PRODUCT SAFETY DATA SHEET. Telephone Number for Information: (USA / CANADA) Date Prepared: January 2012

Transcription

1 fnegizei Page 1 of 5 PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Rechar ea le Batter y Type No.: Volts: TRADE NAMES: ENERGIZER Nickel Metal H y dride Batter y CHEMICAL SYSTEM: Nickel Metal Hydride Approximate Weight: Designed for Recharge: Yes SECTION 1 - MANUFACTURER INFORMATION Manufactured for: Energizer Battery Manufacturing, Inc Columbia Rd. Westlake,, OH Telephone Number for Information: (USA / CANADA) Date Prepared: SECTION 2 HAZARDS IDENTIFICATION Under normal conditions of use, the battery is hermetically sealed. Ingestion: Swallowing a battery can be harmful. Contents of an open battery can cause serious chemical bums of mouth, esophagus, and gastrointestinal tract. Inhalation: Contents of an open battery can cause respiratory irritation. Hypersensitivity to nickel can cause allergic pulmonary asthma. Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Nickel, nickel compounds, cobalt and cobalt compounds can cause skin sensitization and an allergic contact dermatitis. Eye Contact: Contents of an open battery can cause severe irritation and chemical burns. Note: Nickel, nickel compounds, cobalt and cobalt compounds are listed as possible carcinogens by the International Agency for Research on Cancer (IARC) or National Toxicology Program (NTP). SECTION 3 - INGREDIENTS IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. MATERIAL OR INGREDIENT PEL OSHA TLV ACGIH % /wt. 2 Aluminum 3 10 mg/m 3 TWA (CAS# ) 15 mg/m TWA(total dust) 5 mg/m 3 TWA (respirable fraction) Cobaft 0. 3 mg/m TWA (as Co) mg/m TWA (as Co) as cobalt metal (CAS# ) as cobalt oxide (CAS# ) as cobalt hydroxide (CAS# ) Lithium Hydroxide (CAS# ) None established None established 0-4 Manganese 5 mg/m 3 Ceiling 0.2 mg/m 3 TWA (as Mn) (CAS# ) Mischmetal 3 3 including: 15 mg/m TWA (particulates 10 mg/m TWA (particulates Lanthanum (CAS# ) not otherwise regulated-total not otherwise classifieddust) inhalable) Cerium (CAS# ) < 3 < 13

2 F118mizer. Neodymium (CAS# ) Praseodymium (CAS# ) 5 mg/m 3 TWA (particulates 3 m g /m 3 TWA (particulates not not otherwise regulated- otherwise dassified-respirable) respirable fraction) Nickel as nickel hydroxide I mg/m 3 TWA (as Ni) 1.5 mg/m3 TWA (as inhala3le Ni) (CAS# ) 0.2 mg/m TWA (as inhalable as nickel oxide (CAS# ) Ni, insoluble compounds) as nickel powder (CAS# ) Potassium Hydroxide None established 3 <7 2 mg/m Ceiling (CAS# ) Sodium Hydroxide 2 mg/m 3 TWA 2 mg/m 3 Ceiling 0-4 (CAS# ) 3 3 Zinc 3 10 mg/m TWA (total dust: zinc as zinc metal (CAS# ) 15 mg/m TWA (total dust: oxide) as zinc oxide (CAS# ) zinc oxide) as zinc hydroxide (CAS# ) 5 mg/m 3 TWA (respirable fraction: zinc oxide) Non-Hazardous Components Steel None established None established (iron CAS# ) water, Paper, Plastic and Other None established None established Balance SECTION 4- FIRST AID MEASURES' Page 2 of 5 Ingestion: Do not induce vomiting or give food or drink. Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up ( ) collect day or night. Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical attention. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention. SECTION 5 - FIRE FIGHTING MEASURES If fire or explosion occurs when batteries are on charge, shut off power to charger. in case of fire where nickel metal hydride batteries are present, apply a smothering agent such as METL-X, sand, dry ground dolomite, or soda ash, or flood the area with water. A smothering agent will extinguish burning nickel metal hydride batteries. Water may not extinguish burning batteries but will cool the adjacent batteries and control the spread of fire. Burning batteries will burn themselves out. Virtually all fires involving nickel metal hydride batteries can be controlled with water. When water is used, however, hydrogen gas may evolve. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended. Fire fighters should wear self-contained breathing apparatus. Burning nickel metal hydride batteries can produce toxic fumes including oxides of nickel, cobalt, aluminum, manganese, lanthanum, cerium, neodymium, and praseodymium. SECTION 6 - ACCIDENTAL RELEASE MEASURES To cleanup leaking batteries: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container.,

