April-June JCPS Volume 8 Issue 2

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ISSN: 0974-2115 Effect of variable compression ratio on performance and emission for a diesel engine fuelled with waste plastic pyrolysis oil blended with diethyl ether Devaraj J 1 *, Y. Robinson 2, P.Ganapathi 3 1. HOD, Department of Mechanical Engineering, Sri Ranganathar Institute of Engineering and Technology, Athipalayam, Coimbatore-641110 2. Director, RVS. Technical Campus, Coimbatore-641402 3. RVS Technical Campus, Coimbatore-641402 *Corresponding author: Email id: devajayam@yahoo.com ABSTRACT This work investigates the effect of variable compression ratio on the performance and emission characteristics of a single cylinder, direct injection diesel engine powered by waste plastic pyrolysis oil blended with diethyl ether. Experiments were conducted with different compression ratios of 15, 16, 16.5 and 17 at various load conditions with a constant speed of 1500 rpm. Two blends of WD05 and WD10 on volume basis have been tested and compared with respect to waste plastic pyrolysis oil and diesel fuel. Brake thermal efficiency was slightly higher with respect to diesel fuel. It was observed that the exhaust emissions are significantly decreased with increase in diethyl ether waste plastic pyrolysis oil (DEE WPPO) at full load conditions. By increasing the compression ratio from 15 to 17, produces lower smoke opacity, hydro carbon (HC), Oxides of nitrogen (NO x) and carbon monoxide (CO) respectively. Key words: Waste plastic pyrolysis oil, variable compression ratio, diesel engine, diethyl ether, emission, performance. INTRODUCTION The search of alternative fuels for diesel engines from the non-conventional energy sources are continuously growing owing to rising price of petroleum fuel, the threat to the environment from engine exhaust emissions, the depletion of fossil fuels, the global warming effect and so on Plastics waste management has become a problem world over because of their non-degradable property. A majority of landfills, allotted for plastic waste disposal, are approaching their full capacity. Thus recycling is becoming increasingly necessary. Among the oxygenated alternatives which could work as ignition improvers are dimethyl ether (DME) and diethyl ether (DEE) with advantages of high cetane number and oxygen content. DI ethyl ester is a liquid at ambient conditions, is produced from ethanol by dehydration process which makes it attractive for fuel storage and handling. It can also assist to improve engine performance and reduce the cold starting problem and emissions when using as a pure or an additive in diesel fuel. The performance and emission characteristics of a diesel engine using fuels like DME and DEE offered promising alternatives. Diethyl ether is also a renewable fuel as it is produced from ethanol by dehydration process. It has several favorable properties such as higher cetane number, high oxygen content, low autoignition temperature and high volatility. Therefore it can assist in improving engine performance and reducing the cold starting problem and emission when used as a pure or additive in diesel fuel. The objective of the present investigation is to study the effect of variable compression ratio on the performance and emission of a waste plastic pyrolysis oil fuelled diesel engine, with addition of 05% and 10% diethyl ether (DEE) at various load conditions and the results were compared with diesel EXPERIMENTAL SETUP AND PROCEDURE The engine used in the present study was a Legion brother s engine, single cylinder, air cooled, and vertical direct injection variable compression ratio multi-fuel engine with the specification given in Table 3. The experimental setup is shown in Figure 1. The engine was coupled to an eddy current dynamometer. The exhaust side of the engine consists of exhaust gas temperature indicator, exhaust gas analyzer (AVL Digas 444) and smoke meter (AVL 437). The operating ranges with accuracy for gas analyzer and smoke meter were given in Table 2. The standard compression ratio of the engine was 16.5. The engine was run at four different compression ratios (15, 16, 16.5 and17). All tested fuels were conducted at five different engine loads (2, 4, 6, 8 and 10) at constant engine speed of 1500 rpm. Samples were prepared, namely WD05 and WD10 blends on a volume basis and the experiments were conducted over the same range of loads RESULTS AND DISCUSSION April-June 2015 168 JCPS Volume 8 Issue 2

