Analytical and Testing Instruments for the HPI Market Shimadzu s Total Solutions for the Hydrocarbon Processing Industry

Analytical and Testing Instruments for the HPI Market Shimadzu s Total Solutions for the Hydrocarbon Processing Industry

Shimadzu Customized GC Analyzers GC-2010 Plus Nexis GC-2030 GC-2014 Natural Gas Analyzers * Refinery Gas Analyzer (RGA) ** Green House Gas Analyzers TOGAS Analyzer TOGAS w/ BID Analyzer Application Methods ASTM D1945/D1946, GPA 2261, GPA 2177, GPA 2286, GPA 2186 UOP 539, ASTM D7833, D3588, D1945, D1946 ASTM D3612A,B & C*** ASTM D3612A,B & C*** Air/Nitrogen, Methane, CO2, Ethane, Propane, I-Butane, N-Butane, Neo-Pentane, I-Pentane, N-Pentane and Hexanes+ by backflush C1-C6+ saturates and unstarurates, H2S,Non- Condfensabvle gases, O2,N2,CO & H2, LPG sampling, Vaporizer N2O, CO2 and CH4 in atmospheric air. This system will also separate and provide quantitative information for N2, O2 and CO. *SF6 can be added per special request. The run time can be extended to include ethane, othylene and acetylene in the analysis. Accurate measurement of dissolved gases which include H2, O2, N2, CH4, CO, CO2, C2H6, C2H4, and C2H2 in mineral spirit based transformer oil via direct injection and oil stripper extraction O2, N2, CH4, CO are separated and detected by BID; CO2, C2H2, C2H4, C2H6 and C3H6 detected by FID. CO2 passes through a Methanizer and is reduced to CH4, which, is combustible and analyzed by FID. Turnkey systems Fully configured Customizable systems Automatic BTU reports Automatic Refinery Gas BTU report 6 minute fast analysis time Four simultaneous injections Includes 3 detectors and a methanizer Low-level analysis 15 minute fast analysis time Offer all three methods High sensitivity Extension up to C4 Choice of 2 headspace models TCD replaced by very sensitive BID Hydrogen & methane sensitivity down to 100ppb Turnkey system * Includes Extended Natural Gas Analyzers ** Includes Fast Refinery Gas Analyzer *** Shimadzu pioneered the B&C methods Shimadzu Headspace HS-20 LPG Sampling Devices, Vaporizers Complete application manual and methods Customized Analyzers

Various Applica ons in the Hydrocarbon Processing Industry GC-2014 Nexis GC-2030 GC-2010 Plus Simulated Distillation DHA/PONA Analyzers GPC Analyzer Aromatics Analyzers ASTM D2887, ASTM D3710, ASTM D5307, ASTM D6352, ASTM D6417, ASTM D7096, ASTM D7169, ASTM D7213, and ASTM D7500. Oxygenates in Gasoline Analyzer ASTM D6729, ASTM D6730 ASTM D6474, D6579, D5296 ASTM-D3606, ASTM-D5580 ASTM-D4815 C6 to C44 alkane Single-column application for the separation and identification of five main compound classes in spark ignition fuel samples: paraffins, olefins, naphthalenes, aromatics, and oxygenates. Molecular Weuight distribution of polymers which separates molecules by size. Using D3606, dedicated to the separation and quantification of benzene and toluene in finished gasoline. Benzene can be determined between the levels of 0.1 and 5 volume % and toluene can be determined between the levels of 2 and 20 volume %. Ethanol co-elution is managed by using a special proprietary column set. Individual ethers are determined from 0.1 to 20.0 as %. Individual alcohols are determined from 0.1 to 12.0 mass %. Support all official SimDist methods Simdist software fully integrated into LabSolutions Simple automated operation Distillation curve overlay Distillation reports and curve data can be easily exported as ASCII data to Excel Results correlated to D86 or D1160 Simple single-column method All recommended consumables included Room temperature method Complete DHA reports using Lab Solutions TM Stable detector Easy-to-use GPC software Customizeable report layout Fully integrated HPLC system 10 minute fast analysis time Complete turnkey systems Rugged configuration Economical Shimadzu BID Detector High Sensi vity Detection sensitivity over 100x higher than TCD, 2x higher than FID Novel Universal Detector Single-detector approach for your complex analyses Long-Term Stability Long-term stability with new discharge design Shimadzu Simdist System

