MIL-STD-101B 3 DECEMBER 1970 SUPERSEDING MIL-STD-101A 13 AUGUST 1961 MILITARY STANDARD COLOR CODE FOR PIPELINES AND FOR COMPRESSED GAS CYLINDERS
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1 3 DECEMBER 1970 SUPERSEDING MIL-STD-101A 13 AUGUST 1961 MILITARY STANDARD COLOR CODE FOR PIPELINES AND FOR COMPRESSED GAS CYLINDERS FSC 8120
2 DEPARTMENT OF DEFENSE Washington, D.C Color Code for Pipelines and for Compressed Gas Cylinders 1. This Military Standard is mandatory for use by all Departments and Agencies of the Department of Defense. 2. Recommended corrections, additions, or deletions should be addressed to Commanding Officer, Edgewood Arsenal, ATTN: SMUEA-QAES-A, Edgewood Arsenal, MD ii
3 CONTENTS Page Paragraph 1. SCOPE Object Application Method REFERENCED DOCUMENTS DEFINITIONS GENERAL REQUIREMENTS Colors Warning colors Colors having no significant meaning DETAIL REQUIREMENTS Piping system identification Exact identification Use of colors Primary colors Arrows and secondary color warnings Classification of materials in piping systems Cylinder identification Assignment of colors Exact identification Use of colors Painting of cylinders Additional information FIGURES FIGURE 1. Piping systems Bottle-type cylinders Tube-type cylinders TABLES TABLE I. Size of stencil letters... 4 II. Classification of materials in piping systems... 7 III. Titles and color codes for compressed gas cylinders iii
4 1. SCOPE 1.1 Object. The object of this standard is to establish a common color code for visual warnings to accompany the written identification of materials covered in piping systems and contained in compressed gas cylinders, and to facilitate the segregation of these cylinders at depots. The use of this standard will promote greater safety and will lessen the chances of error, confusion, or inaction in times of emergency by providing a uniform color code to quickly warn personnel of outstanding hazards inherent in the materials involved. However, this standard does not define the manner or conditions under which these materials may be used safely. 1.2 Application. This standard is applicable to ground based piping systems and to all compressed gas cylinders owned by or procured for the Department of Defense including type D one-ton containers (Department of Transportation Specification 10GA-500). The applicability of this standard to industry piping systems and commercial-owned cylinders (see ) is encouraged. Requirements specified herein are optional,for hose lines and nozzles, ship installations, equipment intended for operations in forward area facilities, steam plants, and hydroelectric plants. The identification method for bulk petroleum product systems is covered in MIL-STD-161. The identification of pipe lines for,aircraft, missiles, and space vehicles is covered in MIL-STD Color coding for containers of liquid propellants is covered in MIL-STD Method. This standard establishes, defines, and assigns a color for recognition to each of six classes of materials. Five classes have been selected to represent universally recognized types of hazards involved in the handling of dangerous gases and liquids. The sixth class is assigned for exclusive use of fire protection materials and equipment. This standard requires the application of the color warnings in a distinctive manner, as a visual aid and supplement to written identification. 2. REFERENCED DOCUMENTS 2.1 The issues of the following documents in effect on the date of invitation for bids form a part of this standard to the extent specified herein. FEDERAL STANDARD NO Colors. AMERICAN NATIONAL STANDARD Z Method of Marking Portable Compressed Gas Containers to Identify the Material Contained. 1
5 DEPARTMENT OF TRANSPORTATION REGULATIONS (Copies of specifications, standards, drawings, and publications required by suppliers in connection with specific procurement functions should be obtained from the procuring activity or as directed by the contracting officer.) 3. DEFINITIONS 3.1 For the purpose of this standard, the following definitions shall apply: (a) Commercial colors. Commercial colors are the colors which may be used, in a limited arrangement, on a small portion of the body and bottom of a compressed gas cylinder for commercial identification and designation of ownership. (b) Compressed gas cylinder. A compressed gas cylinder is tube, bottle, or other type of pressure cylinder larger than 3 inches in diameter by 6 inches in length, which contains a pressure that exceeds 104 pounds per square inch at 130 deg. F or any liquid flammable material having a vapor pressure exceeding 40 pounds per square inch absolute at 100 deg. F. One-ton type bulk containers are included. All