ABSTRACT I. INTRODUCTION. Dr.V. Naga Prasad Naidu Principal Intellectual Institute of Technology, Ananthapuramu, Andhra Pradesh, India

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2016 IJSRSET Volume 2 Issue 2 Print ISSN: 2395-1990 Online ISSN : 2394-4099 Themed Section : Engineering and Technology A Comparative Study of Performance and Emission Characteristics of Four Stroke Diesel Engine with Mahua and Cotton Seed Biodiesel blended with diesel Dr.V. Naga Prasad Naidu Principal Intellectual Institute of Technology, Ananthapuramu, Andhra Pradesh, India ABSTRACT The demand and price of petroleum based fuels are increasing at an alarming rate. If this situation continues there is every chance for the scarcity of petroleum products. A major solution to reduce this problem is to search for an alternative fuels. One of the best alternatives is Biodiesels obtained from different vegetable oils. The present study focuses on comparison of performance and emission characteristics of a single cylinder four stoke diesel engine with two different biodiesels namely Mahua and Cotton biodiesels blended with diesel separately. The performance of the engine with biodiesel blend as fuel is compared with the diesel fuel on the basis of brake specific fuel consumption, brake thermal efficiency, exhaust gas temperature and emissions of hydrocarbons and oxides of nitrogen. This study reveals that the performance of the engine with these biodiesel blends differ marginally from diesel and hydrocarbon emissions are less than diesel. It is also observed that the cotton biodiesel blends are showing better performance and emission characteristics as compared with Mahua Keywords: Cotton biodiesel,, Mahua biodiesel. Performance and Emissions I. INTRODUCTION The depletion of world petroleum reserves and the global environmental pollution problems stimulated the search for the alternative source for petroleum based fuels. A major solution to reduce this problem is to search for an alternative fuels. Bio diesel [1] produced from vegetable oils can be used as an important alternative to the diesel oil, since they are renewable and can be produced in rural areas. The inventor of diesel engine Rudolf Diesel predicted that the plant based oils are widely used to operate diesel engine. The vegetable oil [2] has great potentials as alternative diesel fuel. Several researchers found [3] that the use of pure vegetable oils as fuel in diesel engine can cause numerous engine related problem such as injector choking, piston deposit formation and piston ring sticking due to higher viscosity and low volatility of vegetable oils. An effective method of using vegetable oils [4] in diesel engine is by modifying the vegetable oils into its monoesters (Biodiesel) by transestrification. Transesterification [5] of vegetable oil provides a significant reduction in viscosity, thereby enhancing their physical and chemical properties and improve the engine performance. Though the biodiesel has several advantages [6] over pure vegetable oil, it has disadvantages like low calorific value, higher viscosity and poor cold flow properties as compared with diesel. This drawback may be managed with the employment of blended fuel of biodiesel and diesel fuel. II. LITERATURE REVIEW Researchers from various parts of the world have carried out various experiments on a diesel engine IJSRSET184493 Received : 10 March 206 Accepted : 25 March 2016 March-April-2016 [(4) 4 : 1378-1383 ] 1378

Dr. V. Naga Prasad Naidu et al. Int J S Res Sci. Engg. Tech. 2016 Mar-Apr;2(2) : 1378-1383 with various biodiesels and its blends with diesel to evaluate the performance and emission characteristics. Dilip kumar et al (7)] has conducted experiments on a CI engine with the biodiesel blends of cotton and neem biodiesels separately and suggested that the blend is the optimum blend which can produce better performance for diesel engines. Agarwal. A.K et al (8) has investigated the effect of the Karanja biodiesel blends on the DI diesel engine and concluded that the Karnja biodiesel can be used as a partial substitute of diesel up to 20% () without any major modifications in the existing engine. Anbumani et al (9) and LoveKush Prasad et al (10) evaluated the performance of a single cylinder diesel engine with neem biodiesel