50 ppm Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection OSHA-PEL TWA: 200 ppm Ceiling: 300 ppm Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits Mechanical ventilation should be used when handling this product in enclosed s Local exhaust ventilation may be necessary Face shield or chemical goggles Nitrile rubber Viton PVC gloves Tychem BR/LV Tychem TK Use of protective coveralls and long sleeves is recommended If clothing or footwear becomes contaminated with the product, remove it immediately and completely decontaminate it before re-use, or discard it #19038 Page 3 of 10 Issue date 28-Sep-2009

4 Respiratory protection For confined s, wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressure mode with emergency escape provisions Respirator should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR ), CAN/CSA-Z944 and ANSI's standard for respiratory protection (Z882) General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Melting point Freezing point Boiling point Flash point Pour point Clear Water white Liquid Kerosene Liquid Not applicable C ( F) C ( F) Closed Cup C (-40-0 F) Evaporation rate Flammability limits in air, lower, % by volume Flammability limits in air, upper, % 6-75 by volume Vapor pressure C Vapor density Specific gravity 20 C Octanol/water coefficient (log Kow) Auto-ignition temperature 257 C (49460 F) Viscosity F Percent volatile 10 Stability and Reactivity Chemical stability Conditions to avoid Stable under recommended storage conditions Heat, open flames, static discharge, sparks and other ignition sources Do not mix with other chemicals Incompatible materials Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Oxides of nitrogen Aromatic hydrocarbons Possibility of hazardous reactions Hazardous polymerization does not occur 11 Toxicological Information Component analysis - LC50 Ingredient(s) Diesel Fuel No 2 LC ppm rat; mg/l/4h rat > 5 Mg/L rat 125 mg/l/4h rat #19038 Page 4 of 10 Issue date 28-Sep-2009

5 Component analysis - Oral LD50 Ingredient(s) LD50 Diesel Fuel No 2 Effects of acute exposure Eye Skin Causes irritation Causes irritation 690 mg/kg rat; 4700 mg/kg mouse 490 mg/kg rat; 533 mg/kg mouse; 1200 mg/day guinea pig 5000 mg/kg rat 636 mg/kg rat ACGIH - Threshold Limit Values - Skin Notations Skin - potential significant contribution to overall exposure by the cutaneous route Skin - potential significant contribution to overall exposure by the cutaneous route Diesel Fuel No Skin - potential significant contribution to overall exposure by the cutaneous route (listed under Diesel fuel) Inhalation Ingestion Sensitization Chronic effects Carcinogenicity ACGIH - Threshold Limit Values - Carcinogens Diesel Fuel No 2 Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness) Harmful if swallowed May cause stomach distress, nausea or vomiting Non-hazardous by WHMIS/OSHA criteria Prolonged or repeated exposure can cause kidney damage Contains potential carcinogens A1 - Confirmed Human Carcinogen A2 - Suspected Human Carcinogen A4 - Not Classifiable as a Human Carcinogen A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed under Diesel Fuel) IARC - Group 1 (Carcinogenic to Humans) A4 - Not Classifiable as a Human Carcinogen Supplement 7 [1987]; Monograph 29 [1982] Monograph 92 [in preparation]; Supplement 7 [1987]; Monograph 32 [1983] (overall evaluation upgraded from 2B to 1 based on mechanistic and other relevant data) IARC - Group 2B (Possibly Carcinogenic to Humans) Monograph 82 [2002] IARC - Group 3 (Not Classifiable) Monograph 71 [1999]; Monograph 47 [1989] NTP (National Toxicology Program) - Report on Carcinogens - Known Human Carcinogens Known Human Carcinogen Known Carcinogen NTP (National Toxicology Program) - Report on Carcinogens - Reasonably Anticipated to be Human Carcinogens Suspect Carcinogen Reasonably Anticipated To Be A Human Carcinogen (listed under Polycyclic aromatic hydrocarbons) Reasonably Anticipated To Be A Human Carcinogen US - California - Proposition 65 - Carcinogens List carcinogen, initial date 2/27/87 Trace Amount carcinogen, initial date 7/1/87 Trace Amount carcinogen, initial date 4/19/02 Trace Amount Mutagenicity Reproductive effects Teratogenicity Synergistic Materials Contains a potential mutagen Non-hazardous by WHMIS/OSHA criteria Contains a potential teratogen (benzene, methyl-) has caused fetotoxicity (reduced fetal weight), behavioural effects (effects on learning and memory) and hearing loss (in males) These effects have been observed in the offspring of rats exposed by inhalation to 1200 or 1800 ppm toluene These effects were observed in the absence of maternal toxicity Other CNS depressants can be expected to produce additive or synergistic effects #19038 Page 5 of 10 Issue date 28-Sep-2009