Brake Thermal Efficiency: Brake thermal efficiency (BTE) is one of the important performance parameters which indicate the percentage of energy present in the fuel that is converted into useful work. Figure 2 explains the variation of brake thermal efficiency with compression ratio at max load for WD05 and WD10 blends. The increasing trend in efficiency with increasing the concentration of diethyl ether may be due to the lower heating value of waste plastic pyrolysis oil compared to that of diesel. At higher concentration of DEE, the increase in BTE may be due to the ability of DEE to reduce the surface tension or interfacial tension between two or more interacting immiscible liquids helped the better atomization of fuel, which improves the combustion. Also the lower fuel consumption may be one of the reasons for increased brake thermal efficiency. A slight decrease is observed in the BTE for WD05 as compared to diesel fuel. The increasing trend in efficiency with increasing the compression ratio was observed. Exhaust gas temperature: The variation of exhaust gas temperature (EGT) with change in compression ratios were shown in Figure 3 Exhaust gas temperature decreases with compression ratio for all blends when compared to the diesel fuel. This is due to fact that DEE has high latent heat of evaporation value and this leads to reduction in exhaust gas temperature. Brake specific fuel consumption: The variation of brake specific fuel consumption (BSFC) with change in compression ratios were shown in Figure 4. From the graph it is seen that as the compression ratio increases the Brake specific fuel consumption decreases. This may be due to the increase in temperature and pressure leads to increase the rate of complete combustion and there by decreases the brake thermal efficiency because of increase in thermal efficiency. CO Emissions: The variation of CO emission with change in compression ratios for diesel and waste plastic pyrolysis oil-diethyl ether blends at maximum loads were shown in Figure 5. It can be seen all blends are found to emit significantly lower CO concentration compared to that of pure diesel over all compression ratios. When the percentage of diethyl ether increases, CO emission decreases. The excess amount of oxygen content of results in complete combustion of the fuel and supplies the necessary oxygen to convert CO to CO 2. Both HC and CO emissions are low at higher percentage of diethyl ether. NO x Emissions: Figure 6 shows the variation of NO x emissions with variation compression ratio for diesel and waste plastic pyrolysis oil-diethyl ether blends at maximum loads. It is seen from the graph that, increase in compression ratio increases the NO x emission whereas the increase in DEE percentage decreases the formation of NO x. This may be due to increase in temperature of the intake air at higher compression ratio and availability of oxygen in DEE leads to decrease in NO x. Smoke Opacity: Figure 7 presents the variation of smoke opacity with compression ratio for diesel and waste plastic pyrolysis oil diethyl ether blends. It is observed that smoke opacity of diesel and various blends of diethyl ether was lower at low loads, but increased at higher engine loads because more fuel is injected at higher load so less oxygen will be available for the reaction. Also it is noticed that smoke opacity for all diethyl ether percentages are lower than that of pure diesel. This is because smoke decreases with high oxygen content in the biodiesel that contributes to complete fuel oxidation. HC Emissions: Figure 8 shows the variation of HC emission with compression ratio for waste plastic pyrolysis oil blended with diethyl ether. Hydrocarbon emission is an important parameter for evaluating emission behavior of the engine. The HC value continuously decreases with the increase in the percentage of diethyl ether for all compression ratios. The obvious reason for that is the complete combustion and higher inside temperature due to the availability of excess content of oxygen as compared to pure diesel fuel. At high compression ratio the temperature of the intake air increases which leads to complete combustion. Table.1.Engine Specifications Make Legion BHP 3-5 Number of cylinder 1 Bore 80 Stroke 110 Compression ratio 5:1 20:1 Method of loading Eddy current dynamometer Method of cooling Water Speed 1450-1600 rpm April-June 2015 169 JCPS Volume 8 Issue 2

Table.2.Properties of fuels Properties Standard test Diesel WPPO DEE methods Calorific Value J/Kg ASTM D 445 46500 45216* 33900 Specific gravity ASTM D 2217 0.840 0.798* 0.713 Flash point C ASTM D93 50 42* 45 Fire point C ASTM D93 56 45* 55 Chemical structure C 12H 26 C nh 2n-1 C 2H 5-O- C 2H 5 Cetane number 40-45 51 126 Table.3.Instrumentation and their accuracies Instruments Range Accuracy Measurement techniques AVL Digas 444 Gas Analyzer AVL 437 Smoke Meter smoke CO 0-10% CO 2 0-20% HC 0-10000 NOx 0-5000 Smoke-BSN 0-10 Absorption k m- 10-99.99 ±0.02% ±0.03% ±20ppm ±10ppm ±0.1 NDIR NDIR Electro Chemical Sensor Electro Chemical Sensor Percentage uncertainties ±0.15% ±1% ±0.01 Tachometer ((Speed) 0-10,000 rpm ±10rpm Magnetic Pick up type ±0.1% Load 0-50 kg ±0.1 kg Stain gauge type Burette ±0.1 cc ±1% Pressure Pickup 0-100bar ±0.1 kg ±1% Crank angle Encoder ±1 Magnetic Pick up type Ignition delay ±0.3% Figure.1.Experimental setup Figure.2.Brake Thermal Efficiency vs. Compression ratio Figure.3.Exhaust gas temperatures vs. Compression ratio April-June 2015 170 JCPS Volume 8 Issue 2

