Demonstration of 2 nd Generation Vegetable Oil Fuels in Advanced Engines

Transcription

1 Demonstration of 2 nd Generation Vegetable Oil Fuels in Advanced Engines Workpackage WP4 Engine Oil Development Deliverable N 4.11: Lubricant Supply (inc. Base Oil, VM, Additive) Publishable Version: 4.0 Hazelwood, 23 rd December 2009 prepared by: Lubrizol Ltd. Simon Peal, Dr. Craig Jones Lubrizol Limited The Knowle, Hazelwood GB Derbyshire DE 56 4AN Tel.: Fax.: craig.jones@lubrizol.com Partner website : Project website :

2 This publication has been produced with financial support of the European Commission in the frame of the FP7 Seventh Framework Programme under the grant agreement N TREN/FP7EN/219004/ 2ndVegOil. The sole responsibility for the content of this publication lies with the authors. It does not necessarily reflect the opinion of the European Communities. The European Commission is not responsible for any use that may be made of the information contained therein. 2

3 TABLE OF CONTENTS 1 LUBRICANT SUPPLY Page 4 2 ENGINE LUBRICANTS SELECTION FOR THE 2 nd VEGOIL PROJECT Page 8 LIST OF ACRONYMS PRODUCT DATA SHEETS FOR ENGINE LUBRICANT ADDITIVES AND VISCOSITY MODIFIERS MATERIAL SAFETY DATA SHEETS (MSDS) FOR ENGINE LUBRICANTS Appendix A Appendix B Appendix C 3

4 1 Lubricant Supply Appropriate amounts of engine lubricant were sent to the various test facilities for them to conduct their field trial and bench testing exercises. The table below summarises the quantity of engine lubricant supplied. All lubricant deliveries for first reporting period have been sent and received by the relevent test facility. TEST LOCATIONS: Type of Testing Tractor/Engine Types - Timing Lubricant Supply Germany Field Trial 4 Tractors/ Stage 3 (1 for TFZ, other 3 converted to Stage 3B for France Austria and Poland) 2 tractors/stage 3B - Summer '10. 2 Tractors/Stage 4 - Feb '11) 60l E7 sent to TFZ. 60l E7 and 120l E9 sent to JDWM (March '09) France Field Trial 2 tractors/stage 3A - March tractors/ Stage 3A (JDWM) - add retrofit DPF March x 60l of E7 sent (March '09). Austria Field Trial 4 tractors/stage 3A - March tractor/stage 3A (JDWM) - add retrofit DPF March x 60l E7 2 x 60l E9 (Sent Feb '09) Poland Field Trial 4 tractors - Stage 3A 1 tractor - Stage 3A (JDWM) 240l of E7 sent (March '09). TU- Kaiserslautern Bench Testing (Stage 4 Development) 1 x 200l of E9 sent in Oct 09 LVK - TU- Munich Bench Testing (Stage 4 Development, hybrid simulation) 1 x 200l of E9 sent in Oct 09 VWP Bench Testing (engine conversion) Sent 60l E7 & 20l E9 in Feb 09 4

5 The following photograph shows, as an example, a representative oil drum (with attached despatch note) just before delivery to TU-Kaiserslautern. 5

6 Below is a copy of the despatch note for the 60 litres of ACEA E7 engine lubricant sent to John Deere Mannheim. 6

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8 2 Engine Lubricants Selection for 2 nd VegOil Project The engine lubricants chosen to be researched as part of the 2 nd VegOil project are: OS = a lubricant which is capable of meeting the ACEA E specification OS = a lubricant which is capable of meeting the ACEA E specification The ACEA 2008 nomenclature and specifications for E7 and E9 lubricants is detailed in Appendix A in deliverable 4.1. The composition of the engine lubricant formulations (e.g. engine lubricant additives, viscosity modifiers and base oil type) to be used in the 2 nd VegOil project are detailed in Table 1. Table 1 Engine Lubricant Formulations to be used in 2 nd VegOil Project ACEA E7 Engine Lubricant ACEA E9 Engine Lubricant Lubrizol Oil Code OS OS Viscosity Grade 15W-40 15W-40 ExxonMobil AP/E 150N Group I Base Oil ExxonMobil AP/E 600N Group I Base Oil 20 - Chevron 220R (220N) Group II Base Oil Chevron 600R (600N) Group II Base Oil Lubrizol 4986E Engine Lubricant Additive Lubrizol Engine Lubricant Additive Lubrizol 7077 Viscosity Modifier Lubrizol 7075F Viscosity Modifier Lubrizol 6662 Pour Point Depressant The Product Data Sheets for Lubrizol 4986E, Lubrizol 40007, Lubrizol 7077 and Lubrizol 7075F are shown in Appendix B. The Product Data Sheets for Lubrizol 4986E and Lubrizol 40007detail the performance claims that can be made if these engine lubricant additives are blended with the appropriate base oils and viscosity modifiers. The Product Data Sheets for Lubrizol 7077 and Lubrizol 7075F detail the typical amounts of viscosity modifier that needs to be added to the formulation to obtain different viscosity grades. The Material Safety Data Sheets for the engine lubricants (OS and OS ) are shown in Appendix C. 8

