BASF Polyurethanes - innovative sole materials for true comfort and performance

BASF Polyurethanes - innovative sole materials for true comfort and performance BASF_SportShoesBrochure_24June.indd 2

BASF Polyurethanes Worldwide Network Blackie, Alberta Toronto, Ontario Minneapolis, Minnesota Livonia, Michigan Wyandotte, Michigan Clemson, South Carolina Orange, California Geismar, USA Houston, Texas Lerma, Mexico Lemförde, Germany Moerdijk, The Netherlands Angered, Sweden Boxtel, The Netherlands Schwarzheide, Germany Srem, Poland Schwarzheide, Germany Nzshnekamsk, Russia Antwerp, Belgium á Mitry-Mory, France Matacky, Slovakia Zingonia, Italy Seoul, Korea Pendik, Turkey Beijing, China Ulsan, Korea Qingtao, China Shinshiro-shi, Japan Islamabad, Pakistan Yeosu, Korea Yokkaichi Japan Lahore, Pakistan Shanghai, China Dubai, UAE New Delhi, India Caojing, China Karachi, PakistanDhaka, Bangladesh Nansha, China Hsinchu, Taiwan Mumbai, India Thane, India Bangpoo, Thailand Manila, Philippines Ho Chi Minh City, Vietnam Colombo, Sri Lanka Bukit Jelutong, Kuala Lumpur, Malaysia Malaysia Jurong Island, Singapore Jakarta, Indonesia Mauà, Brazil ã Burzaco, Argentina Elandsfontein, South Africa Altona, Australia Auckland, New Zealand BASF Polyurethane Headquarters Regional Headquarters Regional Technical Development Center Basic Chemical Plant System House TPU Plant TDI/MDI Cellasto Plant Asia Pacific Sales Office BASF is the leading supplier of polyurethane basic products, systems and specialties. The brand Polyurethane Solutions stands for the worldwide leading supplier of polyurethane systems and specialty elastomers. We provide excellent problem solving expertise and product quality from a global network of 39 BASF Systems Houses which offer tailor-made solutions to our customers. PU Customers all over the world experience first hand customized consulting and development services in polyurethane systems and specialties whenever they do business with BASF s polyurethanes specialists. Polyurethane Solutions brings BASF close to the customer, providing local support to help customers become even more successful. For further information, please visit www.polyurethanes.asiapacific.basf.com BASF_SportShoesBrochure_24June.indd 3

contents Introduction 2 BASF Polyurethane Solutions 3 Performance Solutions 8 Bio Solutions 15 New Technology 18 BASF_SportShoesBrochure_24June.indd 4

BASF Sport Shoe System With over 40 years of experience, BASF has an industry reputation for offering the best in comfort footwear applications for the most famous sports branded footwear worldwide. Our innovative technology and PU systems have set the benchmark for good cushioning and flexibility combined with excellent durability. BASF Polyurethanes Solutions have been tailored for comfort as well as to reduce the chance of injuries while wearing and running. Benefits of PU in sport sole applications Excellent cushioning Good stability and durability Good rebound resilience for natural running Environmentally friendly BASF PU Solutions are divided into four categories 1. Basic Systems 2. Performance Solutions 3. Bio Solutions 4. New Technology BASF_SportShoesBrochure_24June.indd 5

BASF Polyurethane Solutions 1 Insole Excellent mechanical properties vs. EVA foam Consistent resiliency and cushioning Long lasting durability that reacts to every step Comprehensive insole solutions breathable insole molded and poured insole bio insole 2 PU Filler Shock absorbing 3 Midsole Excellent mechanical properties Design flexibility and good appearance Good flexibility in cold temperatures Solutions cover lightweight high rebound good hydrolysis resistance bio applications 4 Outsole PU Good mechanical properties Good flexibiliy in cold temperatures Easy processing TPU Good transparency Low abrasion loss Low temperature flexibility Hydrolysis resistant Good wet slip resistance BASF_SportShoesBrochure_24June.indd 6

BASIC SYSTEMS BASF_SportShoesBrochure_24June.indd 7

BASIC SYSTEMS Breathable for comfort Excellent mechanical properties vs. EVA foam Good flexing under temperature changes Easy processing Design flexibility Environmentally friendly Insole CS9500 A polyether based system that is designed for insole application. 0.33 ± 0.02 DIN EN ISO 845 35 ± 3 DIN 53505 2 > 5 > 180 > 2.5 DIN ISO 34-1 (50C, 6 hours, 50) < 15 ASTM D395 CS9600 A polyether based system that is designed for casting moulded insole application. 0.35 ± 0.02 DIN EN ISO 845 33 ± 3 ASTM D2240 2 9.0 > 250 > 3.5 DIN ISO 34-1 (50C, 6 hours, 50) < 20 ASTM D395 5 BASF_SportShoesBrochure_24June.indd 8

