RECOVERY CHEM TM ECBLRBAC SPRING 2008 SAINT JOHN, NB

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1 RECOVERY CHEM TM ECBLRBAC SPRING 2008 SAINT JOHN, NB

2 RECOVERY CHEM TM PRESENTATION OVERVIEW COMPUTATIONAL FLUID DYNAMICS (CFD) MODELING TARGETED IN FURNACE INJECTION (TIFI) APPLICATION EQUIPMENT ANATOMY OF AN INJECTION SYSTEM CHEMICAL PRODUCTS- WHY USE Mg(OH) 2? CASE HISTORY- IRVING PULP & PAPER.

3 TARGETED IN FURNACE INJECTION THE USE OF COMPUTATIONAL FLUID DYNAMICS MODELING TO EFFECTIVELY TARGET CHEMICAL TREATMENT TO THE AREAS NEEDED IN THE BOILER.

4 TARGETED IN FURNACE INJECTION BOILER GEOMETRY INJECTOR LOCATIONS GAS FLOW DIRECTION & TEMPERATURE ADEQUATE CHEMICAL CONCENTRATION IN CRITICAL AREAS

5 WHAT TYPE OF EQUIPMENT IS TYPICALLY USED IN TIFI?

6 RECOVERY CHEM APPLICATION EQUIPMENT CHEMICAL STORAGE TANK

7 RECOVERY CHEM APPLICATION EQUIPMENT CHEMICAL BOOST/RECIRCULATION PUMP

8 RECOVERY CHEM APPLICATION EQUIPMENT CHEMICAL METERING PUMP

9 RECOVERY CHEM APPLICATION EQUIPMENT CHEMICAL AND AIR MANIFOLDS CHEMICAL AIR

10 RECOVERY CHEM APPLICATION EQUIPMENT MANIFOLD INSTALLATION

11 RECOVERY CHEM APPLICATION EQUIPMENT FUEL TECH STANDARD INJECTOR

12 RECOVERY CHEM APPLICATION EQUIPMENT INJECTOR PORT

13 ANATOMY OF A TYPICAL INJECTION SYSTEM INJECTORS AIR WATER MANIFOLDS TANK BOOST/ RECIRC CHEMICAL METERING

14 WHY DOES FUEL TECH USE Mg(OH) 2 BASED PRODUCTS FOR RECOVERY CHEM?

15 BENEFITS OF MAGNESIUM HYDROXIDE FOR SLAG CONTROL STARTS AS 5mu PARICLES IN SLURRY. PLATLET STRUCTURE CAUSES EXPLOSION OF PARTICLES..04mu PARTICLES MUCH SMALLER AND HAVE GREATER SURFACE AREA. MUCH HIGHER REACTIVITY. SUCCESS IS ACHEIVED BY PROPER DISTRIBUTION & SMALLER PARTICLE SIZE.

16 RECOVERY CHEM TM CASE HISTORY: IRVING PULP & PAPER SAINT JOHN, NB CANADA

17 CASE HISTORY- IRVING PULP & PAPER 1970 B&W UK DESIGN; 2.4MM#/DAY DEG F BOILER NEARLY RECTANGULAR (28 6 WIDE X 27 5 X 76 6 HIGH) SLIGHLTY LOW ASPECT RATIO 2.72 OVERLOADING & PLUGGING BEGAN IN 1980 S BLACK LIQUOR WAS TRUCKED DAILY

18 CASE HISTORY- IRVING PULP & PAPER UPGRADES PRIOR TO TREATMENT ADDED PRIMARY 2 SUPERHEATER ADDED10 IK SOOTBLOWERS (#71-80) ADDED IKS TO BACK OF NEW ECON. WATER COIL AIR HEATER TERTIARY FAN UPGRADE

19 CASE HISTORY- IRVING PULP & PAPER UPGRADES PRIOR TO TREATMENT NEW SEC. SUPERHEATER NEW UPPER SCREEN TUBES STATIONARY FIRING OPTIMIZED SOLIDS INCREASED FROM 65% TO 71%

20 CASE HISTORY- IRVING PULP & PAPER UPGRADES PRIOR TO TREATMENT NEW STEAM DRUM INTERNALS. IMPLEMENTED CONSUMED AIR STRATEGY OPERATION. INCREASED TO 3.2 MM# DRY SOLIDS/DAY LATE 1994 ASH MODIFIER TRIAL.

