Worksheet 1 - General Information Address: 113 Hillside Ave Unit 3 Londonderry, NH Primary Business: metal coating - job shop Tech Contact: Rojana LaPlume Phone number and/or email address: 421-0916 PROCESS OPERATION INFORMATION Material Usage Basis Actual Actual or Potential Reporting Year (if actual used) 2009 Coating Usage- ALL COATINGS 671 gal/yr Days per week of normal operation 4 days/week Hours per day of normal operation 2.0 hr/day Weeks per year of normal operation 50 wk/yr Days per year of normal operation 200 days/yr Spray gun transfer efficiency 1 60% percent Overspray 40% percent Spray booth filter particulate capture efficiency 2 98.2% percent Particulate emissions 1.8% percent 1 Spray gun transfer efficiency is the amount of paint that will remain on the part during painting 2 Spray booth filter particulate capture efficiency (from the filter vendor); must meet Env-A 1403.03(b) for control device exemption Permit application 08-0042 - the facility indicated the booths are used 2hr/day and 200 days per year; Average removal efficiency information from filter vendor received 11/19/2010
Worksheet 2 - Usage Data No. Product ID Gallon /2009 Description C1 Xylene 1548684 1 C2 Acetone 1548775 1 C3 D61W24 Spray fil white 5 C4 R7K44 Catalyst Reducer 40 C5 V66V27 Polane Catalyst 16 C6 Lacquer thinner 119 1544709 10 C7 F63VXA15065-5267 Polane T Plus PMS425C 5 C8 V66V44 Polane Plus Catalyst 2 C9 P60G2 Wash Primer 15 C10 F63T1 Polane Flat Base 1 C11 T63TXL4440-5267 Polane T F/S35190 6 C12 F63TXA4038-5267 Polane T PMS432C 5 C13 D61A23 Polane Spray fil Light Gray 10 C14 F63B12 Polane T Carbide Black 5 C15 X1221 33446B Tan Urachem 5 C16 X4858 Data Tech Gray Urachem 5 C17 F63TXW16376-5267 Horizon White 5 C18 F63VSX10494-5267 Dark blue metallic 1 C19 F63TXL13605-5267 Blue 5 C20 W7816 Flat black Urachem-T 6 C21 X1914 Data chem Blue Urachem 25 C22 W283 Solvent blend #3 380 C23 W4041 Maroon Urachem 5 C24 F63TXA16563-5267 PMS 401C 5 C25 MEK MEK 42 C26 S414 27875A White Urachem 60 C27 F63TAX15712-5267 PMS 425C 5 Usage amounts taken from 2009 emissions report for facility when located in Londonderry APP: 3301590963 APP: 10-0133
Worksheet 3 - Chemical Data Choose one Choose one R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 Density Weight Percent VOC Ethyl benzene Xylene Acetone Toluene No. Product ID Description [lb/gal] [%W] 100-41-4 1330-20-7 67-64-1 108-88-3 108-94-1 123-86-4 67-63-0 78-93-3 584-84-9 112-07-2 67-56-1 108-21-4 110-43-0 C1 Xylene 1548684 7.17 100.0% 15.0% 85.0% C2 Acetone 1548775 6.59 100% C3 D61W24 Spray fil white 14.11 30.2% 0.20% 2.0% 3.0% 7.0% 18.0% C4 R7K44 Catalyst Reducer 6.76 94% 50.0% 44.0% C5 V66V27 Polane Catalyst 9.57 40.0% 0.30% C6 Lacquer thinner 119 1544709 6.64 79% 0.80% 5.0% 21% 33.0% 10.0% 1.0% 4.0% C7 F63VXA15065-5267 Polane T Plus PMS425C 