Renewable Fuels Integrated with Petroleum Refineries and Existing Infrastructure UOP Renewable Energy & Chemicals

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1 Anjan Ray April 18, 2016 Renewable Fuels Integrated with Petroleum Refineries and Existing Infrastructure UOP Renewable Energy & Chemicals May 11, 2016 Symposium on Biofuels and Bio-Energy New Delhi, India UOP UOP LLC. A Honeywell Company All rights reserved.

2 1 The Goals: Reduce Fossil Energy Import Dependence and Emissions Simultaneously UOP 7301A-1

Carbon Intensity (tco 2 /$m GDP 2014) India s Commitment to Emissions Reduction 2 Goal: Reduce emissions intensity of GDP by ~33-35% (2030 vs 2005) Avoided emissions ~ 3.

3 Carbon Intensity (tco 2 /$m GDP 2014) India s Commitment to Emissions Reduction 2 Goal: Reduce emissions intensity of GDP by ~33-35% (2030 vs 2005) Avoided emissions ~ 3.59B tons CO 2 e over BAU Thrusts on renewable energy, green transport Urban air quality issues Euro-VI transition Ban on open biomass burning Linkages to Swachh Bharat Mission, Make in India India INDCs Towards Climate Justice, Ministry of Environment, Forests & Climate Change, 2015 How ambitious is India s 33-35% GHG intensity reduction target? Business as Usual (-1.4% per year) Paris Target (-2.1% per year) Global Average 2ºC Pathway (-6.3% per year) Philip Massey, PwC, India: Emission Targets and Implications for Business, 2015 Action Proposed on Multiple Fronts

4 Drop-in Renewable Fuels for India 3 Pipeline-compatible distillate fuels seamless adaptation - No separate handling, storage, distribution infrastructure needed unlike biodiesel (FAME, fatty acid methyl ester) or ethanol Comparable or superior quality supports move to Euro-VI - Ultralow sulfur, ultrahigh cetane (Green Diesel) - Higher energy density (Green Diesel, Green Jet Fuel) - Lower sulfur (HR F-76 Renewable Marine Fuel) High OEM acceptability - European and Japanese automakers favor green diesel over FAME biodiesel - 100% green diesel approved in select Mercedes, Volvo and Scania trucks - Major aircraft engine and Auxiliary Power Unit (APU) manufacturers supported ASTM D7566 specification for Bio-SPK (Green Jet) Biomass-derived partially renewable gasoline and diesel - Creates incentive for farmers not to burn biomass in the fields - Converts locally available waste carbon to renewable fuels UOP

Product Quality from the Ecofining process and the UOP Renewable Jet Fuel Process Green Diesel Honeywell Green Diesel also known as: Renewable Diesel HVO (hydrotreated vegetable oil) HRD

renewable jet) HEFA-SPK (hydroprocessed esters and fatty acids) 4 ULSD FAME Biodiesel Green Diesel Oxygen, % 0 11 0 Cetane 40-55 50-65 75-90 Energy Density, MJ/kg 43 38 44 Sulfur, ppm <10 < 2 < 2

5 Product Quality from the Ecofining process and the UOP Renewable Jet Fuel Process Green Diesel Honeywell Green Diesel also known as: Renewable Diesel HVO (hydrotreated vegetable oil) HRD (hydrotreated renewable diesel) BHD (bio-hydrogenated diesel) Green Jet Honeywell Green Jet Fuel also known as: Renewable Jet SPK, or Bio-SPK (synthetic paraffinic kerosene) HRJ (hydrotreated renewable jet) HEFA-SPK (hydroprocessed esters and fatty acids) 4 ULSD FAME Biodiesel Green Diesel Oxygen, % Cetane Energy Density, MJ/kg Sulfur, ppm <10 < 2 < 2 Cold Flow Baseline Poor Excellent Oxidative Stability Baseline Poor Excellent Jet A-1 Spec. 50/50 Blend Green Jet Flash Point, C 38 min Freeze Point, C Energy Density, MJ/kg Thermal Stability Aromatics -47 max min Baseline Excellent Excellent 8 min 25 max 8.5 Nil High quality drop-in fuels that fully meet specifications

