Section 1: Identification of the,substance/mixture and of the Company/Undertaking

Transcription

1 While Sidewall Veneer Safety Data Sheet Section 1: Identification of the,substance/mixture and of the Company/Undertaking 1.1 Product identifier Product Name Product Code White Sidewall Veneer 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) Tire repair 1.3 Details of the supplier of the safety data sheet Manufacturer Patch Rubber Company 100 Patch Rubber Road Weldon, NC United States Telephone (General) (252) Responsible party Christian Gimenez lntertek Analytical Services France France Telephone (Technical) 33 (0) Emergency telephone number Manufacturer Manufacturer I Section 2: Hazards Identification EU/EEC According to EU Directive 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010) According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP t Classified - Classification criteria not met DSD/DPD t Classified - Classification criteria not met 2.2 Label Elements CLP Hazard statements. label element(s) required Page 1 or 26 Fom1at: EU CLP/REACH Language: English (US)

2 DSD/DPD 2.3 Other Hazards CLP DSD/DPD Risk phrases label element(s) required. United States (US) According to OSHA 29 CFR HCS 2.1 Classification of the substance or mixture OSHA HCS Label elements OSHA HCS 2012 According to Regulation (EC). 1272/2008 (CLP) this material is not considered hazardous. According to European Directive 1999/45/EC this preparation is not considered dangerous. Skin Sensitization 1 - H317 Reproductive Toxicity 2 - H361 WARNING Hazard statements. May cause an allergic skin reaction - H317 Suspected of damaging fertility or the unborn child. - H361 Precautionary statements Prevention Obtain special instructions before use. - P201 Do not handle until all safety precautions have been read and understood. - P202 Avoid breathing dust/fume. - P261 Contaminated work clothing should not be allowed out of the workplace. - P272 Wear protective gloves/protective clothing/eye protection/face protection. - P280 Response If on skin: Wash with plenty of water. Specific treatment, see supplemental first aid information. - P321 If skin irritation or rash occurs: Get medical advice/attention. - P333+P313 Wash contaminated clothing before reuse. - P363 IF exposed or concerned: Get medical advice/attention. - P308+P313 Storage/Disposal Store locked up. - P405 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P Other hazards OSHA HCS 2012 Canada According to WHMIS 2.1 Classification of the substance or mixture WHMIS 2.2 Label elements WHMIS Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Other Toxic Effects - D2A Other Toxic Effects - D2A Page 2of 28 Fonnat: EU CLP/REACH Language: English (US)

3 2.3 Other hazards WHMIS In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). See Section 12 for Ecological Information. Section 3 - Composition/Information on Ingredients 3.1 Substances 3.2 Mixtures Material does not meet the criteria of a substance in accordance with Regulation (EC) 1272/2008. Chemical Name Titanium dioxide Kaolin Zinc oxide Stearic acid Silica, amorphous Composition Identifiers % LD50/LC50 CAS: % EC TO NDA Number: % Benzothiazolesulfenamide, N-tert-butyl- CAS: CAS: EC Number: CAS: EINECS: CAS: EC Number: % NDA 4.89% TO 4.94o/o NOA Skin-Rabbit L050 > % TO mg/kg 0.56 /o Ingestion/Oral-Rat L050 >6000 mg/kg 0.45o/o CAS: EC 0.28 /o NOA Number: Skin-Rabbit L050 >5 g/kg Ingestion/Oral-Rat L mg/kg Classifications According to Regulation/Directive EU DSDIDPD: Self Classified: Care. 3 R40; N R51-53 EU CLP: Self Classified: Care. 2, H351 OSHA HCS 2012: Care. 2 EU DSD/DPD: ne EU CLP: ne OSHA HCS 2012: ne EU DSDIDPD: Annex I: N; R50-53 EU CLP: Annex VI: Aquatic Acute 1, H400; Aquatic Chronic 1, H41 O OSHA HCS 2012: Eye lrrit. 28 EU DSDIDPD: Self Classified: Xi, R43 R36/37/38; Xn, R48/22 EU CLP: Self Classified: Skin Sens. 1; STOT RE 2 (Blood, Liver, Kidney); Skin lrrit. 2; Eye lrrit. 2A; STOT SE 3: Resp. lrrlt. OSHA HCS 2012: Skin Sens. 1; Skin lrrit. 2; Eye lrrit. 2A; STOT SE 3: Resp. lrrit.; STOT RE 2 (Blood, Liver, Kidney) EU DSD/DPD: Self Classified: Xi R38 EU CLP: Self Classified: Skin lrrit. 2, H315 OSHA HCS 2012: Skin lrrit. 2 EU DSD/DPD: Self Classified: Xn, R48/20 EU CLP: Self Classified: STOT RE 2 (Lungs), H373 OSHA HCS 2012: Eye lrrit. 28; STOT RE 2 (Lungs) Comments NDA NDA NOA NDA NOA NOA Revision Date: 24!0ctober/2013 Page 3 of28 Format: EU CLP/REACH Language: English {US) WHMIS, EU CLP, EU DSD/DPD, OSHAHCS 2012