13.87 19% 0.30% 2.0% 1.0% 5.0% 7.0% 2.0% C8 V66V44 Polane Plus Catalyst 9.32 28.0% 0.80% 28.0% C9 P60G2 Wash Primer 7.46 75.0% 0.30% 2.0% 2.0% 28.0% C10 F63T1 Polane Flat Base 10.51 51.2% 0.50% 3.0% 4.0% 6.0% 37.0% 1.0% C11 T63TXL4440-5267 Polane T F/S35190 9.71 55.5% 0.40% 2.0% 3.0% 27.0% 17.0% 5.0% C12 F63TXA4038-5267 Polane T PMS432C 8.91 18.2% 0.40% 2.0% 3.0% 33.0% 16.0% 8.0% C13 D61A23 Polane Spray fil Light Gray 13.86 30.7% 0.20% 2.0% 3.0% 7.0% 18.0% C14 F63B12 Polane T Carbide Black 8.51 63.4% 0.60% 4.0% 8.0% 21.0% 23.0% 7.0% C15 X1221 33446B Tan Urachem 11.89 31.0% 2.21% 17.1% 2.4% 0.020% C16 X4858 Data Tech Gray Urachem 11.22 36.85% 2.60% 19.39% 2.7% 0.020% C17 F63TXW16376-5267 Horizon White 11.69 41.2% 0.20% 2.0% 4.0% 20.0% 11.0% 4.0% C18 F63VSX10494-5267 Dark blue metallic 10.58 28.1% 0.10% 3.0% 2.0% 8.0% 6.0% 3.0% C19 F63TXL13605-5267 Blue 9.26 60.3% 0.40% 2.0% 3.0% 30.0% 16.0% 6.0% C20 W7816 Flat black Urachem-T 9.5 52.29% 0.57% 6.08% 10.8% 6.6% 5.1% C21 X1914 Data chem Blue Urachem 9.53 49.25% 2.77% 32.99% 2.5% 0.020% C22 W283 Solvent blend #3 7.28 100.0% 16.48% 64.0% C23 W4041 Maroon Urachem 9.36 51.0% 2.71% 33.18% 2.9% 0.030% C24 F63TXA16563-5267 PMS 401C 10.82 47.3% 0.30% 2.0% 4.0% 23.0% 13.0% 5.0% C25 MEK MEK 6.74 100.0% 100.0% C26 S414 27875A White Urachem 11.73 34.17% 2.52% 17.88% 2.3% 0.020% C27 F63TAX15712-5267 PMS 425C 9.5 59.4% 0.40% 3.00% 3.0% 29.0% 18.0% 5.0% %W-VOCs calculated using % content of volatile constituents Weight % VOC information from MSDS provided with application 08-0042 HAP Cyclohexano ne n-butyl Isopropanol Methyl ethyl (MEK) Toluene-2,4- diisocyanate 2- Butoxyethyl Methanol Isopropyl Methyl amyl
Worksheet 3 - Chemical Data Facility Name: R14 R15 R16 R17 R18 R19 R20 R21 R22 R23 R24 R25 R26 R27 R28 R29 R30 No. Product ID C1 Xylene C2 Acetone C3 D61W24 C4 R7K44 C5 V66V27 C6 Lacquer thinner 119 C7 F63VXA15065-5267 C8 V66V44 C9 P60G2 C10 F63T1 C11 T63TXL4440-5267 C12 F63TXA4038-5267 C13 D61A23 C14 F63B12 C15 X1221 C16 X4858 C17 F63TXW16376-5267 C18 F63VSX10494-5267 C19 F63TXL13605-5267 C20 W7816 C21 X1914 C22 W283 C23 W4041 C24 F63TXA16563-5267 C25 MEK C26 S414 C27 F63TAX15712-5267 %W-VOCs calculated using Weight % VOC information HAP Phosphoric acid Silica, Crystalline-aquartz - respirable fraction 2,6-Toluene diisocyanate (as TDI) Methyl isobutyl (MIBK) Isobutyl alcohol Titanium dioxide Talc (containing Methylpyrroli Stoddard asbestos fibers) done solvent Isobutyl 2- butoxyethano l DBE PM Acetate mineral spirits mineral spirits Chromium, insoluble (CrVI compounds) 7664-38-2 14808-60-7 91-08-7 108-10-1 78-83-1 13463-67-7 14807-96-6 872-50-4 8052-41-3 110-19-0 111-76-2 119-40-0 108-65-6 64742-89-8 64742-88-7 7440-47-3 1314-13-2 3.0% 40% 25% 0.20% 2% 0.20% 35.0% 9.0% 0.70% 4.0% 0.10% 4.0% 10.0% 2.50% 0.13% 1.7% 5.0% 2.82% 0.18% 1.63% 1.9% 5.7% 1.00% 4.0% 1.0% 1.0% 0.80% 0.18% 0.12% 4.33% 0.06% 17.5% 2.64% 0.090% 0.090% 1.11% 1.7% 5.3% 14.59% 5.0% 3.06% 0.84% 0.13% 0.01% 2.0% 6.2% 2.45% 0.21% 2.17% 1.6% 4.9% 1.0% THESE ARE NOT RTAPs Zinc oxide not reported in emissions report