blends and established that the neem biodiesel blend can be used as fuel to run CI engine. III. MATERIALS & METHODS In the present work engine tests were conducted with Mahua and Cotton Biodiesel blends separately to evaluate performance and emission characteristics. The performance of the engine with biodiesel blend as fuel is compared with diesel fuel. Cotton [11] has long been known as nature's unique food and fiber plant. It produces both food for man and feed for animals in addition to a highly versatile fiber for clothing, home furnishings and industrial uses. Cotton oil [12] has a ratio of 2: 1 of poly un saturated to saturated fatty acids and generally consists of 65-70% unsaturated fatty acids including 18-24% monounsaturated (ole ic) and 42-52% polyunsaturated (linoleic) and 26-35% saturated (palmitic and stearic). Mahua [13] is additionally known as Kochia Latifolia, Madhuca indica. It s also referred as Indian Butter Tree. Mahua may be a medium to giant tree, which can attain a height of up to twenty meters. Its provender (oil cake) is employed as bio-fertilizer and organic manure. Biological science name is Madura long folia. The foremost element fatty acids of mahua oil are Palmitic (16-28%), lipoid (20-25%), Arachidic (0-3.3%), Oleic (41-51%) and Linoleic (9-13%). Mahua may be nontraditional and non-edible oil. Mahua is a very important plant having vital socio-economic worth. This species will be planted on edges of roads and canal banks etc., on large scale and in social biological science programme, notably in social group (tribal) areas. The various properties [14] of the above bio diesels are presented in table 1. TABLE 1. PROPERTIES OF FUS USED Properties Cotton Mahua biodiesel biodiesel Diesel Density (kg/m3) 874 880 830 Calorific Value 40600 39500 43000 (kj/kg) Viscosity @400C(cSt) 4.34 5.8 2.75 Cetan Number 55 50 51 Flash Point (oc) 70-110 145 74 Technical specifications of the engine In this work experiments were conducted on 4 stroke, single cylinder, C.I engine (Kirloskar Oil Engineers Ltd., India) of maximum power-3.68 KW with AVL smoke meter and Delta 1600 S gas analyser. IV. RESULTS AND DISCUSSIONS A. Brake thermal Efficiency The Figure 1 shows the variation of brake thermal efficiency of the engine with break power output. It is observed that the brake thermal efficiency of the 1379

Brake thermal Efficiency (%) Brake Specific Fuel Consumption (kg/kw-hr) Dr. V. Naga Prasad Naidu et al. Int J S Res Sci. Engg. Tech. 2016 Mar-Apr;2(2) : 1378-1383 engine represents very similar trends for all the fuel samples. In general the thermal efficiency depends on the combustion process which is a complex phenomenon that is influenced by several factors such as design of combustion chamber, type of injection nozzle, injection pressure, spray characteristics and fuel characteristics such as cetane number, volatility, viscosity, homogeneous mixture formation, latent heat of vaporization, calorific value etc. DIE SE L cott on see d It is evident that diesel fuel has the higher brake thermal efficiency compared to It is also found that the cotton biodiesel blends has the highest thermal efficiency because of its calorific value and viscosity as compared with Mahua biodiesel blends. With the higher calorific value the amount of heat produced in the combustion chamber is more, further the combustion is complete and produced higher temperatures. The efficiency of the engine with diesel is 29.18%, Mahua biodiesel blend is 27.58% and for the cotton biodiesel blend it is 28.45% at 3/4 th of rated load. It is observed that the brake thermal potency of the engine with Mahua biodiesel blends is lower than the cotton Figure 1. The variation of Brake thermal efficiency B. Brake specific Fuel Consumption The variation of brake specific fuel consumption (BSFC) with break power is shown in Figure 2. Cotto n Mahu a Figure 2. The variation of BSFC with brake power The BSFC reduced with the load for all the fuels. The BSFC for all the biodiesel blends are higher than diesel fuel. The BSFC of cotton biodiesel blends are lower than the Mahua The specific fuel consumption is increased by 16% and 9.31% respectively with Mahua and cotton biodiesel blends compared with the diesel fuel. The BSFC is increased with increasing quantity of biodiesel in