ammunition is excluded. (c) Piping systems. Piping systems consist of any pipe line or conduct used for the transport of gases, liquids, semiliquids, but not those used for carrying solids in air or gas. Valves, fittings, operating accessories, pipe coverings, and pipe installations of any kind (including submerged or buried pipe lines, their markers or buoys, and their points of tie-in with pumping stations and storage or dispensing facilities) shall be considered as parts of a piping system. Supports, brackets, or other nonoperating accessories are not considered parts for application of warning colors. (d) Primary color warning. A primary color warning is the color assigned to the class into which a material is classified in accordance with its primary hazard from a safety standpoint. These colors appear as a circular band on piping systems, and as main body, top, or band colors on compressed gas cylinders. (e) Secondary color warning. A secondary color warning is the color assigned as a warning of a secondary hazard possessed by a material having a.type of hazard distinctly different from that indicated by its primary color warning. These colors appear as arrows (or triangles) on piping systems and as main body, top, or band colors on compressed gas cylinders. (f) Title. A title is any lettered identification required on a piping system or a compressed gas cylinder. Titles shall identify the contents by complete names, or by generally recognized abbreviations, symbols, letters, numerals. or combinations thereof. 2
6 4. GENERAL REQUIREMENTS 4.1 Colors. The colors assigned in this standard shall conform in hue and chroma to the requirements identified by number in Fed. Std. No No change shall be made in the assigned colors without prior approval of the preparing activity of this standard. 4.2 Warning colors. The following colors are assigned for use as both primary and secondary warnings: (a) Yellow, No flammable materials. All materials known ordinarily as flammables or combustibles. (b) Brown, No toxic and poisonous materials. All materials extremely hazardous to life or health under normal conditions as toxics or poisons. (c) Blue, No anesthetics and harmful materials. All materials productive of anesthetic vapors and all liquid chemicals and compounds hazardous to life and property but not normally productive of dangerous quantities of fumes or vapors. (d) Green, No oxidizing materials. All materials which readily furnish oxygen for combustion and fire producers which react explosively for with the evolution of heat in contact with many other materials. (e) Gray, No physically dangerous materials. All materials, not dangerous in themselves, which are asphyxiating in confined areas or which are generally handled in a dangerous physical state of pressure or temperature. (f) Red, No fire protection materials. All materials provided in piping systems or in compressed gas cylinders exclusively for use in fire protection. 4.3 Colors having no significant meaning. (a) Black, No and White, No These colors are assigned, without significant meaning, for general use where specified in this standard except as follows: Water-piping systems containing water suitable for human consumption and installed for this purpose shall be painted White, No throughout or shall be painted to match surroundings when not in conflict with other color designations in this standard. 3
7 (b) Orange, No and Buff, No These colors are assigned, without significant meaning, for use as colors on selected compressed gas cylinders for segregation of identical material requiring recognition within more than one assigned class (see table III). 5. DETAIL REQUIREMENTS 5.1 Piping system identification Exact identification. Exact identification of materials in any piping system for hazardous materials and the use classification for fire protection is mandatory and shall be made only by means of titles lettered in black or white. These titles shall be prominently displayed adjacent to color warnings to obviate errors by personnel. It is recommended, where the view is unobstructed, that titles be lettered on the two lower quarters of the pipe or covering. Lettering in this position is unlikely to be obscured by dust collection or mechanical damage. However, titles should be clearly visible from operating positions, especially those adjacent to control valves. The use of stencils with standard size letters specified in table I is recommended. For pipe lines smaller than 3/4 inch in diameter, the use of securely fastened metal tags, with lettering etched or filled in with enamel, is suggested. It is recommended that titles be applied by use of upper case letters and arabic