Worksheet 4 - VOC Emissions Reporting year: 2009 Material Usage basis: Actual Total TPY 2.1 26.4. VOC Use Potential No. Product ID Description [lb/gal] [gal/yr] [lb/yr] [lb/yr] C1 Xylene 1548684 7.17 1.0 7.17 89.5 C2 Acetone 1548775 1.0 C3 D61W24 Spray fil white 4.26 5.0 21.3 266 C4 R7K44 Catalyst Reducer 6.35 40 254 3,172 C5 V66V27 Polane Catalyst 3.83 16 61.2 764 C6 Lacquer thinner 119 1544709 5.23 10 52.3 653 C7 F63VXA15065-5267 Polane T Plus PMS425C 2.68 5.0 13.4 167 C8 V66V44 Polane Plus Catalyst 2.61 2.0 5.22 65.1 C9 P60G2 Wash Primer 5.60 15 83.9 1047 C10 F63T1 Polane Flat Base 5.38 1.0 5.38 67.2 C11 T63TXL4440-5267 Polane T F/S35190 5.39 6.0 32.3 404 C12 F63TXA4038-5267 Polane T PMS432C 1.62 5.0 8.11 101.2 C13 D61A23 Polane Spray fil Light Gray 4.26 10 42.6 531 C14 F63B12 Polane T Carbide Black 5.40 5.0 27.0 337 C15 X1221 33446B Tan Urachem 3.69 5.0 18.4 230 C16 X4858 Data Tech Gray Urachem 4.13 5.0 20.7 258 C17 F63TXW16376-5267 Horizon White 4.82 5.0 24.1 301 C18 F63VSX10494-5267 Dark blue metallic 2.97 1.0 2.97 37.1 C19 F63TXL13605-5267 Blue 5.58 5.0 27.9 348 C20 W7816 Flat black Urachem-T 4.97 6.0 29.8 372 C21 X1914 Data chem Blue Urachem 4.69 25 117 1,464 C22 W283 Solvent blend #3 7.28 380 2766 34,525 C23 W4041 Maroon Urachem 4.77 5.0 23.9 298 C24 F63TXA16563-5267 PMS 401C 5.12 5.0 25.6 319 C25 MEK MEK 6.74 42 283 3,533 C26 S414 27875A White Urachem 4.01 60 240 3,001 C27 F63TAX15712-5267 PMS 425C 5.64 5.0 28.2 352 Total potential VOC emissions are greater than the VOC RACT threshold [Env-A 1204.15] HAPs lb/2009 Potential tpy Ethyl benzene 100-41-4 32.7 0.204 Xylene 1330-20-7 726 4.53 Toluene 108-88-3 1815 11.3 Toluene-2,4-diisocyanate 584-84-9 0.0548 0.000342 Methanol 67-56-1 2.66 0.0166 Methyl isobutyl (MIBK) 108-10-1 67.7 0.422 Chromium, insoluble (CrVI compounds) 7440-47-3 0.00627 0.0000391 Glycol ethers 0-00-0 0.664 0.00414 Potential hours of operation are based on: Hours of operation in 2009* = 400 Potential hours of operation/yr = 4,992 Ratio of actual : potential = 0.0801 16 hours of spraying operation per day 6 days per week 52 weeks per year tpy HAP 1.32 16.5 * - facility was in operation in Londonderry during this period. Potential emissions are calculated assuming the same coatings in the same ratios would be used at the new facility