the blend because of the injection of less quantity of fuel due to the higher viscosity and lower heating value. The oxygenated biodiesels may lead to the leaner combustion resulting in higher BSFC.. It is also observed that the BSFC of the engine with Mahua biodiesel blends is higher than the cotton C. Exhaust Gas Temperature The Figure 3 shows the variation of exhaust gas temperature of the engine with break power output. The exhaust gas temperature in the combustion chamber depends on the calorific value, latent heat and viscosity of the fuel injected. The exhaust gas temperature was found to extend with increase in both the concentration of biodiesel within the blend and engine load. The rise in EGT with engine load is due to the actual fact that a more quantity of fuel is needed within the engine to get additional power required to take up conditional loading. For the diesel the exhaust gas temperature is low as compared with the The exhaust gas temperature for 1380

Hydro Carbon Emissions(ppm) Smoke density (bosch) Exhaust Gas Temperture ( 0 C) Dr. V. Naga Prasad Naidu et al. Int J S Res Sci. Engg. Tech. 2016 Mar-Apr;2(2) : 1378-1383 the diesel is 320 0 C, where as for Cotton biodiesel blend and 332 0 C, for Mahua biodiesel blend it is 336 0 C respectively at 3/4 th of rated load. The exhaust gas temperature of Mahua biodiesel blends is slightly higher than the cotton Figure 3. The variation of EGT with brake power D. Smoke Density The variation of the smoke densities with power output is shown in Figure 4. Cotton Mahua locally rich region and limit primary smoke formation and lower smoke emissions. Higher smoke emissions at higher loads may be due to poor atomization of biodiesel. When compared to diesel the increase in smoke emissions of biodiesel blends is higher due its high viscous nature. Due to higher viscosity of biodiesel the bigger size fuel molecules occurs and results in poor atomization of fuel. E. Hydrocarbon emissions (HC Emissions) The variation of hydrocarbon emissions with break power is shown in Figure 5. The HC emissions depend upon mixture strength i.e. oxygen quantity and fuel viscosity in turn atomization. The HC emissions increase with increasing load as well as increasing the amount of biodiesel in the blend. There will be similar trends for all the fuels. Lower heating value of biodiesel leads to the injection of higher quantities of fuel for the same load condition. More the amount biodiesel leads to more oxygen availability, either inherent in fuel or present in the charge. When compared to diesel, the oxygen availability in the biodiesels is more. So the HC emissions of the engine with biodiesel blends are less than diesel. The HC emissions of Mahua biodiesel blends are slightly higher than the cotton Figure 4. The variation of Smoke density with power output cotto n cotton Mahu a The smoke opacity emissions increased with the increase of engine load. This is compensated up to certain extent due to the absence of aromatics and presence of inherent oxygen molecules in the biodiesel. These oxygen particles helps to promote stable and complete combustion by delivering oxygen to the combustion zone of burning fuel by reducing Figure 5. The variation of HC emissions with brake power F. Carbon Monoxide Emissions (co emissions) The variation of carbon monoxide emissions for is illustrated in Figure 6. It has been observed that the 1381

CO Emissions (%volume) NOx Emissions (ppm) Dr. V. Naga Prasad Naidu et al. Int J S Res Sci. Engg. Tech. 2016 Mar-Apr;2(2) : 1378-1383 CO emissions are inflated with increase in engine load for all fuel samples. The CO emission of the engine with diesel oil is higher than the Cotton and Mahua The lower CO emission of biodiesel compared to diesel oil is due to the presence of oxygen in biodiesel that helps in complete oxidization of fuel. The surplus oxygen offered within the biodiesel converts the some of the CO into carbon dioxide and thus the CO emission is reduced. The CO emission for diesel oil is 0.67% volume, for Cotton biodiesel blend is 0.615% volume and for Mahua biodiesel blend is 0.623% volume at ¾th of rated load. The CO emissions of Mahua biodiesel blends are slightly higher than the cotton biodiesel blends compared with pure diesel. The NOx emissions of Mahua biodiesel