Aviation Alternate Fuels Roadmap Level 1 / Scenario 1

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1 Aviation Alternate Fuels Roadmap Level 1 / Scenario 1 Category Market Drivers Environmental, Political, Resources Anticipated Fuel Price Availability (% Demand Filled) Concerns about Global Warming dictates addressing worldwide carbon dioxide emissions Security of crude oil questioned World crude oil production reaches its peak 2006 base price/gallon with continued volatility Alternative Fuel Products (Volume Anticipated / Required) SASOL Jet Fuel Shell Bintulu GTL Qatar GTL Syntroleum Jet fuel in B 52 Nigeria GTL Boeing/Airline HRJ s Qatar GTL Production US CTL Production US CTL Biomass Co fired US Coal CTL Bio jet fuel approved China Coal GTL Bio butanol for ground use Cellulose ethanol for ground use Resurgence in Nuclear Power Industrial Solar Energy Start of Hydrogen Economy Ocean Bio fuel Factories Future Energy Source * Fuels produced from seeds and other organic sources such as Soybean Methyl Ester 2007

2 Aviation Alternate Fuels Roadmap Level 2 / Scenario 1 Long Term Category Alternative Fuel Products Economics & Business Certification Environmental R&D SASOL Jet Fuel Shell Bintulu GTL ASTM Spec for SASOL SSJF Tar Sands Online Qatar GTL Syntroleum Jet Fuel in B 52 CTL Economics Scully Financial B 52 emissions Boeing/Virgin g Test Qatar GTL Production US Coal CTL Bio jet fuel China Coal approved GTL Bio butanol for ground use ACRP Handbook work starts CRJ xx% ASTM Industrial Solar Energy Nigeria GTL US CTL US CTL Cellulose Resurgence in Production Biomass ethanol for Nuclear Power Initial Airline MOU Co fired ground use with Rentech and Altair DOE Step Gain in Ten alternative jet 50% USAF Syn fuel use USDA regional CO2 Sequestration ti fuel production study proposals Efficiency projects in place Carbon Neutral Growth Target submitted 200M Gals F/T Prod 600K gal HRJ ACRP 02 Two alternative jet procurement 18 Siting fuel production ASTM Spec by DoD Study projects in place SASOL FSJF ASTM Spec ASTM Spec ASTM D7566 Spec HRJ xx% Generic FT Generic FT Blend Blend Fuel App d GE/cruise ships burn biofuel in turbines B 52 syn fuel flight test Scoping study HBR TF MIL HNDBK 510 Bio fuel Emissions Test emissions Benefits 1st bio jet Lab tested Impacts Jet fuel spec revis Generic mat. Compat list Biofuel Boeing/Airline Tested HRJ s F/T swell lubricity issues solved USAF App l Generic FT Fuel Coal to New bio fuel liquids impacts Operational PSU coal derived JP 8 PRJ xx% ASTM App d FRJ xx% ASTM App d Start of Hydrogen Economy 70% USAF Domestic CTL Sourcing (2025) Carbon Neutral Growth Target Carbon Neutral Growth Target Adv bio fuel emissions Low emissions Bio fuel certified High energy deoxygenated Bio jet Bio jet bio jet fuel from algae tests done fuel Carbon Neutral Growth Target approved F T Fuel Carbon Sequester F T and biojet blend tests done Synthetic biology jet fuels developed Ocean Bio fuel Factories Advanced aviation fuel dev Advanced Aviation Fuel Spec Future Energy Source Future Aircraft for Advanced Fuel 12/22/2009

3 Level 3 Certification and Qualification DARPA Bio-JP8 Meeting ASTM Warsaw ASTM Tampa ASTM Norfolk Planning & Coordination ASTM Anaheim ASTM ASTM ASTM ASTM ASTM ASTM ASTM ASTM Annual Mtg ASTM Syn Fuel TF R&D CRC & CQ Annual Mtg R&D CRC & CQ Annual Mtg CRC & CQ Annual Mtg CRC & CQ Annual Mtg CRC & CQ Annual Mtg MIL- HNDBK-510 ASTM D4054 Balloted ASTM D4054 Approved Guidance & Procedures SAE Paper FAA Adv Circ Initial Draft IATA Rpt on Alt Fuels FAA Adv Circ FAA Review FAA Adv Circ Public Cmnt FAA Adv Circ Issued 05/09