4 Quartz CAS: EU DSD/DPD: Self Classified: Care A; R % EC NOA EU CLP: Self Classified: Care. 1A, NOA T % Number:238- H OSHA HCS 2012: Care. 1A CAS: EU DSD/DPD: Annex I: Xi; R38 Sulfur EC /o NOA EU CLP: Annex VI: Skin lrrit. 2; H315 NOA Number:231- OSHA HCS 2012: Skin lrrit Limestone EU DSD/DPD: Self Classified: Xn CAS: R48/20 3 EU CLP: Self Classified: STOT RE 1 EC 0.05o/o NOA (Lungs) Number:215- OSHA HCS 2012: STOT RE (Lungs) NOA EU DSD/DPD: Annex I: Xn; R20/22-48/22 Xi; R36/38 R43 N; R50-53 EU CLP: Annex VI: Acute Tox. 4, Ingestion/Oral- H332; Acute Tox. 4, H302; STOT RE CAS: Rat L , H373; Eye lrrit. 2, H319; Skin lrrit. Disulfide, bis EC 0.024% TO mg/kg 2, H315; Skin Sens. 1, H317; Aquatic (dimethylthiocarbamoyl) Number: % Inhalation-Rat Acute 1, H400; Aquatic Chronic 1, NOA LC mg/m' H410; M Hour(s) OSHA HCS 2012: Eye lrrit. 2; Skin lrrit. 2; STOT SE 3: Resp. lrrit.; Skin Sens. 1; Acute Tox. 4 (Oral, Inhalation) Propionic acid lngestion!oral- CAS: Rat L EC % EU CLP: Community workplace mg/kg Number:201- T % exposure limit Skin-Rabbit L µl/kg NOA CAS: Mineral oil, petroleum 52-5 EU DSD/DPD: Data Lacking Contains 0.004% TO distillates, hydrotreated (mild) EC NOA EU CLP: Annex VI: Care. 18; H350 less than 3% 0.012% heavy naphthenic Number:265- OSHA HCS 2012: Skin lrrit. 2 OMSO CAS: EU DSD/DPD: Annex I: Carc.Cat.2; Mineral oil, petroleum % TO R45 distillates, hydrotreated (mild) EC NOA 0.004% EU CLP: Annex VI: Care. 18; H350 light naphthenic Number:265- OSHA HCS 2012: Care. 1A NOA Amorphous silica EU DSD/DPD: Data Lacking CAS: % TO NOA EU CLP: Data Lacking % OSHA HCS 2012: Data Lacking NOA Guanidine, 1,3-diphenyl- EU DSD/DPD: Annex I: Xn; R22 Xi; R36/37/38 N; R51-53 Repr.Cat.3; R62 lngestion!oral- EU CLP: Annex VI: Repr. 2, H361f; CAS: Rat L Acute Tox. 4, H302; Eye lrrit. 2, EC mg/kg 0 /o H319; STOT SE 3, H335; Skin lrrit. 2, Number:203- Skin-Rabbit H315; Aquatic Chronic 2, H L050 >794 OSHA HCS 2012: Eye lrrit. 2A; mg/kg Acute Tox. 4 (Dermal); Acute Tox. 4 NOA (Oral); Repr. 2 See Section 11 for Toxicological Information. See section 16 for full text of H-statements and R-phrases. Preparation Dale: 24/0ctober/2013 Page4 of28 Format: EU CLP/REACH Language: English (US)