3 k _ Fliergizer. Page 3 of 5 SECTION 7 - HANDLING AND STORAGE Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Batteries normally evolve hydrogen which, when combined with oxygen from the air, can produce a combustible or explosive mixture unless vented. If such a mixture is present, short circuits, high temperature, or static sparks can cause an ignition. Do not obstruct safety release vents on batteries. Encapsulation (potting) of batteries will not allow cell venting and can cause high pressure rupture. Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices. If soldering or welding to the battery is required, consult your Energizer Battery Manufacturing, Inc. representative for proper precautions to prevent seal damage or short circuit. Do not open battery. The negative electrode material may be pyrophoric. Should an individual cell from a battery become disassembled, spontaneous combustion of the negative electrode is possible. This is much more likely to happen if the electrode is removed from its metal container. There can be a delay between exposure to air and spontaneous combustion. Charging: This battery is made to be charged many times. Because it gradually loses its charge over a few months, it is good practice to charge battery before use. Use recommended charger. Improper charging can cause heat damage or even high pressure rupture. Observe proper charging polarity. Labeling: If the Energizer label or package warnings are not visible, it is important to provide a package and/or device label stating: WAPNING. CHARGE ONLY WITH SPECIFIED CHARGERS ACCORDING TO DEVICE MANUFACTURER'S INSTRUCTIONS. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE OR SHORT CIRCUIT - MAY IGNITE, EXPLODE, LEAK OR GET HOT CAUSING PERSONAL INJURY. Where accidental ingestion of small batteries is possible, the label should state: WARNING: (1) KEEP AWAY FROM SMALL CHILDREN. IF SWALLOWED, PROMPTLY SEE DOCTOR: HAVE DOCTOR PHONE (202) COLLECT. (2) CHARGE ONLY WITH SPECIFIED CHARGERS ACCORDING TO DEVICE MANUFACTURER'S INSTRUCTIONS. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE OR SHORT CIRCUIT - MAY IGNITE, EXPLODE, LEAK OR GET HOT CAUSING PERSONAL INJURY. SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION 1 Ventilation Requirements: Not necessary under normal conditions. Respiratory Protection: Not necessary under normal conditions. Eye Protection: Not necessary under normal conditions. Gloves: Not necessary under normal conditions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling 760 mm Hg ( C) Vapor Pressure (mm 25 C) Vapor Density (Air = 1) Density (g/cm3)

4 Ffle m in r. Page 4 of 5 Percent Volatile by Volume (%) Evaporation Rate (Butyl Acetate = 1) Physical State Solubility in Water (% by weight) ph Appearance and Odor Solid Solid object / no odor SECTION 10 STABILITY AND REACTIVITY Nickel metal hydride batteries do not meet any of the criteria established in 40 CFR for reactivity. SECTION 11 TOXICOLOGICAL INFORMATION Nickel metal hydride batteries are not hazardous waste. Under normal conditions of use, nickel metal hydride batteries are non-toxic, SECTION 12 ECOLOGICAL INFORMATION Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles. SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in accordance with all applicable federal, state and local regulations. Appropriate disposal technologies include incineration and land filling. Nickel metal hydride batteries can also be collected as part of the Rechargeable Battery Recycling Corporation (RBRC) program. Visit for the nearest recycling center or call battery for rechargeable battery recycling and disposal information. SECTION 14 TRANSPORT INFORMATION In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that batteries be packaged in a manner that prevents short circuits and be contained in "strong outer packaging" that prevents spillage of contents. All original packaging for Energizer nickel metal hydride batteries has been designed to be compliant with these regulatory concerns. Energizer nickel metal hydride batteries (sometimes referred to as "Dry cell" batteries) are not defined as dangerous goods under the IATA Dangerous Goods Regulations, ICAO Technical Instructions and the U.S. hazardous materials regulations (49 CFR). Nickel metal hydride batteries are defined as dangerous goods under the IMDG code. For air and ground transportation, these batteries are not subject to the dangerous goods regulations as they are compliant with the requirements contained in the following special provisions. Regulatory Body Special Provisions ADR , 598 IMDG UN3496 SP 963 UN UN 3028 Provisions US DOT 49 CFR Provision 130 IATA Al23 ICAO UN 3028 Provisions In addition, the IATA Dangerous Goods Regulations and ICAO Technical Instructions require the words "not restricted" and the Special Provision number Al23 be provided on the air waybill, when an air waybill is issued.