blends are slightly higher than the cotton cotton Mahu a Figure 7. The variation of Nitrogen oxide emissions V. CONCLUSIONS Figure 6. The variation of CO emissions with brake power G.. Nitrogen oxide Emissions cotton Mahua The variation of Nitrogen oxide emissions of the engine with diesel and biodiesels are illustrated in Figure 7. The NOx emission will increase with increase in load on the engine for each diesel and These higher NOx emissions could be due to the higher exhaust gas temperature at higher loads. The NOx emissions are slightly higher for Cotton biodiesel blends as compared with pure diesel. The rise of NOx emissions could also be related to the oxygen content of the biodiesel, since the biodiesel fuel provided extra oxygen for NOx formation. This one amongst the most reasons for the formation of higher NOx with the biodiesel blends as The following conclusions are drawn based on the experimental results of the above work: The brake thermal efficiency of the engine depends majorly on the heating value and viscosity. The brake thermal efficiency of biodiesel blends is lower than the diesel. The cotton biodiesel blends is having brake thermal efficiency higher than the Mahua The BSFC of the engine with diesel fuel is lower than the biodiesel blends and the BSFC of cotton biodiesel blends is lower than the Mahua The exhaust gas temperature of the engine with diesel fuel is higher than the The CO and HC emissions of the engine with biodiesel blends is lower than the diesel fuel and the CO and HC emissions of cotton biodiesel blends is lower than the Mahua The Smoke and NOx emissions of the engine with diesel fuel is lower than the biodiesel blends. 1382

Dr. V. Naga Prasad Naidu et al. Int J S Res Sci. Engg. Tech. 2016 Mar-Apr;2(2) : 1378-1383 It is concluded that out of the two biodiesels cotton biodiesel is best as compared with Mahua biodiesel in terms of performance and emissions. So the cotton oil can be used as alternative to diesel. VI. ACKNOWLEDGMENT Authors thank authorities of Intellectual Institute of Technology and Intell Engineering College Anantapuramu, AP, India for providing facilities for carrying out research work VII. REFERENCES [1]. Cummins, C., Lyle, Jr. (1993). Diesel's Engine, Volume 1: From Conception to 1918.Wilsonville, OR, USA: Carnot Press, ISBN 978-0-917308-03-1. [2]. Agarwal A.K and Das L.M, Bio diesel development and characterization for use as a fuel in CI engine, Transaction of ASME 2001-123, 440-447 [3]. Senthil Kumar, M.; Ramesh, A.; Nalagingam, B., Proceedings of the International Conference on WASTE to ENERGY, Jaipur, India, 2002, 85-92. [4]. Bari, S., Lim, T.H., Yu, C.W. (2002). Effect of preheating of crude palm oil on injection system [5]. Scholl Wk, Sorenson CS Combustion of soyabean oil methyl ester in DI diesel engine. SAE 1983 930-934. [6]. Sahoo PK, Das LM, Babu MKG and Naik SN, Biodiesel development from high acid value polanga oil and performance evaluation in CI engine. 2007;86(3): 448-454. [7]. Dilip kumar, and Ravindra kumar, Experimental investigation of cotton oil and neem methyl esters as biodiesel on CI engine, International journal of modern engineering research (IJMER), Vol. 2, Issue. 4,July- Aug-2012. PP. 1741-1746. [8]. Avinash Kumar agarwal and Atul Dhar, Experimental investigations on the effect of Karanja biodiesel on engine performance, combustion and durability, in collabration with Shell technology India PVT, Directions -2013, PP. 93-100. [9]. Anbumani and Ajith pal sing, Performance of Mustard and Neem oil blends with diesel in CI engine, ARPN Journal of engineering and applied science, Vol. 5, Issue. 4, April-2010, PP. 14-20. [10]. Love Kush prasad and Alka Agrawal, Experimental investigations of diesel engine working on diesel and neem oil blends, IOSR Journal of mechanical and civil engineering (IOSRJMCE), Vol. 1, Issue. 4, July-AUG- 2012, pp. 48-51. [11]. Adelola and Andrew, International Journal of Basic & Applied Science Vol 1, 02 Oct 2012. [12]. Dinesh and Singh, Cotton Seed oil quality utilization and processing-cicr Technical bulletin No. 25. [13]. Bhat, Y C.; Murthy, N.S.; and Datta, R.K., 2004, Journal of Institute of Engineers (India)-AG, 85, 10-14. [14]. Report of the committee on Development of Bio fuels-planning Commission, Government of India. 1383