Worksheet 5 - RTAP Emissions Reporting Year 2009 R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 Material Usage Basis: Actual Ethyl benzene Xylene Acetone Toluene Cyclohexanon e No. Product ID Description 100-41-4 1330-20-7 67-64-1 108-88-3 108-94-1 123-86-4 67-63-0 78-93-3 584-84-9 112-07-2 67-56-1 108-21-4 110-43-0 Percent Emitted --> 100% 100% 100% 100% 100% 100% 100% 100% 9% 100% 100% 100% 100% C1 Xylene 1548684 1.076 6.095 C2 Acetone 1548775 6.590 C3 D61W24 Spray fil white 0.1411 1.411 2.117 4.939 12.70 C4 R7K44 Catalyst Reducer 135.2 119.0 C5 V66V27 Polane Catalyst 0.04134 C6 Lacquer thinner 119 1544709 0.5312 3.320 13.94 21.91 6.640 0.6640 2.656 C7 F63VXA15065-5267 Polane T Plus PMS425C 0.2081 1.387 0.6935 3.47 4.855 1.387 C8 V66V44 Polane Plus Catalyst 0.01342 5.219 C9 P60G2 Wash Primer 0.3357 2.238 2.238 31.33 C10 F63T1 Polane Flat Base 0.05255 0.3153 0.4204 0.6306 4 0.1051 C11 T63TXL4440-5267 Polane T F/S35190 0.2330 1.165 1.748 15.73 9.9042 2.913 C12 F63TXA4038-5267 Polane T PMS432C 0.1782 0.8910 1.337 14.70 7.128 3.564 C13 D61A23 Polane Spray fil Light Gray 0.2772 2.772 4.158 9.702 24.95 C14 F63B12 Polane T Carbide Black 0.2553 1.702 3.404 8.936 9.787 2.979 C15 X1221 33446B Tan Urachem 1.314 10.17 1.403 0.01189 C16 X4858 Data Tech Gray Urachem 1.459 10.88 1.492 0.01122 C17 F63TXW16376-5267 Horizon White 0.1169 1.169 2.338 11.69 6.430 2.338 C18 F63VSX10494-5267 Dark blue metallic 0.01058 0.3174 0.21160 0.8464 0.6348 0.3174 C19 F63TXL13605-5267 Blue 0.1852 0.9260 1.389 13.89 7.408 2.778 C20 W7816 Flat black Urachem-T 0.3249 3.466 6.1788 3.739 2.907 C21 X1914 Data chem Blue Urachem 6.600 78.60 5.932 0.04765 C22 W283 Solvent blend #3 455.9 1770 C23 W4041 Maroon Urachem 1.268 15.53 1.348 0.01404 C24 F63TXA16563-5267 PMS 401C 0.1623 1.082 2.164 12.44 7.033 2.705 C25 MEK MEK 283.1 C26 S414 27875A White Urachem 17.74 125.8 16.26 0.1408 C27 F63TAX15712-5267 PMS 425C 0.1900 1.425 1.425 13.78 8.550 2.375 HAP n-butyl Isopropanol Methyl ethyl (MEK) Toluene-2,4- diisocyanate 2- Butoxyethyl Units: lb RTAP / yr Total Emitted: 32.65 726.3 20.53 1815 140.0 102.09 173.2 425.6 0.05476 0.6640 2.656 5.489 10.06 Methanol Isopropyl Methyl amyl
Worksheet 5 - RTAP Emissions Facility Name: Reporting Year R14 R15 R16 R17 R18 R19 R20 R21 R22 R23 R24 R29 R30 No. Material Usage Basis: Product ID C1 Xylene C2 Acetone C3 D61W24 C4 R7K44 C5 V66V27 C6 Lacquer thinner 119 C7 F63VXA15065-5267 C8 V66V44 C9 P60G2 C10 F63T1 C11 T63TXL4440-5267 C12 F63TXA4038-5267 C13 D61A23 C14 F63B12 C15 X1221 C16 X4858 C17 F63TXW16376-5267 C18 F63VSX10494-5267 C19 F63TXL13605-5267 C20 W7816 C21 X1914 C22 W283 C23 W4041 C24 F63TXA16563-5267 C25 MEK C26 S414 C27 F63TAX15712-5267 Phosphoric acid Silica, Crystalline-aquartz - respirable fraction 2,6-Toluene diisocyanate (as TDI) Methyl isobutyl (MIBK) Isobutyl alcohol Titanium dioxide Talc (containing Methylpyrroli Stoddard asbestos fibers) done solvent Isobutyl Chromium, 2- insoluble butoxyethano (CrVI l compounds) Zinc oxide 7664-38-2 14808-60-7 91-08-7 108-10-1 78-83-1 13463-67-7 14807-96-6 872-50-4 8052-41-3 110-19-0 111-76-2 7440-47-3 1314-13-2 1% 1% 9% 100% 100% 1% 1% 100% 100% 100% 100% 1% 1% 0.05808192 0.0011096 0.0033552 39.17 10.07 0.00627 0.03581 0.0003564 0.01426 0.03564 1.486 0.07729 1.582 0.1010 0.9144 0.1058 0.4560 0.1026 0.06840 2.47 0.034 6.290 0.214 0.2144 2.64 403.6 1.432 0.39312 0.06084 0.00468 17.24 1.478 15.27 Units: lb RTAP / yr 0.05808 0.001466 0.003355 67.65 10.68 0.0143 0.0356 0.1026 2.106 424.9 0.03420 0.006266 0.03581 HAP
