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1 Exova Warringtonfire, Frankfurt Industriepark Höchst, C369 Frankfurt am Main D Germany T : +49 (0) F : +49 (0) E : EBH@exova.com W: Test report no issued Applicant: ALFA Klebstoffe AG Vor Eiche 10 CH-8197 Rafz Switzerland Date of order: Date of sampling: No official sampling of the tested product by a representative from Exova Warringtonfire, Frankfurt Date of delivery: Date of test: and Order 1. Testing the smoke density and toxicity of a material in the test chamber according to EN ISO (NBS-Box) 2. Testing the heat release-, smoke production- and mass loss rate of a material according to DIN ISO (Cone-Calorimeter). 3. Classification according to DIN EN : Description / designation of the test object Adhesive designated as: SIMALFA 3095 Description of the relevant test procedure ISO ISO Registered Office: Exova GmbH, Industriepark Höchst, C369, Frankfurt, D-65926, Registered Company No. HRB Ust-Id Nr. DE
2 Test report no issued Page 2 of 9 1. Description of the test material 1.1 Details of the customer: Product name: SIMALFA 308 FR Sampel / Material descripition: Pressure sensitive dispersion adhesive with a water base 7 x samples (Aluminum plate 10.0 x 10.0 cm x 0.1 cm ( cm²) with dried adhesive film) Ø g/ cm², application 254 g/m² (2,7 g, 2,3 g, 2,7 g, 2,4 g, 2,6 g, 2,6 g, 2,5 g) Ø = 2,542 g 3 x samples (Aluminum plate 7.5 x 7.5 cm x 0.1 cm (56.25 cm²) with dried adhesive film) Ø g/56.25 cm², application 296 g/m² (1.6 g, 1.7 g, 1,7 g) Ø = 1,666 g Intended end use of product: Foam bonding for passenger seats 1.2 By the specimen preparation by Exova Warringtonfire, Frankfurt determined values: Material: Colour: Total thickness: Total square weight: Test arrangement: Adhesive applied on aluminium sheets red av.1.3 mm (including the 1 mm aluminium sheet) av g/m² (calculated from 10 x 10 cm sample dimension including the aluminium carrier plate) Surface with applied adhesive to the heat source. Testing after climatic storage at 23 C and 50 % humidity..
3 Test report no issued Page 3 of 9 2. Test results 2.1 Test results Cone-Calorimeter according to ISO 5660 Clima storage (23 C/50%r.F.): >48h Nominal heat flux [KW/m²]: 25 Heat flux calibration constant C: 0.04 Testroom temperature / -humidity: 23 C / 40% rel. LF Single test results of 3 tests: Average Time to ignition [s] ,33 Mass of specimen [g] 29,74 29,51 29,54 29,60 Mass loss rate [g/m²s] 0,41 0,43 0,73 0,52 Mass loss [g] 2,55 2,12 1,68 2,12 Marhe after start [KW/m²] 10,59 6,89 8,53 8,67 Heat release rate (180 s) [KW/m²] 4,83 6,13 4,22 5,06 Heat release rate (300 s) [KW/m²] 3,13 4,34 2,95 3,47 Heat release rate (top) [KW/m²] 40,62 54,24 42,88 45,91 Effective heat of combustion [MJ/Kg] 5,89 6,07 10,40 7,45 Total heat release THR THR 1,87 1,77 2,01 1,88 Specific extinction area [m²/kg] 756,25 744, ,19 867,43 Carbon monoxid [g/g] 0,05 0,18 0,10 0,11 Carbon dioxid [g/g] 0,98 0,53 0,85 0,79 Total smoke production TSP 253,04 219,12 250,61 240,92 End of test [s] ,67 Remarks: none
4 Test report no issued Page 4 of Diagrams [ kw ] AHRE (kw) AHRE (kw) AHRE (kw) Versuchsdauer [ sec ] [ kw/m 2 ] HRR HRR HRR Versuchsdauer [ sec ] [ MJ/m 2 ] THR THR THR Versuchsdauer [ sec ]
5 Test report no issued Page 5 of 9 3. Test results NBS-Box according to ISO 5659: Clima storage (23 C/50%r.F.): >48h Testmodus: 25 KW/m² Test duration: 1200 s Testroom temperature/humidity: 23 C / 35% humidity Average Initial mass [g] 17,4 14,1 17,1 16,2 Final mass [g] 16,1 12,8 16,2 15,03 Mass loss [g] 1,3 1,3 0,9 1,17 Mass loss [%] 7,5 9,2 5,3 7,33 Max. spec. opt. density up to 4 minutes DS 119,64 102,03 103,62 108,43 Max. spec. opt. density DS 122,85 104,74 106,79 111,46 Time to max. opt. density [s] Valeur obscurcissement fumée Conventional Index of Toxicity Conventional Index of Toxicity VOF4 [min] (CIT) 4 min (CIT )8 min 176,13 211,51 130,46 172,7 0,0052 0,0130 0,0049 0,0077 0,0197 0,0232 0,0184 0,0205 Time to ignition [s] Time to extinguishing [s] Remarks: none.