numerals whenever applicable. Table I. Size of stencil letters ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Outside diameter of pipe or covering, ³ Size of stencil letters, ³ ³ inches ³ inches ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Less than 1-1/2 ³ 1/2 ³ ³ 1-1/2 to 3-1/2 ³ 3/4 ³ ³ 3-1/2 to 6 ³ 1-1/4 ³ ³ 6 to 9 ³ 2 ³ ³ 9 to 13 ³ 3 ³ ³ Over 13 ³ 3-1/2 ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ Use of colors. The appearance of any of the six colors specified in 4.2 on a piping system shall provide a warning of danger from the hazard involved in the system according to the definitions for warning colors specified therein. Piping systems which do not require warning colors may be painted to match surrounding, if not in conflict with other color designations in this standard or such systems may be painted aluminum, black, or remain unpainted. 4
8 5.1.3 Primary color warning Use and application. A primary color warning shall appear on dangerous piping systems and on fire protection materials in any installation which is color coded in accordance with this standard. Primary color warnings shall consist of a single color applied as a band or bands which completely encircle the piping system. Color bands shall be applied in conformance with dimensional information shown on figure 1. In lieu of color bands, all pipe and covering on an entire system, including encircling or partially encircling straps, hangers, and supports, may be painted with the primary color warning. However, the use of color bands is preferred because they will indicate dangerous systems to color-blind personnel Location on piping systems. Immediately adjacent to all operating accessories such as valves, regulators, flowchecks, strainers, cleanouts, pumps, dispensing points, and vents, coded piping systems shall be painted with a primary color warning. In addition, primary color warnings shall be painted throughout the system at convenient intervals, e.g., where branch lines join the system, where the system passes underground or through walls, and at any other conspicuous places where warnings are required by safety authorities. If desired, operating accessories may also be painted with the primary color warning Arrows and secondary color warnings. An arrow shape shall appear on coded piping systems in any installation which is color coded in accordance with this standard. Any material system possessing an outstanding hazard of a type distinctly different from that indicated by its primary color warning shall have a secondary color warning applied in the shape of an arrow. The color of the arrow shall be selected according to the definitions for warning colors specified in 4.2. Systems which do not involve such additional hazards shall have arrows either the same color as the primary warning, or black or white. When bands are used for the primary warnings, the colored arrows shall appear adjacent to each primary color warning applied to the piping system. When the entire piping system is painted with the primary color warning, the colored arrows shall appear in locations specified in The arrows shall indicate the normal directions of flow of material in the system. A double-headed arrow shall be placed on lines subject to reverse flow. Dimensional information is shown on figure 1. Tails may be emitted on arrows, creating triangles with one corner indicating the normal direction of flow. Operating accessories may also be painted with the secondary color warning. 5
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10 5.1.5 Classification of material in piping systems. The classification of materials in a piping system shall be as specified in table II. N.O.S. refers to materials of like name and hazardous properties but "not otherwise specified." When no secondary color warning is specified, the arrow may be the same color as the primary warning or black or white, as preferred. Table II. Classification of materials in piping systems ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Acetaldehyde ³ Yellow ³ Blue ³ ³ Acetic acid, aqueous solution ³ Blue ³ Yellow ³ ³ Acetic acid, glacial ³ Blue ³ Yellow ³ ³ Acetic anhydride ³ Blue ³ Yellow ³ ³ Acetone ³ Yellow ³ ³ ³ Acetone oils ³ Yellow ³ ³ ³ Acetyl chloride ³ Blue ³ ³ ³ Acetylene ³ Yellow ³ ³ ³ Acid, liquid, N.O.S. ³ Blue ³ ³ ³ Acrolein ³ Brown ³ Yellow ³ ³ Acrylonitrile ³ Yellow ³ Brown ³ ³ Aerosol insecticide ³ Gray ³ ³ ³ Air, compressed ³ Gray ³ Green ³ ³ Alcohol, allyl, liquid ³ Yellow ³ Brown ³ ³ Alcohol, amyl, butyl, ethyl, propyl, ³ ³ ³ ³ N.O.S. ³ Yellow ³ ³ ³ Alcohol, methyl ³ Yellow ³ Blue ³ ³ Alkaline corrosive liquids, N.O.S. ³ Blue ³ ³ ³ Aluminum borohydride ³ Yellow ³ Brown ³ ³ Ammonia, anhydrous ³ Brown ³ Yellow ³ ³ Amyl acetate ³ Yellow ³ ³ ³ Aniline (oil), liquid ³ Brown ³ Yellow ³ ³ Argon ³ Gray ³ ³ ³ Argon-oxygen mixture ³ Green ³ ³ ³ Arsenic trichloride ³ Brown ³ Blue ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 7