5 ILIIJ Fflargizer. Page 5 of 5 I SECTION 15 - REGULATORY INFORMATION Batteries marketed by Energizer Battery Manufacturing, Inc. are not classified as dangerous goods by the US Department of Transportation or the major international regulatory bodies and are therefore not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To- Know Act. SECTION 16 - OTHER INFORMATION None. Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section (c), Eveready/Energizer batteries are manufactured articles, which do not result in exposure to a hazardous chemical under normal conditions of use. The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC, MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMA TION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT Energizer

6 Eneigirec Page 1 of 3 Lithium Ion Batteries As a courtesy to our customers, Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section (c), Eveready/Energizer batteries are manufactured "articles", which do not result in exposure to a hazardous chemical under normal conditions of use. For this reason, Material Safety Datasheets are not required. The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC., MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT. PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Rechargeable ACCU Ba ttery Type No.: Volts: TRADE NAME: Lithium Ion Battery CHEMICAL SYSTEM: Lithium Ion Approximate Weight: Designed for Recharge: Yes I SECTION I MANUFACTURER INFORMATION: Manufactured for: Energizer Battery Manufacturing, Inc Columbia Rd. Westlake, OH Telephone Number for Information: (USA) Date Prepared: SECTION II - HAZARDOUS INGREDIENTS IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) % wt. Acetylene Black 3.5 mg/m 3 TWA 3.5 mg/m 3 TWA 0-2 (CAS# ) (as carbon black) as carbon black Biphenyl (CAS# ) 1 mg/m 3 TWA 0.2 ppm TWA 0.2 ppm TWA 0-15 Diethyl Carbonate None established None established 0-15 (CAS# ) Dimethyl Carbonate None established None established 0-15 (CAS# ) Ethyl Methyl Carbonate None established None established 0-15 (CAS# ) Ethylene Carbonate None established None established 0-15 (CAS# ) MATERIAL OR INGREDIENT PEL OSHA TLV ACGIH Graphite 5 mg/m 3 TWA (respirable fraction) 2 mg/m 3 TWA (respirable fraction) 7-22 (CAS# ) 15 m m 3 TWA total dust Lithiurn Cobalt Oxide 0.1 mgjm 3 TWA (as Co) 0.02 mg/m 3 TWA (as Co) (CAS# ) Lithium Hexafluorophosphate None established None established 0-5 (CAS# ) Lithium Tetrafluoroborate None established None established 0-5 (CAS# ) n-methyl Pyrrolidinone None established None established 0-1 CAS#

7 fifferfizar. Page 2 of 3 Lithium Ion Batteries Oxalic Acid 1 mg/m 3 TWA 1 mg/m 3 01 TWA (CAS# ) 2 m /m 3STEL Propylene Carbonate None established None established 0-15 (CAS# 10S-32-7) I SECTION III - FIRE AND EXPLOSION HAZARD DATA If fire or explosion occurs when batteries are on charge, shut off power to charger. In case of fire where lithium ion batteries are present, flood the area with water. If any batteries are burning, water may not extinguish them, but will cool the adjacent batteries and control the spread of fire. CO2, dry chemical, and foam extinguishers are preferred for small fires, but also may not extinguish burning lithium ion batteries. Burning batteries will burn themselves out. Virtually all fires involving lithium ion batteries can be controlled with water. When water is used, however, hydrogen gas may be evolved which can form an explosive mixture with air, LITH-X (powdered graphite) or copper powder fire extinguishers, sand, dry ground dolomite or soda ash may also be used. These materials act as smothering agents. Fire fighters should wear self-contained breathing apparatus. Burning lithium ion batteries can produce toxic fumes including HF, oxides of carbon, aluminum, lithium, copper, and cobalt. Volatile phosphorus pentafluoride may form at a temperature above 230 F. SECTION IV - HEALTH HAZARD DATA Under normal conditions of use, the battery is hermetically sealed. Ingestion: Swallowing a battery can be harmful. Contents of an open battery can cause serious chemical burns of mouth, esophagus, and gastrointestinal tract. if battery or open battery is ingested, do not induce vomiting or give food or drink. Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up ( ) collect, day or night. Inhalation: Contents of an open battery can cause respiratory irritation. Inhalation of vapors may cause irritation of the upper respiratory tract and lungs. Provide fresh air and seek medical attention. Skin Absorption: N-methyl pyrrolidinone, ethylene carbonate, ethyl methyl carbonate, dimethyl carbonate, and biphenyl may be absorbed through the skin causing localized inflammation. Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Remove contaminated clothing and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical attention. Eye Contact: Contents of an open battery can cause severe irritation and chemical burns. Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention. Note: Acetylene black and cobalt compounds are listed as possible carcinogens by the International Agency for Research an Cancer (IARC). SECTION V - PRECAUTIONS FOR SAFE HANDLING AND USE Storage: The lithium ion battery should be between 25% and 75% of full charge when stored for a long period of time. Store in a cool, dry, well ventilated area. Elevated temperatures can result in loss of battery performance, leakage, or rust. Do not expose the battery to open flames. Mechanical Containment: Containment of this battery in a manner that obstructs or defeats the safety vent or electrical disconnect mechanisms designed into this battery can result in fire and/or explosion and cause personal injury and device damage. This battery is not designed to be potted, enclosed in hermetic overpackaging, or sealed by any means that prevents free operation of the designed safety mechanisms. Handling: Do not expose the battery to excessive physical shock or vibration. Short circuiting should be avoided, however, accidental short circuiting for a few seconds will not seriously affect the battery. Prolonged short circuits will cause the battery to rapidly lose energy, could generate enough heat to burn skin, and may cause the safety release vents of the enclosed cells to open. Sources of short circuits include jumbled batteries in bulk containers, coins, metal jewelry, metal covered tables, or metal belts used for assembly of batteries in devices. To minimize risk