Worksheet 6 - Stack Information STACK INFORMATION Parameter Stack 1 Stack 2 Stack 3 Stack 4 Height Above Ground (ft) 34 34 Inside Diameter (ft) 3.0 2.0 Orientation (Vertical / Horizontal) Vertical Vertical Obstructed (Cap? Yes or No) NO NO Distance to nearest property boundry <40 feet <40 feet Air Flow (acfm) 5,000 5,000 Exhaust Temperature ( F) Stack Flow (m 3 /sec) 2.36 2.36 0.00 0.00 Total stack flow 4.72 m 3 /sec What process or processes are associated with the stack? Stack 1 Stack 2 Stack 3 Stack 4 Distance to property boundry was determined based on GoogleEarth maps
Worksheet 7 - De minimis Method days/yr: 200 Basis: Actual RTAP Emissions 24-hour De minimis Is 24-hour De minimis RTAP Emissions Annual De minimis Is Annual De minimis RTAP CAS # [lb/day] [lb/day] exceeeded? [lb/yr] [lb/yr] exceeeded? R1 Ethyl benzene 100-41-4 0.16 12 Pass 33 4,336 Pass R2 Xylene 1330-20-7 3.6 18 Pass 726 1,628 Pass R3 Acetone 67-64-1 0.10 50 Pass 21 18,400 Pass R4 Toluene 108-88-3 9.1 59 Pass 1,815 21,682 Pass R5 Cyclohexanone 108-94-1 0.70 4.8 Pass 140 1,752 Pass R6 n-butyl 123-86-4 0.51 43 Pass 102 15,555 Pass R7 Isopropanol 67-63-0 0.87 21 Pass 173 7,619 Pass R8 Methyl ethyl (MEK) 78-93-3 2.1 59 Pass 426 21,682 Pass R9 Toluene-2,4-diisocyanate 584-84-9 0.00027 0.0015 Pass 0.055 0.56 Pass R10 2-Butoxyethyl 112-07-2 0.0033 7.8 Pass 0.66 2,858 Pass R11 Methanol 67-56-1 0.013 16 Pass 2.7 5,715 Pass R12 Isopropyl 108-21-4 0.027 103 Pass 5.5 37762 Pass R13 Methyl amyl 110-43-0 0.050 58 Pass 10 21,049 Pass R14 Phosphoric acid 7664-38-2 0.00029 0.18 Pass 0.058 65 Pass R15 Silica, Crystalline-a-quartz - respirable fraction 14808-60-7 0.0000073 0.0011 Pass 0.0015 0.39 Pass R16 2,6-Toluene diisocyanate (as TDI) 91-08-7 0.000017 0.0015 Pass 0.0034 0.56 Pass R17 Methyl isobutyl (MIBK) 108-10-1 0.34 36 Pass 68 13,009 Pass R18 Isobutyl alcohol 78-83-1 0.053 9.1 Pass 11 3,317 Pass R19 Titanium dioxide 13463-67-7 0.000071 0.59 Pass 0.014 217 Pass R20 Talc (containing asbestos fibers) 14807-96-6 0.00018 0.0084 Pass 0.036 3.1 Pass R21 Methylpyrrolidone 872-50-4 0.00051 17 Pass 0.10 6,197 Pass R22 Stoddard solvent 8052-41-3 0.011 31 Pass 2.1 11,453 Pass R23 Isobutyl 110-19-0 2.1 176 Pass 425 64,414 Pass R24 2-butoxyethanol 111-76-2 0.00017 154 Pass 0.034 56,374 Pass R29 Chromium, insoluble (CrVI compounds) 7440-47-3 0.000031 0.00043 Pass 0.0063 0.16 Pass R30 Zinc oxide 1314-13-2 0.00018 0.59 Pass 0.036 217 Pass