ASTM D 6591, D6379, D5186, IP 391, IP 436, IP 548 Aromatics in fuels Switching Valve Configuration Aromatics Analyzer HPLC Super Performance and Expandability Precise Sample Injection ASTM D5837 Individual Furanic Components in Transformer Oil Fully Integrated System Furan HPLC Network Connectivity High Sensitivity Detector Additives in polymers High Speed and High Sensitivity LC / MS / MS Scan Speed 30000u / sec MRM 555 Ch / Sec EPA 8270B, TO-14 Volatile Organic Compounds Arsine Phosphine in Ethylene Accessories HS, TD and P&T VOC s with GCMS High Sensitivity and Reduced Cost High Efficient Multicomponent

Customized Trace Elements in Naphtha Easy Method Development ICPMS-2030 Lowest Running Cost High Stability, High Sensitivity and Low Interfernce Elemental ASTM D4951, D5184 ASTM D4951,D5184 UOP 389, UOP 303 UOP 714, APHA 3120, IFP 9507 All Elements Lubricating oils Petroleum Naphtha, Gasoline Low Argon Consumption Easy Method Development All Wavelength Acquisition ICP-9820 ASTM D6595, D3237, D3567 D3605, D3635, D3831, D3919 D4628 Additives in polymers All Elements Lubricating oil Petroleum oils Comprehensive Safety Functions Unique 3D Double Beam Optics Dual Background Correction Functions AA-7000 ASTM D5839, ASTM D4294, C114 ISO 8754 Sulfur in Oil All Elements High Sensitivity, High Speed and High Resolution EDX-7000 / 8000 Large Sample Chamber Easy-To-Use Operation

D7371, EN 14078 Fame in Biodiesel Total Petroleum Hydrocarbons Addi ves in Polymers Excellent and Reliability FTIR A New ASTM D1840, D2008 Petroleum Products Turbine Fuels Mineral Oils High Resolu on Broad range of Products Easy Opera on UV-Vis ASTM D3417, D3418, D4419, D4591, D5483, ASTM D3850, D6370, D6375, Thermal Proper es of Polymers DSC, TGA, TG/DTA, TMA Diverse Measurements by Simple Opera ons High Performance DSC / TGA High Sensi vity Thermal Analyzers ASTM D5412 Measuring Oil in Water High Stability and High Speed Spectroflurophotometer High Speed 3D Scanning Fluorescence Quantum Yield and Fluorescence Quantum Efficiency Measurement

ASTM D7573, EN 1484, EPA 415.1 APHA 5310B TOC 680 DegC Combus on Method TOC in Various Types of Water High Salt Content Water Standalone System High Salt Kit Online TOC Superior Sampling Units TOC in Various Types of Water O Low Low Maintenance Cost Cost ISO 6892, ISO 527, ASTM D638 Testing Machines Short Test Cycle Time Tensile Proper es of Metals Tensile Proper es of Plas cs Ultrafast Sampling Rate ASTM D6474, D6579, D5296 Eight Fold High Resolu on Stable Detec on Gel Permea on Chromatography Ease of Use GPC So ware Fully Integrated HPLC Gel Permea on Chromatography

Total Solutions for the Hydrocarbon Industry North American HQ Solution Center Integrated Technology Center Networking Center Classroom Training Shimadzu Corporation URL: www.shimadzu.com/an/ Shimadzu Scientific Instruments 7102 Riverwood Drive, Columbia, Maryland 21046, U.S.A. Phone: 800-477-1227/410-381-1227, Fax: 410-381-1222 URL: www.ssi.shimadzu.com Company names, product/service names and logos used in this publication are trademarks and trade names of Shimadzu Corporation and its affiliates, whether or not they are used with trademark symbol TM or R. Third-party trademarks and trade names may be used in this publication to refer to either the entities or their products/services. Shimadzu disclaims any proprietary interest in trademarks and trade names other than its own. For Research Use Only. Not for use in diagnostic procedures. The contents of this publication are provided to you as is without warranty of any kind, and are subject to change without notice. Shimadzu does not assume any responsibility or liability for any damage, whether direct or indirect, relating to the use of this publication.