BASIC SYSTEMS Midsole CS7359 / 101 / OA A polyester system delivers comfort and performance for sport midsole. Property Unit Value Test Standard 0.40 ± 0.02 DIN EN ISO 845 60 ± 3 DIN 53505 2 > 40 > 300 > 15 DIN ISO 34-1 Split tear > 3.0 SATRA TM 165 (10mm thickness) (50C, 6 hours, 50) < 30 ASTM D395 Outsole - TPU Elastollan B95A Polyester grade which has good cold flexibility for soccer, American football and baseball sole applications. 1.21 DIN EN ISO 1183-1-A Shore A 95 ± 3 DIN 53505 MPa 55 -S2 550 -S2 N/mm 100 DIN ISO 34-1Bb Abrasion loss mm 3 45 DIN ISO 4649-A Grades available: B80A, B85A, B90A, B98A, B60D, B64D Abrasion resistance enhanced products: B85A 11S, B90A 11S (<20mm 3 ) 6 BASF_SportShoesBrochure_24June.indd 9

BASIC SYSTEMS Transparent Outsole Elastollan 685 AU Transparent polyester grade UV stabilized. Elastollan 1285 AU Transparent polyether grade UV stabilized for soccer and golf shoe. Properties Unit Value Value Test Standard Grade Elastollan 685AU Elastollan 1285AU 1.21 1.21 DIN EN ISO 1183-1-A Shore A 85 ± 3 85 ± 3 DIN 53505 MPa 50 45 -S2 at break 600 600 -S2 N/mm 75 70 DIN ISO 34-1Bb Abrasion loss mm 3 45 40 DIN ISO 4649-A Grades available: 670APU, 685AU, 690AU, 695AU, 660DU, 664DU, 670DU Grades available: 1285AU, 1295AU, 1298AU, 1254DU, 1260DU, 1264DU, 1278DU, 1283DU 7 BASF_SportShoesBrochure_24June.indd 10

PERFORMANCE solutions BASF_SportShoesBrochure_24June.indd 11

PERFORMANCE SOLUTIONS Performance PU systems feature: Good flowability for filler or airbag encapsulation Good mechanical properties Lightweight High rebound resilience Excellent hydrolytic stability Constant stiffness under temperature changes Performance TPU applications include: Excellent mechanical properties Good slip and abrasion resistance Good transparency Super-soft series Insole CS 7579 / 100 A polyether system for super lightweight breathable insole application. 0.08 ± 0.005 DIN 53479 25 ± 4 ASTM D2240 2 > 4.0 70 > 1.5 DIN ISO 34-1 (50C, 6 hours, 50) < 25 ASTM 395: 2003 9 BASF_SportShoesBrochure_24June.indd 12

PERFORMANCE SOLUTIONS CS 7579-103 A polyether system for superlow density insole application by casting molded processing. 0.19 ± 0.01 DIN 53479 20 ± 3 ASTM D2240 2 > 3.0 > 140 (50C, 6 hours, 50) > 1.2 DIN ISO 34-1 < 30 ASTM 395: 2003 CS7879 / 100 C-A A polyether system with more than 55 rebound resilience, super low density and 28-day hydrolysis resistance for high-end sports insole application. 55 0.28 ± 0.03 DIN 53479 35 ± 3 ASTM D2240 2 > 15 > 350 > 7 DIN ISO 34-1 (method B) (50C, 6 hours, 50) Hydrolysis resistance (70C, 95 RH, 28 days machanical retainment)) < 15 ASTM 395: 2003 > 80 ISO 5423 10 BASF_SportShoesBrochure_24June.indd 13

PERFORMANCE SOLUTIONS Midsole CS7359 / 100 / OA A polyester midsole system that delivers excellent shock absorption and mechanical properties for filler or airbag encapsulation. 0.36 ± 0.02 58 ± 3 DIN EN ISO 845 ASTM D2240 Shock 2 > 30 > 300 > 14 DIN ISO 34-1 Split tear > 3.5 ASTM 3574 (10mm thickness) (50C, 6 hours, 50) < 30 ASTM 395: 2003 Rebound resilience Vertical rebound > 25 DIN 53512 CS7359 / 110 A polyester based lightweight midsole system with good shock absorption. 0.30 ± 0.02 55 ± 3 DIN EN ISO 845 ASTM D2240 Shock 2 > 25 > 250 > 10 DIN ISO 34-1 Split tear > 2.0 ASTM 3574 (10mm thickness ) (50C, 6 hours, 50) < 30 ASTM 395: 2003 11 BASF_SportShoesBrochure_24June.indd 14