11 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ Arsenical acids and liquids, N.O.S. ³ Brown ³ Blue ³ ³ Benzaldehyde ³ Yellow ³ ³ ³ Benzene (benzol, coal tar light oil) ³ Yellow ³ Brown ³ ³ Benzine (petroleum ether, petroleum ³ ³ ³ ³ naphtha) ³ Yellow ³ ³ ³ Benzoyl chloride ³ Blue ³ ³ ³ Benzyl chloride ³ Blue ³ Yellow ³ ³ Boron hydrides (alkyl decaborane, ³ ³ ³ ³ alkyl pentaborane, diborane, ³ ³ ³ ³ dihydrotetraborane, hexaborane, ³ ³ ³ ³ pentaborane, and N.O.S.) ³ Brown ³ Yellow ³ ³ Boron trichloride ³ Brown ³ ³ ³ Boron trifluoride ³ Brown ³ Gray ³ ³ Bromine ³ ³ ³ ³ Bromine pentafluoride ³ Brown ³ Green ³ ³ Bromine trifluoride ³ Brown ³ Green ³ ³ Bromoacetone ³ Brown ³ ³ ³ Bromobenzene ³ Yellow ³ ³ ³ Bromochloromethane ³ Brown ³ Gray ³ ³ Bromochloromethane, fire ³ Red ³ Brown ³ ³ Bromotrifluoromethane ³ Gray ³ ³ ³ Bromotrifluoromethane, fire ³ Red ³ ³ ³ Butadiene ³ Yellow ³ ³ ³ Butane (see petroleum gas) ³ Yellow ³ ³ ³ Butyl acetate ³ Yellow ³ ³ ³ Butyl ether ³ Yellow ³ ³ ³ Camphor oil ³ Yellow ³ ³ ³ Carbon bisulfide (carbon disulfide) ³ Yellow ³ Brown ³ ³ Carbon dioxide ³ Gray ³ ³ ³ Carbon dioxide, fire ³ Red ³ ³ ³ Carbon monoxide ³ Yellow ³ Brown ³ ³ Carbon tetrachloride ³ Brown ³ Blue ³ ³ Caustic potash, liquid (potassium ³ ³ ³ ³ hydroxide) ³ Blue ³ ³ ³ Caustic soda, liquid (sodium ³ ³ ³ ³ hydroxide) ³ Blue ³ ³ ³ Chloroacetyl chloride ³ Blue ³ ³ ³ Chlorine ³ Brown ³ Green ³ ³ Chlorine trifluoride ³ Brown ³ Green ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 8
12 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Chloroacetone ³ Brown ³ Yellow ³ ³ Chlorosulfonic acid ³ Blue ³ Green ³ ³ Chloropicrin ³ Brown ³ ³ ³ Chloropropane ³ Yellow ³ Blue ³ ³ Chromic acid solution ³ Blue ³ Green ³ ³ Coal gas (see manufactured gas) ³ Yellow ³ Brown ³ ³ Coal tar distillates, N.O.S. ³ Yellow ³ Brown ³ ³ Crotonaldehyde ³ Blue ³ Yellow ³ ³ Crude oil, petroleum ³ Yellow ³ ³ ³ Cyanide, liquid (potassium ³ ³ ³ ³ solutions, sodium solutions), ³ ³ ³ ³ N.O.S. ³ Brown ³ ³ ³ Cyanogen gas ³ Brown ³ Yellow ³ ³ Cyclopropane ³ Yellow ³ Blue ³ ³ Decalin (decahydronaphthalene) ³ Yellow ³ ³ ³ Dibromodifluoromethane ³ Gray ³ ³ ³ Dibromodifluoromethane, fire ³ Red ³ ³ ³ Dichloropentane ³ Yellow ³ ³ ³ Diethanolamine ³ Yellow ³ ³ ³ Diethylenetriamine ³ Yellow ³ ³ ³ Difluorochloroethane ³ Gray ³ Yellow ³ ³ Difluoroethane ³ Gray ³ Yellow ³ ³ Diisobutyl ketone ³ Blue ³ Yellow ³ ³ Dimethylamine, anhydrous ³ Yellow ³ Blue ³ ³ Dimethyl ether ³ Yellow ³ Brown ³ ³ Dimethyl sulfate ³ Brown ³ Blue ³ ³ Dimethyl sulfide ³ Yellow ³ Blue ³ ³ Diphenyl-diphenyl oxide ³ ³ ³ ³ ("Dowtherm A") ³ Gray ³ ³ ³ Dispersant (dichlorodifluoromethane- ³ ³ ³ ³ difluoroethane mixture) ³ Gray ³ ³ ³ Electrolyte acid, N.O.S. ³ Blue ³ ³ ³ Ethane ³ Yellow ³ Blue ³ ³ Ethers, anesthetic: diethyl, ethyl, ³ ³ ³ ³ isopropyl, sulfuric, N.O.S. ³ Yellow ³ Blue ³ ³ Ethyl acetate ³ Yellow ³ ³ ³ Ethyl benzene ³ Yellow ³ ³ ³ Ethyl bromide ³ Yellow ³ Blue ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 9
13 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ Ethyl butyl acetate ³ Yellow ³ ³ ³ Ethyl butyrate ³ Yellow ³ ³ ³ Ethyl chloroacetate ³ Yellow ³ ³ ³ Ethyl chloride ³ Yellow ³ Blue ³ ³ Ethylenediamine ³ Yellow ³ Blue ³ ³ Ethyl hexaldehyde ³ Yellow ³ ³ ³ Ethyl lactate ³ Yellow ³ ³ ³ Ethyl methyl ketone ³ Yellow ³ Blue ³ ³ Ethyl nitrate ³ Yellow ³ Blue ³ ³ Ethyl nitrite ³ Yellow ³ ³ ³ Ethyl silicate ³ Yellow ³ ³ ³ Ethylamine ³ Yellow ³ Blue ³ ³ Ethylene ³ Yellow ³ Blue ³ ³ Ethylene chlorohydrin ³ Yellow ³ ³ ³ Ethylene dichloride ³ Yellow ³ Blue ³ ³ Ethylene glycol ³ Yellow ³ ³ ³ Ethylene oxide ³ Yellow ³ Blue ³ ³ Fluorine ³ Brown ³ Green ³ ³ Formaldehyde ³ Yellow ³ Brown ³ ³ Formic acid ³ Blue ³ Yellow ³ ³ Fuel oil, N.O.S. ³ Yellow ³ ³ ³ Fuels: JP, RP, RS, diesel, N.O.S. ³ Yellow ³ ³ ³ Fumigant, carbon dioxide - ethylene ³ ³ ³ ³ oxide mixture ³ Gray ³ Blue ³ ³ Furfural ³ Blue ³ Yellow ³ ³ Gasoline (motor fuel) ³ Yellow ³ ³ ³ Helium ³ Gray ³ ³ ³ Hydrazine ³ Brown ³ Yellow ³ ³ Hydrocarbons, heavy: hexanes, ³ ³ ³ ³ heptanes, octanes, N.O.S. ³ Yellow ³ ³ ³ Hydrochloric acid ³ Blue ³ ³ ³ Hydrocyanic acid ³ Brown ³ ³ ³ Hydrofluoric acid ³ Brown ³ ³ ³ Hydrofluorosilic acid ³ Blue ³ ³ ³ Hydrogen ³ Yellow ³ ³ ³ Hydrogen bromide ³ Brown ³ ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 10
