Gasoline Compression Ignition GCI Opportunities and Challenges Gautam Kalghatgi

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Lecture 7 Gasoline Compression Ignition GCI Opportunities and Challenges Gautam Kalghatgi Fuel/Engine Interactions, Ch.6 Kalghatgi, G., Johansson, B. 218 Gasoline compression ignition (GCI) approach to efficient, clean, affordable future engines Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, Vol 232 (1), pp118-138. 218 Kalghatgi, G.T., Risberg, P. and Ångström, H-E, Advantages of a fuel with high resistance to auto-ignition in late-injection, low-temperature, compression ignition combustion, SAE Paper No. 26-1-3385, Journal of Fuels and Lubricants-V115-4 Kalghatgi, G.T., Risberg, P. and Ångström, H-E, Partially pre-mixed auto-ignition of gasoline to attain low smoke and low NOx at high load in a compression ignition engine and comparison with a diesel fuel, SAE 27-1-6 Kalghatgi, G.T., Hildingsson, L. Johansson, B. and Harrison, A.J., Low- NOx, low-smoke operation of a diesel engine using premixed enough compression ignition Effects of fuel autoignition quality, volatility and aromatic content, THIESEL 21, Thermo and fluid dynamic processes in diesel engines, September 14-17, Valencia,21 Kalghatgi, G.T., Hildingsson,L., Harrison, A.J., L. and Johansson, B. Surrogate fuels for premixed combustion in compression ignition engines, International Journal of Engine Research, October 211; vol. 12, 5: pp. 452-465

Demand increase heavily skewed towards commercial transport middle distillates Greater Efficiency Improvements in Passenger Car Sector (mostly uses gasoline) a) future global average car will be smaller/lighter and drive fewer miles compared to today b) electrification Passenger car numbers might increase to 1.6-1.9 billion by 24 but gasoline demand will not change much. Diesel and Jet fuel demand will increase by around 7%. WEC Freeway Scenario - http://www.worldenergy.org/wpcontent/uploads/212/9/wec_transport_scenarios_25.pdf Increasing pressure on gasoline antiknock quality Marine transport moves to diesel 1s of billions $ investments will be needed in refineries Homeless Hydrocarbons low octane light components like naphtha will be in abundance High efficiency engines which can use such components need to be developed

CI Engine Development Trends High efficiency, low emissions and affordable Compression Ignition (CI) engines currently are diesel engines High efficiency - no throttling, high compression ratio, reduced compression losses High Emissions: Soot and NOx. Difficult to control through exhaust after-treatment unlike in SI engines High Cost : With conventional diesel fuel, High injection pressures (to reduce soot) High engine/after-treatment cost with existing diesel fuel

Model of Conventional Diesel Combustion John Dec, Proceedings Combust. Inst., 32 (29) pp 2727-2742 At very low loads, fuel injection is over before combustion starts At all other loads combustion starts while fuel is still being injected

Gasoline Compression Ignition (GCI) Engines 5

Low NOx, Low Particulates for Compression Ignition Particulates and NOx emissions causing more concern and standards are getting more stringent Conventional diesel fuel ignites easily, before it has a chance to mix with oxygen in the cylinder giving high particulates and NOx Advanced diesel engines are expensive and complicated because they are trying to control particulates and NOx while using conventional diesel fuel Control of particulates and NOx much easier with fuels with high ignition delay - Gasoline-like Fuels Gasoline Compression Ignition (GCI) Inject gasoline in a diesel engine much earlier in the cycle compared to diesel fuel Higher ignition delay allows more time for mixing before combustion In cycle control of combustion phasing by injection timing as in a diesel engine

Equivalence Ratio Premixed Compression Ignition (PCI) Dec (29) Proc. CI, 32:2727-2742 Regulations to control NOx and soot getting tighter NOx can be controlled by EGR which brings down combustion temperature Increasing EGR reduces soot oxidation and increases engine-out soot Soot formation should be avoided Final fuel injection must be completed sufficiently before combustion starts to avoid soot-forming equivalence ratios Φ < 2. Premixed Compression Ignition, PCI Advanced diesel engines are expensive and complicated because they are trying to achieve PCI while using conventional diesel fuel (DCN > 4) PCI much easier with fuels with high ignition delay i.e. Gasoline CI (GCI)