5 I Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation Skin Eye Ingestion Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. In case of contact with substance, immediately fiush skin with running water for at least 20 minutes. Get medical attention if symptoms occur. In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. 4.2 Most important symptoms and effects, both acute and delayed Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed tes to Physician All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. I Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, C02, water spray or regular foam. Unsuitable Extinguishing data available. Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products 5.3 Advice for firefighters n-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. data available. Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). Runoff from fire control may cause pollution. LARGE FIRES: Dike fire-control water for later disposal. Section 6-Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions Emergency Procedures 6.2 Environmental precautions Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid any skin contact. emergency procedures are expected to be necessary if material is used under ordinary conditions as as recommended. Avoid run off to waterways and sewers. 6.3 Methods and material for containment and cleaning up Containment/Clean-up Measures 6.4 Reference to other sections Pick up pieces and place in container or bag for disposal. For spills of molten product - allow product to cool/solidify and pick or scrape up as a solid. Page 5 of28 Format: EU CLP/REACH language: English {US)

6 While Sidewall Veneer Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. I Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling Wear appropriate personal protective equipment. Use only with adequate ventilation. Avoid breathing processing vapors. Avoid contact with skin and eyes. Use good safety and industrial hygiene practices. 7.2 Conditions for safe storage, including any incompatibilities Storage 7.3 Specific end use(s) Ventilate enclosed areas. Refer to Section Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters ' Result ACGIH Exposure Limits/Guidelines. Canada Ontario Canada Quebec China France STELs 10 mg/m3 STEL (total dust) Amorphous silica ( ) 6 mg/m3 TWAEV (containing no 10 mg/m3 TWA Asbestos and < 1 /o Crystalline silica, respirable dust) 5 mg/m3 TWA (total dust) Propionic acid () STELs 10 ppm TWA 10 ppm TWA 10 ppm TWAEV; 30 mg/m3 TWAEV 60 mg/m3 STEL 30 mg/m3 TWA 20 ppm STEL [VLCT] (indicative limit); 62 mg/m3 STEL [VLCT] (indicative limit) 10 ppm TWA [VME] (indicative limit); 31 mg/m3 TWA [VME] (indicative limit) STELs 2 mg/m3 STEL (10%- 50o/o free Si02, total dust); 1.4 mg/m3 STEL (50%-80% free Si02, total dust); 1 mg/m3 STEL (containing >80% free Si02, total dust); 1.4 mg/m3 STEL (10%-50% free Si02, respirable dust); 0.6 mg/m3 STEL (50%-80% free Si02, respirable dust); 0.4 mg/m3 STEL (containing >80% free Si02, respirable dust) Quartz 0.7 mg/m3 TWA Preparation Dale: 24/0ctober/2013 Page 6 of28 Formal: EU CLP/REACH Language: English (US)

7 ( ) Disulfide, bis (dimethylthiocarbamoyl) () Limestone ( ) STE Ls mglm3 TWA (respirable fraction) 0.10 mglm3 TWA (designated substances regulation, respirable, listed under Silica, crystalline) 0.1 mglm3 TWAEV (respirable dust) 0.05 mglm3 TWA 0.05 mglm3 TWA (inhalable fraction (inhalable fraction 5 mglm3 TWAEV and vapor) and vapor) 10 mglm3 TWAEV (Limestone, containing no Asbestos and <1 % Crystalline silica, total dust) (containing /o free Si02, total dust); 0.3 mglm3 TWA (containing 50-80%1 free Si02, respirable dust); 1 mglm3twa (containing /o free Si02, total dust); 0.7 mglm3 TWA (containing 10-50o/o free Si02, respirable dust); 0.5 mglm3 TWA (containing >80% free Si02, total dust); 0.2 mglm3 TWA (containing >80 /o free Si02, respirable dust) 0.1 mglm3 TWA [VME] (restrictive limit, alveolar fraction) 5 mglm3 TWA [VME] 16 mglm3 STEL (total dust); 8 mglm3 STEL (respirable dust) 8 mg/m3 TWA (total dust); 4 mglm3 TWA (respirable dust) Titanium dioxide ( ) Zinc oxide ( ) Kaolin () - --.,. ST Els STELs Result STE Ls 10 mglm3 TWAEV (containing no 10 mglm3 TWA 10 mg/m3 TWA Asbestos and <1 % Crystalline silica, total dust) 10 mg/m3 STEL 10 mglm3 STEL 10 mg/m3 STEV (respirable fraction) (respirable) (fume) 10 mglm3 TWAEV (containing no 2 mg/m3 TWA 2mglm3TWA Asbestos and <1 /o (respirable fraction) (respirable) Crystalline silica, total dust); 5 mg/m3 TWAEV (fume) 2 mg/m3 TWA (particulate matter containing no asbestos and <1 o/o crystalline silica, 2mglm3TWA 5 mglm3 TWAEV (containing no (containing no Asbestos and < 1 % Asbestos and <1 /0 Crystalline silica, Crystalline silica, respirable) respirable dust) respirable fraction) --.,. Exposure Limits/Guidelines Icon'!} Germany DFG Germany TRGS Italy 20 ppm STEL; 62 mglm3 STEL 16 mglm3 STEL (total dust) 8 mg/m3 TWA (total 10 mglm3 TWA dust) [VME] (as Ti) 5 mglm3 STEL 5 mglm3 TWA [VME] 3 mglm3twa (fume); 10 mglm3 TWA [VME] (dust) NIOSH 15 ppm STEL; 45 mglm3 STEL 10 mg/m3 TWA [VME] OSHA Page 7 of28 Formal: EU CLP/REACH Language: English {US)