14 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ Hydrogen chloride, anhydrous ³ Brown ³ ³ ³ Hydrogen cyanide, anhydrous ³ Brown ³ Green ³ ³ Hydrogen fluoride, anhydrous ³ Brown ³ Green ³ ³ Hydrogen, liquid ³ Yellow ³ Gray ³ ³ Hydrogen peroxide ³ Green ³ Blue ³ ³ Hydrogen sulfide ³ Yellow ³ Brown ³ ³ Hydroxyacetic acid (glycolic acid), ³ ³ ³ ³ aqueous solutions ³ Blue ³ ³ ³ Ink (solvent type), N.O.S. ³ Yellow ³ ³ ³ Insecticide, liquid, N.O.S. ³ Brown ³ Yellow ³ ³ Iodine heptafluoride ³ Brown ³ Green ³ ³ Isopentane ³ Yellow ³ Blue ³ ³ Jet fuel (all grades) ³ Yellow ³ ³ ³ Kerosene ³ Yellow ³ ³ ³ Krypton ³ Gray ³ ³ ³ Lacquer ³ Yellow ³ ³ ³ Manufactured gas (coal, oil, ³ ³ ³ ³ pintsch, producer, water, and ³ ³ ³ ³ N.O.S.) ³ Yellow ³ Brown ³ ³ Mercaptans (thioalcohols, N.O.S.) ³ Yellow ³ ³ ³ Mercury componds (solutions), N.O.S. ³ Brown ³ ³ ³ Methane ³ Yellow ³ ³ ³ Methylamine ³ Yellow ³ Brown ³ ³ Methyl acetate ³ Yellow ³ ³ ³ Methyl acetone ³ Yellow ³ ³ ³ Methyl acetylene propadiene mixture ³ ³ ³ ³ (MAPP) ³ Yellow ³ ³ ³ Methyl amyl acetate ³ Yellow ³ ³ ³ Methyl amyl ketone ³ Yellow ³ ³ ³ Methyl bromide ³ Brown ³ ³ ³ Methyl bromide, fire ³ Red ³ Brown ³ ³ Methyl chloride ³ Yellow ³ Brown ³ ³ Methyl cyanide (acetonitrile) ³ Brown ³ Yellow ³ ³ Methyl formate ³ Yellow ³ Blue ³ ³ Methyl hydrazine ³ Brown ³ Yellow ³ ³ Methyl mercaptan ³ Yellow ³ Brown ³ ³ Methyl sulfide ³ Yellow ³ Brown ³ ³ Methylene chloride ³ Blue ³ Gray ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 11
15 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ Natural gas, fortified, N.O.S. ³ Yellow ³ Brown ³ ³ Neon ³ Gray ³ ³ ³ Nickel carbonyl ³ Brown ³ Yellow ³ ³ Nicotine compounds ³ Brown ³ ³ ³ Nitrating acid (mixed acid) ³ Blue ³ Green ³ ³ Nitric acid:blue ³ Green ³ ³ ³ Nitric acid, fuming ³ Brown ³ Green ³ ³ Nitrobenzene ³ Brown ³ Yellow ³ ³ Nitrogen ³ Gray ³ ³ ³ Nitrogen dioxide ³ Brown ³ Green ³ ³ Nitrogen peroxide ³ Brown ³ Green ³ ³ Nitrogen tetroxide ³ Brown ³ Green ³ ³ Nitrogen-helium mixture ³ Gray ³ ³ ³ Nitrogen-oxygen mixture ³ Gray ³ Green ³ ³ Nitrogen trifluoride ³ Blue ³ Green ³ ³ Nitromethane ³ Yellow ³ Blue ³ ³ Nitrosyl chloride ³ Brown ³ ³ ³ Nitrous oxide ³ Blue ³ ³ ³ Oil, hydraulic ³ Yellow ³ Gray ³ ³ Oil, lubricating, N.O.S. ³ Yellow ³ ³ ³ Oil, fish, vegetable, edible, N.O.S. ³ Yellow ³ ³ ³ Oxygen ³ Green ³ ³ ³ Oxygen-carbon dioxide mixture ³ Gray ³ Green ³ ³ Oxygen, electrolytic ³ Green ³ ³ ³ Oxygen fluoride ³ Brown ³ Green ³ ³ Oxygen, liquid (LOX) ³ Green ³ Gray ³ ³ Ozone ³ Green ³ Brown ³ ³ Paint ³ Yellow ³ ³ ³ Paraldehyde ³ Yellow ³ ³ ³ Pentane ³ Yellow ³ ³ ³ Perchloric acid ³ Green ³ Blue ³ ³ 1-Pentene ³ Yellow ³ ³ ³ Petroleum gas (acetogen, butane- ³ ³ ³ ³ propane mixture, 1-butene, ³ ³ ³ ³ cyclopropane, isobutane, neo- ³ ³ ³ ³ pentane, and N.O.S.) ³ Yellow ³ ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 12
16 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ Perchloroethylene ³ Blue ³ ³ ³ Perchloryl fluoride ³ Brown ³ Green ³ ³ Phenylcarbylamine chloride ³ Brown ³ Gray ³ ³ Phosgene ³ Brown ³ ³ ³ Phosphorus oxychloride ³ Blue ³ Green ³ ³ Phosphorus tribromide ³ Blue ³ Green ³ ³ Phosphorus trichloride ³ Blue ³ Green ³ ³ Potassium permanganate solution ³ Green ³ ³ ³ Propylene ³ Yellow ³ Gray ³ ³ n-propyl nitrate ³ Yellow ³ Brown ³ ³ Propyne ³ Yellow ³ Gray ³ ³ Pyrosulfuryl chloride ³ Blue ³ ³ ³ R-11, Trichlorofluoromethane ³ Gray ³ ³ ³ R-12, Dichlorodifluoromethane ³ Gray ³ ³ ³ R-14, Tetrafluoromethane ³ Gray ³ ³ ³ R-21, Dichlorofluoromethane ³ Gray ³ ³ ³ R-22, Chlorodifluoromethane ³ Gray ³ ³ ³ R-112, Tetrachlorodifluoroethane ³ Gray ³ ³ ³ R-113, Trichlorotrifluoroethane ³ Gray ³ ³ ³ R-114, Dichlorotetrafluoroethane ³ Gray ³ ³ ³ R-115, Chloropentafluoroethane ³ Gray ³ ³ ³ R-124A, Chlorotetrafluoroethane ³ Gray ³ ³ ³ E-C-316, Dichlorohexafluoro- ³ ³ ³ ³ cyclobutane ³ Gray ³ ³ ³ R-C-317, Chloroheptafluoro- ³ ³ ³ ³ cyclobutane ³ Gray ³ ³ ³ R-C-318, Octafluorocyclobutane ³ Gray ³ ³ ³ Shellac ³ Yellow ³ ³ ³ Solvents, N.O.S. ³ Yellow ³ ³ ³ Steam ³ Gray ³ ³ ³ Stoddard solvent ³ Yellow ³ ³ ³ Sulfur dichloride ³ Brown ³ ³ ³ Sulfur dioxide ³ Brown ³ Gray ³ ³ Sulfur hexafluoride ³ Gray ³ ³ ³ Sulfur monochloride ³ Blue ³ ³ ³ Sulfur trioxide ³ Brown ³ Green ³ ³ Sulfuric acid ³ Brown ³ Green ³ ³ Sulfuric acid, fuming (oleum) ³ Brown ³ Green ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 13
