DuPont Biofuels: Building a Sustainable Future. Dennis Magyar Industry Manager North America DuPont Biofuels IFMA 17 July 22, 2009

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1 DuPont Biofuels: Building a Sustainable Future Dennis Magyar Industry Manager North America DuPont Biofuels IFMA 7

2 DuPont Mission Sustainable Growth 2 The creation of shareholder and societal value while we reduce the environmental footprint* along the value chains in which we operate. * DuPont defines footprint as all injuries, illnesses, incidents, waste, emissions, use of water and depletable forms of raw materials and energy.

3 Sales by Market $30.5B PLASTICS & CHEMICALS 9% AIRCRAFT & AEROSPACE 4% 3 AGRICULTURE/ FOOD 29% MOTOR VEHICLES 20% TEXTILES / HOME FURNISHINGS 5% OTHER 3% ELECTRONICS 9% CONSTRUCTION MATERIALS %

4 Applied BioScience Platform at DuPont exploring carbohydrate based business opportunities 4 Agricultural Inputs Plant Feedstocks Conversion to Sugars Fermentation Processes Biofuels Biochemicals Seed Crop Protection CO2 Sugar Molecular Biology Starch Biomaterials Cellulose Differentiated Products Biofuels

5 Biofuel Demand Drivers and Market Issues Transportation Fuels - Abundance of Issues 5 Pending demand increase for transport fuel Global concern over the environment Biofuels BGY Opportunity* Real concern over security of supply and cost Increasing demand on agriculture World continues its historic change Energy is the globe s greatest economic threat and opportunity over the next decade * 2020 DuPont estimate

6 6 Global Biofuel Value Chain Challenges Upstream Downstream Feedstock Adequate Regional Supply Developing Non-food Feedstock Refinery & Pipeline Biofuel Compatibility With Existing Gas Refinery Infrastructure Retail & Consumer Uncompromised Fuel Performance Compatibility with existing infrastructure Current biofuel solutions are inadequate to meet global needs

7 DuPont Technologies Address Market Challenges Feedstock Options Better Fuels 7 PRODUCTION PER ACRE CELLULOSE CONVERSION REFINERY BLENDING FUEL COMPATIBILITY MILEAGE ENGINE DURABILITY DuPont Danisco Cellulosic Ethanol LLC DuPont BP Partnership

8 DuPont Biofuels: Three Strategies 8 Solutions for Sustainable Feedstock Agricultural Inputs Seeds & Crop Protection Cellulosic Ethanol Biofuels From Biomass Biobutanol Advanced Biofuels

9 # - Solutions for Sustainable Feedstock 9 more bushels per acre & more ethanol per bushel

10 Pioneer the World Leader in Seed Genetics ~$4.0 billion in sales 8,500 employees ~$2MM / day in research # or #2 position in most crops worldwide Corn Soybean Canola Sunflower Alfalfa Wheat Sorghum Rice Hybrid Rice Cotton 0 Founded By Henry Wallace as the Hi-Bred Seed Company in 926 the first company to develop, produce and market hybrid seed corn

11 Commercial Honduras Nicaragua Guatemala Costa Rica Countries where Pioneer Markets Seed Panama Production 9 locations Countries with Production Facilities Research 92 locations Countries with Research Facilities Pioneer s Global Reach Sales, Seed Production and Research Canada 3 Colombia 7 USA Venezuela Bolivia México Chile 4 3 Jamaica Haiti Belize Brazil 6 Dominican Republic Puerto Rico 7 Barbados Uruguay Argentina Morocco Grenada Trinidad & Tobago Paraguay Finland Sweden Norway Estonia Latvia Lithuania Belarus South Africa Zambia Belgium Luxembourg Switzerland Portugal Russia Turkey Malawi Zimbabwe Netherlands United Kingdom Saudi Arabia Spain Pakistan Egypt 2 Ethiopia Kenya 2 Tanzania Denmark 4 France India Germany Thailand China Indonesia Czech Republic Poland Austria Romania Vietnam Australia Slovakia Ukraine Japan Italy Moldova Slovenia Hungary Croatia Bosnia- Bulgaria Herzegovina Greece Serbia & Albania Macedonia South Korea Montenegro Philippines New Zealand more bushels per acre & more ethanol per bushel