21 BASELINE DATA- DRY PROGRAM IRVING RECOVERY BOILER GEN BANK Dp- BASELINE / DRY PROGRAM dp INCHES WATER DAYS

22 CASE HISTORY- IRVING PULP & PAPER RECOVERY CHEM SYSTEM INSTALLED IN 1995

23 RECOVERY CHEM 2 ND RUN IRVING RECOVERY BOILER GEN BANK dp- 2 nd RUN dp INCHESWATER DAYS

24 RECOVERY CHEM 3 RD RUN IRVING RECOVERY BOILER TARGETED-IN-FURNACE INJECTION, 3 RD RUN INCHES WATER NO MgO FED MgO FEED BACK ON MLBS DRY SOLIDS/DAY DAYS

25 WILL MECHANICAL CHANGES ELIMINATE THE NEED FOR RECOVERY CHEM TREATMENT?

26 CASE HISTORY- IRVING PULP & PAPER BOILER UPGRADES AFTER TREATMENT (1996 TO CURRENT) ANOTHER (3 RD PARTY) CFD MODEL COMPLETED. AIR OPTIMIZATION OF BOILER. ADDED TERTIARY OPENINGS RE-ROUTED SCREEN RISER TUBES.

27 CASE HISTORY- IRVING PULP & PAPER BOILER UPGRADES/CHANGES AFTER TREATMENT (1996 TO CURRENT) NEW SEC AIR DAMPERS NEW WINDBOXES STARTED PURGING PRECIP. CHLORIDES

28 CASE HISTORY- IRVING PULP & PAPER BOILER UPGRADES/CHANGES AFTER TREATMENT (1996 TO CURRENT) OPTIMIZED PERIMETER FIRING. DECREASED SOLIDS TO 72% MAINTAINED 3.8 MM#/DAY DRY SOLIDS EVEN AFTER LOWERING %

29 CASE HISTORY- IRVING PULP & PAPER BOILER UPGRADES/CHANGES AFTER TREATMENT (1996 TO CURRENT) CONTINUOUS SO2 ANALYZER. INCREASING HARDWOOD FIBER. CAN PEAK TO 4.1 MM#/DAY DRY SOLIDS FIRING.

30 50% DOSAGE REDUCTION TRIAL /26/98 IRVING RECOVERY BOILER DOSAGE REDUCTION TRIAL- DEC LBS/TON 0.35 LBS/TON 0.7 LBS/TON dp INCHES WATER NORMAL HALF NORMAL 11/26/98 11/21/98 11/16/98 12/6/98 12/1/98 12/16/98 12/11/98 12/21/98

31 25% DOSAGE REDUCTION TRIAL IRVING RECOVERY BOILER DOSAGE REDUCTION TRIAL- AUG-OCT dp INCHES WATER NORMAL DOSAGE 10% BELO W 25% BELO W NORMAL 7/8/2000 6/24/2000 8/5/2000 7/22/2000 9/2/2000 8/19/2000 9/30/2000 9/16/ /28/ /14/ /25/ /11/2000

32 2X DOSAGE INCREASE TRIAL 0.35 dp (inches of H2O) Linear Regression FC100RB Dosage (lbs/ton) Recovery Boiler SH + GB dp Inches of H2O FC100RB dosage (lbs/ton) FC100RB Baseline Dosage 0.7 lbs/ton Dosage Increase Trial 1.4 lbs/ton /1/01 6/8/01 6/22/01 6/15/01 7/6/01 6/29/01 7/20/01 7/13/01 8/3/01 7/27/01 8/17/01 8/10/01 9/7/01 8/31/01 8/24/01 9/21/01 9/14/01 10/5/01 9/28/01 10/26/01 10/19/01 10/12/01 DATE

33 WHY CHOOSE FUEL TECH FOR YOUR RECOVERY BOILER TREATMENT NEEDS? OUR EXPERIENCE- DERIVED FROM FOCUSING SOLELY ON FIRESIDE ISSUES. OUR PEOPLE - DEDICATED LOCAL REPRESENTATION. OUR COMMITMENT- TO PROVIDING VALUE ADDED-SERVICE AND CLEARLY DEMONSTRATINGTHE CUSTOMER S ROI.

34 THANK YOU QUESTIONS?

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