8 Propionic acid () 10 ppm TWAAGW (The risk of damage to the embryo or fetus can be excluded when AGWand BGW values are observed, exposure factor 2); 31 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGWand BGW values are observed, exposure factor 2) 10 ppm TWA; 31 mg/m3 TWA 10 ppm TWA; 30 mg/m3 TWA Quartz ( ) Disulfide, bis (dimethylthiocarbamoyl) () Limestone ( ) Titanium dioxide ( ) Silica, amorphous ( ) Ceilings MAKs Ceilings MAKs MA Ks 20 ppm Peak; 62 mg/m3 Peak 10 ppm TWA MAK; 31 mg/m3 TWA MAK 2 mg/m3 Peak (inhalable fraction) 1 mglm3 TWA MAK (inhalable fraction) 4 mglm3 TWA MAK (inhalable fraction) 1 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGWand BGW values are observed, inhalable fraction, exposure factor 2) 4 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGWand BGW values are observed, inhalable fraction) 0.05 mg/m3 TWA (respirable dust) 5 mg/m3twa 5 mglm3 TWA 10 mg/m3 TWA (total 15 mg/m3 TWA (total dust); 5 mg/m3 TWA dust); 5 mglm3 TWA (respirable dust) (respirable fraction) 6mg/m3TWA 15 mg/m3 TWA (total dust) 5 mg/m3 TWA Page8 of28 Format: EU CLP/REACH Language: English (US)

9 5 mg/m3 TWA (dust and fume) (fume); 15 mg/m3 TWA (total dust); 5 mg/m3twa (respirable fraction) 1 mg/m3 Peak Zinc oxide Ceilings (respirable fraction, ( ) fume) 15 mg/m3 Ceiling (dust) STE Ls 10 mg/m3 STEL (fume) MA Ks 1 mg/m3 TWA MAK (fume, respirable fraction) Kaolin () 1 O mg/m3 TWA (total 15 mg/m3 TWA (total dust); 5 mg/m3 TWA dust); 5 mg/m3 TWA (respirable dust) (respirable fraction) Exposure Control tations Italy Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic ( ): Carcinogens: (Category 2 Carcinogen) I Carcinogens: (Category 2 Carcinogen) I Mutagens: (Category 3 Mutagen) Germany DFG Kaolin (): Carcinogens: (Category 3B (could be carcinogenic for man)) I Carcinogens: (Category 3A (could be carcinogenic for man, inhalable fraction with the exception of ultra small particles)) I Carcinogens: (Category 3A (could be carcinogenic for man, inhalable fraction with the exception of ultra small particles)) I Carcinogens: (Category 3A (could be carcinogenic for man, inhalable fraction with the exception of ultra small particles)) [Carcinogens: (Category 1 (causes cancer in man, alveola fraction)) I Carcinogens: (Category 1 (causes cancer in man, alveola fraction)) I Carcinogens: (Category 1 (causes cancer in man, alveola fraction)) I Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) I Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) I Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) I Sensitizers: (skin sensitizer) 8.2 Exposure controls Engineering Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. Measures/Controls Personal Protective Equipment Respiratory 0 In case of insufficient ventilation, wear suitable respiratory equipment. Eye/Face 0 Wear protective eyewear (goggles, face shield, or safety glasses). Skin/Body 0 Wear appropriate gloves. General Industrial Hygiene Considerations Environmental Exposure Controls 0 Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Do not get in eyes or on skin or clothing. Follow best practice for site management and disposal of waste. Avoid release to the environment. Key to abbreviations ACGIH =American Conference of Governmental Industrial Hygiene STEL = ~=;~~::~m Exposure Limits are based on 15-minute NIOSH =National Institute of Occupational Safety and Health OSHA =Occupational Safety and Health Administration Max1male Arbe1tsplatz Konzentration is the maximum perm1ss1ble MAK concentration TWAEV =Time-Weighted Average Exposure Value _Time-Weighted Averages are based on Sh/day, 40h/week TWA exposures Section 9 - Physical and Chemical.Properties 9.1 Information on Physical and Chemical Properties Page 9 of28 Format: EU CLP/REACH Language: English {US)