12 2 Pioneer Corn Yield Growth Target Current rate of genetic gain is expected to double from today s.5% per year Pioneer is targeting a 40% growth in U.S. corn yield in the next 0 years Current World Record: 442 bushels / acre 54 bushels per acre in 2008 (US average) 20 bushels per acre targeted by 208 Factors contributing to yield lift: Elite germplasm Accelerated Yield Technology (AYT) combination of breeding technologies and techniques that enable genetic gains far greater than any of the individual components Product positioning (getting the right product on the right acre) Next generation herbicide tolerance and insect protection more protection on more acres Agronomic traits drought tolerance, nitrogen use efficiency, disease and pest resistance Transgenic yield (corn trait target is 0% increase; soybean trait target is 8% increase) Yield Lift 40% 30% 20% 0% 40% Corn Yield Improvement (Projection) 0% Agronomic Traits Optimum Bt AcreMax Product Positioning AYT Elite Germplasm

13 3 Pioneer Research Focus Opportunities for crop productivity research include: The need to make presently unusable soils productive The need to increase the genetic potential of individual production and farming systems Pioneer is working on technologies to better utilize input resources Drought tolerance traits in corn Nitrogen use efficiency (NUE) With & Without NUE Trait

14 Pioneer Cellulosic Feedstock Development 4 Pioneer is evaluating options with alternative feedstock crops Cob and Stover characterization how much variation exists in existing corn genetics Define compositional improvement targets Exploration of new energy crop alternatives (switchgrass, sweet sorghum, other) Harvest and storage considerations Soil management and fertility how much residue should be removed Impact on farming operations (farming speed, management complexity)

15 #2 Cellulosic Ethanol 5 Deliver Innovations that Transform the Market Upstream Feedstock Technology for Conversion of Non-Food Feedstock to Ethanol DuPont Danisco Cellulosic Ethanol LLC

16 6 Uniting two leaders in cellulosic ethanol 50/50 joint venture between DuPont and Danisco/Genencor $40 million investment over 3 years Commercialize integrated technology to produce cellulosic ethanol Full license & engineering package including: on site enzyme production future design improvements Feedstock-flexible demonstration plant in 2009 Commercial deployment 25MGY cob plant in Midwest in 202 5MGY switchgrass plant in TN in ~203

17 The Challenges: Path to Commercialization Technical Development Capital costs Operating costs Develop Feedstock Supply Chain External Factors Political support Market demand Access to capital 7

18 The world s first robust, integrated solution for biomass-to-ethanol 8 Pretreatment Enzymatic hydrolysis Mixed sugar ethanologen Including: >$00 million invested since 2000 DOE & NREL support & collaboration Significant enabling patent estate Demonstrated capabilities in scale up & design

19 Demonstration Plant Vonore, Tennessee Joint investment including $40.7 million from Tennessee Nameplate capacity 250kgal/yr On-line 4Q 2009 Process development unit, pelletizer on site Applications lab/ support capability Focus on optimal US feedstocks: corn cob and switchgrass 9

20 Technology Status Key Metrics Cobs to Ethanol 20 Enzyme Cost; Initial Introduction Current Estimates SELECT INPUT VARIABLES Commercial Scale Percent Reduction CAPEX; ($ / Gal) (2008 Dollars) Total process yield; (Gal/T) $8+ $5 to $7 ~$3 to $5 PROCESS RESULTS MESP; ($/Gal) ~ $3.00 ~$2.00 ~$.50 $50/T BIOMASS

21 2 Cellulosic Ethanol and Gasoline Trends $3.70 GASOLING EQUIVALENT COMPETITIVE COMPARISONS Gasoline Equivalent Competitive Comparison $40 $3.50 $3.30 Crude Oil $/BBL Gasoline Rack Price $/Gal $20 $00 Price $/gal $3.0 $2.90 $80 $60 $2.70 Technology (50MM) $/Gal $40 $2.50 Technology (00MM) $/Gal $20 $ $0 Price$/gal is energy equivalent and $50/ton biomass

