New England Farm Energy Conference March 15-16, 2010 Manchester, NH

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New England Farm Energy Conference March 15-16, 2010 Manchester, NH Doug Schaufler, P.E., Ph.D. Farm Operations & Services Penn State University Park, PA email

Services to the College of Agriculture Farms ~1,500 acres of cropland Hay, corn, soybeans, oats, wheat, cover crops Gaining experience with crops for biomass & biofuels Manure hauling & spreading Bussing for laboratory classes Operates agricultural arena Supports research, education and outreach

Biomass Switchgrass Sudan grass Miscanthus Biofuels Camelina Canola Flax Safflower Sunflower Biodiesel

Bio-based hydraulic oils Biodiesel blends and B100 Straight vegetable oil

Bioenergy opportunities End of cheap fossil fuels Wind, solar, other renewable energy opportunities Food vs. fuel World population growth New USDA programs Climate change Emerging carbon markets Energy supply disruptions?

Most farms are highly self-sufficient in food & energy. Farm energy is 100% renewable: biomass, wind, water, animals.

1900 Rudolph Diesel demonstrates his new engine at the World s Fair in Paris, running on peanut oil. 1908 Henry Ford unveils his Model T, designed to run on either gasoline or ethanol, the fuel of the future.

US opts for petroleum instead of plant-based fuels.

Jmp 2-2007 Glenn Cauffman - Farm Operations Joseph M. Perez Sr. - Chemical Engineering Department

occur often may contain regulated substances that cause pollution to soil, surface water, and ground water are always cleaned up at Penn State but are often not cleaned up elsewhere

Hydraulic systems lose fluids to the environment during normal use Biodegradable fluids are environmentally friendly Biodegradable fluids reduce costs of spill cleanups

Why use a more expensive bio-lubricant when petroleum lubricants provide satisfactory performance? Cost of inadvertent spill cleanups led to consideration of use of biolubricants Jmp 2-2007

Cost comparison Tractor Supply 5 gal UTF (Universal Tractor Fluid) $36.99 ($7.40/gal) John Deere Bio HyGard $127.50 ($25.50/gal) Settled on BioBlend Flo UTF $959.75/55 gal $17.45/gal

Vegetable-based renewable resource Supports agriculture Reduces dependence on foreign oil Compatible with petroleum-based hydraulic fluids Increased lubricity - lower operating temperatures

Started in fall of 2003 Involved 200+ pieces of farm equipment

Program started - summer 2003 Obtained information on available fluids from suppliers Reviewed OEM requirements Collaboration Cost factors Initial trial Fall 2003 Obtained Pennsylvania DEP approval for use Changeover of all equipment Summer 04 Periodic analysis 2005 Project 1 (Pa Soybean Board) Periodic analysis 2006 Project 2 (Pa Soybean Board) Jmp 2-2007

Equipment Case John Deere Caterpillar Massey Ferguson New Holland Fiat Kubota Brand Specification MS-1204, MS-1205, MS-1206, MS-1207, MS-1210 J20A, J20C, J14C, J21A TO-2 M1135, M1141, M1110, M1127, M1129-A M2C134-D, M2C41-B, M2C48-B, M2C53-A, M2C134-B, M2C134-C, M2C86-B Tuttella Muti F UDT Fluid

Property Test Method Cargill THF Petr. Oil ISO Grade --------- 46 46 Viscosity 40 C, csts ASTM D-445 48.44 46 100 C, csts ASTM D-445 9.887 6.8 @ -35 C, cp 25,000 Viscosity Index ASTM D-2270 196 98 Density, 15.6 C ASTM D-1298 0.9089 0.876 C.O.C Flash, C ( F) ASTM D-92 251 (483) 218 (424) Pour Point, C ( F) ASTM D-97-36 (-33) -30 (-22) Biodegradability, % CEC L 33-A-93 82 (15-30)

The following are areas of concern: Hydrophilic nature of biobased materials Corrosivity Greater solvency Microbial growth Stability over long term storage Material compatibility issues Bulk modulus elasticity Temperature range of materials

Metals Content Oxidation Stability Friction and Wear Particle Counts Viscosity Acid Number Water FTIR (Fourier transform infrared spectroscopy)

Petroleum Samples at Changeover PPM 180 160 140 120 100 80 60 40 20 0 Total - Red Copper - Yellow Lead - Green Iron - Blue 0 2000 4000 6000 8000 10000 Unit Hours PPM 180 160 140 120 100 80 60 40 20 0 Metals Analyses - 2006 Biodegradable Hydraulic Fluid Samples Total - Red Copper - Yellow Lead - Green Iron - Blue 0 2000 4000 6000 8000 10000 Jmp 2-2007 Unit Hours

Jmp 2-2007 Load

Four-ball Tests: Three used oil samples were run on the four-ball. The samples exhibit no change in wear or friction compared to the new oil. The wear values after three years were 0.36 mm respectively. The coefficient of friction for all samples was 0.090

2006 Penn State University began converting all hydraulic equipment to bio-hydraulic fluid including the elevators in buildings. This has been completed.