10 Material Description Physical Form Solid Appearance/Description Black solid rubber with characteristic odor. Color Black Odor Characteristic Odor Threshold General Properties Data lacking Boiling Point Data lacking Melting Point Data lacking Decomposition Temperature Data lacking ph Data lacking Specific Gravity/Relative Density 1.43 to 1.49 Water= 1 Water Solubility Data lacking Viscosity Data lacking Explosive Properties t Explosive. Oxidizing Prope1iies: Volatility t an Oxidizer. Vapor Pressure Data Jacking Vapor Density Data lacking Evaporation Rate Flammability Data lacking Flash Point Data lacking UEL Data lacking LEL Data lacking Autoignition Data lacking Flammability (solid, gas) Environmental Octanol/Water Partition coefficient 9.2 Other Information t Flammable. Data lacking additional physical and chemical parameters noted. I Section 10: Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability dangerous reaction known under conditions of normal use. Stable 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials 0 Hazardous polymerization will not occur. 0 data available. 0 ne known Hazardous decomposition products Carbon Monoxide, Carbon Dioxide, Smoke, Aliphatics, Aromatics, Sulfur Oxides. Section 11 Toxicological Information 11.1 Information on toxicological effects Component Name CAS Data Multi-dose Toxicity: ihl-rat TCLo:30 mg/m3/96w-i; Kaolin (12.95%) Reproductive: orl-rat TDLo:370 gm/kg (370 pre/1-220 preg) Page 10 of28 Formal: EU CLP/REACH Language; English (US)

11 Quartz ( % TO %) Titanium dioxide ( % TO %) TumorigenJCarcinogen: ihl-rat TCLo:50 7 mg/m3/6h/71w-i Irritation: skn-hmn 300 ug/30-1 MLD; TumorigenJCarcinogen: ih!-rat TCLo:250 mglm3/6h/2y-i Acute Toxicity: orl-rat LD50:4600 mg/kg; skn-rbt Stearic acid (0.45%) LD50:>5 gm/kg; Irritation: skn-rbt 500 mg/24h MOD Irritation: eye-rbt 500 mg/24h MLD; skn-rbt 500 mgl24h Zinc oxide (4.89% TO 4.94 /o) MLD; Reproductive: orl-rat TDLo:6846 mg/kg (1-220 preg) Propionic acid ( % TO %) Acute Toxicity: orl-rat LD50:2600 mg/kg; skn-rbt LD50:500 ul/kg; Irritation: eye-rbt 990 ug SEV; skn-rbt 495 mg open SEV Sulfur (0.108%) Irritation: eye-hmn 8 ppm Silica, amorphous (0.28o/o) Irritation: eye-rbt 25 mg/24h MLD Amorphous silica (0.0004% TO 0.002%) Multi-dose Toxicity: ihl-rat TCLo:25.2 mg/m3/5d-i 8 Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic (0.002% TO 0.004%) 6 Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic (0.004% TO 0.012%) 5 Disulfide, bis(dimethylthiocarbamoyl) (0.024% TO 0.04%) Guanidine, 1,3-diphenyl- (0%) Irritation: skn-rbt 500 mg SEV; TumorigenJCarci no gen: skn-mus TDLo:480 gm/kg/bow-i Irritation: skn-rbt 500 mg SEV Acute Toxicity: orl-rat LD50:560 mg/kg; ihl-rat LC50:500 mg/m314h; Irritation: eye-rbt 100 mg/24h MOD; Reproductive: orl-rat TDLo:125 mg/kg (6-10D preg) Acute Toxicity: orl-rat LD50:323 mg/kg; skn-rbt LD50:> 794 mg/kg; Reproductive: orl-mus TDLo:76 mg/kg (1-190 preg) GHS Properties Acute toxicity Aspiration Hazard Carcinogenicity Germ Cell Mutagenicity Skin corrosion/irritation Skin sensitization STOT-RE STOT-SE Classification EU/CLP. Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP. Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Skin Sensitizer 1 EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met Page 11 of28 FonTiat: EU CLP/REACH Language: English (US)

