Material Safety Data Sheet

Transcription

1 * * * Section 1 - Chemical Product and Company Identification * * * Material Name DAS-Wipe 100 Product Use Stainless Steel Cleaner and Turntable Lubricant Manufacturer Information Veltek Associates, Inc. Phone: Lee Blvd. Fax: Malvern, PA USA (Emergency) FIRST RESPONDERS: For Spill/Exposure Emergency Response Service from the USA and Canada in English, Spanish, Portuguese, French, and Dutch call CARECHEM24 at For Arabic call , for Chinese call * * * Section 2 - Hazards Identification * * * Emergency Overview WARNING -- Material is an OSHA/WHMIS Combustible, DOT/TDG Flammable liquid (Flash Point = 110 F (43 C)). See Sections 5 and 14 for more information. Vapor may cause flash fire. Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back. Product is a cloudy liquid with a mint odor. This product may be irritating to the eyes, skin, gastrointestinal tract and respiratory system. May cause central nervous system depression. If swallowed, product may act as a laxative and may be aspirated into lungs and cause lung damage. Potential Health Effects: Eyes This product may cause irritation to the eyes. Potential Health Effects: Skin This product may cause irritation to the skin. Potential Health Effects: Ingestion Ingestion of this product may result in irritation and central nervous system effects including headache, sleepiness, dizziness, slurred speech and blurred vision. Material, if swallowed, can be aspirated into lungs and cause lung damage. Material can act as a laxative. Potential Health Effects: Inhalation May cause irritation to the nose and respiratory tract. Inhalation may cause central nervous system depression with symptoms such as weakness, dizziness, confusion and drowsiness. Medical Conditions Aggravated by Exposure Persons with pre-existing skin, eye and respiratory disorders may be aggravated by exposure to product. HMIS Ratings: Health: 2 Fire: 2 Physical Hazard: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 3 - Composition / Information on Ingredients * * * CAS # Component/CAS # Percent White mineral oil Naphtha (petroleum), hydrotreated heavy Petroleum distillates, hydrotreated middle Page 1 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10

2 Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Oil mist, mineral ( ), Petroleum distillates (naphtha) ( ). Component Information/Information on Non-Hazardous Components This product is considered hazardous under 29 CFR (Hazard Communication). This product is a controlled product according to the Canadian Controlled Product Regulations. * * * Section 4 - First Aid Measures * * * First Aid: Eyes Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists get medical attention. First Aid: Skin For skin contact flush with large amounts of water while removing contaminated clothing. Wash contaminated clothing before reuse. If irritation persists, get medical attention. First Aid: Ingestion Aspiration hazard. If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. First Aid: Inhalation If inhaled, immediately remove the affected person to fresh air. Call a physician if symptoms develop or persist. Give artificial respiration if not breathing. Call a physician immediately. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards See Section 9 for Flammability Properties. Moderate fire hazard. Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back. Vapor/air mixtures are explosive. Hazardous Combustion Products Oxides of carbon. Extinguishing Media Dry chemical, alcohol-resistant foam, carbon dioxide, water fog. Fire Fighting Equipment/Instructions Firefighters should wear full protective clothing including self contained breathing apparatus. Clear area of unprotected personnel. Move container from area if it can be done without risk. Cool containers with water spray until well after fire is out to prevent vapor build up, which could result in container rupture. Do not scatter spilled material with high-pressure water streams. NFPA Ratings: Health: 2 Fire: 2 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Contain the discharged material, if this is without risk. Reduce vapors with water spray. Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Equipment must be grounded to prevent sparking. Block any potential routes to water systems. Clean-Up Procedures Wear appropriate protective equipment and clothing during clean-up. Eliminate ignition sources including sources of electrical, static or frictional sparks. Ventilate the contaminated area. Absorb with inert material. Shovel material into appropriate container for disposal. Use non-sparking tools and ensure all equipment is grounded. Page 2 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10

