Explanatory sheet about safety of product for transportation

Transcription

1 1. Basic item Product name: Explanatory sheet about safety of product for transportation (Safety data sheet for transportation) Lithium ion battery ( Lithium ion battery includes lithium ion polymer battery in this document) UN number: 3480 Product Part Number: Refer to Table 1. Manufacturer: Address: LG Chemical, Ltd. LG Twin Towers, 128 Yeoui-daero, Yeongdeungpo-gu Seoul 07336, Korea Phone number: Product information Basic composition of the product This product is a battery which consists of such main component as core battery pack assembled with some Lithium ion cell s. And it consists of any combination of plastic casing, tube casing, protection circuit boards, safety devices and interface ter minals. 3. Safety information - LG Chemical certifies the battery has passed and satisfied the UN Manual of Tests and Criteria Part III, sub-section 38.3 t esting in LG Chemical Shipping. - LG Chemical manufactured the battery under the quality management program required in UN model regulations 2.9.4(e). 3-1) Component cell The Watt-hour rating of the component Lithium ion cells is not more than 20Wh. 3-2) Battery pack 1. The Watt-hour rating of the battery is not more than 100Wh. 2. Package of the battery satisfy the following conditions when LG Chemical ships. (1) The product name Lithium ion batteries and how to deal with the damage of the package are written on the label. (2) The package has passed the drop test from the height of 1.2m. (3) The package net weight is not more than 10kg. 3. The battery is not defective for safety reasons, not damaged. It is not collected battery for recycling or disposal. 4. The battery is not subject to the fully regulated requirements for Dangerous Goods in ocean and ground transportation. 5. The battery should be transported by Cargo aircraft as UN3480, class 9 Dangerous Goods, and state of charge not exceedi ng 30%, attached by required marks and labels, according to Packing Instruction 965 Section IB of the ICAO and IATA re gulations. Feb, 9, 2017 Jin Soo Park LG Chemical Ltd

2 Table 1. Model list of application Battery Information Cell Battery Pack Lenovo ASM Part Number Equivalen Lenovo Nominal Rating Watt hour Lenovo FRU Weight t Lithium Option Part MSDS Type # Voltage Voltage Rating Part Number (grams) Content Number (V) (V) (Wh) (grams) 45N N1113 SDS_LGPR N1112_UN N N1119 SDS_LGPR N1118_UN38.3 UN38.3 report 45N N1127 SDS_LGPR N1126_UN N N1755 SDS_LGPR N1754_UN38.3 SB10J HW041 SDS_LGPR SB10J78989_UN38.3 SB10K NY639 SDS_LGPR SB10K12721_UN38.3

3 MATERIAL SAFETY DATA SHEET Product Name: Lithium Ion Rechargeable Battery Product Code: None ( All Prismatic Cell LG Chem. manufactured and whose capacity is less than 20Wh, And All Prismatic pack capacity is less than 100Wh) 1. Company Identification Manufacturer LG Chemical Ltd. Twin Tower Youido-Dong 120, Youngdeungpo-Ku Seoul, Korea Emergency Telephone Number Composition Information Hazardous Ingredients % CAS Number Aluminum Foil Metal Oxide (proprietary) MSDS Page 1 of 13 Printed

4 Polyvinylidene Fluoride (PVDF) < Copper Foil Emergency Overview May explode in a fire, which could release hydrogen fluoride gas. Use extinguishing media suitable for materials burning in fire. Carbon (proprietary) Electrolyte (proprietary) Stainless steel, Nickel and inert materials Remainder N/A Stylene-butadiene-rubber <5 * Not every product includes all of these materials. 3. Hazards Identification Primary routes of entry Skin contact : NO Skin absorption : NO Eye contact : NO Inhalation : NO Ingestion : NO Symptoms of exposure MSDS Page 2 of 13 Printed

5 Skin contact No effect under routine handling and use. Skin absorption No effect under routine handling and use. Eye contact No effect under routine handling and use. Inhalation No effect under routine handling and use. Reported as carcinogen Not applicable 4. First Aid Measures Inhalation Not a health hazard. MSDS Page 3 of 13 Printed

6 Eye contact Not a health hazard. Skin contact Not a health hazard. Ingestion If swallowed, obtain medical attention immediately. IF EXPOSURE TO INTERNAL MATERIALS WITHIN CELL DUE TO DAMAGED OUTER CASING, THE FOLLOWING ACTIONS ARE RECOMMENDED ; Inhalation Leave area immediately and seek medical attention. Eye contact Rinse eyes with water for 15 minutes and seek medical attention. MSDS Page 4 of 13 Printed