Premixed-enough CI Fuel/air must not be fully pre-mixed unlike in HCCI Allows in-cycle control over combustion phasing At low loads, with high ignition delay fuels, combustion occurs by auto-ignition in lean packets zero smoke, low NOx and low noise but high HC and CO Low injection pressures help. Perhaps larger hole size. At high loads, multiple injection strategies help alleviate high pressure-rise rates and noise Ideal fuel is low-quality gasoline Gasoline Compression Ignition (GCI) With GCI, efficiency at least as good as with diesel, much lower injection pressures needed and after-treatment focus shifts to HC and CO control rather than NOx and soot control

9 Results from 2 L single-cylinder, 14 CR Reported in SAE 26-1-3385 and SAE 27-1-6 CA5, CAD 54CN,.6 g/s,no EGR 39 CN,.6 g/s, no EGR 3 CN,.6 g/s,no EGR Gasoline,.6 g/s, No EGR 3 25 2 15 1 Engine will not run on gasoline with very early SOI in HCCI mode Expected results CA5 decreases with CN 5-4 -3-2 -1 1-5 SOI, CAD.6 g/s, No EGR, Pin =1.5 bar abs, Tin = 4 C, 12 RPM λ= 3.8 CN Density IBP T1 T5 T9 FBP Aromatics LHV** Fuel g/cc ºC ºC ºC ºC ºC % vol MJ/kg Swedish MK1 54.81 195 28 24 273 297 ~ 3 43.8 Diesel 1 39.81 167 179 196 22 246 34 43.5 Diesel 2 3.83 167 179 198 222 246 5 43.3 Gasoline ~15*.726 32 5 12 144 176 29 43.2 Three Diesel fuels and one 95 RON gasoline. ** Lower Heating Value

1 Results from 2 L single-cylinder, 14 CR 14 NOx, ppm 12 1 8 6 4 54CN,.6 g/s,no EGR 39 CN,.6 g/s, no EGR 3 CN,.6 g/s,no EGR Gasoline,.6 g/s, No EGR 2 1 2 3 4 5 6 IMEP,bar Very much lower NOx for the same IMEP for gasoline because of higher Combustion Delay. Increasing fuelling rate will increase IMEP but also smoke for the diesel fuel and NOx for all fuels. NOx can be reduced by EGR

11 Results from 2 L single-cylinder, 14 CR 14 NOx, ppm 12 1 8 6 4 54CN,.6 g/s,no EGR 39 CN,.6 g/s, no EGR 3 CN,.6 g/s,no EGR Gasoline,.6 g/s, No EGR 2 1 2 3 4 5 6 EID, Engine Ignition Delay (CA5-SOI), CAD.6 g/s, No EGR, Pin =1.5 bar abs, Tin = 4 C, 12 RPM NOx decreases with Combustion delay

Ignition/combustion delay and mixing At low loads For all fuels, injection is over before combustion starts Smoke is very low FSN <.8 for D1 Packets of different mixture strength at the start of combustion The longer the ignition delay, the leaner these packets because the global mixture strength is lean HC and CO are inverse of NOx High cetane diesel will burn in richer packets while gasoline (high octane) will burn in lean packets. HC, CO

Results from.537 L, 15.9 CR eng. at 12 RPM. No EGR. 4 bar IMEP. Diesel (56 CN) vs 84 RON gasoline At low loads both NOx and Max Pressure Rise Rate are lower for gasoline i.e. with long ignition delay but high HC and CO 12 2 Diesel, 1.1 bar Pi ISNOx, g/kwh 1 8 6 4 Diesel, 1.1 bar Pi Gas, 84 RON, 1.1 bar Pi Max PRR, bar/cad 18 16 14 12 1 8 6 Gas, 84 RON, 1.1 bar Pi 2 4 2 3.4 3.6 3.8 4 4.2 3 3.2 3.4 3.6 3.8 4 4.2 Mean IMEP, bar Mean IMEP, bar ASME, ICES29-7634, J. Eng. For Gas Turbines Power, vol 152 SOI sweep at fixed fuel rate 13