9 Appendix A List of Acronyms ACEA European Automobile Manufactures Association E7 An engine lubricant which meets the ACEA E7 engine lubricant specification E9 An engine lubricant which meets the ACEA E9 engine lubricant specification DPF Diesel Particulate Filter VM Viscosity Modifier 9

10 Appendix B Product Data Sheets for Engine Lubricant Additives and Viscosity Modifiers 10

11 Product Type LUBRIZOL 4986E Heavy Duty Diesel Engine Oil Additive Application An engine oil additive for the formulation of Super High Performance Diesel (SHPD) lubricants meeting the requirements of ACEA E7, API CI-4 and MB- Approval Recommended for use at: 12.6 % by weight When blended with appropriate base oils and viscosity modifier, the formulated lubricant meets the following performance specifications as a SAE 15W-40 viscosity grade: ACEA E7-08 (2008) ACEA A3/B4-04 (2007) ACEA E5-02 (2002) ACEA E3-96 Issue 4 (2002) API CI-4 API CH-4 API CG-4 API CF-4 API CF API SL MB-Approval MB-Approval MAN 3275 MTU Type 2 Volvo VDS-3 Mack EO-M Plus Renault Truck RLD/RLD-2 CUMMINS CES CUMMINS CES CAT ECF-2 CAT ECF-1-a ZF TE-ML 07C Physical Characteristics < th> FLASH POINT, C, PMCC 150 Minimum Target Maximum LBS PER U.S C 8.11 LBS PER IMP 15.6 C 9.74 POUR POINT, C -18 SPECIFIC 15.6 C C, CST C, CST

12 Chemical Characteristics Minimum % Weight Typical Maximum % Weight CALCIUM NITROGEN PHOSPHORUS SULFATED ASH 9.1 SULFUR 3.0 ZINC

13 2.1.3 LUBRIZOL 4986E Unloading, storage and blending instructions General handling instructions - In general, The Lubrizol Corporation recommends, as a minimum, the use of neoprene or nitrile rubber gloves and safety glasses or chemical splash goggles. The Material Safety Data Sheet should be consulted for specific information and for information on health and safety when handling this product. Fire and explosion hazard data Flash Point (method) Classification 150 o C PMCC N/A Temperature recommendations Unloading Pumping Temperature 55 o C 131 o F Maximum temperature* 70 o C 158 o F Storage Maximum temperature for long-term storage 45 o C 113 o F Blending Maximum base oil temperature for mechanical or in-line mixing 70 o C 158 o F Equipment recommendations Type of Pump Positive Displacement Type of transfer line Ball Launched, Insulated,Steam Traced Using 107 C/225 F Steam Max. Transfer line size 3 inch/8 cm. Min. Heat source 13

14 Type Steam 107 C/225 F Max. Storage tank Suction Heater Recommended Viscosity data cst SUS at 25 C,77 F at 40 C, 104 F at 100 C, 211 F Notes Pour Point -18 C, 0 F Additional Recommendations * Holding the material in excess of this temperature may cause chemical degradation. Use steam for heating and tracing only when the material is in motion to avoid localized overheating. Cold Temperature Storage - If product has been stored below its pour point temperature it should be heated to 21 C/70 F before using. Effective: 10/9/2009 9:18:48 AM 14

15 Product Type LUBRIZOL Heavy Duty Diesel Engine Oil Additive Application An advanced API CJ-4 Heavy Duty Diesel Additive Package Recommended for use at: 16.5 % by weight Specifically formulated for use with Lubrizol viscosity modifiers to produce lubricants required for EPA 2007 compliant diesel engines equipped with after treatment devices such as diesel oxidation catalysts and particulate filters. LUBRIZOL used in combination with Group II base oils meet the following performance categories in the 15W-40 viscosity grade: API CJ-4 API CI-4 PLUS API CI-4 API CH-4 API SM CUMMINS CES Mack EO-O Premium Plus Detroit Diesel DDC 93K218 CAT ECF-3 CAT ECF-2 CAT ECF-1-a ACEA E9-08 (2008) ACEA E7-04 Issue 2 (2007) MB-Approval MAN 3575 MAN 3275 MTU Type 2.1 Volvo VDS-4 Volvo VDS-3 Renault Truck RLD-3 Deutz DQC III-05 LUBRIZOL provides unsurpassed control of soot, protection of highly stressed piston rings and cylinder liners as well as exceptional protection of valve train systems used in modern diesel engines. 15

