The Influence of Fuel Cetane Number on Catalyst Light-Off Operation in a Modern Diesel Engine 2nd CRC Advanced Fuel and Engine Efficiency Workshop Nov 3, 2016 Eric Kurtz, Ford Motor Company Diesel Combustion System Technical Expert 1
Emissions Challenge Light-Duty Vehicles (Fleet Average) NOx [g/mi] NMOG [g/mi] NOx + NMOG [g/mi] Tier 2, Bin 5 0.07 0.09 0.160 Tier 3, 2025 0.030 Difference -81% Heavy-Duty Pickups & Vans NOx [g/mi] Class 2b Class 3 NMOG [g/mi] NOx + NMOG [g/mi] NOx [g/mi] NMOG [g/mi] NOx + NMOG [g/mi] Tier 2 0.2 0.143 0.343 0.4 0.167 0.567 Tier 3 0.170 0.230 Difference -50% -60% Future emissions standards require solutions that deliver substantial reductions in NOx + NMOG. 2
Sources of Diesel Emissions SCR Temperature Catalyst Light-off temperature Shut down 10 min soak Bag 1 Bag 2 Bag 3 Cumulative Tailpipe NOx + HC* *HC acts as a surrogate for NMOG The majority of tailpipe emissions are emitted before the aftertreatment reaches operating temperature Most manufacturers operate in a catalyst light-off mode during that time to provide exhaust heat to sufficiently low emissions Increased exhaust temperature and enthalpy for faster light-off and lower emissions are needed during catalyst light-off operation. 3
Engine Operation for Catalyst Light-Off Typical catalyst light-off strategy (retard combustion) Retard SOIs Shift fuel to post injections Temperature increases as combustion is retarded Lower efficiency shifting energy to exhaust Increase fuel quantity Late phasing degrades stability Higher HC emissions Exhaust Temperature [ C] 360 340 320 300 280 Pilot Injections 20 C Maximum Unconstrained Potential HC NOx+HC Constrained < target HC Main Post Injections All injections burning T exh penalty to control emissions 260-5 0 5 10 15 Post Injection Retard [deg] Poor ignition and combustion stability of late fuel injections can lead to excessive HC emissions. 4
Exhaust Temperature vs. Emissions *HC acts as a surrogate for NMOG * Various calibrations (one speed-load point): Injection pressure Injection timings (pilots, main, posts) Injection quantities (pilots, posts) EGR rate Boost pressure +110% Curve of best emissions vs. exhaust enthalpy +36% Exhaust Enthalpy (to hasten catalyst light-off) A tradeoff exists between exhaust temperature/enthalpy and emissions. Need to improve ignition and combustion stability of late fuel injections. 5
Fuel Cetane Number Cetane Number: a measure of the ignition quality of a diesel fuel. Min CN EU: 48CN US: 40CN Avg CN EU: 54CN US: 45CN =9CN =8CN Minimum CN Does the relatively low cetane number with US fuel influence the ability to generate exhaust temperature and enthalpy while controlling emissions? 6
Test Fuels US Certification Fuel High Cetane Fuel Cetane Number 46 =7CN 53 Lower Heating Value [MJ/kg] 42.9 42.9 Density [kg/m 3 ] 842 837 H/C ratio 1.82 1.97 O/C ratio 0 0 Aromatics [wt%] 29.2 8.2 Kinematic Viscosity [cst] 2.9 2.3 T90 [ C] 307 334 Tested two fuels with a cetane number difference similar to the gap between United States & European diesel fuel. 7
Single-Cylinder Study Single-cylinder version of the 6.7L PowerStroke Four test conditions Two speed-load points to represent first 200s of FTP 20 and 90 C coolant and oil 60-point experiment at each test condition to cover calibration space Injection pressure Injection timings Injection quantities EGR rate 8
Vehicle Populations to Consider in Fuels Studies 2007-2010 Legacy Fleet Present Future Fleet Older vehicles Modern vehicles Fixed engine calibration Fixed engine calibration Catalyst light-off calibration Catalyst light-off calibration Bulk of cetane effects studies Study focus cetane effect on catalyst light-off operation 9
Data Analysis Methods A-B comparison at production calibration Pairwise statistical comparison across multiple calibrations, isolating fuel difference Comparison at optimum calibrations for each fuel Use experimental data to optimize calibration for each fuel Compare optimums Legacy Fleet Future Fleet
Paired T-Test Statistical comparison across pairwise data (calibrations) isolating difference between two fuels Example: Exhaust Temperature Fuel #1 Fuel #2 Difference Calibration 1 X 1 Y 1 X 1 Y 1 Calibration 2 X 2 Y 2 X 2 Y 2 Calibration 3 X 3 Y 3 X 3 Y 3 Calibration 4 X 4 Y 4 X 4 Y 4 : : : : Calibration 60 X 60 Y 60 X 60 Y 60 Null hypothesis: fuels have no effect 0 inside CI = fuel has no effect (verify null hypothesis) 0 outside CI = fuel has an effect
Effect on Legacy Fleet in a Catalyst Light-Off Mode Comparison across identical calibrations (analysis of all data) Little/no difference in exhaust T & H, noise, smoke Higher NOx, but lower NOx + HC 60 40 20 0-20 -40-60 3 2 1 0-1 -2-3 Analysis of data from all 4 points together Difference (high CN Low CN) X production calibration paired t-test 95% conf. interval Exh. Temp. [ C] Exh. Enthalpy [%] NOx [%] THC [%] NOx & & THC [%] Smoke [%] Noise [db] Abs. or Rel. Difference [ C or %] Abs. Difference [db] Increased cetane would have minimal impact on legacy fleet A/T function, but may reduce NOx + HC during catalyst light-off operation. 12
Effect on Future Fleet in a Catalyst Light-Off Mode Optimize calibration for the fuel 30% higher exhaust temperature and enthalpy for faster cast light-off Higher NOx, but lower NOx+HC and smoke 60 40 20 0-20 -40-60 3 2 1 0-1 -2-3 Analysis of data from all 4 points together Difference (high CN Low CN) X production calibration paired t-test 95% conf. interval optimized calibration Exh. Temp. [ C] Exh. Enthalpy [%] NOx [%] THC [%] NOx & & THC [%] Smoke [%] Noise [db] Abs. or Rel. Difference [ C or %] Abs. Difference [db] Potential to more quickly light-off catalysts while controlling emissions with higher cetane fuel, thus reducing TP emissions. 13
Heat Release Analysis 1200 rpm, 8% load, 90 C Heat Release Rate Mass Burn Fraction 40 Fed Low Fed Low Cert Cetane Cert Fuel Fuel @ @ Base Base Cal. Cal. High High Cetane @@ Optimized Base Cal. Cal. 100 AHHR [J/deg] Inj. Signal [-] 30 20 10 0-30 -15 0 15 30 45 60 75 90 Engine Postion [CA [datdc] 2 1 0-30 -15 0 15 30 45 60 75 90 Engine Postion [CA ATDC] MFB [%] 80 60 40 20 0-30 -15 0 15 30 45 60 75 90 Engine Postion [CA [datdc] Higher cetane fuel enabled significantly later combustion while controlling emissions. 14
Conclusions This study suggests that: increasing cetane would have minimal impact on catalyst light-off and may slightly reduce tailpipe emissions in legacy vehicles. the relatively low cetane fuel in the US may limit the ability to lightoff catalysts while controlling for future emissions standards. further study is warranted. To fully understand the effect of changing fuels specifications, fuels testing should include: evaluation with production calibrations to define effects on today s vehicles. optimization of the calibration for the new fuel to estimate the impact on tomorrow s vehicles. 15
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