12 Toxicity for Reproduction Respiratory sensitization Serious eye damage/irritation EU/CLP Classification criteria not met OSHA HCS 2012 Toxic to Reproduction 2 EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS Classification criteria not met Route(s) of entry/exposure Potential Health Effects Inhalation Acute (Immediate) Chronic (Delayed) Skin Acute (Immediate) Chronic (Delayed) Eye Acute (Immediate) Chronic (Delayed) Ingestion Acute (Immediate) Chronic (Delayed) Carcinogenic Effects,,,;... CAS Inhalation, Skin, Eye adverse effects likely for general handling at room temperature. Hot processing (e.g. milling, extrusion, curing, etc.) can release fumes and other volatiles which may cause irritation. Long term exposure to concentrated hot processing fumes has caused lung function loss and chronic bronchitis. May cause skin sensitization. Symptoms include redness, and skin rash. data available. adverse effects likely for general handling at room temperature. Hot processing (e.g. milling, extrusion, curing, etc.) can release fumes and other volatiles which may cause irritation. data available. Under normal conditions of use, no health effects are expected. data available. The CB4REACH Consortium has concluded that carbon black is classified as not carcinogenic. This classification is currently under review. This product contains carbon black (encapsulated)( ). Accordng to IARC " significant exposure to carbon black is thought to occur during the use of products in which carbon black is bound to other materials, such as rubber, printing ink or paint." The quartz and titanium dioxide components are also encapsulated in the rubber therefore no significant exposure to either of these components is expected.. Carcinogenic Effects Quartz Group 1-Carcinogenic Known Human Carcinogen IARC Titanium dioxide Group 28-Possible Carcinogen Reproductive Effects Key to abbreviations LO =Lethal Dose MLD =Mild MOD= Moderate SEV =Severe TC =Toxic Concentration TD =Toxic Dose. Tests in animals have shown that some components of this material have reproductive effects.,,,;... NTP I Section 12 Ecological Information 12.1 Toxicity data available Preparation Dale: 24/0ctober/2013 Page 12 of28 Format: EU CLP/REACH Language: English (US)

13 12.2 Persistence and degradability Material data lacking Bioaccumulative potential Material data lacking Mobility in Soil 0 Material data lacking Results of PBT and vpvb assessment PBT and vpvb assessment has been conducted Other adverse effects studies have been found. I Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. I Section 14 -Transport Information 14.1 UN 14.2 UN proper number shipping name DOT NOA t Regulated TOG NOA t Regulated IMO/IMOG NOA t Regulated IATA/ICAO NOA t Regulated 14.3 Transport hazard 14.4 Packing 14.5 Environmental class( es) group hazards NOA NOA NOA NOA NOA NOA NOA NOA NOA NOA NOA NOA 14.6 Special precautions for ne known. user 14.7 Transport in bulk t relevant. according to Annex II of MARPOL 73/78 and the IBC Code I Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute. Component 1,3-Butadiene, 2- methyl~, oligomer Kaolin Quartz..... CAS State Right To Know MA NJ PA Page 13 of28 Format: EU CLP/REACH Language: English (US)

14 While Sidewall Veneer Titanium dioxide Water Limestone Stearic acid Polyterpene resin Zinc oxide Propionlc acid Sulfur homopolymer Sulfur Amylphenol disulfide polymer Silica, amorphous Benzothiazolesulfenamide, N-tert-butyl Amorphous silica Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Disulfide, bis (dimethylthiocarbamoyl) Guanidine, 1,3- di phenyl Component --'- CAS _: :_ Inventory --'- Canada DSL Canada NDSL China EU EINECS _:_.. EU ELNICS 1,3-Butadiene, 2- methyl-, ollgomer Kaolin Quartz Titanium dioxide Water Limestone Stearic acid Polyterpene resin Zinc oxide Propionic acid Sulfur homopolymer Sulfur Amylphenol disulfide polymer Page 14 of28 Fonnat: EU CLP/REACH Language: English (US) WHMIS, EU CLP, EU DSD/DPD, OSHAHCS 2012