6 Test report no issued Page 6 of Measurement of the smoke density: specimen weight [ g ] ignition [ s ] extinguish [ s ] 1 17, , , DS specimen DS specimen DS specimen Minutes ,90 4,91 1, ,83 60,67 15, ,58 94,91 62, ,64 102,03 103, ,60 103,90 106, ,58 101,46 105, ,67 196,94 102, ,89 94,92 98, ,97 90,84 95, ,62 87,22 92,26 DS max 4 Minuten 119,64 102,03 103,62 VOF4 176,13 211,51 130,46
7 Test report no issued Page 7 of Smoke density diagram:
8 Test report no issued Page 8 of Measurement of the toxicity: Analytic procedure: Clima storage: (23 C/50% humidity): Measurement of the toxicity with FTIR at 25 kw/m² Temperature sample extraction point: <40 C >48 h Testroom temperature / 23 C 35 % humidity Gas conc. after 4 min conc. after 8 min no. ppm ppm Carbon dioxid CO average Carbon monoxid CO average Hydrogen fluride HF Hydrogen chloride HCl Hydrogen cyanide HCN average 2 3 Nitrous gases NO-NO Sulfur Dioxid Hydrogen sulfide SO 2 -H 2 S Hydrogen bromide HBR
9 Test report no issued Page 9 of 9 4. Assessment The material described in chapter 1 fulfills the requirements of class HL3 for R21 according to EN : Table 5 Set of material requirements, R21 (F1A; F1B; F1E; F3) Test Methode reference Parameter Unit Requirement Definition HL 1 HL 2 HL 3 Result/ Average T03.02 ISO : 25 kwm-2 T10.03 EN ISO : 25 kwm-2 T11.02 EN ISO : 25 kwm-2 n.e.: not executed MARHE kwm-2 Maximum ,67 Ds max. dimensionless Maximum ,46 CITG dimensionless Maximum 1,2 0,9 0,75 0,0077 (4 min.) 0,0205 (8 min.) Special comment The fire test result is valid for the in section 1 described material. The burning behaviour in combination with other materials has to be tested separately. In the combination with other materials (for example coatings, deposits) the burning behaviour could be influenced unfavourable so that the classification above is not valid any longer. This test report replace the test report issued (Date of signature), which is invalid from now on. Frankfurt, the M. Ronzheimer Dipl.-Ing. T. Zachäus Tester in Charge Head of the business We refer to the Regulation (EU) No. 1302/2014 of the Commission of 18 November 2014 concerning a technical specification for interoperability of the subsystem "Vehicles - locomotives and passenger cars" of the rail system in the European Union. To demonstrate the conformity of a material with a standard it has to get renew every five years. The results of the tests relate only to the behaviour of the test specimen which is designated on the top. Test reports are only allowed to be published or reproduced, not changed in form and tenor without permission of the Exova Warringtonfire, Frankfurt. The abridged account of a test report is only allowed with the agreement of ther Exova Warringtonfire, Frankfurt. This test report is a translation of the German version (issued ). In case of doubt only the German version is valid This test report contains 9 pages
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