6 12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Algae Data 72 Hr EC50 Selenastrum capricornutum: 29 mg/l 96 Hr EC50 Skeletonema costatum: 04 mg/l Hr EC50 Selenastrum capricornutum: >433 mg/l Ecotoxicity - Freshwater Fish Species Data 96 Hr LC50 Pimephales promelas: mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:53 mg/l [flow-through]; 96 Hr LC50 Lepomis macrochirus:2249 mg/l [static]; 96 Hr LC50 Poecilia reticulata:286 mg/l [static]; 96 Hr LC50 Pimephales promelas: μg/l [static]; 96 Hr LC50 Lepomis macrochirus: μg/l [static] 96 Hr LC50 Pimephales promelas: mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:16 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [static]; 96 Hr LC50 Pimephales promelas:199 mg/l [static]; 96 Hr LC50 Lepomis macrochirus: mg/l [static] Diesel Fuel No Hr LC50 Pimephales promelas: 35 mg/l [flow-through] Hr LC50 Pimephales promelas: mg/l [flow-through] (1 day old); 96 Hr LC50 Pimephales promelas:126 mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss:58 mg/l [semi-static]; 96 Hr LC50 Lepomis macrochirus: mg/l [static]; 96 Hr LC50 Oryzias latipes:54 mg/l [static]; 96 Hr LC50 Poecilia reticulata:282 mg/l [semi-static]; 96 Hr LC50 Poecilia reticulata: Ecotoxicity - Microtox Data 30 Min EC50 Photobacterium phosphoreum: 093 mg/l; 18 Hr EC50 Pseudomonas putida: >20 mg/l Min EC50 Photobacterium phosphoreum: 197 mg/l Ecotoxicity - Water Flea Data 48 Hr EC50 water flea: 356 mg/l [Static]; 48 Hr EC50 Daphnia magna: 10 mg/l 48 Hr EC50 water flea: 216 mg/l Hr EC50 water flea: 113 mg/l; 48 Hr EC50 water flea: 310 mg/l; 48 Hr EC50 Daphnia magna: 113 mg/l Environmental effects Aquatic toxicity Persistence / degradability Non-persistent/ Group 1 Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects (log Kow) 13 Disposal Considerations Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, provincial, and local government requirements prior to disposal #19038 Page 6 of 10 Issue date 28-Sep-2009

7 14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Diesel fuel Hazard class 3 UN number UN1202 Packing group III Additional information: Special provisions Packaging exceptions ERG number 144, B1, IB3, T2, TP Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name Hazard class UN number Packing group DIESEL FUEL; FUEL OIL; GAS OIL; or HEATING OIL LIGHT 3 UN1202 III 15 Regulatory Information Canadian federal regulations Canada - WHMIS - Ingredient Disclosure List 01 % 01 % 1 % % This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - CEPA - High Priority Chemicals as Identified by DSL Categorization Batch 1, published February 3, 2007 Canada - CEPA - Schedule I - List of Toxic Substances [SOR/ ] [SOR/ ] #19038 Page 7 of 10 Issue date 28-Sep-2009

8 US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the US EPA TSCA Inventory List US - CERCLA/SARA - Hazardous Substances and their Reportable Quantities 10 Lb final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989 final rule); 454 kg final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989 final rule) 1 Lb final RQ; 0454 kg final RQ 100 Lb final RQ; 454 kg final RQ Lb final RQ; 454 kg final RQ US - CERCLA/SARA - Section Emission Reporting 01 % de minimis concentration 01 % Supplier notification limit (listed under Chemical Category N590, Polycyclic aromatic compounds) 01 % de minimis concentration % de minimis concentration US - CWA (Clean Water Act) - Hazardous Substances US - CWA (Clean Water Act) - Priority Pollutants US - CWA (Clean Water Act) - Toxic Pollutants Occupational Safety and Health Administration (OSHA) 29 CFR hazardous Yes chemical CERCLA (Superfund) reportable quantity, methyl-: : : : Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) WHMIS status WHMIS classification WHMIS labeling Controlled Class B - Division 3 - Combustible Liquid, Class D - Division 2A, 2B #19038 Page 8 of 10 Issue date 28-Sep-2009