3 Evacuation Procedures Isolate area. Keep unnecessary personnel away. Special Procedures Regulations vary. Consult local authorities before disposal. * * * Section 7 - Handling and Storage * * * Handling Procedures Avoid getting this material into contact with your skin and eyes. Avoid breathing vapors or mists of this product. Keep this product from heat, sparks, or open flame. Use non-sparking tools when opening or closing containers. Do not cut or weld on empty drums. Sufficient vapors from residues may be present to cause explosion and serious injury and/or death. Storage Procedures Keep the container tightly closed and in a cool, well-ventilated place. Do not store in sunlight. Eliminate all sources of ignition. Do not store, incinerate, or heat this material above 110 F (43 C). Keep away from incompatible materials. * * * Section 8 - Exposure Controls / Personal Protection * * * A: Component Exposure Limits ACGIH: 5 mg/m3 TWA (excluding metal working fluids, highly & severely refined, inhalable fraction) OSHA (Final): 5 mg/m3 TWA OSHA (Vacated): 5 mg/m3 TWA NIOSH: 5 mg/m3 TWA 10 mg/m3 STEL Alberta: 5 mg/m3 TWA 10 mg/m3 STEL British Columbia: 1 mg/m3 TWA (severely refined) Manitoba: 5 mg/m3 TWA (excluding metal working fluids, highly & severely refined, inhalable fraction) New Brunswick: 5 mg/m3 TWA (as sampled by a method that does not collect vapor) (related to Oil mist, mineral) 10 mg/m3 STEL 5 mg/m3 TWA (excluding metal working fluids, highly & severely refined, inhalable fraction) NW Territories: 5 mg/m3 TWA 10 mg/m3 STEL Nova Scotia: 5 mg/m3 TWA (excluding metal working fluids, highly & severely refined, inhalable fraction) Nunavut: 5 mg/m3 TWA 10 mg/m3 STEL Ontario: 5 mg/m3 TWAEV 10 mg/m3 STEV (mist) 5 mg/m3 TWA (excluding metal working fluids, highly & severely refined, inhalable fraction) Quebec: 5 mg/m3 TWAEV (mist) 10 mg/m3 STEV (mist) Saskatchewan: Present 5 mg/m3 TWA 10 mg/m3 STEL Yukon: 5 mg/m3 TWA 10 mg/m3 STEL Page 3 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10

4 OSHA (Vacated): 400 ppm TWA; 1600 mg/m3 TWA (related to Petroleum distillates (naphtha)) NIOSH: 350 mg/m3 TWA (related to Petroleum distillates (naphtha)) 1800 mg/m3 Ceiling (15 min) (related to Petroleum distillates (naphtha)) OSHA (Vacated): 400 ppm TWA; 1600 mg/m3 TWA (related to Petroleum distillates (naphtha)) NIOSH: 350 mg/m3 TWA (related to Petroleum distillates (naphtha)) 1800 mg/m3 Ceiling (15 min) (related to Petroleum distillates (naphtha)) Engineering Controls Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Explosion proof exhaust ventilation should be used. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear chemical goggles; face shield (if splashing is possible). Personal Protective Equipment: Skin Chemical resistant gloves should be used at all times when handling this product. Personal Protective Equipment: Respiratory If ventilation is not sufficient to effectively prevent buildup of vapors, appropriate NIOSH/MSHA respiratory protection must be provided. If oil mist is generated, appropriate dust/mist respirator should be provided. Personal Protective Equipment: General Eye wash fountain and emergency showers are recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: White, cloudy liquid Odor: Mint Physical State: Liquid ph: Not available Vapor Pressure: <0.5 mmhg Vapor Density: Not available Boiling Point: >330 F (166 C) Melting Point: Not available Freezing Point: Not available Solubility (H2O): Not available Specific Gravity: Evaporation Rate: <1 VOC: <12% Upper Flammability Limit (UFL): Not available Lower Flammability Limit (LFL): Not available Flash Point: 110 F (43 C) Flammability Class: Class IIIA Auto Ignition: F ( C) Odor Threshold Not available Water/Oil Dist Coeff Not available Octanol/H2O Coeff.: Not available Oxidizing Properties None Explosive Properties Not available * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability Stable under recommended conditions of storage and handling. Chemical Stability: Conditions to Avoid Keep away from heat, ignition sources and incompatible materials. Incompatibility Acids, oxidizing materials, combustible materials, peroxides, chlorine. Hazardous Decomposition Oxides of carbon. Page 4 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10