6 5 Technologies to Produce Low Carbon Emission Fuels UOP

7 Renewable Fuels from Fats, Oils & Greases 6 Plant-derived Oils Animal Fats UOP Technology Honeywell Green Diesel Algal Oil Used Cooking Oil Honeywell Green Jet Fuel Proven Technologies for Feedstock Flexible Drop-in Fuels

8 Renewable Fuel Oil from Biomass 7 Forest Residue Ensyn RTP Unit Renfrew, Canada RTP Green Fuel Agricultural Waste Energy Crop RTP Green Fuel is liquid wood made from Cellulosic Biomass

Oil (LCO) Unconverted Oils (UCO) Partially renewable

9 Renewable Fuel Blend Stock from FCC Co-Processing RTP Biocrude 8 LPG Vacuum Gas Oil (VGO) Gasoline Light Cycle Oil (LCO) Unconverted Oils (UCO) Partially renewable products sent downstream Utilize existing refinery assets & infrastructure

10 9 Commercial Status of Renewable Fuels UOP

11 Multiple Feedstock Options 10 UOP Renewable Fuel Projects Natural Oils Adjacent to existing refinery ( brown field ) 10,000+ bpsd Renewable Diesel 2013 Animal Fats 2014 Algal Oils Retrofit of existing refinery unit (s) bpsd Renewable Diesel bpsd Green Diesel & Green Jet 2016 Used Cooking Oil Options for Effective Use of Capital and Assets

12 Green Diesel User Walt Disney World 11 Green Diesel Used Commercially

13 Green Fuels On The Seas 12 50% HRF-76 Blend in US Navy Destroyer 50% HRF-76 in US Navy RCB-X Small Craft Italian Navy Patrol Boat Foscari New marine fuel standards can be met using Ecofining technology

Some Honeywell Green Jet Fuel Flights 13 Airline Date Remarks Air New Zealand Dec 08 First commercial airliner Bio-SPK demo KLM Nov 09 First biofuel test flight with passengers TAM, Brazil Nov 10

First corporate jet to fly on biofuel Boeing, USA Jun 11 First Trans-Atlantic commercial aircraft with engines on 15% Bio-SPK blend Aeroméxico Aug 11 First transcontinental commercial flight, 30%

14 Some Honeywell Green Jet Fuel Flights 13 Airline Date Remarks Air New Zealand Dec 08 First commercial airliner Bio-SPK demo KLM Nov 09 First biofuel test flight with passengers TAM, Brazil Nov 10 First Biofuel flight in Latin America Honeywell (Corporate Jet) Jun 11 First Trans-Atlantic biofuel flight. First corporate jet to fly on biofuel Boeing, USA Jun 11 First Trans-Atlantic commercial aircraft with engines on 15% Bio-SPK blend Aeroméxico Aug 11 First transcontinental commercial flight, 30% blend (Mexico City to Madrid) Aeroméxico Oct 11 Weekly commercial flight, 52 flights (Mexico City to San Jose, Costa Rica) Iberia Oct 11 First commercial flight in Spain (Madrid to Barcelona) Air China, China Oct 11 First Biofuel demonstration flight in China United Airlines, USA Nov 11 First U.S. commercial passenger flight (Houston to Chicago) Porter Airlines Apr 12 Canada s First Biofuel-Powered Revenue Flight GOL Oct 13 Sao Paulo to Brasilia- first commercial biofuels flight in Brazil GOL Jul commercial flights during the FIFA World Cup in Brazil Many demonstration, commercial and military flights since 2008

15 Commercial Renewable Aviation Biofuels Now a Reality 14 United Airlines is first commercial airline in U.S. to use renewable jet fuel on scheduled flights Fuel provided by AltAir Fuels in first dedicated commercial production of renewable jet fuel Honeywell UOP Technology Produces First Commercial Aviation Biofuel