4 Level 3 Certification and Qualification DRAFT FRL 6 Full Scale Technical Evaluation HRJ FRL 6.1 FFP Testing Fermented Renewable Jet (FRJ) Catalytic Renewable Jet (CRJ) Pyrolytic Renewable Jet (PRJ) FRLs 6.2 & 6.3 Turbine Hot Section & Component/Rig Testing CRJ FRJ PRJ FRL 6.4 Engine/APU Testing CRJ FRJ PRJ FRL 7 Fuel Class Listed in Specification 50/50 FT in JP8 MIL Spec ASTM D7566 App d By Av Fuel Subcom HRJ Research Rpt Generic FT Blend USAF Fleet Certification FRJ Research Rpt Sasol FSJF UK AFC App l Generic 50/50 FT Research Rpt Sasol FSJF ASTM App l ASTM D7566 App d By D.02 Com HRJ 50% Blend App d in DXXXX Generic 100% FT Fuel ASTM App d HRJ 100% Approved 05/09

5 Level 3 Research and Development (1 of 6) Feedstock Sept 5, Camelina Oilseed inventory study Oil Seed Plants Optimized Jatropha harvesting Optimized Large scale regional castor castor plot solution farms prototype study Masdar developed 9K gal of Halophyte salicornia oil Prod Study Halophytes Euphorbia analysis Salicornia analysis NRDC Study Halophyte Euphorbia prototype Seashore plots mallow analysis DOE Algae Roadmap Optimized Halophytes Cost of algae study Modified Halophyte prototype plots Algae Large scale Halophyte farms developed GMO Halophyte test plot 8M tons salicornia oil (2019) Cyanobacteria study Dewater study Oil extraction Algae Algae strain demo study plants Heavy metal removal study Light & GMO CO 2 Cyanobacteria level study study Results from DARPA project USDA algae funding report Cellulosic New algae Techs ready Cyanobacteria Large scale algae Cyanobacteria Scaled demo plants plant developed GMO developed algae GMO plants for sugar ORNL Billion Ton study BCIWG report Cellulose to biojet flight demo (via synthetic biology) Cellulosic Ethanol becomes cost competitive Cellulose to biojet demo plant (via pyrolysis) Large scale cellulose farms Cellulose/ sugar/ algae prototype demo Revise EISA to include biomass credit Other biofeedstock roadmap DOE s CBTL study done USDA feedstock roadmap USDA feedstock rankings & R&D plan *LCAs of biofuels are included in the Environmental team s roadmap Terra Preta test plot for CBTL DOE s CBTL & algae demos done USDA advanced biofuel summary 10/22/2009 = Done = In work = Not Funded 5

6 Level 3 Research and Development (2 of 6) Planning, Protocol, and Performance Category Biofeedstock Roadmap (10.1) AlphaBird Kick Off Meeting (10.3) Nat. Biofuels Action Plan Biomass Summit (10.20) DoE Algae Roadmap Meet g (10.5) (10.6) AFRL Active, Biomass Compr ve Workshop Feas. Study Integrated Roadmap (10.10) (10.11) (10.13) USDA Feedstock Rankings & R&D Plan (10.15) Workshop Workshop (10.16) (10.18) USDA Advanced Biofuel Summary (10.19) R&D Planning Activities Certification Protocol Development Sustainable Alt. Fuel Roadmap Workshop (DRAFT) (10.2) (10.4) R&D Workshop (10.7) Cert. Process Dev. D4054 (1.6) AF combustion Cert. Process "rules and tools" Dev pgm begins (1.1) (1.5) AFCO Biofuel DoE Algae Cert. Roadmap Roadmap (10.9) (Draft) (10.8) Swift Turbine Fuel Testing (7.2) USDA Feedstock Roadmap (10.12) Alt Av Gas Spec (1.8) Effort to Codify Contaminant levels for DXXXX (1.2) R&D Workshop (10.14) Cert. Process Dev (1.7) AF Rule & Tools Released (1.4) AFRL Biomass Feas. Study (7.4) R&D Workshop (10.17) AlphaBird Program Complete (10.21) See Also Certification Roadmap Performance Studies Rentech NG F T Syntroleum R 8 evaluation beg. HRJ evaluation (7.1) completed (7.3) Completed Funded Plans (Public/Private) Unfunded Needs Result Target Vision 10/22/2009 6

