Thermoelectric Network Meeting Engineering Challenges and the Thermoelectric Roadmap Market Applications and Future Activities

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Thermoelectric Network Meeting Engineering Challenges and the Thermoelectric Roadmap Market Applications and Future Activities Dr Cedric Rouaud, Chief Engineer, Engines Product Group

2 Content Key market applications Potential research activities

3 Key market applications focus on Internal Combustion Engines Seebeck effect Heat to Electrical Power for reduction of fuel consumption and CO2 emissions: Internal Combustion Engines: Passenger car Diesel, gasoline engines ~ 0.5-1 kw Heavy Duty Vehicles Diesel, natural engines ~ 2-5 kw Stationary engines Diesel, Natural gas > 5-100kW Combined Heat and Power - Diesel, Natural gas Industrial plants, furnaces Autonomous sensors Source: DEER, Fairbanks Peltier effect Electrical Power to Heat / Cold for thermal comfort, cooling of electronics Transport applications: cabin thermal comfort (steering wheel, seat), battery cooling/heating, power electronics cooling Buildings heating and cooling

4 Passenger car Electrification trend Legislative drivers will continue to demand ever lower CO2 emissions and with zero air quality impact

5

6 Advanced combustion engines & electrification of the powertrain are key to future of light duty vehicles

7 Passenger car Electrification trend Estimates of Market Penetration of Diesel/gasoline Engines: Passenger Cars & SUVs without chassis frames Europe & US Europe: PC & SUV (without frame) 100% 90% 80% 70% 60% 50% 40% 30% EV & others CNG Full Hybrid (Gasoline) Mild Hybrid (Gasoline) Gasoline (SI) Full Hybrid (Diesel) 20% Mild Hybrid (Diesel) 10% Diesel (CI) 0% 2015 2020 2025 2030 2035

8 Commercial Vehicles - Electrification trend Estimates of Market Penetration of Diesel/gasoline Engines: Heavy Commercial Vehicles (HCV) Europe & US

9 Possible integration of thermoelectric generator (TEG) on engines (Diesel, gasoline, Natural gas) Example: Application on 3 cylinder downsized gasoline engine wit or without EGR (HP or LP) Thermoelectric Generator can be installed after Exhaust After Treatment or as EGR cooler (HP or LP) and cooled by engine coolant and/or engine lubricating oil Objectives: Recover exhaust / EGR heat and convert it into electricity using thermoelectric effect (Seebeck materials) Recover exhaust/egr heat and transfer it to engine coolant and/or engine lubricating oil Improve engine coolant and/or engine oil warm-up Fuel Consumption benefit over NEDC: 3-5%, WLTC: 2-4% Example of different installations of TEG on EGR or exhaust line (including IEM): 5 possible integrations TEG 2 3 1 airf TEG 3WC/GPF TEG 5 TEG TEG 4 CAC

Marine Large Diesel engines Example of installation of TEG Installation TEG in chimney Source: Wartsila, example of heat exchanger for WHR (ORC here) Thermoelectric Network Meeting 10

11 Boundary conditions hot / cold for transport applications Exhaust gas temperature * EGR temperature Cold source temperature Passenger car gasoline engine Passenger car Diesel engine Heavy Duty Diesel vehicle Large Engine (Marine) - Diesel 300-800ºC 150-650ºC 300-450ºC 300-350ºC 400-900ºC 250-700ºC 350 650ºC N/A 40-100ºC (engine or Low temperature circuit coolant) 40-100ºC (engine or Low temperature circuit coolant) 40-100ºC (engine or Low temperature circuit coolant) < 45ºC (sea) * Temperature after after-treatment system

Hot/cold sources Gasoline & Diesel engines - NEDC Gasoline engine Coolant and exhaust gas temperature ( C) - Speed (km/h) 600 550 500 450 400 350 300 250 200 150 100 50 Speed Coolant temp. Exhaust gas temp. Exhaust gas mass flowrate 60 50 40 30 20 10 Exhaust gas mass flowrate (kg/h) 0 0 0 200 400 600 800 1000 1200 time (s) Coolant and exhaust gas temperature ( C) - Speed (km/h) 350 300 250 200 150 100 50 Speed Coolant temp. Exhaust gas temp. Exhaust gas mass flowrate Diesel engine 300 250 200 150 100 50 Exhaust gas mass flowrate (kg/h) 0 0 0 200 400 600 800 1000 1200 time (s) Thermoelectric Network Meeting 12