16 FCC Co-processing Commercialization Concept Selection Pilot Plant Trials Commercial Design Proof of Concept EPA Part EPA Part 80 Technology Deployment 15 RTP Unit RTP Green Fuel or Pyrolysis Oil or Renewable Fuel Oil (RFO) Refiner co-processes RFO with VGO to produce renewable fuel blendstocks RFO produced by outside project developer and delivered to refinery Renewable Fuel Mixture to Refinery Pool Multiple Refiners Assessing FCC Co-Processing

Renewable Heat from RTP Green Fuel 16 Hospital in New Hampshire Switched from #4 fuel oil Added storage tank and modified two boilers ($500K cost) Five year supply agreement

for 77 building Displace 50% of natural gas Supply ~10 million liters per year Five year supply agreement Iron ore facility in Canada Four month trial on three burners

17 Renewable Heat from RTP Green Fuel 16 Hospital in New Hampshire Switched from #4 fuel oil Added storage tank and modified two boilers ($500K cost) Five year supply agreement Hospital in New Hampshire Switched from #2 fuel oil Added storage tank and new single boiler ($500K cost) Seven year supply agreement District heating in Ohio Heat & cooling for 77 building Displace 50% of natural gas Supply ~10 million liters per year Five year supply agreement Iron ore facility in Canada Four month trial on three burners Potentially replace 20% heavy fuel oil use per year Negotiations for long-term contract 2016 by Honeywell International Inc. All rights reserved. GHG and SOx Reduction Driving Adoption

18 17 The Enablers: Regulations drive adoption UOP

19 RIN Price ($/RIN) Current US Renewable Environment 18 EPA Ruling, Nov % increase in RIN values CA Low Carbon Fuel Standard (LCFS) Credits >$100/MT CO 2 e Cellulosic Waiver Credits set to more than double $1.80 $1.60 $1.40 $1.20 $1.00 $0.80 $0.60 $0.40 $0.20 $0.00 Source: Pira RIN Values D3/D7 D4 $140 $120 $100 $80 $60 $40 $20 $0 California LCFS ($/MT CO 2 e) Source: Jacobsen $2.00 $1.50 $1.00 $0.50 $- $1.56 Cellulosic Waiver Historical Prices (set by EPA) $1.13 $0.78 $0.42 $0.49 $0.64 UOP Estimate $1.88 $ Source: EPA US Mandates Driving Renewable Fuels Adoption

Summary 19 Renewable fuel demand growing based on regulations Honeywell Green Diesel and Green Jet technologies provide commercially proven drop-in transportation fuels Renewable Diesel & Gasoline

20 Summary 19 Renewable fuel demand growing based on regulations Honeywell Green Diesel and Green Jet technologies provide commercially proven drop-in transportation fuels Renewable Diesel & Gasoline from FCC Co-Processing of RTP Fuel Oil is EPA Certified Seamless integration into refineries eliminates need for separate biofuels handling, storage and transport infrastructure Revamp of existing refinery assets significantly reduces capex The dream of the Great Green Fleet came to life in January, 2016 as the aircraft carrier John C. Stennis left on its latest deployment, with five biofuel-powered ships alongside for the first time. UOP Renewable Technology Options Can Address India Objectives

21 HONEYWELL RENEWABLE ENERGY & CHEMICALS THANK YOU Honeywell is committed to providing technology options that enable our customers to produce the highest quality renewable fuels UOP

Production of Transportation Fuels by Co-processing Biomass-Derived Pyrolysis Oils in a Petroleum Refinery Fluid Catalytic Cracking Unit

Stanley J. Frey R&D Fellow November 5, 2015 Production of Transportation Fuels by Co-processing Biomass-Derived Pyrolysis Oils in a Petroleum Refinery Fluid Catalytic Cracking Unit TCBiomass2015 Chicago,