15 While Sidewall Veneer Silica, amorphous 2- Benzothiazolesutfenamide, N-tert-butyl- Amorphous silica Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Disulfide, bis (dimethylthiocarbamoyl) Guanidine, 1,3- diphenyl-. Component 1,3-Butadiene, 2- methyl-, oligomer Kaolin Quartz Titanium dioxide Water Limestone Stearic acid Polyterpene resin Zinc oxide Propionic acid Sulfur homopolymer Sulfur Amylphenol disulfide polymer Silica, amorphous Amorphous silica Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Benzothiazolesulfenamide, N-tert-butyl CAS Inventory (Con't.) Japan ENCS -'- Korea KECL --,- -:- TSCA Page 15 of28 Fonnal: EU CLP/REACH Language: English {US)

16 Disulfide, bis (dimethylthiocarbamoyl) Guanidine, 1,3- di phenyl Canada Labor Canada M WHMIS Stearic acid M Classifications of Substances Kaolin Zinc oxide 2-Benzothiazolesulfenamide, N-tert butyl- Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer Uncontrolled product according to WHMIS classification criteria D2A 83, D1B, E D2A (In certain cases, this classification does not apply. For more information, consult the section Substance Specific Issues - Titanium dioxide, mixture containing on Health Canada's WHMIS Division website.) Uncontrolled product according to WHMJS classification criteria D2A Uncontrolled product according to WHMIS classification criteria D2A (In certain cases, this classification does not apply. For more information, consult the section Substance Specific Issues - Silica, crystalline, encapsulated on Health Canada's WHMIS Division website.) Canada M WHMIS M Ingredient Disclosure List Stearic acid Kaolin Zinc oxide /o 1 /o 1 /o 1 Ofo 1% 1 o/o Page 16 of 28 Fonnal: EU CLP/REAGH Language: English {US) WHMIS, EU CLP, EU DSD/DPD, OSHA HGS 2012

17 Mineral oil, petroleum distillates, hydrotreated (mi!d) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer Environment~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~--~~~~~~~~ Canada~ CEPA ~Priority Substances List Stearic acid 1,3~Butadiene, 2-methyl-, oligomer Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer Europe Other~~~~~~~~~~~~~~~~~~~~-~~~~~~~~~~~~~~~~~~~~~ EU - CLP (1272/2008) - Annex Vt -Table Classification Stearic acid Kaolin Propionic,acid Zinc oxide Xn: R20/22-48/22 Xi: R36/38 R43 N: R50-53 C; R N: R Xi: R Xn: R22 Xi; R36/37/38 N; R51-53 Repr.Cat.3; R Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Carc.Cat.2: R45 Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic Carc.Cat.2; R45 homopolymer EU - CLP (1272/2008) - Annex VI -Table Concentration Limits Stearic acid Page 17 of28 Format: EU CLP/REACH Language: English (US)

18 While Sidewall Veneer 1,3~Butadiene, 2-methyl-, oligomer Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer %<=C: N; R: %<=C<2.5%: N; R: % <=C<0.25%: R: %<=C<25%: Xi; R:36/37/38 25%<=C: C; R:34 EU CLP (1272/2008) Annex VI Table 3.2 Labelling Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy T R:45 S:53-45 naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic T R:45 S:53-45 homopolymer Xn N R:20/22-36/ /22-50/53 S:(2)-26-36/ C R:34 S:(1/2) N R:50/53 S: Xi R:38 S:(2) Xn N R:22-36/37/38-51 /53-62 S:(2)-26-36/37/ EU. CLP (1272/2008) Annex VI Table 3.2 tes Substances and Preparations Stearic acid Kaolin B Page 18 of28 Format: EU CLP/REACH Language: English (US)

19 While Sidewall Veneer Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer EU - CLP (1272/2008) Annex VI Table 3.2 Safety Phrases Stearic acid Disulfide, bis(dimelhylthiocarbamoyl) Kaolin Propionlc acid Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer L L S: (2)-26-36/ :(1/2) S: S:(2) :(2)-26-36/37 / : : United States Labor U.S.~ OSHA~ Process Safety Management R Highly Hazardous Chemicals Stearic acid Kaolin Zinc oxide Preparation Dale: 24/0ctober/2013 Page 19 of28 Fonnat: EU CLP/REACH Language: English (US) WHMIS, EU CLP, EU DSOIOPO, OSHA HCS 2012

20 Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - OSHA - Specifically Regulated Chemicals Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer Environment~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ U.S. - CAA (Clean Air Act) 1990 Hazardous Air Pollutants Stearic acid Kaolin Zinc oxide 2-Benzothiazolesutfenamide, N-tert-butyl- Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - CERCLA/SARA Hazardous Substances and their Reportable Quantities Page 20 of28 Format: EU CLP/REACH language: English {US)