16 Physical Characteristics Minimum Target Maximum FLASH POINT, C, PMCC 171 LBS PER U.S C 7.86 LBS PER IMP 15.6 C 9.44 POUR POINT, C -21 SPECIFIC 15.6 C C, CST C, CST 1818 Chemical Characteristics < th> Minimum % Weight Typical Maximum % Weight CALCIUM NITROGEN PHOSPHORUS SULFATED ASH 5.9 SULFUR 2.31 ZINC Benefits LUBRIZOL is engineered to provide: Exceptional control of soot related viscosity thickening Unsurpassed protection against wear due to corrosion of bearing and cylinder liners Exceptional protection of diesel and gasoline engine valve train components The highest level of prevention against damaging deposits common in high temperature modern multi-cylinder diesel engines 16

17 2.1.6 LUBRIZOL Unloading, storage and blending instructions General handling instructions - In general, The Lubrizol Corporation recommends, as a minimum, the use of neoprene or nitrile rubber gloves and safety glasses or chemical splash goggles. The Material Safety Data Sheet should be consulted for specific information and for information on health and safety when handling this product. Fire and explosion hazard data Flash Point (method) Classification 171 o C PMCC N/A Temperature recommendations Unloading Pumping Temperature 55 o C 131 o F Maximum temperature* 70 o C 158 o F Storage Maximum temperature for long-term storage 45 o C 113 o F Blending Maximum base oil temperature for mechanical or in-line mixing 70 o C 158 o F Equipment recommendations Type of Pump Positive Displacement Type of transfer line Ball Launched, Insulated,Steam Traced Using 107 C/225 F Steam Max. Transfer line size 3 inch/8 cm. Min. Heat source 17

18 Type Steam 107 C/225 F Max. Storage tank Suction Heater Recommended Viscosity data cst SUS at 25 C,77 F at 40 C, 104 F at 100 C, 211 F Notes Pour Point -21 C,-5 F Additional Recommendations * Holding the material in excess of this temperature may cause chemical degradation. Use steam for heating and tracing only when the material is in motion to avoid localized overheating. Cold Temperature Storage - If product has been stored below its pour point temperature it should be heated to 21 C/70 F before using. Effective: 11/6/2009 4:46:31 PM 18

19 Product Type LUBRIZOL Viscosity Improver Application A 25 SSI* shear stable non-dispersant olefin copolymer viscosity modifier.. Recommended for use in suitable base stocks to prepare multigrade crankcase engine oils meeting international requirements for shear stability. Approximate treating levels for stay-in-grade (Seq VIII, Orbahn Shear) performance are: SAE 5W wt % vol % SAE 10W wt % vol % SAE 10W wt % 8 11 vol % SAE 10W wt % vol % SAE 15W wt % 7 9 vol % SAE 20W wt % vol % SAE 20W wt % vol % Physical Characteristics < th> FLASH POINT, C, PMCC 200 Minimum Target Maximum LBS PER U.S C 7.25 LBS PER IMP 15.6 C 8.71 OIL BLEND 100 C, CST POUR POINT, C 2 SPECIFIC 15.6 C C, CST C, CST Special Handling Viscosity Modifier (VM) additives are sensitive to contamination. The most common problems result from their direct contact with other concentrated motor oil and gear oil additives. Very small levels of additive contamination can produce gels that are difficult to solubilize in oil. For this reason, it is imperative that all equipment to be used in the manufacture and transfer of VM additives be thoroughly cleaned and inspected to ensure no residue from previous additives is present. Ideally, the system should be dedicated to handling VM additives only. 19

20 Quality Control It should be noted that the viscosity of the concentrate should not be used as a measure of the amount of polymer in solution. The thickening contributed by the polymer to the finished lubricant may vary slightly from batch to batch but is guaranteed to be limited to a range corresponding to the following parmeters: An 10.0% by weight solution of LUBRIZOL 7077 in a HVI-200N paraffinic base stock (95 VI minimum, 100 degrees C=6.1 cst) will have a 100 degrees C, cst of 12.5(min) (max). Comments * 30 pass Orbahn shear LUBRIZOL 7077 Unloading, storage and blending instructions General handling instructions - In general, The Lubrizol Corporation recommends, as a minimum, the use of neoprene or nitrile rubber gloves and safety glasses or chemical splash goggles. The Material Safety Data Sheet should be consulted for specific information and for information on health and safety when handling this product. Fire and explosion hazard data Flash Point (method) Classification 200 o C PMCC N/A Temperature recommendations Unloading Pumping Temperature 115 o C 239 o F Maximum temperature* 125 o C 257 o F Storage Maximum temperature for long-term storage 45 o C 113 o F Blending Maximum base oil temperature for mechanical or in-line mixing 125 o C 257 o F Equipment recommendations Type of Pump Positive Displacement 20

