MATERIAL/PRODUCT SAFETY DATA SHEET

Transcription

1 MATERIAL/PRODUCT SAFETY DATA SHEET **Revision 1): Revise on Jan following New IATA Regulation for Air shipment of Lithium battery 1. Ientification of the Substance or Preparation an Company 1.1 Prouct : Lithium/Thionyl Chlorie(Li/SOCl 2 ) Cells & Batteries 1.2 Moel : TEKCELL (Bran name) Which is name as SB-AA02, SB-AA11, SB-A01, SB-C02, SB-D02, SW-AA11, SW-C01, SW-D02 an series of SB an SW. 1.3 Company Name : Vitzrocell, Co. Lt Aress : Dugok-ri, Sinam-myon, Yesan-gun, ChungCheong Nam-Do Tel : ~5 Fax : Website : 2. Composition & Information on Ingreients Ingreient Content (%) CAS No. Lithium(Li) 3.0 ~ 4.5% Carbon (C) 3.0 ~ 4.5% Electrolyte(SOCl 2 ) 30 ~ 45% Aluminium Chlorie(AlCl 3 ) 2.0 ~ 4.0% Hazars Ientification The lithium thionyl chlorie batteries escribe in this MSDS are hermetically seale unit, which are not hazarous when use accoring to the recommenations of the manufacturer. Uner normal conition of use of the batteries, the electroe materials an the liqui electrolyte they containe are non-reactive provie the battery integrity is maintaine. Risk of exposure exists only in case of mechanical, electrical or thermal abuse. Thus, the batteries shoul not short circuit, recharge, puncture, incinerate, - Page 1/8 MSDS Li-SOCl 2

2 crush, immerse in water, force ischarge, or expose to above the temperature range of the cell or battery. In these cases, there is risk of fire or explosion. 4. First Ai Measures Hanle accoring to emergency measures uner in case of battery rupture, explosion or leakage an evacuate personnel from contaminate area an provie goo ventilation to clear out corrosive fumes, gases or the pungent oour. Seek immeiate meical attention. Inhalation Remove from exposure, rest an keep warm. In severe cases, obtain meical attention Skin Contact Wash off skin thoroughly with flow water for 10~15 minutes an obtain meical attention. Eye Contact Irrigate thoroughly with Water for at least 15 minutes an obtain meical attention. Ingestion Wash out mouth thoroughly with water an give plenty of water to rink for vomit an obtain meical attention. 5. Fire Fighting Measures It is effective to use col water in orer to prevent sprea of fire cause by lithium cells. However, never use hot water. Lith-X(Class D extinguishing meia) is the only effective on fires involving a few lithium batteries. If the cells are irectly involve in a fire, DO NOT USE WATER, SAND, CO2, HALON an DRY POWDER or SODA ASH EXTINGUISHERS. If a fire is in ajacent area, an cells are packe in their original containers, the fire can be fought base on fuelling material, e.g. paper an plastic proucts. 6. Acciental Release Measures Do not breathe vapours or touch liqui with bare han. If the skin has come into contact with the electrolyte, take an action in accorance with 4. First Ai Measures. Graphite power shoul be use to absorb the exuation, seal leaking battery an graphite power in plastic bag an ispose of Special Waste. - Page 2/8 MSDS Li-SOCl 2

3 7. Hanling an Storage Hanling - Prevent short circuit an o not use the battery above the temperature rating of battery. Do not recharge, force over-ischarge (voltage below 0.0V), puncture an compress. Storage - Storage preferably in cool (below 30 C) an non- elevate temperatures place. Storage in high temperatures can result in shortene battery life an egrae performance. Do not store batteries in high humiity, shock an vibration environments. Others Do not charge Li/SOCl 2 primary battery which is not chargeable battery. Follow manufacturer s recommenations regaring maximum recommene current an operating temperature range. 8. Exposure Controls & Personal Protection The following safety measures are not necessary in normal use. They nee only be applie if there is a risk that, in use or hanling, the recommenations, as outline in Section 3, have not been followe. Respiratory protection - In all fire situations, use filter mask or self- containe breathing Apparatus for harmful gases or other material prevention. Han protection In leakage situations, use specific gloves for leaking chemical substance an heat prevention. Eye protection Use safety goggles or face shiel which can separate eyes an the outsie for chemical substance an heat prevention. Other protective equipment Aitional equipments are neee to prevent from chemical substance, harmful material an heat. (Clothes, boots etc.) 9. Physical an Chemical Properties Appearance Oour ph Boiling point Cylinrical shape Oourless. If leaking, gives off a pungent an corrosive oour. - Page 3/8 MSDS Li-SOCl 2