PERFORMANCE SOLUTIONS CS7379 / 102 / OA + 187 / 47 A polyester based filler system that offers maximum comfort and cushioning support for every step. 0.28 ± 0.02 DIN EN ISO 845 32 ± 3 ASTM D2240 2 > 21 > 540 Split tear > 1.5 ASTM 3574 (10mm thickness) (50C, 6 hours, 50) < 20 ASTM 395: 2003 Rebound resilience Vertical rebound Hydrolysis resistance (70 degree, 95 RH, 21 days mechanical retainment) > 40 DIN 53512 > 60 ISO 5423 12 BASF_SportShoesBrochure_24June.indd 15

PERFORMANCE SOLUTIONS CS7559 / 100-C-A A polyether-based system that offers excellent flexibility and constant stiffness with different temperatures. 0.36 ± 0.02 DIN EN ISO 845 55 ± 3 ASTM D2240 2 > 21 > 280 > 10 DIN ISO 34-1 Split tear > 1.8 ASTM 395: 2003 (50C, 6 hours, 50) < 30 ASTM 3574 (10mm thickness ) Hydrolysis resistance (70 degree, 95 RH, 21 days mechanical retainment) > 80 ISO 5423 CS7859 / 100 / OA A polyether based midsole system that is good for high performance sports, which boost rebound energy to over 55 with 28-day superior hydrolytic stability. 55 0.36 ± 0.02 DIN EN ISO 845 28 Days 55 ± 3 ASTM D2240 2 > 30 > 350 Trouser tear strength > 3.5 DIN ISO 34-1 Split tear > 2.5 ASTM 3574 (10mm thickness) (50C, 6 hours, 50) < 20 ASTM 395: 2003 Rebound resilience Vertical rebound Hydrolysis resistance (70 degree, 95 RH, 21 days mechanical retainment) > 55 DIN 53512 > 80 ISO 5423 13 BASF_SportShoesBrochure_24June.indd 16

PERFORMANCE SOLUTIONS Outsole - TPU Elastollan SP9324 Soft polyester grade - plasticizer free with good chemicals and slip resistance. 1.21 DIN EN ISO 1183-1-A Shore A 60 ± 3 DIN 53505 MPa 35 -S2 850 -S2 Tear strength N/mm 40 DIN ISO 34-1Bb Abrasion loss mm 3 50 DIN ISO 4649-A Grades Available: SP9324, SP9339 Elastollan Soft 50AP Super soft and transparent polyester grade - phthalate-free, excellent abrasion, wet and dry slip resistance. 1.18 DIN EN ISO 1183-1-A Shore A 50 ± 3 DIN 53505 MPa 34 -S2 950 -S2 N/mm 42 DIN ISO 34-1Bb Abrasion loss mm 3 50 DIN ISO 4649-A Grades Available: Soft 40AP, Soft 50AP 14 BASF_SportShoesBrochure_24June.indd 17

Bio solutions Eco-friendly production and high productivity through automation 11 BASF_SportShoesBrochure_24June.indd 18

BIO SOLUTIONS Non-food chain based, bio-renewable materials Flexibility to adjust bio content from 10 to 45 Excellent mechanical properties Good hydrolysis resistance Insole CS7579 / 112 C-A A polyether bio-based* system which contains bio-renewable source, Castor oil to replace oil-based raw materials. Bio content can be adjusted from 10 to 45 with good mechanical properties. 0.32 ± 0.02 DIN 53479 33 ± 3 ASTM D2240 2 > 8.0 > 150 > 3.0 DIN ISO 34-1 (method B) (50C, 6 hours, 50) Bio carbon content < 30 ASTM 395: 2003 > 12 ASTM D 6866 BASF_SportShoesBrochure_24June.indd 19

BIO SOLUTIONS Midsole H9107+7359 / 102 C-B A polyester based midsole system that offers environmentally friendly solution Not only retains good mechanical properties, but also has flexibility to adjust bio content from 10-45 based on individual brand s needs. 0.38 ± 0.02 DIN EN ISO 845 55 ± 3 ASTM D2240 2 > 35 > 12 DIN ISO 34-1 > 330 Split tear > 2.8 ASTM 3574 (10mm thickness) (50C, 6 hours, 50) < 30 ASTM 395: 2003 Outsole - TPU Elastollan N A bio-based* polyester grade solution based on bio-renewable raw materials. Offers comparable mechanical properties and good hydrolytic stability as Elastollan range. Properties Grades Bio-Content ASTM D6866 (w/wc) ( ) (Shore A) Tensile Strength (MPa) () Tear Strength (kn/m) Abrasion Loss (mm 3 ) Elastollan N65AP 47 1.15 63 29 660 34 55 Elastollan N75AP 46 1.17 76 30 490 41 50 Elastollan N85A 45 1.19 85 40 420 70 45 Elastollan N95A 40 1.21 93 46 430 130 45 * The bio-based part is derived from non-food biomass. 17 BASF_SportShoesBrochure_24June.indd 20

