REFRIGERANT EMISSIONS ALONG THE MAC SYSTEM LIFETIME Session 1 D. Clodic, Ecole des Mines de Paris J. Harnisch,, ECOFYS W. Schwarz, Öko - Recherche CENTRE D ENERGETIQUE 1
EU MAC R-134a actual technology Emission optimistic scenario Nominal refrigerant charge 750g Emissions at manufacture Capacity heels Total emissions (g R-134a) 7,5 Filling of the system 2 Emissions during life time Regular emissions 690 Accidents 170 End of life Emissions during servicing Emissions at End Of Life 198 67,5 1 135g 2
Leak rates data collection The main issue: DATA QUALITY Component by component approach : Leak tightness measurement Fleets monitoring : garage survey and weighing residual charge in representative panels of vehicles 3
Emissions along the refrigerant distribution Heels in a refrigerant container 7,5 180 4
Summary of emissions of refrigerant capacity handling and MAC manufacturing process Capacity heels (CH) 7.5 < CH < 45g/lifetime Emissions when filling the MAC system 0 < Emissions < 2g/lifetime 5
Emissions during the AC system manufacturing process Refrigerant charge connection and disconnection of the AC system and the charge machine 0 < emission < 2 g /yr/ 6
Emissions during the AC system manufacturing process Refrigerant charge connection and disconnection of the AC system and the charge machine 0 < emission < 2 g /yr/ 7
Where emissions are coming from? 8
Evaporator connections Evaporator connections (2): 0.5 < LR < 3g/yr TXV connections (2 ): 0.5 < LR < 3g/yr 9
Condenser connections Condenser connections (2): 0.5 < LR < 3g/yr 10
Compressor spare parts 11
Compressor shaft seal Compressor shaft seal (1): 10 < LR < 20 g/yr Face view Shaft seal 12
The service valves The Schrader valves and their caps Schraders with caps 13
The service valves The Schrader valves (and their caps) Schraders without their caps 14
Summary of emissions from service valves For Brand new cars (if well fitted): LR < 1g/yr After 1 st opening, with cap and O-ring: LR < 1g/yr After 1 st opening (without( cap): 3 < LR < 15g/yr After multiple openings (without( cap): 5< LR < 25g/yr 15
Emissions from hoses Rubber and elastomer parts of the hose 16
Two permeation rates of rubber hoses The permeation rate: Pr in g/yr depending on the pressure. 90 80 70 60 50 40 30 20 A 10-10 0 0 5 10 15 20 25 30 B Pressure (bar abs) 17
Summary of controlled emissions Technology m(g/yr) Total Hoses Fittings Crimps g/yr Usual technology 12.8 4.25 1.3 18.35 Best available technology 1.15 0.9 0.3 2.35 18
Summary of total emissions Estimates (g/yr) Hoses and fittings Compressor shaft seal Service valves Total High estimate 18.3 20 2 40.3 Low estimate 2.3 10 0.5 12.8 19
Emissions during the lifetime A European Survey Method of measurement 3 fleets in Sweden, Germany, Portugal The main results : average emissions (g/year), trends for annual leak rates depending on countries. 20 19
The EC/Novem440 study Empirical basis for regular emissions from EU car fleet Carried out by Öko- Recherche and ECOFYS 440 measurements at 10 used car dealerships S - Helsingborg 100 D - Osnabrück 240 P - Rio Maior 100 Time of tests: Oct 2002 Jan 2003 Dedicated protocol and equipment applied by one technician 20
Selection of EC/Novem440* data 140 120 100 80 60 40 20 0 0-6 age mnths 36-42 24-30 12-18 108-114 96-102 84-90 72-78 60-66 48-54 refrigerant loss more than 0% and less than 70% age greater equal 12 months and less than 72 months of 442 vehicles 354 vehicles remain under-weighting of young vehicles Age distribution of original data set EC/Novem440 22 21