4 Vapour pressure (mmhg, 25ºC) Relative ensity Flash point Flammability Solubility (water) Solubility (other) Physical state Soli 10. Stability an Reactivity Prouct is stable uner conitions escribe in Section 7 (Hanling an storage). Conitions to avoi heating an incineration above 90, transformation, abscission, compression, puncture, isassembly, charge, a short circuit, storage in high humiity for a long time. Material to avoi Prevent to contact Oxiizer, Strong carbonate water, Alkali solutions, Water (H 2 O), Aluminium, Zinc, an Electrolyte. Harmful materials cause by isassembly 1. Water (H 2 O) reacts with lithium metal to form power such as lithium hyroxie (LiOH), lithium oxie an hyrogen gas (H 2 ) 2. In case of heating Thionyl chlorie(socl 2 ) above 150, chlorine(cl 2 ), sulfur ioxie(so 2 ), sulphur trioxie(so 3 ), isulfur ichlorie(s 2 Cl 2 ), sulphur ichlorie (SCl 2 ), lithium oxie(li 2 O) may occur. 3. Water (H 2 O) reacts with thionyl chlorie(socl 2 ) in room temperature to form hyrochloric aci(hcl) an sulphur ioxie(so 2 ). 11. TOXICOLOGICAL INFORMATION Symptoms an Signs None, unless battery ruptures. In the event of exposure to internal contents, corrosive fumes will be very irritating to skin, eyes an mucous membranes. Inhalation - Lung irritant. - Page 4/8 MSDS Li-SOCl 2

5 Skin contact Skin irritant Eye contact Eye irritant Ingestion if swallow, it can be poisone. Meical conition aggravate by exposure - In the event of exposure to internal contents, eczema, skin allergies, lung injuries, asthma an other respiratory isorers may occur. 12. Ecological Information When properly use of ispose the battery oes not present environmental hazar. Cells of Vitzrocell o not contain mercury, camium, lea an Cr 6+ which has a ba influence on environment. 13. Disposal Consierations Do not incinerate or subject cells to temperatures in excess of 85 C. In the event of such abuse can result in loss of seal that causes explosion. Cells shoul be separate after use in orer to prevent short circuit terminal by using tape or other tools an ispose of in accorance with regulations. 14. Transportation Lithium cells an batteries are classifie as UN Depenent on the lithium content, cells (less than 1g) or batteries (less than 2g) can be transporte uner the requirements of special provision 188/A45. Lithium cell must pass relevant examination regarless of lithium content. Vitzrocell s cells an batteries successfully passe the tests of UN Manual of Tests an Criteria. Relevant regulation an examination regulation for prouct are as follows. The UN Recommenations on the Transport of Dangerous Goos, Moel Regulations The UN recommenations on the Transport of Dangerous Goos, Manual of Tests an Criteria, Part Ⅲ, Section 38.3 Hazar Classification: Class9 UN Number: 3090 Lithium batteries Packing group: Ⅱ - Page 5/8 MSDS Li-SOCl 2