21 While Sidewall Veneer Stearic acid O lb final RO; 4.54 kg final RO Kaolin 5000 lb final RO; 2270 kg final RO Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. ~ CERCLA/SARA ~ Radionuclides and Their Reportable Quantities Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs Stearic acid Kaolin Zinc oxide Limestone Page 21 of28 Format EU CLP/REACH Language: English {US) WHMJS, EU CLP, EU DSD/DPD, OSHAHCS 2012

22 While Sidewall Veneer Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S.~ CERCLA/SARA ~Section 313 ~Emission Reporting Stearic acid %1 de minimis concentration Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic /o de minimis concentration (Chemical Category N982) Preparation Dale: 24/0ctober/2013 Page 22 of28 Fom1at: EU CLP/REACH Language: English {US)

23 White Sidewall VeneGr Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - CERCLAISARA Section 313 PBT Chemical Listing Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - RCRA (Resource Conservation & Recovery Act) - Hazardous Constituents - Appendix VIII to 40 CFR 261 Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer waste number U U.S. - RCRA (Resource Conservation & Recovery Act) - U Series Wastes - Acutely Toxic Wastes & Other Hazardous Characteristics Stearic acid Kaolin waste number U244 Page 23 of28 Fonnat: EU CLP/REACH Language: English (US)

24 Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated {mild) light naphthenic homopolymer United States - California Environmen u.s. - California Proposition 65 Carcinogens List Stearic acid Kaolin carcinogen, initial date 9/2/11 (airborne, unbound particles of respirable size) Zinc oxide carcinogen, initial date 10/1/88 (airborne particles of respirable size) Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. California Proposition 65 - Developmental Toxicity Stearic acid Kaolin Zinc oxide Preparation Dale: 24/0ctober/2013 Page 24 of28 Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, EU DSD/OPD, OSHA HCS 2012

25 Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - California - Proposition 65 - Significant Risk Levels (NSRL) Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) liqht naphthenic Revision Dale: 24/0ctober/2013 Page 25 of28 Fonnal: EU CLP/REACH Language: English {US)

26 homopolymer U.S. - California - Proposition 65 - Reproductive Toxicity - Female Stearic acid Kaolin Zinc oxide Limestone Amy!phenol disulfide polymer Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - California - Proposition 65 - Reproductive Toxicity - Male Stearic acid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer United States - Pennsylvania Labor U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List Stearic acid Preparation Date; 24/0ctober/2013 Page 26 of28 Fonnat: EU CLP/REACH Language: English (US) WHMIS, EU CLP, EU DSD/DPO, OSHA HCS 2012

27 While Sidewall Veneer Kaolin Zinc oxide (fume) Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances Stearicacid Kaolin Zinc oxide Mineral oil, petroleum distillates, hydrotreated (mild) heavy naphthenic Mineral oil, petroleum distillates, hydrotreated (mild) light naphthenic homopolymer Chemical Safety Assessment 15.3 Other Information Chemical Safety Assessment has been carried out. WARNING: This product contains a chemical known to the State of California to cause cancer. I Section 16 - Other Information Relevant Phrases (code & full text) H302 - Harmful if swallowed H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation Preparation Dale: 24/0ctober/2013 Page 27 of28 Format: EU CLP/REACH Language: English (US) WHMIS, EU CLP, EU DSD/DPO, OSHA HCS 2012

28 Last Revision Date Preparation Date Disclaimer/Statement of Liability Key to abbreviations NDA::: data available H335 - May cause respiratory irritation H350 - May cause cancer. H351 - Suspected of causing cancer. H361f - Suspected of damaging fertility. H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects H411 - Toxic to aquatic life with long lasting effects R22 - Harmful if swallowed. R36/38 - Irritating to eyes and skin. R36/37/38 - Irritating to eyes, respiratory system and skin. R38 - Irritating to skin. R40 - Limited evidence of a carcinogenic effect. R43 - May cause sensitisation by skin contact. R45 - May cause cancer. R50 - Very toxic to aquatic organisms. R51 - Toxic to aquatic organisms. R53 - May cause long-term adverse effects in the aquatic environment. R62 - Possible risk of impaired fertility. 24/0ctober/ /0ctober/2013 The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current, applicable and suited to the circumstance of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as described in Section 1. Page 28 of28 Format: EU CLP/REACH language: English (US)