7 Level 3 Research and Development (3 of 6) Fuel Property Testing Category Swift Turbine Research Fuel Report 50% Formulation HRJ (5.8) Studies (5.10) Chemical Kinetics Mechanism Development for Combustion of F T Fuels (5.12) Fuel Thermal Stability Studies for new alternative fuels (5.18) Fuel Property Testing See Also Certification Roadmap Shell in situ Shale kero evaluation (5.1) Swift Turbine Fuel Materials compatibility (5.7) Fuel Thermal Stability Studies for 3 F T (5.9) Fuel Thermal Stability Studies for available Biofuels (5.14) FRJ (5.32) CRJ (5.33) PRJ (5.34) Basic Fuel Prop. (5.2) Spec. Prop. (5.4) Fit for Purpose Prop. (5.6) HRJ Fuel Award (5.25) HRJ Extended Prop. (5.11) Eval. of Mat Compat. Cand. 1 (5.13) Ground Fire Protect (5.15) Fuel Sys. Comp nts (5.16) Eval. of Mat. Compat. Cand. 2 (5.17) Survivability/ Vulnerability (5.19) Infrastructure (5.20) Eval. of Fuel Tox. Cand. 2 (5.23) Fuel Property Testing (Military) From AFRL/AFCO Combined Roadmap BioJet Certification Being Updated Gov t Fuel Buy 1 (5.3) Gov t Fuel Buy 2 (5.5) FFP Report HRJ 50/50 (5.30) HRJ Delivery #1 & #2 (5.26, 5.27) HRJ Delivery #3 (5.28) Eval. of Fuel HRJ FFP Report 100% Synth Tox. Cand. 1 Delivery #4 (5.31) (5.21) (5.29) HRJ SE&V (5.22) Completed Funded Plans (Public/Private) Unfunded Needs Result Target Vision 10/22/2009 7

8 Level 3 Research and Development (4 of 6) Component and Engine Testing Category Component & Engine Testing Biofuel Comb Rig Test (2.8) Biofuel APU & Eng Test (2.9) Testing of F T and Indiana F Biofuels 16 Study Concept 1 (2.11) (2.10) Testing of F T and Bio fuels Concept 2 (2.20) Testing of F T and Bio fuels Concept 3 (2.24) Evaluation of Biofuels Using NASA DC 8 (2.29) FRJ CRJ PRJ Component Rig (2.37) Component Rig (2.36) Component Rig (2.38) See Also Certification Roadmap F 15 F T Fuel Eng Test (2.2) F 22 F T Eng Test (2.4) Swift Fuel Eng Testing (2.11 and 2.12) F 18 Biofuel Engine HRJ Compn t (2.35) Tests (2.7) F404 Canada (2.32) Eval. of 2 F Swift T Fuels Fuel Eng Using NASA Testing DC 8 (2.15) (2.16) HRJ Small Engine Demo (2.17) Canada High Alt 100% F T/ 100% Ethanol (2.34) HRJ Cand. Fuel 1 A/B Eng. Test (2.23) Alt Av Gas pump test (2.42) All USAF Sys F T Certification( 2.25) Cand. Fuel 2 A/B Eng. Test (2.28) HRJ Cand. 2 APU Tests (2.26) P&W Canada Bio Blend (2.33) FRJ Eng/APU (2.39) CRJ PRJ Eng/APU Eng/APU (2.40) (2.41) Component & Engine Testing (Military) F T Fuel GSE/ESOH/ Infrastructure Certification (2.3) F 16 F T Eng Test (2.6) F 35 F T Eng Test (2.18) From AFRL/AFCO Combined Roadmap BioJet Certification Being Updated HRJ HRJ Cand. 1 Comngld. APU Test (FT/Bio) A/B (2.22) Eng. (2.19) Comngld. (FT/Bio) A/B APU (2.27) Completed Funded Plans (Public/Private) Unfunded Needs Result Target Vision 10/22/2009 8

9 Level 3 Research and Development (5 of 6) Testing Category Airbus 380 GTL flight (4.4) 747 ANZ 50% 737 Qatar GTL HRJ Jathropa (4.15) CAL 50% (4.36) HRJ (4.16) Airbus 50% Synth. Fuel Test (4.37) Testing 747 VAA 20% FAME (4.3) Alt Av Gas (4.39) 747 JAL 50% HRJ Camelina (4.17) F 15 F T Fuel (4.6) B 1 F T Fuel (4.5) C 17 F T Fuel (4.7) KC 135 F T Cert. Complete (4.13) T 38 F T Fuel (4.12) A 10 F T (4.18) B 2 F T Fuel (4.21) T 6 F T (4.22) HH 60 F T (4.19) F 18 Biofuel (4.38) Eval. Of Pathfinder A/C Cand.1 (4.29) Eval. Of Pathfinder A/C Cand. 2 (4.31) Bio & FT Bio High Alt. s (4.33) Testing (Military) From AFRL/AFCO Combined Roadmap BioJet Certification Being Updated KC 135 F T Fuel (4.8) F 22 F T Fuel Test (4.9) CV 22 F RQ 4 C 5 and C 130 F T (4.35) T Fuel (4.23) (4.14) F 35 F T (4.24) Bio & FT Bio Fighter s (4.32) Bio & FT Bio Fighter FSE (4.34) Completed Funded Plans (Public/Private) Unfunded Needs Result Target Vision 10/22/2009 9