Absorbance 6.0 5.5 5.0 4.5 4.0 Cargil New O il Chevron HF New 3-3-06 Cargill biohydraulic fluid 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 4000 3000 2000 1000 W avenumbers (cm-1) Petroleum fluid Jmp 2-2007

Absorbance Infra-red Analysis (FTIR) 1.5 1.4 1.3 JD 6750 H arvester 2-6-06 -- /1184 Hydr Cargill Novus Sample (1yr) 2-10-06 1.2 1.1 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1-0.0 4000 3000 2000 1000 Wavenumbers (cm-1)

PPM Unit Test Data - Total Metals 350 300 250 200 150 100 50 0 Transmission Not BioTHF 0 2000 4000 6000 8000 UNIT Hours Fendt NH JD WS Jmp 2-2007

ppm 200 150 100 50 0 FIG. 3. JD UNITS Total Metals Fe Cu Pb 0 100 200 300 400 "OIL" Hours

mg KOH/g ; cst/10 8 7 6 5 4 3 2 1 0 Acid No. 40oC Visc/10 0 10 20 30 UNITS Jmp 2-2007

Cost of fluid too high Search for lower cost but OK fluid Selected a few via sales folks Tested for metals All exceeded PA Dept. of Environmental Protection limits Worked with supplier(s) changed additive package Re-tested and okayed

Testing 100% biodiesel and SVO in agricultural tractors

In collaboration with New Holland, four new tractors ran 3 years on B100 1 continues on B100, others have been returned to New Holland. 2 new tractors running SVO Exploring long term effects of high levels of biodiesel and SVO

Discover the pros and cons Disseminate information based on experience through Cooperative Extension and Outreach

In 2002 biodiesel discouraged by most equipment manufacturers Penn State College of Ag Sciences Farm Operations began using B20

Reduce greenhouse gas emissions Improve environmental air quality Reduce diesel smoke irritation for operators Renewable energy and carbon credits Support agricultural producers

Fuel Type BTU/US gallon Regular gasoline 125,000 Ethanol 84,600 Methanol 64,600 Gasohol (10% ethanol) 120,900 Diesel 138,700 Biodiesel 126,200 Vegetable oil 123,000 Liquified natural gas 90,800

Environmental Impacts of Biodiesel Large Reductions in: CO2 SOx Particulates Odor Slight Increase in: NOx

Engine crankcase oil analysis Observe power and performance Note tasks performed and operator observations Dismantle engines and measure internal effects

Penn State University converted diesel fuel station for all diesel fuel to B20 in 2006 Received the Governors Renewable Energy Leadership Award in 2006 New Holland endorses B100 in 2007

New Holland TC40 injectors after 2 years on B100

May require engine modifications Heated to change the viscosity Start engine on petro-diesel fuel Shut down on petro-diesel fuel

Vegetable oils have high viscosity which leads to injector coking and eventual engine failure. This is not biodiesel but straight vegetable oil (SVO) fuel

Case 621E Loader (146 net HP) New Holland T7060 (180 PTO HP)

Types of SVO systems Single tank Double tank Small lift with single tank setup

Fuel type (diesel or SVO) criteria Sensors Engine coolant temperature sensor Exhaust temperature sensor Logic Engine cold runs on petroleum diesel Engine warmed up Below 25% engine load runs on petroleum diesel Above 25% engine load runs on SVO

Engine startup and shutdown Start on petroleum diesel Run on SVO or diesel (depends on engine load) Shutdown 10 minutes running on petroleum diesel, then shutdown

SVO control inside the cab

Exhaust temperature sensor/relay

Compensation for reduced energy in SVO

Our challenges with the SVO systems NH T7060 SVO too hot from heat exchanger engine derating SVO filter clogging (?) Low temperatures mix with petroleum diesel Case 621E Engine coolant not reaching operating temperature SVO filter clogging (?) Low temperatures mix with petroleum diesel Power supply 12V vs. 24V Fuse location in control box

Types of oils (per Elsbett) Canola or rapeseed.. Ok Sunflower.. Ok if degummed Soybean.. Not ok in direct injection engines

Rapeseed oil quality standard - Germany

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Jan Feb SVO (gallons) 450 400 SVO Usage by Month Mar 2009 - Jan 2010 350 300 250 200 150 7060 621E 100 50 0

Overall SVO vs. Petro-diesel usage NH T7060 (966 hours) Case 621E (843 hours) % SVO used of total fuel use 81% 44% Total SVO used 1666 gallons 418 gallons Total diesel used 392 gallons 528 gallons

Summary Converted agricultural and other machinery to bio-based hydraulic oil Used B100 successfully in New Holland equipment Press and use canola oil in two pieces of equipment

QUESTIONS?