7 Skin contact Wash area thoroughly with soap and water and seek medical attention. Ingestion Drink milk/water and induce vomiting; seek medical attention. 5. Fire Fighting Measures General Hazard Cell is not flammable. Combustion products include, but are not limited to hydrogen fluoride, carbon monoxide and carbon dioxide. Extinguishing Media Use extinguishing media suitable for the materials that are burning. Special Firefighting Instructions If possible, remove cell(s) from fire fighting area. If heated above 160 C, cell(s) may explode/vent. MSDS Page 5 of 13 Printed

8 Firefighting Equipment Use NIOSH/MSHA approved full-face self-contained breathing apparatus (SCBA) with full protective gear. 6. Accidental Release Measures On Land Place material into suitable containers and call local fire/police department. In Water If possible, remove from water and call local fire/police department. 7. Handling and Storage Handling No special protective clothing required for handling individual cells. MSDS Page 6 of 13 Printed

9 Storage Store in a cool, dry place. 8. Exposure Controls / Personal Protection Engineering controls Keep away from heat and open flame. Store in a cool, dry place. Personal Protection Respirator Not required during normal operations. SCBA required in the event of a fire. Eye/face protection Not required beyond safety practices of employer. Gloves MSDS Page 7 of 13 Printed

10 Not required for handling of cells. Foot protection Steel toed shoes recommended for large container handling. 9. Physical and Chemical Properties State Odor PH Vapor pressure Vapor density Boiling point Solubility in water Specific gravity Density Solid N/A N/A N/A N/A N/A Insoluble N/A N/A 10. Stability and Reactivity Reactivity MSDS Page 8 of 13 Printed

11 None Incompatibilities None during normal operation. Avoid exposure to heat, open flame, and corrosives. Hazardous Decomposition Products None during normal operating conditions. If cells are opened, hydrogen fluoride and carbon monoxide may be released. Conditions To Avoid Avoid exposure to heat and open flame. Do not puncture, crush or incinerate. 11. Toxicological Information This product does not elicit toxicological properties during routine handling and use. MSDS Page 9 of 13 Printed

12 Sensitization Teratogenicity Reproductive toxicity Acute toxicity NO NO NO NO If the cells are opened through misuse or damage, discard immediately. Internal components of cell are irritants and sensitizers. 12. Ecological Information Some materials within the cell are bio-accumulative. Under normal conditions, these materials are contained and pose no risk to persons or the surrounding environment. 13. Disposal Considerations California regulated debris RCRA Waste Code : Non-regulated MSDS Page 10 of 13 Printed

13 Dispose of according to all federal, state, and local regulations. 14. Transport Information Lithium batteries are classified in Class 9 Miscellaneous dangerous goods as: UN 3480, Lithium ion batteries UN 3481, Lithium ion batteries contained in equipment; or UN 3481, Lithium ion batteries packed with equipment. With regard to transport of the product, the following regulations are cited and considered: - The International Civil Aviation Organization (ICAO) Technical Instructions, - The International Air Transport Association (IATA) Dangerous Goods Regulations - The International Maritime Dangerous Goods (IMDG) Code, - US Hazardous Materials Regulations 49 CFR(Code of Federal Regulations) Sections Lithium batteries and cells, - The UN Recommendations on the Transport of Dangerous Goods, MSDS Page 11 of 13 Printed

14 Manual of Tests and Criteria 38.3 Lithium batteries, If those lithium-ion batteries are packed with or contained in an equipment, then it is the responsibility of the shipper to ensure that the consignment are packed in compliance to the 58 th edition of 2017 IATA Dangerous Goods Regulations SectionⅡ of either Packing Instruction 966 or 967 in order for that consignment to be declared as NOT RESTRICTED (non-hazardous/non- Dangerous). If those lithium-ion batteries are packed with or contained in an equipment, UN No. is UN3481 Each cell or battery is of the type proven to meet the requirements of each test in the UN Manual of Tests and Criteria, Part III, subsection Regulatory Information OSHA hazard communication standard (29 CFR ) Hazardous Non-hazardous MSDS Page 12 of 13 Printed

15 16. Model list of application Refer to Table 1. MSDS Page 13 of 13 Printed