6 Ref) The batteries are complie with the PACKING INSTRUCTION OF the current IATA g regulations (PI968). This instruction applies to lithium metal or lithium alloy cells an batteries (UN 3090) on passenger an Cargo Aircraft Only. Part 1 Lithium metal or lithium alloy cells an batteries offere for transport are not subject to other aitional requirements of these Regulations if they meet the requirements in Part 1. Lithium batteries ientifie by the manufacturer as being efective for safety reasons, that have been amage or have the potential of proucing a angerous evolution of heat, fire or short circuit are forbien for transport (e.g. those being returne to the manufacturer for safety reasons). Lithium metal or lithium alloy cells an batteries may be offere for transport if they meet the following: 1. a lithium metal cell, the lithium content is not more than 1 g; 2. a lithium metal or lithium alloy battery, the aggregate lithium content is not more than 2 g; 3. each cell or battery is of the type proven to meet the requirements of each test in the UN Manual of Tests an Criteria, Part III, subsection Quantity per package Passenger aircraft Lithium metal cells an batteries General requirements Quantity per package Cargo Aircraft Only 2.5 kg G 2.5 kg G Cells an batteries must be packe in strong outer packagings that conform to , an Aitional requirements Cells an batteries must be packe in inner packagings that completely enclose the cell or battery. Cells an batteries must be protecte so as to prevent short circuits. This inclues protection against contact with conuctive materials within the same packaging that coul lea to a short circuit. Each package must be capable of withstaning a 1.2 m rop test in any orientation without: amage to cells or batteries containe therein; shifting of the contents so as to allow battery to battery (or cell to cell) contact; release of contents. Each consignment must be accompanie with a ocument such as an air waybill with an inication that: the package contains lithium metal cells or batteries; the package must be hanle with care an that a flammability hazar exists if the package is amage; special proceures shoul be followe in the event the package is amage, to inclue inspection an repacking if necessary; an a telephone number for aitional information. - Page 6/8 MSDS Li-SOCl 2

7 Each package must be labele with a lithium battery hanling label (Figure 7.4.I); Any person preparing or offering cells or batteries for transport must receive aequate instruction on these requirements commensurate with their responsibilities. OUTER PACKAGINGS Type Part 2 Drums Jerricans Boxes Part 2 requirements apply to each cell or battery type that has been etermine to meet the criteria for assignment to Class 9. Each cell or battery must: 1. Be of the type proven to meet the requirements of each test in the UN Manual of Tests an Criteria, Part III, subsection Incorporate a safety venting evice or be esigne to preclue a violent rupture uner conitions normally incient to transport, an be equippe with an effective means of preventing external short circuits. Each battery containing cells or a series of cells connecte in parallel must be equippe with an effective means, as necessary, to prevent angerous reverse current flow (e.g. ioes, fuses). Cells with a liqui cathoe containing sulphur ioxie, sulphuryl chlorie or thionyl chlorie, which have been ischarge to the extent that the open circuit voltage is less than the lower of: 2 volts; or two-thirs of the voltage of the unischarge cell; an batteries containing one or more such cells, are forbien for transport. Quantity per package Passenger aircraft Lithium metal cells an batteries General requirements The General Packing Requirements of must be met. Aitional requirements Quantity per package Cargo Aircraft Only 2.5 kg G 35 kg G all lithium metal cells an batteries prepare for transport as Class 9 must be protecte against short circuits; packagings must meet Packing Group II performance stanars; lithium batteries with a mass of 12 kg or greater an having a strong, impact-resistant outer casing, or assemblies of such batteries, may be transporte when packe in strong outer packagings an protective enclosures not subject to the requirements of Section 6 of these Regulations, if approve by the appropriate national authority of the State of origin. A copy of the ocument of approval must accompany the consignment. Lithium metal cells an batteries prepare for transport on Passenger Aircraft as Class 9: must be packe in either a rigi metal intermeiate or a metal outer packaging; - Page 7/8 MSDS Li-SOCl 2

8 cells an batteries must be surroune by cushioning material that is non-combustible an non-conuctive before being place in either the metal intermeiate or metal outer packaging. OUTER PACKAGINGS De sc Sp ec Ste el Type Drums Jerricans Boxes Alu m- iniu m Plywoo Fib re 1A 2 1B2 1D 1G Pla stic Oth er met al Ste el Alum - iniu m Plast ic Steel Alum - iniu m 1H 2 1N2 3A2 3B2 3H2 4A 4B W oo Ply - woo Reco n- stitut e woo 4C 1 4C 2 4D 4F Fi br e- bo ar 4 G Pl as tic 4H 1 4H 2 Other regulation an guieline ADR, RID 188, 230, 310, P903 IATA A45, A88, A99 IMDG coe 188, 230, 310, P Regulatory Information None 16. Other Information TEKCELL (manufacturer: Vitzrocell) was recognize safety by UL (Unerwriters Laboratories) locate in Northbrook, U.S.A. (UL File No. : MH 18384) Emergency contact phone No.: Vitzrocell has all authorities about this MSDS. In case of use of relevant ata by outsie presentation, shoul get permission by Vitzrocell. - Page 8/8 MSDS Li-SOCl 2