New technology 13 BASF_SportShoesBrochure_24June.indd 21 25/06/2013 3:18 PM

NEW TECHNOLOGY Lightweight midsole, unisole and outsole applications Applications can be produced through pouring and injection processing Environmentally friendly Midsole Elastopan S 7459 / 111 + ISO 187 / 68 A polyester-based, lightweight midsole application that offers good mechanical properties through automated injection processing. 0.32 ± 0.02 / 0.37 ± 0.02 DIN EN ISO 845 Shore A 30 / 40 DIN 53505 (Die C) N/mm 2 > 3.2 / > 3.5 > 280 / > 300 Tear strength (trouser) N/mm 2.2 / 2.1 DIN 53507 (50C, 6 hours, 50) < 30 ASTM 395: 2003 Unisole Elastopan S 7459 / 109 / OA + KX611 + ISO 187 / 68 0.50 ± 0.02 DIN EN ISO 845 Shore A 30 ASTM D2240 (Die C) N/mm 2 > 5 > 600 Tear strength (Trouser) N/mm > 5.5 DIN 53507 (50C, 6 hours, 50) < 30 ASTM 395: 2003 Relative volume loss (Abrasion) mm 3 80 DIN ISO 4649:2006 (method A) 19 BASF_SportShoesBrochure_24June.indd 22 25/06/2013 3:18 PM

NEW TECHNOLOGY Outsole Elastollan LIGHT An expandable TPU system that has excellent mechanical performance and is optimized for injection moulding process. achievable as low as 0.5 Comparison of Mechanical Properties for various Elastomers Characteristic Elastollan Light Soft PVC Rubber ++ o o + - + Tear strength ++ o + Abrasion resistance ++ -- Cold flex + - Dry slip ++ + o o ++ Wet slip ++ + + -- Very Poor - o Neutral + ++ Very Good Materials Currently Available : Elastollan types : Ester-TPU : Soft40AP-TSG Ester-TPU : Soft60AP-TSG phthalate-free Ether-TPU : 1170A-TSG Ether-TPU : 1180A-TSG Physical blowing agents : Masterbatch Konz V 2882 (up to 175C) Masterbatch Konz V 2894 (up to 185C) Chemical blowing agents : Masterbatch Konz V 2893 Masterbatch Konz V 2897 Abrasion resistance improving agent : Masterbatch Konz V 2887 Colour master batch : Masterbatch Konz V 2883 (black) 20 BASF_SportShoesBrochure_24June.indd 23 25/06/2013 3:18 PM

NEW TECHNOLOGY For more than 40 years as the leading PU footwear solution provider, BASF, is your preferred partner of choice for innovations and quality technical support to solve customers design and performances challenges. 21 BASF_SportShoesBrochure_24June.indd 24 25/06/2013 3:18 PM

BASF Polyurethanes Asia Pacific Regional Headquarters BASF East Asia Regional Headquarters Ltd 45/F, Jardine House, No.1 Connaught Place, Central, Hong Kong Tel : +852 2731 0111 Fax : +852 2734 9636 Greater China Region BASF Polyurethanes (China) Co Ltd No.408, Huanshi Road South, Guangzhou Nansha Economic & Technical Development Zone Guangdong, 511458, P.R. China Tel : +86-20 8498 2560 Fax : +86-20 8498 2561 BASF Polyurethane Specialties (China) Co Ltd 2333 Gang Cheng Road, Pudong, Shanghai, 200137, P.R. China Tel : +86-21 3865 5517 Fax : +86-21 3865 5516 Asia Pacific Region BASF Vietnam Co. Ltd HCMC office: Saigon Trade Center, #1701, 37 Ton Duc Thang Street, Dist. 1, Ho Chi Minh City, Vietnam Tel : +84-8 824 3833 Fax : +84-8 824 3832 PT BASF Indonesia Plaza GRI, 10th & 11th Floor, JI. HR Rasuna Said Bl. X2/1, Jakarta, 12950, Indonesia Tel : +62-21 526 2481 Fax : +62-21 526 2533 BASF Chemicals & Polymers Pakistan (Pvt) Ltd 46-A, Block-6, P.E.C.H.S., Karachi, 75400, Pakistan Tel : +92-21 111 550 550 Fax : +92-21 3454 63 11 BASF India Ltd Plot No 12 Thane Belapur Road, Turbhe, Navi Mumbai, 400705, India Tel : +91-22 6712 7665 Fax : +91-22 6712 7628 = registered trademark of BASF The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors from the responsibility of carrying out their own tests and experiments; neither do they imply and legally binding (assurance) of certain properties of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed. 13WB-EG_1K/06/13 BASF_SportShoesBrochure_24June.indd 1