Does method achieve full recovery? Nameplate Fill and Recovery from 18 New Cars [two different models, mileage 0 km, each] grams per MAC 550 +-25 516 21 750+-50 730 norm fill 12 MACs recovery 12 MACs [mean] norm fill 6 MACs recovery 6 MACs [mean] Question: : First fill inaccurate or the recovery? 23 21
EC/Novem440*: age distribution 50 40 30 20 10 Std. Dev = 15.78 Mean = 37 0 N = 265.60 0-6 24-30 48-54 72-78 12-18 36-42 60-66 age mnths Cases weighted by AGEWEIG2 24 23
EC/Novem440*: manufactures 50 MAKE 40 30 20 Frequency 10 0 VW Volvo Toyota Suzuki Skoda Seat Saab Renault Peugeot Opel Nissan Mitsubi MB Mazda Honda Ford Fiat Citroen Chrysler BMW Audi Alfa MAKE Cases w eighted by AGEWEIG2 25 24
EU regular leakage rate: 57 g/yr 50 40 30 20 10 0 0-10 160-170 140-150 120-130 100-110 80-90 60-70 40-50 20-30 240-250 220-230 200-210 180-190 lss gpyr Cases weighted by AGEWEIG2 26 25
EU regular leakage rate: 7.7 %/yr 70 60 50 40 30 20 10 0.280 -.300.240 -.260.200 -.220.160 -.180.120 -.140.080 -.100.040 -.060 0.000 -.020 lss pcpyr Cases weighted by AGEWEIG2 27 26
Mean regular loss rate per make 140 120 100 80 95% CI lss gpyr 60 40 20 0 1 3 4 CODE Cases weighted by AGEWEIG2 5 6 7 8 9 12 30 grams per year and 95% confidence intervals 28 27
Results of EC/Novem Study Reliable method established to determine "regular" losses from MACs Broad distribution of leakage rates within EU car population Vehicles measured exhibit a mean "regular" loss for vehicles of 57 grams (7.7%) per year for vehicles between 1 and 6 years old Impact from climate not found to be significant Pronounced differences between makes exist 28
Summary of the Ecofys/Öko Recherche survey Average original refrigerant charge Average regular losses (7.7%) Average irregular losses (1.9%) Total average losses (9.6%) 750g 57,75g/yr 14,25g/yr 72g/yr 30
Emissions during the lifetime Servicing and repair Why servicing? Insufficient refrigerating capacity Method of diagnosis The Gas and Go method Leak control, leak fixing Recovery and recharge (recovery efficiency, connections, refrigerant trapping) 31
Emissions during servicing The 2 connecting valves for R-134a 32
Emissions during servicing Connections installed on the 2 service valves 33
Emissions during servicing Recovery machine 34
Emissions during servicing Service hoses with and without valves 35
Emission estimates during servicing and repair The lower the number of servicing the better Average emission rate (ER) for each servicing in good servicing garage 20 < ER < 50g per serviced car Average emission rate (ER) for each servicing in not so good servicing garage 100 < ER < 200g per serviced car Note: higher thresholds correspond to repair. 36
Emission estimates at End Of Life The EOLV directive: refrigerant recovery is mandatory. Minimum efficiency recovery rate (ERR) 80 < ERR < 95% Bet estimate from NOVEM at scrap: 46% AC systems are empty, and 63% average charge in the still charged AC systems. 37
EU MAC R-134a actual technology Emission optimistic scenario Nominal refrigerant charge 750g Emissions at manufacture Capacity heels Total emissions (g R-134a) 7,5 Filling of the system 2 Emissions during life time Regular emissions 690 Accidents 170 End of life Emissions during servicing Emissions at End Of Life 198 67,5 1 135g 38
EU MAC R-134a emission prevision Optimistic and realistic global scenarios Optimistic scenario (g of R-134a) Realistic scenario (g of R-134a) Capacity heels 8 15 Filling of the system 2 2 Regular emissions 690 (7.7%) 690 (7.7%) Accidents, rupture, corrosion, 170 (1.9%) 340 (3.8%) Emissions during servicing 198 409 Emissions at End Of Life 68 41 TOTAL (g of R-134a) 1 136 1 497 TOTAL (kg eq. CO2) 1 477 1 946 39