21 Type of transfer line Ball Launched, Insulated,Steam Traced Using 121 C/250 F Steam Max. Transfer line size 4 inch/10 cm. Min. Heat source Type Steam 121 C/250 F Max. Storage tank Suction Heater Recommended Viscosity data cst SUS at 25 C,77 F at 40 C, 104 F at 100 C, 211 F Notes Pour Point 2 C, 36 F Additional Recommendations A higher storage temperature may be required due to viscosity at 45 C.* Holding the material in excess of this temperature may cause chemicaldegradation.use steam for heating and tracing only when the material is in motionto avoid localized overheating.cold Temperature Storage - If product has been stored below its pourpoint temperatureit should be heated to 21 C/70 F before using. Effective: 4/14/2009 5:10:11 PM 21

22 Product Type LUBRIZOL 7075F Viscosity Improver Application A 35 SSI* shear stable non-dispersant olefin copolymer viscosity modifier.. Recommended for use in suitable base stocks to prepare multigrade crankcase engine oils meeting the international requirements for shear stability. Approximate treating levels for stay-in-grade (Seq VIII, Orbahn Shear) performance are: SAE 5W wt % vol % SAE 10W wt % vol % SAE 10W wt % 8 11 vol % SAE 10W wt % vol % SAE 15W wt % 6 8 vol % SAE 20W wt % vol % SAE 20W wt % vol % Physical Characteristics < th> FLASH POINT, C, PMCC 188 Minimum Target Maximum LBS PER U.S C 7.22 LBS PER IMP 15.6 C 8.67 OIL BLEND 100 C, CST POUR POINT, C -3 SPECIFIC 15.6 C C, CST 1000 Special Handling Viscosity Modifier (VM) additives are sensitive to contamination. The most common problems result from their direct contact with other concentrated motor oil Very small levels of additive contamination can produce gels that are difficult to solubilize in oil. For this reason, it is imperative that all equipment to be used in the manufacture and transfer of VM additives be thoroughly cleaned and inspected to ensure ous additives is present. Ideally, the system should be dedicated to handling VM additives only. 22

23 Quality Control It should be noted that the viscosity of the concentrate should not be used as a measure of the amount of polymer in the solution. The thickening contributed by the polymer to the finsihed lubricant may vary slightly from batch to batch, but is guaranteed to be limited to a range corresponding to the following parameters: A 9.1% weight solution of LUBRIZOL 7075F in a 200 Neutral Base Stock (95 VI minimum, paraffinic, 100 degrees C = 6.1 cst) will have a 100 degrees C, cst of 11.2 min max. Comments * 30 pass Orbahn shear LUBRIZOL 7075F Unloading, storage and blending instructions General handling instructions - In general, The Lubrizol Corporation recommends, as a minimum, the use of neoprene or nitrile rubber gloves and safety glasses or chemical splash goggles. The Material Safety Data Sheet should be consulted for specific information and for information on health and safety when handling this product. Fire and explosion hazard data Flash Point (method) Classification 188 o C PMCC N/A Temperature recommendations Unloading Pumping Temperature 105 o C 221 o F Maximum temperature* 115 o C 239 o F Storage Maximum temperature for long-term storage 45 o C 113 o F Blending Maximum base oil temperature for mechanical or in-line mixing 115 o C 239 o F Equipment recommendations Type of Pump Positive Displacement 23

24 Type of transfer line Ball Launched, Insulated,Steam Traced Using 121 C/250 F Steam Max. Transfer line size 4 inch/10 cm. Min. Heat source Type Steam 121 C/250 F Max. Storage tank Suction Heater Recommended Viscosity data cst SUS at 100 C, 211 F Notes Pour Point -3 C, 27 F Additional Recommendations A higher storage temperature may be required due to viscosity at 45 C.* Holding the material in excess of this temperature may cause chemicaldegradation.use steam for heating and tracing only when the material is in motionto avoid localized overheating.cold Temperature Storage - If product has been stored below its pourpoint temperatureit should be heated to 21 C/70 F before using. Effective: 4/13/ :10:46 PM 24

25 Appendix C MSDS for Engine Lubricants 25

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