ISSN: 0974-2115 Figure.4.Brake Specific Fuel Consumption vs. Compression ratio Figure.5.CO Emissions vs. Compression ratio Figure.6.NO x Emissions vs. Compression ratio Figure.7.Smoke Opacity vs. Compression ratio Figure.8.HC Emissions vs. Compression ratio CONCLUSION Abbreviations DEE: Diethyl ether WPPO: Waste plastic pyrolysis oil WD05: Waste plastic pyrolysis oil+5%dee WD10: Waste plastic pyrolysis oil+10%dee CO: Carbon Monoxide CO2: Carbon Di-oxide NOX : Oxides of Nitrogen HC: Unburned Hydro Carbon VCR: Variable Compression Ratio Increasing the percentage of diethyl ether and increase in compression ratio is increasing the brake thermal efficiency and BSFC slightly. Both NO x and CO emissions decrease drastically with the increase in the blends of diethyl ether recorded maximum reduction with diethyl ether for all compression ratios. The measured HC for all blends of diethyl ether is higher than that of diesel. It is found to be higher with higher compression ratio and higher diethyl ether blends. Smoke opacity is reduced for all diethyl ether blends. It is observed to be lower with higher compression ratio. The best fuel combination is diethyl ether which has same combustion results with good reduction in the emissions as compared to base line diesel fuel; also less increase in the NOx emissions is noticed in diethyl ether as compared with diesel. As the cost of the DEE is less, so it can be used as a diesel fuel additive in engines. REFERENCES Amjad Sheik, Shenbaga Vinayaga Moorthi N, and Rudramoorthy R, Variable compression ratio engine: a future power plant for automobiles an overview, Proc. IMechE Vol. 221, 2007, 1159-1168 April-June 2015 171 JCPS Volume 8 Issue 2

Antony Raja, Advaith Murali, Conversion of Plastic Wastes into Fuels, Journal of Materials Science and Engineering B 1, 2011, 86-89 Ashok M.P, Saravanan C.G, Effect of Diethyl Ether with Emulsified Fuel in a Direct Injection Diesel Engine, SAE Paper number: 2007-01-2126 Biplab K. Debnath, Niranjan Sahoo, Ujjwal K. Saha, Thermodynamic analysis of variable compression ratio diesel engine running with palm oil methyl ester, Energy Management, 2013, 147-154. Duraisamy M K, Balusamy T, Senthilkumar T, Effect of compression ratio on CI engine fueled with methyl ester of Thevetia Peruviana Seed Oil, APRN Journal of Engineering and Applied Sciences, 2012, 229-234. Hu seyin Serdar Yu cesu, Tolga Topgul, Can Cinar, Melih Okur, Effect of ethanol-gasoline blends on engine performance and exhaust emissions in different compression ratios, Applied Thermal Engineering, 2006, 2272-2278. Jindal S, Nandwana BP, Rathore NS, Vashistha V, Experimental investigation of the effect of compression ratio and injection pressure in a direct injection diesel engine running on Jetropha Methyl Ester, Applied Thermal Engineering, 2010, 442-448. Kapilan N., Mohanan P, Reddy R.P, Performance and Emission Studies of Diesel Engine Using Diethyl Ether as Oxygenated Fuel Additive, SAE Paper number:2008-01- 2466 Mani M, Subash C, Nagarajan G, Performance, emission and combustion characteristics of a DI diesel engine using waste plastic oil, Applied Thermal Engineering 29, 2009, 2738 2744 Masoud Iranmanesh J, Subrahmanyam P, Babu M.K.G, Potential of Diethyl ether as supplementary fuel to improve combustion and emission characteristics of diesel engines, SAE paper number 2008-28- 0044 Murlidharan K, Vasudevan D, Sheeba K.N., Performance, emission and combustion characteristics of biodiesel fueled variable compression ratio engine, Energy, 2011, 5385-5393. Murlidharan K, Vasudevan D, Performance, emission and combustion characteristics of variable compression ratio engine using methyl esters of waste cooking oil and diesel blends, Applied Energy 88, 2011, 3959-3968. Nilesh Mohite, Study of performance characteristics of variable compression ratio diesel engine using ethanol blends with diesel, International Journal of Engineering Science &Technology, Vol 4, no.6, 2012, 2784-2794 Raheman H, Ghadge S.V, Performance of diesel engine with biodiesel at varying compression ratio and injection timing, Fuel 87, 2008, 2659-2666. Subramanian K.A, Ramesh A, Use of Diethyl Ether Along with Water-Diesel Emulsion in a Di Diesel Engine, SAE Paper number: 2002-01-2720 April-June 2015 172 JCPS Volume 8 Issue 2