22 The Challenges: Path to Commercialization Technical Development Capital costs Operating costs Develop Feedstock Supply Chain External Factors Political support Market demand Access to capital 22

23 23 Value Chain Needs to be Organized Sales Direct or via Marketer Feed Users Seed Farmer corn grain Ethanol grain to ethanol Enzyme Supplier Ethanol cob to ethanol EtOH DDGS or MDGS EtOH Sales Direct or via Marketer Terminal Blender & Distributor Fuel Marketer [gas] Transportation Industry Consumer unique for cellulose to ethanol production Cultivation Farmer Cob Harvest Farmer Cob processing Cob Transport Cob Supply Storage

24 24 US Cellulosic Potential DDCE Feedstocks Tons/ BGY Under RFS # 50 MGY Sq miles Required for feedstock Acre Plants Cobs ,000 Switchgrass 0 6 (20*) Sorghum , ,250 (30*) * DDCE estimates for market potential with increased Cellulosic ethanol demand

25 25 Upstream Value Chain Formation Cob Research in harvest, storage and transport Challenges: Grower programs, densification, moisture issues Switchgrass State of TN program - $30M for upstream development Selected farmers received 3 year acreage based contract: Incentive payment of $450 /acre /year for costs of production and opportunity costs Alamo switchgrass seed & technical expertise Total program expanding to ~6,000 acres

26 Conclusions 26 Cellulosic ethanol is ready for commercial deployment Technical challenges have been largely met Remaining challenges are scale-up, investment & supply chain development DDCE is committed to the long haul and to building this industry Demonstration Facility in MGY Cob plant in MGY Switchgrass plant in 203

27 27 #3 An Advanced Biofuel - biobutanol Deliver Innovations that Transform the Market Downstream Downstream Refinery & Pipeline Compatibility With Existing Gas Refinery Infrastructure Retail & Consumer Uncompromised Fuel Performance

28 28 Biobutanol the Advanced Biofuel BP & DuPont announced June 2006 RENEWABLE FEEDSTOCKS WORLDWIDE FUEL MARKETS Powerful partnership Shared commitment Global reach Complementary capabilities

29 Biobutanol Performance Advantages 29 PIPELINE BIOFUEL PRODUCTION DIVERSE AGRICULTURAL FEEDSTOCKS UTILIZE ETHANOL PRODUCTION ASSETS SUPPORT AGRICULTURAL DEVELOPMENT REFINERY TERMINAL LIMITED WATER ABSORPTION FUNGIBLE BLENDING LOW VAPOR PRESSURE UTILIZE EXISTING INFRASTRUCTURE RETAIL / AUTO INDUSTRY / CONSUMER 26% HIGHER ENERGY DENSITY THAN ETHANOL POTENTIAL FOR HIGHER BLEND LEVELS WITHOUT VEHICLE MODIFICATION (> 0%) NO INCREASE IN CO, HC, NOx EMISSIONS

30 The Challenge: Competitive Biobutanol COM 30 The Feedstock Corn, Wheat, Sugarcane, Cellulose Converted to Sugar for Fermentation C 6 H 2 O 6 Sugar The Molecule Butanol C 4 H 0 O Incumbent Bioprocesses ABE Process (Acetone-Butanol-Ethanol) C 6 H 2 O 6 Sugar C 3 H 6 O Acetone C 4 H 0 O + Butanol + The New and Improved Bioprocess Develop a cost effective route to biobutanol C 6 H 2 O 6 Sugar C 4 H 0 O Butanol C 2 H 6 O Ethanol

31 Biobutanol-Manufacturing 3 Biological Factory (Cell) Carbon (glucose) Approach: Add genes (DNA) for production of biobutanol DNA mrna Butanol Enzymes Toolset Microbiology Molecular Biology Biochemistry Genomics/Bioinformatics Protein Engineering High Throughput Screening Fermentation DuPont was First in World to Demonstrate Biobutanol via Synthetic Pathways Patents filed 2005 Fermentation Metrics Rate Titer Yield