5 Possibility of Hazardous Reactions Will not occur. * * * Section 11 - Toxicological Information * * * Acute Dose Effects Excessive inhalation or ingestion of this material may cause central nervous system depression. Symptoms include headache, dizziness, nausea and loss of coordination. May cause irritation of the eyes, skin, gastrointestinal tract or respiratory system. If ingested, product may act as a laxative. If ingested, product can be aspirated into the lungs and cause lung damage.. B: Component Analysis - LD50/LC50 Oral LD50 Rat >5000 mg/kg Oral LD50 Rat >5000 mg/kg; Dermal LD50 Rabbit >3160 mg/kg Inhalation LC50 Rat 4.6 mg/l 4 h; Oral LD50 Rat 7400 mg/kg; Dermal LD50 Rabbit >2000 mg/kg Carcinogenicity No carcinogenicity data available for this product. B: Component Carcinogenicity ACGIH: A4 - Not Classifiable as a Human Carcinogen (highly & severely refined) IARC: Monograph 45 [1989] (related to Petroleum distillates (naphtha)) (Group 3 (not classifiable)) IARC: Monograph 45 [1989] (related to Petroleum distillates (naphtha)) (Group 3 (not classifiable)) Target Organ Effects Central Nervous System (CNS), Lungs. * * * Section 12 - Ecological Information * * * Ecotoxicity No information available for the product. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Test & Species Conditions 96 Hr LC50 Lepomis macrochirus >10000 mg/l Test & Species Conditions 96 Hr LC50 Pimephales promelas 2200 mg/l 96 Hr LC50 Chaetogammarus marinus 2.6 mg/l Page 5 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10

6 Test & Species Conditions 96 Hr LC50 Pimephales promelas 35 mg/l Flow-through 96 Hr LC50 Pimephales promelas >10000 mg/l Static 24 Hr EC50 Daphnia magna 36 mg/l 48 Hr EC50 Daphnia magna <0.26 mg/l Static; related to Petroleum distillates (naphtha * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions No additional information available. B: Component Waste Numbers No EPA Waste Numbers are applicable for this product's components. Disposal Instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. If discarded, this product is considered a RCRA ignitable waste, D001. See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Not regulated as hazardous materials. TDG Information Shipping Name: Not regulated as dangerous goods. * * * Section 15 - Regulatory Information * * * US Federal Regulations All components are on the U.S. EPA TSCA Inventory List. B: Component Analysis None of this products components are listed under SARA Section 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR ), or CERCLA (40 CFR 302.4). SARA 311/312 Acute Health: Chronic Health: No Fire: Pressure: No Reactive: No State Regulations Other state regulations may apply. Check individual state requirements. CARB/OTC VOC regulations for consumer products: Check state or local air quality regulations regarding the sale of this product for consumer use. B: Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI White mineral oil (related to Oil mist, mineral) Page 6 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10

7 Naphtha (petroleum), hydrotreated heavy (related to Petroleum distillates (naphtha) Petroleum distillates, hydrotreated middle (related to Petroleum distillates (naphtha) No No Canadian WHMIS Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all information required by CPR. All components in this product are listed on the Canadian Domestic Substances List (DSL). B: Component Analysis - WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List: Component/CAS # CAS # Minimum Concentration White mineral oil % WHMIS Classification: B3- Combustible Liquid D2B- Toxic Material Additional Regulatory Information No additional information available. B: Component Analysis - Inventory Component/CAS # CAS # TSCA CAN EEC White mineral oil DSL EINECS Naphtha (petroleum), hydrotreated heavy DSL EINECS Petroleum distillates, hydrotreated middle DSL EINECS * * * Section 16 - Other Information * * * Other Information No additional information available. MSDS History Revision , Regulatory update: 30 June Revision 1:0000, New MSDS: 06 July Key/Legend ACGIH = American Conference of Governmental Industrial Hygienists; CERCLA = Comprehensive Environmental Response, Compensation and Liability Act; CFR = Code of Federal Regulations; CNS = Central Nervous System; DSL = Domestic Substances List; EINECS = European Inventory of Existing Commercial Chemical Substances; EPA = Environmental Protection Agency; HEPA = High Efficiency Particulate Air filters; IARC = International Agency for Research on Cancer; LC50 = Lethal Concentration 50%; LD50 = Lethal Dose 50%; NIOSH = National Institute for Occupational Safety and Health; NJTSR = New Jersey Trade Secret Registry; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit; RCRA = Resource Conservation and Recovery Act; SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit; TDG = Transport Dangerous Goods TSCA = Toxic Substance Control Act; TWA = Time Weighted Average; WHMIS = Workplace Hazardous Materials Information System. End of Sheet DAS-0001 Page 7 of 7 Issue Date: 06/30/10 Revision: Effective Date: 6/30/10