- Supercritical Water Cracking Technology -

Transcription

1 JOGMEC Techno Forum 2014, November 26 th -27 th 2014 Upgrading of Heavy Crude Oil - Technology - Hisato Aoyama Manager, Technology Development Center JGC CORPORATION

2 Organization--Background The Super Critical Water Partial Upgrading technology has been developed by JGC Corporation of Japan, along with the financial, governmental and technical support of JOGMEC (Japan Oil, Gas and Metals National Corporation.) Laboratory testing and analysis have been completed and the technology is now moving into the actual demonstration phase set to commence in 2014.

3 JGC Business Areas Up & Mid Stream EPC ( Engineering / Procurement / Construction) Project Development & Investment LNG Refineries Power Generation IWPP CO 2 Solution Gas Processing Petrochemicals & Chemicals Environmental & Energy Conservation Urban Development Water Business Medical Facilities & Research Laboratories Industrial CSP Oil & Gas Development 3

4 Background Process Advantages Supply Chain Benefits 5BPD Pilot Plant in Canada Summary 4

5 Background Copyright 2014JGC all rights reserved

6 Oil: billion barrels Conventional Oil Unconventional Heavy Oil Tight Oil/Shale Oil Recoverable oil resources source: IEA Europe E.Europe/Eurasia North America Asia Africa 14 0 Middle East Latin America Copyright 2014JGC all rights reserved 6

7 Heavy Crude Oil Supply Schemes Upstream Midstream Downstream Diluted Scheme SAGD Diluted Bitumen (DilBit) Diluents CDU, VDU, Coker, HDS Liquid Products Cokes Sulfur Partial Upgrader Scheme SAGD (SCW) Partial Upgrader Sour SCO CDU, HDS Liquid Products Sulfur Full Upgrader Scheme Sweet SCO Liquid Products SAGD Full Upgrader Cokes Sulfur (Waste) CDU 7

8 Properties of Feedstock and Targets Refinery SCWC Feedstock Bitumen Product SCO Pipeline API o Feedstock Target 8.3 > 21 Viscosity@10 o C cst 1,000,000 < 350 Sulfur wt% Ni / V ppm 75 / TAN mg/g Olefins % < 0.5 <1.0 8

9 Results of Direct Observation Water Distillate VGO SCW forms layers in the asphaltene micelle Water, Residue Roles of Supercritical Water 1. Thermal Cracking of VR 2. Extracting Distillate and VGO 3. Inhibiting polymerization of asphaltene (coking) 9

10 Pressure What is Supercritical Water? Water at a temperature and pressure above its critical point Liquid (Water) SCW Solid (Ice) Critical pressure (=22.1MPa) Gas (Steam) Gas SC Fluid Liquid Density kg/m ~1, Viscosity mpa s Diffusion Coefficient m 2 /s ~ Thermal mw/mk Conductivity 5~30 20~150 50~200 Critical temperature SCW has physical properties between liquid and gas (=374 ) Temperature

11 Bench-Scale Test Unit

12 Phase 1 Pre-Test (Mar - Jul 2006) Preliminary Test Preliminary F/S R&D Work Plan Phase 2 Lab Phase Phase 2.1 (Jan - Dec 2007) Optimizing RX Conditions SCO Evaluation Reaction Modeling 2.2 (Sep Mar 2008) Test of other heavy oils Comparison with conventional technologies 2.3 (Apr - Dec 2008) Preliminary Process Design Economic Evaluation Secondary Conversion Test 2.4 (Jan 2010 Mar 2011) Higher Conversion Test Evaluation of Boiler & FDG Waste Water Treating Phase 3 Demonstration 3.1 Pilot Plant 5BPD@Canada (Nov Mar 2016) Reliability Test Scale factor Evaluation Semi-Commercial Design 3.2 Semi-Commercial 2000 BPD Semi-Commercial Plant Long Term Operation Commercial Design 12

13 Process Advantages

14 30,000 BPSD SCWC Scheme Diluent 14KBPD Bitumen 30KBPD (API 8 ) Bitumen Heater Product Cooler Reactor High Temp. Separator Sour Gas Treatment Low Pressure Separator DilBit 44 KBPD Water 30 KBPD Water Heater Pitch 9 KBPD Pitch Cooler Pitch Flash Drum SWS SCO 21KBPD (API 24 o ) SAGD System BFW WWT

15 Yield vol% Liquid Yield Comparison 100% 101% Distillate & Lighter VGO VR 80% (+ Coke 20 wt%) Feedstock Bitumen SCW Cracking Products Delayed Coker Products*1 *1 includes Coker products and straight run Distillate & Naphtha. 15

16 100m SCWC Plant Footprint 70m

17 No. of Equipment Process Complexity 600% 500% 400% 300% 200% 100% 0% Coker Visbreaker SCW (Base =100%)

18 Supply Chain Benefits Copyright 2014JGC all rights reserved 18

19 US$/ BBL-SCO 70 Supply Chain Cost (WTI:$80/bbl, Natural Gas: $4/MMBTU) Diluent Pipeline Upgrader Pitch Boiler CAPEX SAGD OPEX SAGD CAPEX Natural Gas 0 0 By-Product Sales -10 Diluted Bitumen (One Through) Sour SCO (SCWC) -10 Total (Net Cost) <Assumptions> Upgrader cost including utility, catalyst, maintenance cost and Depreciation (20yr straight-line). Diluents cost: $85/bbl (=WTI +$5/bbl) (30 vol % dilution blend ratio) Natural Gas Price: $4/MMBTU (Fuel duty of SAGD Boiler to be 1400MMBTU/hr ) Pipeline cost : $5/bbl (Fort McMurray ~Edmonton), $8/bbl (Edmonton~Houston) OPEX of SAGD: $8.8/bbl-Bitumen (excl. Boiler Fuel Cost), CAPEX of SAGD (sustaining) : $6.3/bbl-Bitumen 19

20 Yield Vol% US$/ BBL-SCO Supply Chain Cost Advantage to Diluted Bitumen (WTI:$80/bbl, Natural Gas: $4/MMBTU) SAGD Fuel (Natural Gas Residue) Sulfur(wt%) API Product v% No Diluents Pipeline Volume Saving (by 40%) Supply Cost $ 12/ bbl SCO Premium $ 8/ bbl Distillate VGO Naphtha Distillate VGO VR Upstream Pipeline Refinery 0 SCO Diluted Bitumen Copyright 2014JGC all rights reserved 20

21 5 BPD Pilot Plant in Canada

22 5 bpd SCWC Pilot 6.7m 8.3m 3.2m

23 5bpsd SCWC Pilot High Pressure Separator: Gas Bitumen Service Tank Electrical Heater Knock out Drum: SCO Water Tank Reactor Low Pressure Separator: Flash Drum: Water Electrical Heater Pitch Flash Drum: Receiver: SCO Pitch

24 Pilot Plant Site in Canmet Facility Existing Building (Pilot Plant Site) 24

25 Summary

26 SCW ~ Simple, Clean, minimal Waste ~ SCWC Delayed Coker Footprint (Excl. Tank Yard) 1 4 Solid Waste (By-product) Sulfur Sulfur Coke Energy Consumption (API 8 o 21 o )

27 Minimal Waste Summary SCWC is a partial upgrading technology aimed at minimizing onsite cokes and sulfur Simple Process SCWC is a simple process applicable for on-site (SAGD) production Supply Chain Advantages Supply cost improved by $20/bbl Energy consumption reduced by 30% Ready for Demonstration SCWC Pilot Plant is ready for demonstration Contact: Hisato Aoyama (aoyama.hisato@jgc.com) 27