14 Heat Release Rate and MPRR.537 L engine 12 rpm, 4 bar IMEP 2 rpm, 1 bar IMEP, 4% EGR G4, cyl. p. n-hept, cyl. p. G4, dq n-hept, dq D1 56 CN,Pr G4 84 RON, Pr. D1 56 CN, dq G4 84 RON, dq 12.2 Cylinder presssure [bar] 6 5 5 4 3 4 2 3 1 2-1 -5. 5. 15. 25. CAD Heat Release Rate kj/m3/cad Cylinder presssure [bar] 1.15 8.1 6.5 4 2 -.5-1 1 2 3 CAD Heat release rate kj/cad Average pressure and heat release rate for G4 (SOI = -12 CAD) and n- heptane (SOI = +.7 CAD)., CA5 = 1.5 CAD Average pressure and heat release rate at high load, 4% EGR for G4 (SOI = -9.5 CAD) and D1 (SOI = -3.6 CAD)., CA5 = 11 CAD At low loads, gasoline will have lower MPRR compared to diesel. At high loads, the reverse is true

15 Heat Release Rate and Maximum Pressure Rise Rate in a Multi-cylinder (V6) Engine MAP cond., diesel fuel, 2 injections MPRR2 [bar/cad] 15 RPM, 4 bar IMEP 3.5 3. 2.5 2. 1.5 1..5. -3-25 -2-15 -1 Start of Injection, SOI [CAD] No EGR 16% EGR 22% EGR 36% EGR Diesel Map Single Inj., diesel fuel, but with the same Position for Max. Heat release Single Inj., 84 RON gasoline, but with the same position for Max. Heat release In real, light-duty engines, efficiency and smoke are sacrificed to reduce MPRR (i.e. noise) when using diesel fuel. This can be avoided if gasoline is used Kalghatgi, G.T., Gurubaran, K., Davenport, A., Harrison, A.J., Taylor, A.K.M.F. and Hardalupas, Y., Some advantages and challenges of running a EuroIV, V6 diesel engine on a gasoline fuel, Fuel 18: pp 197-27, 213

SAE 27-1-6.Smoke increases with injection quantity Pin = 2 bar abs, EGR ~ 38% Swedish MK1 diesel fuel, Single Injection starting at TDC SOI at TDC, different inj. rates AVL smoke opacity % 2 18 16 14 12 1 8 6 4 2 7 9 11 13 IMEP, bar Smoke vs IMEP, SOI at TDC

SAE 27-1-6.Injection timing and smoke Swedish MK1 Diesel 25 13 25 Gasoline Smoke 14 AVL Smoke Opacity % and CA5, CAD 2 15 1 5 Smoke CA5 12.5 12 11.5 Mean IMEP, bar AVL Smoke Opacity % and CA5, CAD 2 15 1 5 CA5 Mean IMEP 13.5 13 12.5 Mean IMEP, bar Mean IMEP 11-4 -2 2 4 6 8 Start of Injection, SOI, CAD 12-2 -15-1 -5 Start of Injection, SOI, CAD Smoke decreases as injection is retarded for diesel but very low for gasoline Pin = 2 bar abs, 1.2 g/s fuel, EGR ~ 38% Single Injection. λ~1.8

SAE 27-1-6.Low smoke for gasoline because of higher EID AVL Smoke,% 25 2 15 1 5 Gasoline Diesel Heat Release Rate, J/CAD 1 HRR, diesel, 11.5 bar, 1.6% smoke NL, diesel 11.5 bar, 1.6% smoke HRR, diesel, 12.5 bar, 2.7% smoke NL, diesel 8 12.5 bar, 2.7% smoke HRR, gas, 12.9bar,.11%smoke NL, gas, 12.9 bar,.11%smoke 6 4 2 5 1 15 2 25 3 Engine Ignition Delay, EID = CA5 - SOI, CAD Smoke vs ignition delay -15-5 5 15 25 35-2 Crank Angle, CAD HRR and needle lift for three cases Pin = 2 bar abs, 1.2 g/s fuel, EGR ~ 38%

Pressure, heat release rate and needle lift curves for gasoline with 14.86 bar IMEP (.115 bar std), 1.8% smoke and ISNOx, ISFC, ISCO and ISHC of 1.21 g/kwh, 178 g/kwh, 3.4 g/ kwh and 3.6 g/kwh respectively. Needle lift, arbitrary scale. High Heat Release Rate. Can it be alleviated by using multiple injections? 19 High IMEP point with gasoline, single injection 14 12 Heat Release Rate Needle lift Pressure 16 14 Heat Release Rate, J/deg 1 8 6 4 2 12 1 8 6 4 Pressure, bar -3-1 1 3-2 Crank Angle Degree, CAD 2