10 Level 3 Research and Development (6 of 6) Production Studies and R&D Category Production Studies Production R&D Other DOE CBTL Study (9.5) DOE CBTL R&D Awards (8.10) Naphthenic dropin HRJ PoC (8.1) DARPA Algal Biofuel Kick Off (9.1) NRDC Algae Study (9.10) Study Req. DARPA Algal UPM BTL Biomass & Biofuel Phase Plant Final Prod. Quantities I Complete Tech s (9.7) (9.4) (9.2) Alt Av Gas Prod (9.9) BioOil Alt. Biomass Processes Cellulosic Study Pyrolysis (9.6) Bio Aromatic Blend Process DARPA Algal Alt. Biomass DARPA Algal Stock (8.18) Demo(8.19) Biofuel Phase I Processes Biofuel Kick Off Naphthenic Complete (8.6) Cellulosic (8.2) drop in HRJ ( ) Pilot demo (8.4) Basic Eng Package for Commercial HRJ Plant (8.3) F T Reactor Baseline Studies (8.5) CRC Aviation fuels MIT/RAND meeting (6.4) Alt Jet Feas LCA Conference (6.12) (6.11) (6.2) UNEP Biofuel Assessment Masdar Halophyte Prod Study (9.8) F T Reactor Studies and Catalyst Development (8.7) DoE Cellulosic Ethanol Demo (8.16) DARPA Algal Biofuel Phase II Complete (9.3) DARPA Algal Biofuel Phase II Complete (8.9) Aromatics for Green Jet from Naphthenic drop in HRJ ligno cellulosic pyrolysis oil pilot subscale (8.8) with wood, corn stover (8.15) Commission and Startup of Renewable Oil Aromatic fraction for Green Jet Renewable Oil Refinery (6.7) from lignocellulosic pyrolysis Construction of oil commercial (6.8) Refinery (6.6) CRC Aviation Fuels Meet g (6.1) Completed Design for OMEGA Aviation renewable Oil (6.3) Refinery (6.5) FRL Paper to ICAO (6.10) See Also Business Roadmap See Also Environment Roadmap Completed Funded Plans (Public/Private) Unfunded Needs Result Target Vision 01/10/10 10

11 Level 3 Environment(1 of 2) Planned Desired Category Industry SASOL Rig Test NASA/ NASA- Industry Industry FT Blend Biojet Rig Rig Tests Test Engine Test Fuel 2 Engine Test Fuel 3 Engine Test Fuel 4 Quantify LTO emissions C130 Test B-52 Test AF Engine Test 2 FT Engine FAA Parametric Studies Altitude Test - if warranted Quantify Altitude emissions Impact analyses Equip test Impact analyses Fuel 2 Impact analyses Fuel 3 Impact analyses Fuel 4 Quantify infrastructure impacts Characterize military GHE with FT fuels Assessment of benefits of single fuel Equip test Fuel 2 Equip test Fuel 3 Equip test Fuel 4 Fuels 2, 3, 4 etc. could be CTL, GTL, BTL via FT, other bio, etc. as defined by what fuel producers are likely to drive to 10/24/08

12 Level 3 Environment(2 of 2) Planned Desired Category If warranted heavy metal impact e Test Fuel 2 Test Fuel 3 Test Fuel 4 Toxicology impacts Net environ. impacts AF Tests Heavy metal content In-depth In-depth Fuel 2 In-depth Fuel 3 In-depth Fuel 4 SASOL Operational plant data Review Other US and internationa l data FAA Scoping Study Air Canada H2 fuel cell GSE Chinese Operational plant data US Operational plant data Compare GHG prdxn FAA Operational Operational Operational Operational Scoping Assessment Assessment Assessment Assessment Study Fuel 2 Fuel 3 Fuel 4 Fuels 2, 3, 4 etc. could be CTL, GTL, BTL via FT, other bio, etc. as defined by what fuel producers are likely to drive to 10/24/08

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