32 32 Biobutanol Value Proposition Biobutanol delivers significantly improved logistics & fuel performance across the value chain Attributes Lower Distribution Costs Higher Blending Value and Higher Blend Levels Infrastructure compatibility Miles per gal. Value Added Pricing Distribution Refinery flexibility efficiencies Higher energy density (26%) Greater compatibility with existing engine designs and other materials Synergistic with Ethanol Price* Ethanol Biobutanol * Normalized ethanol price / Graph illustrates sources of value / Not to scale

33 Biobutanol Value Proposition 33 Break Break through through the the Blend Blend Wall Wall which which is is the the point point where where regulatory regulatory obligations obligations for for ethanol ethanol blending blending exceeds exceeds what what can can be be sold sold in in the themarketplace Barriers to breaching the blend wall Permissible blend levels in fuel Capabilities of existing car park Retail infrastructure Options for breaking through the blend wall -- Fuels Fuels Increased Increased blend blend levels levels for for all all vehicles vehicles Increase Increase blend blend levels levels for for some some vehicles vehicles Increased Increased E85 E85 sales sales Biobutanol Biobutanol Vehicles Vehicles Extend Extend warranties warranties on on existing existing vehicles vehicles Increase Increase capability capability of of new new vehicles vehicles Increase Increase FFV FFV sales sales Biobutanol Biobutanol Retail Retail Recertify Recertify existing existing retail retail kit kit Replace/Upgrade Replace/Upgrade existing existing kit kit Install Install E85 E85 Pumps Pumps Biobutanol Biobutanol

34 34 Biobutanol Commercialization Strategy Scale-up technology from lab to demonstration plant to commercial production Work with biofuel producers, regulators, policy makers, and OEMs to qualify and accelerate global adoption of biobutanol License biobutanol technology to other companies Ethanol plant conversion to biobutanol production Greenfield biobutanol plants Enable supply chain and distribution network for biobutanol product globally

35 35 Conversion to Biobutanol Key Modification Areas: Fermentation Distillation using Standard equipment New microorganism New operating procedures

36 Odometers (Miles) Biobutanol Commercialization Strategy Large Fleet Vehicle Testing Large Fleet Odometers 36 Key objectives objectives are are to to identify identify key key performance performance issues issues (engine (engine cleanliness, cleanliness, deposits deposits and and regulated regulated emissions), emissions), and and assess assess long long term term effects effects (component (component compatibility, compatibility, driveability, driveability, consumer consumer acceptance, acceptance, ) ) Over vehicles, vehicles, up up to to 0 0 years years old old Accumulation of of more more than than.3.3 million million miles miles using using blends blends of of up up to tto 6% 6% butanol butanol Auto company company engagement engagement is is on-going on-going No fuel fuel related related problems problems observed observed Vehicles

37 Biobutanol Technology Demonstration Plant 37 Biobutanol demonstration plant sited on existing BP site at Kingston upon Hull in UK Completion in 200 Biobutanol Demo Plant (proposed) 00MM GPY EtOH Plant (proposed) Accelerate availability of commercial technology for scale-up to 50-00MM GPY Same site as 00 MM GPY ethanol plant

38 Biobutanol Process Performance & Commercial Demonstration 38 % Cost Goal Foundation IP established Synthetic pathways proven Host microorganisms selected Demonstration plant designed Demonstration plant operation Microorganism optimization Process optimization Metrics & Goals 2007 superior to ABE process 20 cost equivalent to ethanol Patents Over 70 patent applications Commercial Goal Commercial Demonstration - Biology - Fermentation process - Chemical conversion - End use applications Time (yr) 203

39 Summary 39 DuPont Delivers Innovations that Transform the Market Upstream Downstream Feedstock Refinery & Pipeline Retail & Consumer Cellulosic Ethanol Biobutanol Thank you!

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