2 Gasoline single vs double injection Pressure, bar 16 14 12 1 8 6 4 14.86 bar IMEP, single inj 2 15.95 bar IMEP. Double inj 15.7 bar IMEP, double inj. -4-2 2 4 Crank Angle Degree, CAD Heat Release Rate, J/deg 14 14.86 bar IMEP, single inj 1215.95 bar IMEP double inj 15.7 bar IMEP, double inj 1 8 6 4 2-2 -2-1 1 2 3 4 Crank Angle Degree, CAD Double injection allows MHRR to be reduced and delayed without increasing cyclic variation and at lower emissions. All experiments at 2 bar abs. inlet pressure, 4 C inlet temp. ~35% EGR based on actual exhaust. Injection Fuel Rate CO2 IMEP* IMEP* AVL ISNOx ISFC ISHC ISCO MHRR* Angle of Mean Intake Mean std smoke MHRR* g/s % bar bar % opacity g/kwh g/kwh g/kwh g/kwh J/deg CAD Single** 1.436 4.5 14.86.115 1.81 1.21 178 3.6 3.4 1446 1.8 Double*** 1.46 4.14 15.7.138.28.59 179 3. 5.8 817 18.2 Double*** 1.549 4.16 15.95.112.33.58 179 2.9 6.8 1393 14.1 * Mean from 1 cycles ** SOI @ -16 CAD from SAE 26-1-3385 *** 1.19 g/s @ -11 CAD and rest at -15 CAD

.537 litre engine, 15.9 CR. Max pressure rise rate control with multiple injections Pressure [bar] 14 12 1 8 6 4 2 84RON 1 inj 84RON 3 inj 84RON 1 inj dq 84RON 3 inj dq 6 5 4 3 2 1 Heat Release Rate [kj/m³cad] -1-2 -1 1 2 3 4 CAD Pressure and heat release rate for single injection and triple injection (some increase in smoke). 84 RON gasoline, 2 RPM, ~35% EGR, 9 bar injection pressure. IMEP of 12.3 bar in each case. A lot of gasoline can be injected early in the cycle without causing heat release during the compression stroke. Not possible with diesel. An injection near TDC initiates combustion. Kalghatgi, G.T., L. Hildingsson, B. Johansson, Low NOx and low smoke operation of a diesel engine using gasolinelike fuels, ASME Paper # ICES29-7634, Journal of Engineering for Gas Turbines and Power (Vol.132, Iss.9), 21 21

Avoid Overmixing Injection pressure effects Should avoid overmixing and overleaning. Lower injection pressures better for fuels with long ignition delays. At higher loads, multiple injections. Bigger injector holes might be better more stratification

Fuel Effects on GCI I. Volatility, Composition, Ignition delay Fuel Aromatic Isooct n- hep tolu density RON MON DCN % vol vol% vol% vol% g/cc PRF 84 84 84 84 16.682 TRF 84 84.5 74.5 65 35 65.785 TRF 82 82.1 78.1 26 5 24 26.723 n-hept 55 1.632 ULG 72 72.9 68.4 19.715 ULG 78 78.5 73 23.726 ULG 84 84.1 78 26.5.736 ULG 91 9.7 81.8 29.8.731 D4 22.5 75.3.865 D1 56 25.2.833 B.P.s of n-hept, isooctane, toluene 98 C, 99 C 11 C SAE 29-1-1964, SAE 21-1-67, THIESEL 21, International Combustion Symposium 21

Fuel Effects on GCI - II If two fuels match for combustion delay, they have similar NOx, CO, smoke and to some extent HC emissions for PCI

Fuel effects III. Combustion delay and Octane Index 12 RPM, 4 bar IMEP, 65 bar inj, 1.1 bar intake, no EGR, CA5 = 11 CAD For gasolines and model fuels we can measure RON and MON OI = (1- K) RON + KMON If two fuels have the same RON and MON, they will have the same OI and hence the same combustion phasing. Then in PCI combustion, they will have comparable emissions Hence a good surrogate for PCI is a toluene reference fuel with the same RON and MON as the target fuel Kalghatgi et al Autoignition quality of gasolines in partially premixed combustion in diesel engines, Proceedings of the Combustion Institute 33 (211) 315 321. Kalghatgi et al Surrogate fuels for premixed combustion in compression ignition engines, International Journal of Engine Research, October 211; vol. 12, 5: pp. 452-465