8 Energizer PRODUCT SAFETY DATASH EET Page 3 of 3 Lithium Ion Batteries of short circuiting, the protective case supplied with the battery should be used to cover the terminals when transporting or storing the battery. Do not disassemble or deform the battery. Should an individual cell within a battery become ruptured, do not allow contact with water. If soldering or welding to the battery is required, consult your Energizer Battery Manufacturing, Inc. representative for proper precautions to prevent damage to the integrity of the battery. Charging: This battery is made to be charged many times. Use an Energizer approved battery charger. Never use a modified or damaged battery charger. Do not charge for over 180 minutes or repeat charging without intermittent discharging. A backup charge termination based on time is recommended to prevent overcharging. The charging temperature should be between 0 C and 50 C (32 F and 120 F). The battery pack will normally warm during charging. Charging Voltages and Currents: Charging voltages are prevented from exceeding the specified limits by an internal battery protection circuit. Never use a battery which shows signs of a damaged protection circuit or broken case. (Such damage to the protection circuit may be indicated by voltages at the battery terminals outside of their specified ranges.) Adhere to all specified charging and discharging voltages and currents. Do not use battery if its voltage drops below the specified minimum voltage. Labeling: If the Eveready label or package warnings are not visible, it is important to provide a package and/or device label stating: WARNING: CHARGE ONLY WITH SPECIFIED CHARGERS ACCORDING TO DEVICE MANUFACTURER'S INSTRUCTIONS. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE, OR SHORT CIRCUIT - MAY IGNITE, EXPLODE, LEAK, OR GET HOT CAUSING PERSONAL INJURY. Disposal: Dispose in accordance with all applicable federal, state and local regulations. SECTION VI - SPECIAL PROTECTION INFORMATION Ventilation Requirements: Not necessary under normal conditions. Respiratory Protection: Not necessary under normal conditions. Eye Protection: Not necessary under normal conditions. Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Not necessary under normal conditions. Use neoprene or natural rubber gloves if handling an open or leaking battery. Open Battery Storage: Battery should not be opened. Should a cell become disassembled, the electrode should be stored in a fireproof cabinet, away from combustibles. I SECTION VII - REGULATORY INFORMATION In general, the transportation of primary lithium cells and batteries (and batteries packaged with or in equipment) is regulated as UN3090 (UN 3091) by the International Civil Aviation Organization (ICAO), International Air Transport Association (IATA), International Maritime Dangerous Goods Code (IMDG), Accord European Sur le Transport des Marchandises Dangereuses par Route (ADR) and the US Department of Transportation (US DOT). However, Energizer lithium ion batteries are exempt from the majority of regulatory requirements of UN3090 (and UN 3091) because they meet the requirements of IATA Packaging Instructions and various special provisions from IMDG, ADR and the US DOT. (Essentially, they are properly packaged and labeled, contain less than 1 gram of lithium and pass the tests defined in UN model regulation section 38.3). By complying with the requirements specified above, Lithium Batteries are not otherwise regulated as Dangerous Goods. Lithium Batteries manufactured, packaged and shipped by Energizer Battery Manufacturing, Inc, meet the requirements specified above. Any Lithium Batteries subsequently repackaged or reshipped are required to meet all of the requirements specified above.