13 Content Key market applications Potential research activities

Thermoelectric generator challenges to reach 10% efficiency thermoelectric generator Several activities are still needed; simulations, specifications, tests, FMEA, risk & hazard analysis Thermoelectric components : Shape of thermoelectric elements/generator (annular or flat plate) Assembly process / High T brazing and differential expansion Insulation for reducing thermal losses between p and n joints (aerogel) Improvement merit coefficient ZT (now 0.4 to 0.8 objective 1.5-2) Interest of the segmentation for materials for optimising ZT / T Thermomechanical behaviour / reliability / durability Reduce the number of material layers between hot and cold sources in order to reduce thermal resistance Efficient heat transfer on exhaust line without increasing the pressure drop (usually: + 100 mbar on exhaust line => - 1 to -4 kw on the engine crankshaft) Electric production strategies (HW / SW) : electric auxiliaries / strategy / DC/DC MPP Tracker with high efficiency Cost / benefit ratio competitive with other Waste Heat Recovery Solutions Interface risks: control of «global efficiency» (holistic approach) Hot and cold BCs Heat transfer on gas side Heat transfer on water side Thermal Contact Resistance Insulation between n and p legs Material impurities Differential expansion Global efficiency > or = 10% (incl. DC/DC) BC: Boundary Condition Thermoelectric Network Meeting 14

Air fuel mix 4H2+2CO2 On/Off On/Off Temp Exhaust heat energy recovery can yield significant efficiency gains for the IC engine Variety of exhaust energy recovery approaches to improve engine efficiency 30-50% of energy is wasted in the exhaust Coolant, Friction, Radiation Turbo-compounding * Thermo-electric (Seebeck) Bottoming cycle (Rankine, Brayton) * Mechanical systems applied to long-haul trucks Electrical systems also offered by suppliers Potential simple solution with no moving parts Research to develop improved materials Commonly used for power generation Packaging and irregular thermal load issues require detailed systems development approach Exhaust heat Thermo-chemical * Ethanol reformation to increase calorific value Has been demonstrated at laboratory level Exhaust manifold Heat Air Fuel Control system Combustor Usable Engine Energy Novel engine cycles Compression and combustion/expansion processes separated Demonstrated at Ricardo for power generation Exhaust *Not presented here Source: Scania, Bowman Power, MTZ, RWE Innogy Thermoelectric Network Meeting 15

16 All WHR systems are costly relative to many application needs Solutions in bold are being studied actively for HDD/passenger cars < 2020 Turbo compounding (m) Turbo compounding (e) Rankine cycle / ORC Heat energy recovery Typical FE gain 5 % 3-5% Heavy duty Truck, Off Highway, Marine, Rail & Power Passenger car Applications Issues Transiency Cost Technology maturity Mechanical losses at low load 15% 3-10% Need for electrical power consumer or motor 20% 3-10% Condenser cooling, bulk and cost +++ - Commercialised in premium products +++ - - Commercially-ready systems available ++ - - Working prototypes developed Thermo electrics (Seebeck) 10% 3-5% Passenger cars Heavy duty diesel Fuel reforming 3-10% Combustion improvement any ICE AMTEC-Alkali Metal Thermal to Electric Converter Cost +++ - - Concept (Automotive) Comm d (Space) Reformate management, transients, Cost 20-30% 3-10% Passenger cars High temperature operations Material (Na, K), BASE Stirling engines 20% 3-12% Micro CHP Marine engines Split cycle engines 60% 36% Power generation Automotive Requires precise matching, Cost + - - - Concepts and prototypes ++ -- Concepts and prototypes ++ - - - Commercialized as standalone devices Complexity, risk, Cost ++ - - - Prototype (Power) Concept (Automotive) > 2020

The high level technology roadmap for Waste Heat Recovery Systems, using exhaust gas and/or any other fluids available on gasoline / diesel vehicles (coolant, oil, EGR, charge air) Europe: Technology Roadmap for Thermal Management gasoline/diesel Emissions kw/l Euro 4 (2005) Euro 5 (2009) Euro 6 (2014) Euro 7 (2020) 130g/km CO 2 95 g/km CO 2 target 75 85 100 Electric oil pump (transmission HEV) Exhaust Heat Recovery for engine/transmission/cabin warm-up Electric oil pump (transmission HEV) Turbocompounding (mechanical) on HDD 1 st market: HDD Turbocompounding (electrical) Waste Heat Recovery Systems 1 st market: Gensets, HDD (2017) 1 st market: passenger car Rankine cycle (mech/electrical) Thermoelectricity (Seebeck) Energy Recovery / Split Cycle Stirling engine Fuel reforming Heat to Cool (absorption, adsorption) AMTEC (Alkali Metal Thermal to Electric Conversion) TAG (ThermoAcoustic Generator) 2005 2010 2015 2020 2025 Source: Ricardo Analysis Thermoelectric Network Meeting 17

18 THANK YOU FOR YOUR ATTENTION ANY QUESTIONS? Ricardo UK Ltd Shoreham Technical Centre, Shoreham-by-Sea, West Sussex, BN43 5FG, UK Dr Cedric Rouaud Chief Engineer Engines Product Group Direct Dial: +44 (0)1273 794 095 Reception: +44 (0)1273 455 611 Mobile: +44 (0)7809 595 874 cedric.rouaud@ricardo.com www.ricardo.com