9 State regulations WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm US - California - 8 CCR Section Director's List of Hazardous Substances US - California - Proposition 65 - Carcinogens List US - Illinois - Toxic Air Contaminant Carcinogens US - California - Proposition 65 - Developmental Toxicity US - California - Proposition 65 - Reproductive Toxicity - Male carcinogen, initial date 2/27/87 Trace Amount carcinogen, initial date 7/1/87 Trace Amount carcinogen, initial date 4/19/02 Trace Amount developmental toxicity, initial date 12/26/97 Trace Amount developmental toxicity, initial date 1/1/91 Trace Amount male reproductive toxicity, initial date 12/26/97 Trace Amount US - Connecticut - Carcinogenic Substances Meets the definition of a carcinogen from the Secretary of Labor IRIS A Carcinogen; NTP Known Carcinogen; ACGIH A2 Carcinogen; IARC Group 1 Carcinogen IRIS B2 Carcinogen; NTP Suspect Carcinogen; ACGIH A2 Carcinogen; IARC Group 2A Carcinogen US - Illinois - Toxic Air Contaminants US - Louisiana - Reportable Quantity List for Pollutants 10 Lb final RQ (receives an adjustable RQ of 10 lbs based on potential carcinogenicity in August 14, 1989 final rule); 454 kg final RQ (receives an adjustable RQ of 10 lbs based on potential carcinogenicity in August 14, 1989 final rule) 1 Lb final RQ; 0454 kg final RQ 100 Lb final RQ; 454 kg final RQ Lb RQ (unauthorized emissions based on total mass emitted into the atmosphere - see regulatory text for applicable parishes The combined emission of highly reactive volatile organic compounds (acetaldehyde, butenes, ethylene, propylene, toluene, xylene, and/or isoprene) shall be totaled to determine if a RQ has been exceeded) US - Massachusetts - Right To Know List Carcinogen; Extraordinarily hazardous Carcinogen; Extraordinarily hazardous US - Michigan - Critical Materials List 100 Lb Annual usage threshold 10 Lb Annual usage threshold Lb Annual usagethreshold US - Minnesota - Hazardous Substance List Carcinogen Carcinogen Skin US - New Jersey - Right to Know Hazardous Substance List sn 0197 sn 0207 sn 1322 Diesel Fuel No sn sn 1866 US - New York - Reporting of Releases Part List of Hazardous Substances 10 Lb RQ (air); 1 lb RQ (land/water) 1 Lb RQ (air); 1 lb RQ (land/water) 100 Lb RQ (air); 1 lb RQ (land/water) Lb RQ (air); 1lbRQ(land/water) US - North Carolina - Control of Toxic Air Pollutants mg/m3 (carcinogens) mg/m3 (carcinogens) mg/m3 (chronic toxicants);56mg/m3 (acute irritants) US - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances #19038 Page 9 of 10 Issue date 28-Sep-2009

10 US - Pennsylvania - RTK (Right to Know) List US - Rhode Island - Hazardous Substance List Inventory name Environmental hazard; Special hazardous substance Environmental hazard; Special hazardous substance Environmental hazard Environmental hazard Toxic (skin); Flammable (skin); Carcinogen (skin) Toxic Toxic; Flammable Toxic (skin); Flammable (skin) Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory No Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Issue date Effective date Expiry date 16 Other Information Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 28-Sep Sep Sep-2012 Prepared by Dell Tech Laboratories Ltd (519) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #19038 Page 10 of 10 Issue date 28-Sep-2009

11 Ultra Low Sulphur Diesel Combustible liquid May cause chronic toxic effects Eye and skin irritant Keep away from sources of ignition No smoking Avoid contact with eyes and skin Wear rubber gloves and safety glasses with side shields Keep out of reach of children EYE: Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists SKIN: Flush with cool water Wash with soap and water Obtain medical attention if irritation persists INHALATION: If symptoms develop, move victim to fresh air If symptoms persist, obtain medical attention If breathing has stopped, trained personnel should administer CPR immediately INGESTION: Do not induce vomiting Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention READ MATERIAL SAFETY DATA SHEET BEFORE USING PRODUCT ================================================================================== Liquide combustible Il peut causer des effets toxiques chroniques Irritant pour les yeux et la peau Conserver à l'écart de toutes sources d'ignition Ne pas fumer Éviter le contact avec les yeux et la peau Porter des gants en caoutchouc et des lunettes de sécurité pourvues de protections latérales Tenir hors de la portée des enfants YEUX: Rincer à grande eau froide Enlever les verres de contact, le cas échéant, et continuer à rincer Obtenir de l'attention médicale si l'irritation persiste PEAU: Rincer à grande eau froide Laver à l'eau et au savon Obtenir de l'attention médicale si l'irritation persiste INHALATION: En cas de symptômes, placer la victime à l'air frais Si les symptômes persistent, obtenir de l attention médicale Si la victime ne respire pas du personnel qualifié devrait immédiatement commencer la réanimation cardio-pulmonaire INGESTION: Ne pas faire vomir Ne jamais rien faire boire ou avaler à une victime inconsciente, ou si la victime a des convulsions Appeler un médecin LIRE LA FICHE SIGNALÉTIQUE AVANT D'UTILISER CE PRODUIT Irving Oil Refining GP