Ignition Delay Changes Non-linearly with OI Little change in ignition delay in diesel autoignition range i.e CN > 4 or OI < 4. Optimum RON between 7 and 85. CN < 25 to see real benefits. Low volatility not required if ignition delay is high enough. ID at 12 RPM, 4 bar IMEP, No EGR Volatility will still play a role in mixing wider volatility range might be beneficial by enabling more stratification. Won et al. (J Auto 211, 212) [1% diesel + 9% gasoline] allowed PCI operation over a wider speed/load range than a gasoline of the same RON and MON Initially GCI will have to use available fuels either in RCCI or as mixture of diesel and gasoline.

Fuel requirements of GCI engines Varying requirements on ignition delay (ID) at different operating conditions - ID (octane) too high start difficult, low load stability ID too low reduced benefits on soot and NOx Challenge of introducing a new fuel use market fuels Use two fuels RCCI. Mostly run on gasoline (high ID) use diesel (low ID) when needed. Relevant for heavy-duty engines today Compromise and find optimum ignition quality ~7 RON. Homeless hydrocarbons can be used with little further processing! Deal with challenges via engine management. No strict requirements on volatility increases refinery flexibility. Wider volatility range seems to be beneficial (by increasing stratification?) Dieseline e.g. 1%-2% vol diesel in gasoline. Existing market fuels could be used RCCI and Dieseline interim enabling technologies.

GCI Efficiencies at least as high as the best diesel engines Indicated efficiencies of around 56% demonstrated in heavy duty (large) engine tests (Lund, Wisconsin) Additional efficiency improvements in light duty engines possible Avoiding pilot injection at low loads Down-sizing / down-speeding to reduce transmission losses Avoid or minimize (if one is used) DPF regeneration Reduced parasitic losses because of low injection pressure Scope for hybridization like a diesel hybrid at lower cost. Hybridization both enabling and enhancing technology

Development Challenges for GCI 1. Cold start and idle 2. Stability at low load 3. Noise/pressure rise rate at medium and high loads 4. Emissions, particularly CO and HC low temperature oxidation and DPF 5. Hardware optimization Injectors, injection system, injection strategy Cooled EGR Turbocharger+ supercharger to get high boost at high EGR 6. Fuel quality lubricity, detergency Could be done with mostly existing technology Different compromises for different applications Enabling technologies hybridization, in-cylinder pressure based control, low temperature oxidation/dpf

GCI -High efficiency, affordable, clean engines using less processed fuels High Cost Low injection Pressure, CO/HC vs NOx/ Soot after-treatment SI Engine Diesel GCI Low-octane Gasoline Efficiency High Low-octane Gasoline RON between 7 and 85, no strict volatility requirement GCI enables high efficiency, low emissions, low cost engines using less processed fuels. Lower overall GHG impact around 3% better compared to SI and 4-5% better compared to diesel Opens up a path to mitigate expected demand imbalance between light and heavy fuels.

Prospects for GCI Fuel Less processed Engine High Eff, affordable GCI Balance supply and demand In the short term diesel engines will continue to use diesel fuels OEMs have too much invested in existing diesel technology and solved the problems Stakeholders need to be aligned Required development will take place when and where Commitment to existing diesel technology is weak and alignment of different stakeholders is easier (China?) The demand imbalance will start to bite Mazda SkyAktiv is a spark assisted GCI engine

Summary Global transport energy demand increasing by 3%- 4% between now and 24. All in non-oecd countries Even by 24, most (~ 9%) of it will come from petroleum Demand growth heavily skewed towards commercial transport - More diesel and jet fuel needed compared to gasoline. Pressure to increase gasoline anti-knock quality. (Revision of gasoline antiknock specifications needed) Great challenge to the refining industry huge investments (1s of billions of $) AND homeless hydrocarbons - low-octane gasoline (More EVs means greater demand imbalance) Highly efficient engines running on such fuels need to be developed Gasoline Compression Ignition (GCI) engines offer such a prospect GCI have advantages from the engine side (low injection pressures etc) and the fuel side (less processed fuel) All stakeholders need to work together to bring such optimized fuel/engine systems to the market rather than only developing engines for existing market fuels