17 Table II. Classification of materials in piping systems (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ Material ³ Primary ³ Secondary ³ ³ ³ color warning ³ color warning ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ Tetraethyl lead ³ Brown ³ ³ ³ Tetrafluoroethylene, inhibited ³ Gray ³ ³ ³ Thionyl chloride ³ Brown ³ Green ³ ³ Tin tetrachloride, anhydrous ³ Blue ³ ³ ³ Titanium tetrachloride ³ Blue ³ ³ ³ Toluene ³ Yellow ³ Brown ³ ³ Triamylamine ³ Brown ³ Yellow ³ ³ Tributylamine ³ Yellow ³ Blue ³ ³ Triethanolamine ³ Blue ³ Yellow ³ ³ Triethylamine ³ Brown ³ Yellow ³ ³ Trimethylamine, anhydrous ³ Brown ³ Yellow ³ ³ Turpentine ³ Yellow ³ ³ ³ Unsymmetrical dimethyl hydrazine ³ Brown ³ Yellow ³ ³ Vacuum (noncontaminated) ³ Gray ³ ³ ³ Varnish ³ Yellow ³ ³ ³ Vinyl bromide ³ Blue ³ ³ ³ Vinyl chloride ³ Yellow ³ ³ ³ Vinyl methyl ether ³ Yellow ³ ³ ³ Waste acid (spent nitrating acid) ³ Blue ³ Yellow ³ ³ Water, over 50 p.s.i.g. or 150 deg. F ³ Gray ³ ³ ³ Water, fire ³ Red ³ ³ ³ Water, potable ³ White ³ ³ ³ Waxes, liquid ³ Yellow ³ ³ ³ Xenon ³ Gray ³ ³ ³ Xylene ³ Yellow ³ Brown ³ ³ Xylidine ³ Brown ³ Yellow ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÙ 5.2 Cylinder identification Assignment of colors. The use of color coding for compressed gas cylinders covered by this standard is mandatory. The assignment of colors to extend coverage of material handled in compressed gas cylinders shall be made only after approval of the preparing activity of this standard. Requests for color coding of additional materials not covered by this standard should include technical details of the material, primary and secondary hazards of the material, and technical details of the cylinder, including the type of cylinder valve used. 14
18 5.2.2 Exact identification. Exact identification of any material contained in a compressed gas cylinder is mandatory and shall be made only by means of the written title as specified in table III. The title shall appear in two locations diametrically opposite and parallel to the longitudinal axis of the cylinder. It is recommended that the titles be applied by use of upper case letters and rabic numerals whenever applicable. On cylinders 4 inches in diameter and larger, the title shall be in approximately 2-inc4 high letters. On cylinders less than 4 inches in diameter, letters may be reduced in size. Where a title includes a modifier, such as "medical" or "oil-free," the modifier shall follow the chemical designation and should be shown in letters approximately three-fourths as high. Cylinders having a background color of yellow, orange, or buff shall have the title painted with black letters. Cylinders having a background color of red, brown, blue, gray, green, or black shall have the title painted with white letters. Mixtures of two or more gases shall show the percent of each gas as part of the title Use of colors Color worries. The appearance on the body, top, or as a band(s) on compressed gas cylinders of any of the six colors specified in 4.2 shall provide a warning of danger from the hazard involved in handling the type of material contained in the cylinder according to the definitions for warning colors in Cylinder color band(s). Cylinder color bands appear upon the cylinder body and serve as color warnings when they are yellow, brown, blue, green, or gray. The bands also provide color combinations to separate and distinguish cylinders for convenience in handling, storage, and shipping. Color bands for segregation purposes will not be specified for new materials not presently covered by this standard when new color codes for them are assigned Painting of cylinders. All cylinders shall be painted in accordance with table III and figures 2 and 3 to provide uniform recognition throughout the Department of Defense. 15
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21 Table III. Titles and color codes for compressed gas cylinders ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ Location on cylinder ³ ³ ÃÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄ ³ Title ³ Top A ³ Band B ³ Band C ³ Body ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄ ³ Acetylene ³ Yellow ³ Yellow ³ Yellow ³ Yellow³ ³ Acrolein ³ Yellow ³ Brown ³ Black ³ Brown ³ ³ Aerosol insecticide ³ Buff ³ Buff ³ Buff ³ Buff ³ ³ Air, compressed, breathing ³ Black ³ Green ³ Black ³ Black ³ ³ Air, dry, special purpose ³ Black ³ Green ³ Black ³ Black ³ ³ Air, oil-free ³ Black ³ Green ³ Black ³ Black ³ ³ Air, oil-tolerant ³ Black ³ Green ³ Green ³ Black ³ ³ Alkyl decaborane ³ Yellow ³ Brown ³ Brown ³ Yellow³ ³ Alkyl pentaborane ³ Yellow ³ Brown ³ Brown ³ Yellow³ ³ Ammonia ³ Brown ³ Yellow ³ Orange ³ Orange³ ³ Argon, oil-free ³ Gray ³ White ³ Gray ³ Gray ³ ³ Argon, oil-tolerant ³ Gray ³ White ³ White ³ Gray ³ ³ Argon-oxygen mixture ³ Gray ³ Green ³ White ³ Gray ³ ³ Boron trichloride ³ Gray ³ Brown ³ Gray ³ Brown ³ ³ Boron trifluoride ³ Gray ³ Brown ³ Brown ³ Brown ³ ³ Bromoacetone ³ Brown ³ Black ³ Black ³ Brown ³ ³ Bromochloromethane ³ Buff ³ Gray ³ Buff ³ Buff ³ ³ Bromochloromethane (Fire only) ³ Red ³ Gray ³ Red ³ Red ³ ³ Bromotrifluoromethane ³ Orange ³ White ³ Gray ³ Orange³ ³ Bromotrifluormethane (Fire only) ³ Red ³ White ³ Gray ³ Red ³ ³ Butadiene ³ Yellow ³ White ³ Buff ³ Buff ³ ³ Carbon dioxide ³ Gray ³ Gray ³ Gray ³ Gray ³ ³ Carbon dioxide (Fire only) ³ Red ³ Red ³ Red ³ Red ³ ³ Carbon monoxide ³ Yellow ³ Brown ³ Brown ³ Brown ³ ³ Chloroacetone ³ Black ³ Brown ³ Black ³ Brown ³ ³ Chlorine ³ Brown ³ Brown ³ Brown ³ Brown ³ ³ Chlorine trifluoride ³ Brown ³ Green ³ Brown ³ Brown ³ ³ Chloropicrin ³ Brown ³ Orange ³ Orange ³ Brown ³ ³ Cyanogen ³ Yellow ³ Brown ³ Yellow ³ Brown ³ ³ Cyclopropane, medical ³ Orange ³ Yellow ³ Blue ³ Blue ³ ³ Cyclopropane, medical ³ Orange ³ Chromium plated³ ³ ³ Diborane ³ Yellow ³ Brown ³ Brown ³ Yellow³ ³ Dibromodifluoromethane ³ Buff ³ White ³ Buff ³ Buff ³ ³ Dibromodifluoromethane (Fire ³ ³ ³ ³ ³ ³ only) ³ Red ³ White ³ Red ³ Red ³ ³ Difluorochloroethane ³ Gray ³ Yellow ³ Yellow ³ Orange³ ³ Difluoroethane ³ Gray ³ Yellow ³ Orange ³ Orange³ ³ Dihydrotetraborane ³ Yellow ³ Brown ³ Brown ³ Yellow³ ³ Dimethylamine, anhydrous ³ Yellow ³ Blue ³ White ³ Buff ³ ³ Dimethylether ³ Yellow ³ Brown ³ Buff ³ Buff ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÙ 18
22 Table III. Titles and color codes for compressed gas cylinders (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ Location on cylinder ³ ³ ÃÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄ ³ Title ³ Top A ³ Band B ³ Band C ³ Body ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ ³ ³ Dispersant, dichlorodifluoro- ³ ³ ³ ³ ³ ³ methane-difluoroethane mixture ³ Buff ³ Gray ³ Gray ³ Buff ³ ³ Ethane ³ Yellow ³ Blue ³ Yellow ³ Yellow³ ³ Ethyl chloride ³ Buff ³ Blue ³ Yellow ³ Buff ³ ³ Ethyl nitrite ³ Yellow ³ Buff ³ Buff ³ Buff ³ ³ Ethylamine, anhydrous ³ Yellow ³ Blue ³ Blue ³ Buff ³ ³ Ethylene, industrial ³ Blue ³ Yellow ³ Buff ³ Buff ³ ³ Ethylene, medical ³ Yellow ³ Blue ³ Blue ³ Blue ³ ³ Ethylene oxide ³ Yellow ³ Blue ³ Buff ³ Buff ³ ³ Fluorine ³ Brown ³ Green ³ Green ³ Brown ³ ³ Fumigant, carbon dioxide- ³ ³ ³ ³ ³ ³ ethylene oxide mixture ³ Buff ³ Blue ³ Buff ³ Buff ³ ³ Fumigant, ethylene oxide- ³ ³ ³ ³ ³ ³ dichlorodifluoromethane mixture- ³ Buff ³ Buff ³ Buff ³ Buff ³ ³ Helium, oil-free or medical ³ Buff ³ Gray ³ Gray ³ Gray ³ ³ Helium, oil-tolerant ³ Gray ³ Orange ³ Gray ³ Gray ³ ³ Helium-oxygen mixture ³ Buff ³ White ³ Green ³ Green ³ ³ Hydrogen ³ Yellow ³ Black ³ Yellow ³ Yellow³ ³ Hydrogen bromide ³ Black ³ Brown ³ Brown ³ Brown ³ ³ Hydrogen chloride, anhydrous ³ Brown ³ White ³ Brown ³ Brown ³ ³ Hydrogen cyanide, anhydrous ³ Yellow ³ Brown ³ White ³ Brown ³ ³ Hydrogen fluoride, anhydrous ³ Green ³ Brown ³ Brown ³ Brown ³ ³ Hydrogen sulfide ³ Brown ³ Yellow ³ Brown ³ Brown ³ ³ Krypton, oil-free ³ Gray ³ Buff ³ Gray ³ Gray ³ ³ Krypton, oil-tolerant ³ Gray ³ Buff ³ Buff ³ Gray ³ ³ Manufactured gas: coal, oil, ³ ³ ³ ³ ³ ³ water, producer, etc. ³ Brown ³ Yellow ³ Yellow ³ Yellow³ ³ Methane ³ Yellow ³ White ³ Yellow ³ Yellow³ ³ Methyl acetylene propadiene ³ ³ ³ ³ ³ ³ (MAPP) mixture ³ Yellow ³ Orange ³ Yellow ³ Yellow³ ³ Methylamine ³ Yellow ³ Brown ³ Yellow ³ Buff ³ ³ Methyl bromide ³ Brown ³ Black ³ Brown ³ Brown ³ ³ Methyl bromide (Fire only) ³ Red ³ Brown ³ Red ³ Red ³ ³ Methyl chloride ³ Yellow ³ Brown ³ Orange ³ Orange³ ³ Methyl mercaptan ³ Brown ³ Yellow ³ Yellow ³ Brown ³ ³ Methyl sulfide ³ Yellow ³ Brown ³ Buff ³ Brown ³ ³ Methylene chloride ³ Gray ³ Blue ³ Orange ³ Orange³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÙ * A' or A" (see figure 2) for medical gas mixtures. ** B' or B" (see figure 2) for medical gas mixtures. 19
23 Table III. Titles and color codes for compressed gas cylinders (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ Location on cylinder ³ ³ ÃÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄ ³ Title ³ Top A ³ Band B ³ Band C ³ Body ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄ ³ Natural gas ³ Yellow ³ Brown ³ Yellow ³ Yellow³ ³ Neon, oil-free ³ White ³ Buff ³ Buff ³ Gray ³ ³ Neon, oil-tolerant ³ White ³ Buff ³ Gray ³ Gray ³ ³ Nickel carbonyl ³ Yellow ³ White ³ Yellow ³ Brown ³ ³ Nitric oxide ³ Brown ³ Buff ³ Brown ³ Brown ³ ³ Nitrogen, oil-free ³ Gray ³ Black ³ Black ³ Gray ³ ³ Nitrogen, oil-tolerant ³ Gray ³ Black ³ Gray ³ Gray ³ ³ Nitrogen dioxide ³ Brown ³ Buff ³ Buff ³ Brown ³ ³ Nitrogen-helium mixture ³ Gray ³ Black ³ Orange ³ Gray ³ ³ Nitrogen-oxygen mixture ³ Black ³ White ³ Green ³ Green ³ ³ Nitrosyl chloride ³ Brown ³ White ³ White ³ Brown ³ ³ Nitrous oxide ³ Blue ³ Blue ³ Blue ³ Blue ³ ³ Oxygen ³ Green ³ Green ³ Green ³ Green ³ ³ Oxygen, aviator's ³ Green ³ White ³ Green ³ Green ³ ³ Oxygen, electroyltic ³ Green ³ White ³ White ³ Green ³ ³ Oxygen, medical ³ White ³ Green ³ Green ³ Green ³ ³ Oxygen-carbon dioxide mixture ³ Gray* ³ White**³ Green ³ Green ³ ³ Oxygen fluoride ³ Green ³ Brown ³ Green ³ Brown ³ ³ Ozone ³ Brown ³ Green ³ Green ³ Green ³ ³ Pentaborane, stable ³ Yellow ³ Brown ³ Brown ³ Yellow³ ³ Petroleum gas: acetogen, butane, ³ ³ ³ ³ ³ ³ butane-propane, butene-1, ³ ³ ³ ³ ³ ³ cyclopropane, isobutane, ³ ³ ³ ³ ³ ³ isobutylene, neopentane, ³ ³ ³ ³ ³ ³ propane, etc. ³ Yellow ³ Orange ³ Yellow ³ Yellow³ ³ Phenylcarbylamine chloride ³ Brown ³ Gray ³ Gray ³ Brown ³ ³ Phosgene ³ Brown ³ Orange ³ Brown ³ Brown ³ ³ Propylene ³ Yellow ³ Gray ³ Buff ³ Buff ³ ³ Propyne ³ Gray ³ Yellow ³ Yellow ³ Yellow³ ³ R-11, Trichlorofluoromethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-12, Dichlorodifluoromethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-13, Chlorotrifluoromethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-21, Dichlorofluoromethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-22, Chlorodifluoromethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-113, Trichlorotrifluoroethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-114, Dichlorotetrafluoroethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-124A, Chlorotetrafluoroethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-500, Dichlorodifluoromethane/ ³ ³ ³ ³ ³ ³ Difluoroethane ³ Orange ³ Orange ³ Orange ³ Orange³ ³ R-502, Monochlorodifluoromethane/ ³ ³ ³ ³ ³ ³ Chloropentafluoroethane ³ Orange ³ Orange ³ Orange ³ Orange³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÙ * A' or A" (see figure 2) for medical gas mixtures. ** B' or B" (see figure 2) for medical gas mixtures. 20
24 Table III. Titles and color codes for compressed gas cylinders (continued) ÚÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄ ³ ³ Location on cylinder ³ ³ ÃÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄÄÂÄÄÄÄÄÄÄ ³ Title ³ Top A ³ Band B ³ Band C ³ Body ³ ÃÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄÄÅÄÄÄÄÄÄÄ ³ ³ ³ ³ ³ ³ ³ Sulfur dioxide ³ Brown ³ Gray ³ Brown ³ Brown ³ ³ Sulfur hexafluoride ³ Gray ³ White ³ Black ³ Gray ³ ³ Tetrafluoroethylene, inhibited ³ Buff ³ White ³ White ³ Buff ³ ³ Trimethylamine, anhydrous ³ Yellow ³ Blue ³ Orange ³ Buff ³ ³ Vinyl bromide ³ Buff ³ Blue ³ Blue ³ Buff ³ ³ Vinyl chloride ³ Yellow ³ Orange ³ Buff ³ Buff ³ ³ Vinyl methyl ether, inhibited ³ Yellow ³ Black ³ Buff ³ Buff ³ ³ Xenon, oil-free ³ White ³ Black ³ Gray ³ Gray ³ ³ Xenon, oil-tolerant ³ White ³ Black ³ Black ³ Gray ³ ÀÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÄÁÄÄÄÄÄÄÄÙ Additional information Commercial-owned cylinders. Commercial-owned cylinders are those not owned by or procured for the U.S. Government. Commercial-owned cylinders are contractor-owned or supplier-owned cylinders in which compressed gas is supplied to the Government. When Department of Defense activities procure compressed gases in commercial-owned cylinders, it is not mandatory that the cylinders be color coded in accordance with this standard. When such commercial-owned cylinders are not color coded in accordance with this standard, they shall be marked in accordance with Department of Transportation regulations and American National Standard Z48.1. If the using Department of Defense activity requires that this standard apply to commercial-owned cylinders, the bottom and lower portion of the cylinder body opposite the valve end may be used for commercial identification. In this area, which shall not exceed one-sixth of the overall length of the cylinder, the use of a solid color other than the body color will not be permitted Decalcomanias. Two decalcomanias may be applied on the shoulder of each cylinder diametrically opposite at right angles to titles. They should include the title of the gas, precautions for handling, and use. A background color corresponding to the primary warning color of the contents should be used Shatterproof designation. Shatterproof cylinders shall be stenciled with the phrase "Non-Shat" longitudinally 90 degrees from the titles. Letters shall be black or white and approximately 1 inch in size. 21
25 Service ownership. On cylinders owned by or procured for the Department of Defense, the bottom and the lower portion of the cylinder body opposite the valve end may be used for Service ownership titles International standardization agreements. This standard be used to implement NATO STAGNAG 2121, CENTO STAGNAG 2121, and SEATO STAGNAG 2121, subject: Medical Gas Cylinders. Custodians: Army - MU Navy - SH Air Force - 68 Review activities: Army - AV, ME, MI, MU(FA), WC Navy - AS, MC, MS, SH, YD Air Force - 12, 43, 68, 70 DSA - CS, GS User activities: Navy - CG Air Force - 19, 71 Preparing activity: Army - MU(EA) Project No
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